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RESEARCH PAPER · ChemSusChem · 2020

Catalytic Hydrogenation/Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran

Päivi Mäki‐Arvela, Dóris Ruiz, Dmitry Yu. Murzin

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Catalytic Hydrogenation/Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐DimethylfuranOriginalEnergy Densification of Biomass-Derived Furfurals to Furanic Biofuels by Catalytic Hydrogenation and Hydrodeoxygenation Reactions17Catalytic Upgrading of Bio‐Based 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran with Non‐Noble Metals17Insight into Biomass Upgrade: A Review on Hydrogenation of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)37Boehmite-derived Aluminum Oxide Catalyst for a Continuous Intramolecular Aldol Condensation of 2,5-Hexanedione to 3-Methyl-2-cyclopentenone in a Liquid-flow Reactor System7A high-efficiency zirconium-based single-atom catalyst for the transformation of biomass-derived 5 hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan with nearly 100% selectivity49Magnetic solid sulfonic acid-enabled direct catalytic production of biomass-derived N -substituted pyrroles18Strategic Design of a WO3/PdOx-Carbon Shell Composite Photocatalyst: Visible Light-Mediated Selective Hydrogenation of 5-Hydroxymethylfurfural17Sustainable Catalytic Transformation of Biomass‐Derived 5‐Hydroxymethylfurfural to 2,5‐Bis(hydroxymethyl)tetrahydrofuran34Integrated Cascade Process for the Catalytic Conversion of 5‐Hydroxymethylfurfural to Furanic and TetrahydrofuranicDiethers as Potential Biofuels36A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran247Recent advances in heterogeneous catalytic hydrodeoxygenation of biomass-derived oxygenated furanics mediated by formic acid13Efficient synthesis of the liquid fuel 2,5-dimethylfuran from biomass derived 5-(chloromethyl)furfural at room temperature38Tailoring the catalytic performance of Cu/SiO2 for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable fuels9A Hybrid Process for Valorization of d -Fructose to 2,5-Bis(hydroxymethyl)furan by Bridging Chemocatalysis and Biocatalysis in a Betaine:Benzenesulfonic Acid System30Desarrollo de catalizadores nanoestructurados para la obtención de bioproductos químicos de fuentes renovables0Highly dispersed Co anchored on Ce-doped hydroxyapatite as a dual-functional catalyst for selective hydrogenolysis of 5-hydroxymethylfurfural10Recent advances in the catalytic production of bio-based diol 2,5-bis(hydroxymethyl)furan40Regulating the interfacial electronic coupling of PtNi/TiO2 via bond evolution for highly efficient hydrogenation of 5-hydroxymethylfurfural40Biobased Paraxylene5The crucial role of catalyst wettability for hydrogenation of biomass and carbon dioxide over heterogeneous catalysts28Selective hydrogenolysis of 5-hydroxymethylfurfural to 5-methylfurfural over Au/TiO265Efficient and Selective Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran by a Bimetallic Copper‐Palladium Catalyst on a Carbon‐Doped Boron Nitride Support4Rational design core-shell Co@CuCo/Al2O3 catalysts for Low-Temperature Hydrodeoxygenation of 5-Hydroxymethylfurfural0TiO2 supported non-noble Ni-Fe catalysts for the high yield production of 2,5-dimethylfuran biofuel17A remarkable bifunctional carbon-based solid acid catalyst derived from waste bio-tar for efficient synthesis of 5-hydroxymethylfurfural from glucose33Construction of core–shell Co@CuCo/Al2O3 catalyst to boost the low‐temperature hydrogenation of 5‐hydroxymethylfurfural10Engineering the Interface Between Au Nanoparticles and CoO-Ov to Enhance the Catalytic Performance of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)82-Methylimidazole-modulated 2D Cu metal–organic framework for 5-hydroxymethylfurfural hydrodeoxygenation8Catalytic hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Pd-Co bimetallic catalysts supported on MoCx27Targeted Synthesis of Hydrocarbon Fuels and Fuel Oxygenates by Catalytic Conversion of Biomass Components1Single-atom iridium doped ultrathin MoS2 layers as a highly efficient catalyst for the hydrodeoxygenation of 5-hydroxymethylfurfural14Nitrogen-doped ordered mesoporous carbon supported ruthenium metallic nanoparticles: Opportunity for efficient hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran by catalytic transfer hydrogenation7Titania-supported sub-nanometer sized Ru-Ni catalysts for the hydroxymethylfurfural hydrodeoxygenation14Selective conversion of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)tetrahydrofuran over Ni-NC/SiO2 at room temperature21Selective hydrogenation of 5-hydroxymethylfurfural triggered bya high Lewis acidic Ni-based transition metal carbide catalyst335‐Hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes259Recent Progress in the Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran With Metal‐Containing Catalysts12Biodegradable Films Added with Conjugates from Residual Agave vinasses: Chemical and Mechanical Characterization2Direct Reductive Amination of HMF to 5‐(Aminomethyl)‐2‐furanmethanol Using Supported Iridium‐based Catalysts5Reductive amination of bio-platform molecules to nitrogen-containing chemicals11Efficient and switchable production of bio-diol/triol chemicals from 5-hydroxymethylfurfural12Production of value-added chemicals and fuels from selective conversion of CO, CC, and C–O bonds in 5-hydroxymethylfurfural over bimetallic catalysts8Efficient Hydrogenolysis of C–O Bond over Pd/P-TiO2: The Generation and Role of Brønsted Acid Site Triggered by Spillover Hydrogen25Biomass-derived furfural hydrogenation via copper-based magnesia-alumina layered double hydroxide-like material4Atomically Dispersed Electron-Rich Ru Species in CoOx for the Efficient Catalytic Hydrogenolysis of 5-Hydroxymethylfurfural7Conversion of biomass sugar to 5-hydroxymethylfurfural catalyzed by acid-base bifunctional polyphenylene sulfide fiber1Multiple Brønsted acidic sites in nitrogen-rich dicyandiamide immobilized on silica gel as a heterogeneous catalyst for efficient conversion of fructose into 5-hydroxymethylfurfural1Recent advances in solvent effects for biomass-derived platform molecule conversion: experimental and theoretical perspectives11Ru/TiO 2 catalysts for selective formation of ring hydrogenation or ring-opening products from biomass-derived 5-hydroxymethylfurfural1Preparation of Novel Humic Acid-Derived Graphene Oxide-Like Supported Pt–Co Bimetallic Catalyst for Hydrogenation and Hydrodeoxygenation of 5-Hydroxymethylfurfural0Synergistic Catalysis at Engineered Ru–Fe 2 O 3 Interfaces on Iron Silicate for Selective Conversion of Sucrose to Diols and Lower Alcohols1Selective Hydrogenation of Quercetin to Dihydroquercetin Using a Carbon Nanotube-Supported Non-Noble Nickel Catalyst0Non-noble Co coordinated with Ge ions in stable UTL framework robust the 2,5-dimethylfuran selectivity for hydrodeoxygenation of 5-hydroxymethylfurfural1Recent Progress of Advanced Biofuel 2,5-Dimethylfuran Production from 5-Hydroxymethylfurfural0Edge Sulfur Vacancies on MoS 2 Enable Room‐Temperature Hydrodeoxygenation of 5‐Hydroxymethylfurfural2Edge Sulfur Vacancies on MoS 2 Enable Room‐Temperature Hydrodeoxygenation of 5‐Hydroxymethylfurfural1Continuous flow synthesis of CuPd/C catalysts for the conversion of 5-hydroxymethylfurfural to 2,5-dimethylfuran0One-pot sustainable synthesis of 2,5-hexanedione from biomass-derived HMF using a HZSM-5+Ni/SiO2 composite catalyst with metal-acid synergy0Tuning Metal–Acid Cooperativity of Beta Zeolite-Supported Pt Catalysts for Selective Hydrogenolysis of 5-Hydroxymethylfurfural to Methyl Levulinate0Synergistic effect of porous carbon and nickel species for selective hydrogenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran: structure-performance relationships and kinetic insights0Adaptive Catalytic Interfaces for Biomass-Derived Model Compounds: Dynamic Active Sites, Microenvironments, and Operando-Guided Design0

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  1. Energy Densification of Biomass-Derived Furfurals to Furanic Biofuels by Catalytic Hydrogenation and Hydrodeoxygenation Reactions

    Sustainable Chemistry · 2021-09-16

    Nivedha Vinod, Saikat Dutta

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  2. Catalytic Upgrading of Bio‐Based 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran with Non‐Noble Metals

    Energy Technology · 2021-09-18

    Songdang Zhang, Yixuan Liu, Song Yang, Hu Li

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  3. Insight into Biomass Upgrade: A Review on Hydrogenation of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)

    Molecules · 2021-11-13

    Nor Azam Endot, Ramli Junid, Mohamad Shazwan Shah Jamil

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  4. Boehmite-derived Aluminum Oxide Catalyst for a Continuous Intramolecular Aldol Condensation of 2,5-Hexanedione to 3-Methyl-2-cyclopentenone in a Liquid-flow Reactor System

    Chemistry Letters · 2021-12-22

    Shun Nishimura, Son Dinh Le, Yusaku Asai, Natsuki Takahashi, Maho Endo, Shintaro Ohmatsu

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  5. A high-efficiency zirconium-based single-atom catalyst for the transformation of biomass-derived 5 hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan with nearly 100% selectivity

    Green Chemistry · 2022-01-01

    Lei Hu, Aiyong He, Xinming Shen, Qinyin Gu, Jingyi Zheng, Zhen Lin Wu, Yetao Jiang, Xiaoyu Wang, Jiaxing Xu, Yu‐He Kan, Feng Xu

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  6. Magnetic solid sulfonic acid-enabled direct catalytic production of biomass-derived N -substituted pyrroles

    New Journal of Chemistry · 2022-01-01

    Keping Wang, Mei Wu, Yixuan Liu, Ying Yang, Hu Li

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  7. Strategic Design of a WO3/PdOx-Carbon Shell Composite Photocatalyst: Visible Light-Mediated Selective Hydrogenation of 5-Hydroxymethylfurfural

    ACS Applied Energy Materials · 2022-02-24

    Alok Kumar, Rajakumar Ananthakrishnan

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  8. Sustainable Catalytic Transformation of Biomass‐Derived 5‐Hydroxymethylfurfural to 2,5‐Bis(hydroxymethyl)tetrahydrofuran

    ChemSusChem · 2022-03-14

    Cong Chien Truong, Dinesh Kumar Mishra, Sang Hyeok Ko, Yong Jin Kim, Young‐Woong Suh

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  9. Integrated Cascade Process for the Catalytic Conversion of 5‐Hydroxymethylfurfural to Furanic and TetrahydrofuranicDiethers as Potential Biofuels

    ChemSusChem · 2022-04-05

    Sara Fulignati, Claudia Antonetti, Tommaso Tabanelli, Fabrizio Cavani, Anna Maria Raspolli Galletti

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  10. A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran

    Nature Communications · 2022-06-27

    Shuang Xiang, Lin Dong, Zhi-Qiang Wang, Xue Han, Luke L. Daemen, Jiong Li, Yongqiang Q. Cheng, Yong Quan Guo, Xiaohui Liu, Yongfeng Hu, Anibal Javier Ramirez-Cuesta, Sihai Yang⧫, Xue‐Qing Gong, Yanqin Wang

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  11. Recent advances in heterogeneous catalytic hydrodeoxygenation of biomass-derived oxygenated furanics mediated by formic acid

    Materials Today Sustainability · 2022-07-15

    Sudeep Mudhulu, Zi-Jie Gong, Hao-Chuan Ku, Yi‐Hsuan Lu, Wen‐Yueh Yu

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  12. Efficient synthesis of the liquid fuel 2,5-dimethylfuran from biomass derived 5-(chloromethyl)furfural at room temperature

    Applied Catalysis B: Environmental · 2022-08-12

    Binglin Chen, Yunchao Feng, Renjie Huang, Shibo Yang, Zheng Li, Jonathan Sperry, Shuliang Yang, Xing Tang, Yong Qiang Sun, Lu Lin, Xianhai Zeng

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  13. Tailoring the catalytic performance of Cu/SiO2 for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable fuels

    Frontiers in Chemistry · 2022-08-22

    Hongyan Jia, Qing Lv, Qineng Xia, Wanpeng Hu, Yanqin Wang

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  14. A Hybrid Process for Valorization of d -Fructose to 2,5-Bis(hydroxymethyl)furan by Bridging Chemocatalysis and Biocatalysis in a Betaine:Benzenesulfonic Acid System

    ACS Sustainable Chemistry & Engineering · 2022-09-06

    Yu Peng, Luyao Jiang, Junhua Di, Cuiluan Ma, Qi Li, Yu-Cai He

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  15. Desarrollo de catalizadores nanoestructurados para la obtención de bioproductos químicos de fuentes renovables

    AJEA · 2022-10-03

    María V. Fraire, Andrea R. Beltramone, Brenda C. Ledesma

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  16. Highly dispersed Co anchored on Ce-doped hydroxyapatite as a dual-functional catalyst for selective hydrogenolysis of 5-hydroxymethylfurfural

    Dalton Transactions · 2023-01-01

    Zhuoyou Gao, Mengying Wang, Ningzhao Shang, Wei Gao, Xiang Cheng, Shutao Gao, Gao Y, Zhi Wang

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  17. Recent advances in the catalytic production of bio-based diol 2,5-bis(hydroxymethyl)furan

    Carbon Resources Conversion · 2023-01-03

    Wenguang Zhao, Feng Wang, Kangyu Zhao, Xianxiang Liu, Xiaoting Zhu, Le Yan, Yuan Yin, Qiong Xu, Dulin Yin

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  18. Regulating the interfacial electronic coupling of PtNi/TiO2 via bond evolution for highly efficient hydrogenation of 5-hydroxymethylfurfural

    Applied Catalysis B: Environmental · 2023-03-05

    Entian Cui, Qingping Li, Xiang Wang, Ning Xu, Feng Zhang, Feng Zhang, Guihua Hou, Ming‐Hua Xie, Xiu‐Li Yang, Xiu‐Li Yang, Yajun Zhang

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  19. Biobased Paraxylene

    Unknown journal · 2023-03-10

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  20. The crucial role of catalyst wettability for hydrogenation of biomass and carbon dioxide over heterogeneous catalysts

    Cell Reports Physical Science · 2023-04-03

    Miaomiao Wei, Yongqi Kuang, Zhongyu Duan, Hao Li

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  21. Selective hydrogenolysis of 5-hydroxymethylfurfural to 5-methylfurfural over Au/TiO2

    Applied Catalysis B: Environmental · 2023-05-19

    Lin Dong, Jordi Morales‐Vidal, Lili Mu, Licheng Li, Núria López, Javier Pérez‐Ramírez, Zupeng Chen

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  22. Efficient and Selective Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran by a Bimetallic Copper‐Palladium Catalyst on a Carbon‐Doped Boron Nitride Support

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  23. Rational design core-shell Co@CuCo/Al2O3 catalysts for Low-Temperature Hydrodeoxygenation of 5-Hydroxymethylfurfural

    Unknown journal · 2023-06-14

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  24. TiO2 supported non-noble Ni-Fe catalysts for the high yield production of 2,5-dimethylfuran biofuel

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  25. A remarkable bifunctional carbon-based solid acid catalyst derived from waste bio-tar for efficient synthesis of 5-hydroxymethylfurfural from glucose

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  26. Construction of core–shell Co@CuCo/Al2O3 catalyst to boost the low‐temperature hydrogenation of 5‐hydroxymethylfurfural

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  27. Engineering the Interface Between Au Nanoparticles and CoO-Ov to Enhance the Catalytic Performance of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)

    Chemical Research in Chinese Universities · 2023-12-07

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  28. 2-Methylimidazole-modulated 2D Cu metal–organic framework for 5-hydroxymethylfurfural hydrodeoxygenation

    Dalton Transactions · 2023-12-15

    Zhuofei Li, Yanting Li, Qiang Zhang, Tong‐Liang Hu

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  29. Catalytic hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Pd-Co bimetallic catalysts supported on MoCx

    Fuel · 2023-12-28

    Yu Chen, Haoquan Guo, Junye Yang, Kaiyang Xu, Xinyu Lu, Yue Yang, Hongqiao Lin, Lizhi Wu, Li Tan, Guohui Yang, Noritatsu Tsubaki, Xiaoli Gu, Yu Tang

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  30. Targeted Synthesis of Hydrocarbon Fuels and Fuel Oxygenates by Catalytic Conversion of Biomass Components

    Sustainable materials and technology · 2024-01-01

    Navya Subray Bhat, Saikat Dutta, Girdhar Joshi

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  31. Single-atom iridium doped ultrathin MoS2 layers as a highly efficient catalyst for the hydrodeoxygenation of 5-hydroxymethylfurfural

    Chemical Engineering Science · 2024-02-22

    Jianwei Ji, Jinyang Wang, Julian Skagfjörd Reinhold, Wenqing Zhu, Yuanlong Tan, Sen Meng, Xiaoyan Liu, Xiaohui Ji, Bo Zhang

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  32. Nitrogen-doped ordered mesoporous carbon supported ruthenium metallic nanoparticles: Opportunity for efficient hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran by catalytic transfer hydrogenation

    Heliyon · 2024-02-23

    J. G. Buta, Bayisa Dame, Tariku Ayala Chamada

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  33. Titania-supported sub-nanometer sized Ru-Ni catalysts for the hydroxymethylfurfural hydrodeoxygenation

    Catalysis Today · 2024-03-13

    Agnieszka M. Ruppert, Magdalena Brzezińska, Nicolas Keller

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  34. Selective conversion of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)tetrahydrofuran over Ni-NC/SiO2 at room temperature

    Chemical Engineering Science · 2024-05-14

    Renjie Huang, Shaoyu Yuan, Binglin Chen, Zihao Yang, Ye Tian, Zheng Li, Lu Lin, Xianhai Zeng

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  35. Selective hydrogenation of 5-hydroxymethylfurfural triggered bya high Lewis acidic Ni-based transition metal carbide catalyst

    Green Energy & Environment · 2024-05-20

    Rulu Huang, Jianchun Jiang, Jie Liang, Shanyong Wang, Yuwei Chen, Xianhai Zeng, Kui Wang

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  36. 5‐Hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes

    Advanced Materials · 2024-05-29

    Chunlin Chen, Mingxin Lv, Hualei Hu, Liyuan Huai, Bin Zhu, Shilin Fan, Q.Z. Wang, Jian Zhang

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  37. Recent Progress in the Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran With Metal‐Containing Catalysts

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  38. Biodegradable Films Added with Conjugates from Residual Agave vinasses: Chemical and Mechanical Characterization

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    Miguel Angel Lorenzo-Santiago, Edgar García‐Hernández, Rodolfo Rendón–Villalobos, Jacobo Rodríguez-Campos, Diego Antonio Tuesta-Popolizio, Silvia Maribel Contreras-Ramos

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  39. Direct Reductive Amination of HMF to 5‐(Aminomethyl)‐2‐furanmethanol Using Supported Iridium‐based Catalysts

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  40. Reductive amination of bio-platform molecules to nitrogen-containing chemicals

    Carbon Neutrality · 2024-08-20

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  41. Efficient and switchable production of bio-diol/triol chemicals from 5-hydroxymethylfurfural

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  42. Production of value-added chemicals and fuels from selective conversion of CO, CC, and C–O bonds in 5-hydroxymethylfurfural over bimetallic catalysts

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  43. Efficient Hydrogenolysis of C–O Bond over Pd/P-TiO2: The Generation and Role of Brønsted Acid Site Triggered by Spillover Hydrogen

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  44. Biomass-derived furfural hydrogenation via copper-based magnesia-alumina layered double hydroxide-like material

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  45. Atomically Dispersed Electron-Rich Ru Species in CoOx for the Efficient Catalytic Hydrogenolysis of 5-Hydroxymethylfurfural

    ACS Sustainable Chemistry & Engineering · 2025-08-13

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  46. Conversion of biomass sugar to 5-hydroxymethylfurfural catalyzed by acid-base bifunctional polyphenylene sulfide fiber

    Biomass and Bioenergy · 2025-09-27

    Pengyu Li, Haitao Cui, Yongqiang Chen, Yahui Yuan, Senhao Wang, Kai Lin Xu, Wenying Ai, Yuanyuan Liu, Mingli Jiao

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  47. Multiple Brønsted acidic sites in nitrogen-rich dicyandiamide immobilized on silica gel as a heterogeneous catalyst for efficient conversion of fructose into 5-hydroxymethylfurfural

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  48. Recent advances in solvent effects for biomass-derived platform molecule conversion: experimental and theoretical perspectives

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  49. Ru/TiO 2 catalysts for selective formation of ring hydrogenation or ring-opening products from biomass-derived 5-hydroxymethylfurfural

    Green Chemistry · 2026-01-01

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  50. Preparation of Novel Humic Acid-Derived Graphene Oxide-Like Supported Pt–Co Bimetallic Catalyst for Hydrogenation and Hydrodeoxygenation of 5-Hydroxymethylfurfural

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