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RESEARCH PAPER · Chemical Engineering Journal · 2020

Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environment

David Maria Tobaldi, Dana Dvoranová, Luc Lajaunie, Nejc Rožman, Bruno R. Figueiredo, M.P. Seabra, Andrijana Sever Škapin, José J. Calvino, Vlasta Brezová, João António Labrincha

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Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environmentOriginalCuxO and carbon–modified TiO2–based hybrid materials for photocatalytically assisted H2 generation16Fabrication and photocatalytic performance of C, Pt‐comodified TiO 2 nanotubes2Defects and internal electric fields synergistically optimized g-C3N4−x/BiOCl/WO2.92 heterojunction for photocatalytic NO deep oxidation50Constructing S-Scheme CeO 2/CN Heterojunction for High Efficiency Light-Induced Photothermal Synergistic Catalytic Degradation of Gaseous Formaldehyde Under Visible Light Irradiation0Functionalized nanomaterials and the environment4Simultaneous Catalytic Removal of VOCs and NOx with the Dual-layered Catalyst of CoCeOx and V2O5/TiO210Graphene coupled TiO2 photocatalysts for environmental applications: A review311An important phenomenon in Fe2O3-TiO2 photocatalyst: Ion-inter-doping6A stable photoelectrochemical graphene/CdS/TiO2 film for nano-photoanode2MOFs-derived porous carbon materials for gas adsorption and separation11In situ hydrothermal synthesis of TiO2–RGO nanocomposites for 4-nitrophenol degradation under sunlight irradiation11High-Performance Polylactic Acid Materials Enabled by TiO2–Polydopamine Hybrid Nanoparticles263D MXene/Ag2S material as Schottky junction catalyst with stable and enhanced photocatalytic activity and photocorrosion resistance124Hydroxyl/amino and Fe(III) co-grafted graphite carbon nitride for photocatalytic removal of volatile organic compounds33An environmental approach for the photodegradation of toxic pollutants from wastewater using silver nanoparticles decorated titania-reduced graphene oxide31Porous titanium dioxide supported on glass microbubbles to prepare a low-density photocatalyst for AR1 degradation5Gas sensing of fibrous red phosphorene towards inorganic air pollutants: Insights from first-principles calculations12Mechanism and Purification Effect of Photocatalytic Wastewater Treatment Using Graphene Oxide-Doped Titanium Dioxide Composite Nanomaterials24Photocatalytic degradation of sulfamonomethoxine by mesoporous phosphorus-doped titania under simulated solar light irradiation25Effects of ZSM‐5 Treatment on the Properties of Gd2Ti2O7‐nHZSM‐5 Composites for RBR‐X3B Degradation0Photocatalytic Destruction of Gaseous Benzene Using Mn/I-Doped TiO 2 Nanoparticle Catalytic Under Visible Light10Synthesis, Characterization, and Photocatalytic Activities of Graphene Oxide/metal Oxides Nanocomposites: A Review140Crystalline phase formation of Na2W2O7 using microwave-assisted solution combustion synthesis for photocatalytic degradation of organic pollutants from aqueous solutions3Determination of photocatalytic properties of supported catalysts with low-cost NOx sensors and the Arduino platform0Sol-gel synthesized ZnTiO3/SiO2 composite photocatalyst for Reactive Brilliant Red X-3B degradation9Au single atom-anchored WO 3 /TiO 2 nanotubes for the photocatalytic degradation of volatile organic compounds57Hierarchical laminated Al2O3 in-situ integrated with high-dispersed Co3O4 for improved toluene catalytic combustion28Sonochemical preparation and characterization of Sm‐doped GO/KSrPO4 nanocomposite photocatalyst for degradation of methylene blue dye10Adsorption and In-Situ Photocatalytic Synergy Degradation of 2,4-Dichlorophenol by Three-Dimensional Graphene Hydrogel Modified with Highly Dispersed TiO 2 Nanoparticles0Functionalized membranes for multipollutants bearing air treatment0Graphitic Carbon Nitride -Based Panchromatic Composite Photocatalysts: Visible Light-Driven Elimination of Nicotine and Pathogenic Microorganisms3Oxygen Vacancy Mediated Band-Gap Engineering Via B Doping for Enhancing Z-Scheme Heterojunction Photocatalytic Performance0Photocatalytic hydrogen generation from a methanol–water mixture in the presence of g-C 3 N 4 and graphene/g-C 3 N 410Recent progress on catalysts for catalytic oxidation of volatile organic compounds: a review117Superior photocatalytic degradation performance for gaseous toluene by 3D g-C 3 N 4 -reduced graphene oxide gels9Transparent TiO 2 thin films with high photocatalytic activity for indoor air purification23Ti–Dopamine Hybrid Nanoparticles with UV-Blocking and Durable Poly(butylene adipate-co-terephthalate) Materials15Molybdenum Sulfide (MoS2)/Ordered Mesoporous Carbon (OMC) Tubular Mesochannel Photocatalyst for Enhanced Photocatalytic Oxidation for Removal of Volatile Organic Compounds (VOCs)10The effects of ZSM-5 zeolite on ofloxacin degradation on Sm2Ti2O7 photocatalyst22D Photocatalytic Materials for Environmental Applications0Constructing S-scheme CeO2/CN heterojunction for high efficiency light-induced photothermal synergistic catalytic degradation of gaseous formaldehyde under visible light irradiation27Benzene and NO photocatalytic-assisted removal using indoor lighting conditions11Adsorption and in-situ photocatalytic synergy degradation of 2,4-dichlorophenol by three-dimensional graphene hydrogel modified with highly dispersed TiO2 nanoparticles31Calcination effects on sol–gel preparation of porous TiO2/zeolite composites for Acid Red 1 degradation2Investigation of microwave enhanced catalytic degradation of VOCs with a novel double ridge field compressed cavity20Preparation of TiO2-CNT-Ag Ternary Composite Film with Enhanced Photocatalytic Activity via Plasma-Enhanced Chemical Vapor Deposition16Aramid textile with near-infrared laser-induced graphene for efficient adsorption materials33Carbon-titanium dioxide heterogeneous (photo)catalysts (C–TiO2) for highly efficient visible light photocatalytic application51Graphene-Based Materials for the Removal of Volatile Organic Compounds0Tetrabutylammonium hydroxide mediated sol-gel synthesis of samarium titanate to enhance photocatalytic activity5Polyethylene glycol-modified sol-gel synthesis of ZnTiO3(n)- quartz composite microspheres for enhanced photocatalytic degradation of Reactive Brilliant Red X–3B10Steering interfacial charge kinetics: Synergizing cocatalyst roles of Ti3C2M (MXene) and NCDs for superior photocatalytic performance over TiO240Development of CuO/CuS/MnO2 ternary nanocomposite for visible light-induced photocatalytic degradation of methylene blue53TiO2/activated carbon synthesized by microwave-assisted heating for tetracycline photodegradation69ZSM-5 nanocrystal promoted low-temperature activity of supported manganese oxides for catalytic oxidation of toluene14Sb-based photocatalysts for degradation of organic pollutants: A review47Graphene-based porous nanohybrid architectures for adsorptive and photocatalytic abatement of volatile organic compounds38A Study on the Evaluation Methods of Nitrogen Oxide Removal Performance of Photocatalytic Concrete for Outdoor Applications7Engineering ZnSn(OH)6 with ternary active sites-directed hydroxyl vacancies for robust deep C6H6 photo-oxidation: Experiment and DFT calculations24First-principles study of (Ni, Pd, Au)-embedded VS2 monolayers for adsorption of CO, H2S, NO, NO2 and SO222Antifouling CuO@TiO2 coating on plasma-grafted PAA/PES membrane based on photocatalysis and hydrogen peroxide activation16Carbon-based nanostructures for emerging photocatalysis: CO2 reduction, N2 fixation, and organic conversion46Carbon-integrated semiconductor photocatalysts for removal of volatile organic compounds in indoor environments84Effect of substrate roughness on NOx removal of poly heptazine imides coated cement pastes exposed to washing and weathering9Fabrication of noble-metal-free copper-doped TiO2 nanofibers synergized with acetic acid-treated g-C3N4 nanosheets for enhanced photocatalytic hydrogen evolution37Surface Modification of GdMn2O5 for Catalytic Oxidation of Benzene via a Mild A-Site Sacrificial Strategy7Recent development of graphene-based composite for multifunctional applications: energy, environmental and biomedical sciences82Photocatalytic Oxidation for Volatile Organic Compounds Elimination: From Fundamental Research to Practical Applications146Gaseous ethylbenzene removal by photocatalytic TiO2 nanoparticles immobilized on glass fiber tissue under real conditions: evaluation of reactive oxygen species contribution to the photocatalytic process20Oxygen-vacancy-rich Ag/Bi5O7Br nanosheets enable improved photocatalytic NO removal and oxygen evolution under visible light exposure8The influences of molecular weight of polyethylene glycol on porous Sm2Ti2O7 for degradation of reactive Brilliant Red X-3B0Carbon nanocoils decorated with scale-like mesoporous NiO nanosheets for ultrasensitive room temperature ppb-level NO 2 sensing8Effects of Na/Ti ratio on the properties of sodium titanate for photocatalytic degradation of ofloxacin0Investigation on performance of Eu:GO:KSrPO4 nanocomposite for MB dye photocatalytic degradation: Experimental and ANN modeling13V-Cu bimetallic oxide supported catalysts for synergistic removal of toluene and NOx from coal-fired flue gas: The crucial role of support59Enhanced photocatalytic degradation of ofloxacin by Sm2Ti2O7 supported on quartz sand14Polyethylene glycol in the sol–gel synthesis of zinc titanate for the improved photocatalytic degradation of an azo dye1Oxygen Vacancy Mediated Band-Gap Engineering via B-Doping for Enhancing Z-Scheme A-TiO2/R-TiO2 Heterojunction Photocatalytic Performance22Recent Developments of Graphene-Based Nanotechnology towards Energy and Environment3Enhancing the photocatalytic removal of toluene by modified porous TiO2 with internal hydrophobic interface12An Overview of Recent Developments in Improving the Photocatalytic Activity of TiO2-Based Materials for the Treatment of Indoor Air and Bacterial Inactivation23Recent Developments of Light-Harvesting Excitation, Macroscope Transfer and Multi-Stage Utilization of Photogenerated Electrons in Rotating Disk Photocatalytic Reactor4Visible‐light‐driven Oxygen Vacancy and Carbon Doping of C@TiO2‐x Photocatalyst for Enhanced Pollutants Degradation Performance8Synthesis of Asymmetrical CsPbBr3/TiO2 Nanocrystals with Enhanced Stability and Photocatalytic Properties18Recent Progress in Multifunctional Graphene-Based Nanocomposites for Photocatalysis and Electrocatalysis Application40TiO2/WO3/graphene for photocatalytic H2 generation and benzene removal: Widely employed still an ambiguous system29Recent trends in two-dimensional graphene derivatives-based composites: Review on synthesis, properties and applications22Catalyzing Artificial Photosynthesis with TiO2 Heterostructures and Hybrids: Emerging Trends in a Classical yet Contemporary Photocatalyst221Interfacial interaction promoted titanium oxide-based organic-inorganic nanoheterojunctions by chiral host-guest binding6The effects of chain length of polyethylene glycol on porous Na2Ti6O13 for photocatalytic degradation of ofloxacin2A Bibliometric Analysis of Graphene-Based Materials for Wastewater Treatment: Trends and Future Directions (2010-2023)1Emerging Technologies in Catalyst Research1Fabrication and Characterization of Hybrids with Graphene Derivatives/Analogues for Analytical Applications0Facile synthesis of TiO 2 –carbon composite doped nitrogen for efficient photodegradation of noxious methylene blue dye12Graphene-Based Hybrid Photocatalysts for Environmental Remediation0Graphene-Based Photocatalysts for Air Purification2Next-Generation Graphene-Based Photocatalysts for Purification of Air and Water2Synthesis, mechanical characterization, and mechanism investigation of graphene-wrapped nano-titanium dioxide composite0TiO2-Based Photocatalysts for Environment Application2Present Status and Perspectives of Graphene and Graphene‐related Materials in Cultural Heritage54Sol-gel synthesis and photocatalytic activity of In0.05TiO2(x)/HGB composite suspended in azophloxine solution0Photocatalytic degradation of ciprofloxacin by using tannin-doped BaTiO3 catalyst24Microwave-Solvothermal Synthesis of Mesoporous CeO2/CNCs Nanocomposite for Enhanced Room Temperature NO2 Detection5Low-density ZnTiO3–ceramic hollow microsphere composite photocatalyst for degradation of azophloxine9Enhanced photocatalytic degradation of rhodamine B dye and antibacterial activity of diatomite-supported TiO2/ZnS hybrid catalyst via additional calcination8Sol-gel synthesis of La0·05Mg0·95TiO3/SiO2 microspheres for photocatalytic degradation of azophloxine3A novel photocatalytic mechanism of volatile organic compounds degradation on BaTiO3 under visible light: Photo-electrons transfer from photocatalyst to pollutant9Structural evolution of anodized TiO2 nanotubes and their solar energy applications13A Review of Synthesis Methods, Modifications, and Mechanisms of ZnO/TiO 2 -Based Photocatalysts for Photodegradation of Contaminants410Weather-resistant wood for sound absorption, thermal insulation and NO removal15AIE-based UiO-66/TiO2:fast response toluene detection and photocatalytic degradation1Recent progress and perspectives on metal oxide catalysts for thermocatalytic and photocatalytic oxidation of VOCs: a review22Thioxanthone Functionalized NanoTiO2 Composites as Photocatalyst for Degradation of Organic Dyes1Enhanced photocatalytic degradation of toluene on surface C- and CN-modified TiO2 microspheres84Synergistic mechanisms of carbon-based materials for VOCs photocatalytic degradation: A critical review42INVESTIGATION OF STRUCTURAL, MORPHOLOGY AND OPTICAL PROPERTIES OF GO@METAL OXIDE THIN FILMS PREPARED BY SPRAY PYROLYSIS TECHNIQUE1Enhanced photocatalytic removal of NOx through the synergistic effect of photothermal activation and bipyroelectricity2Facile construction of Sb2WO6/AgCl heterojunction for enhanced photocatalytic degradation for rhodamine B and tetracycline8Enhanced photoelectrochemcial activity of TiO2 nanoparticles by graphene intercalation1Eco-friendly synthesis and applications of graphene-titanium dioxide nanocomposites for pollutant degradation and energy storage88Sol-gel synthesized flexible Na2Ti6O13–aluminium oxide fibres for photocatalytic degradation of Acid red 14Effects of ytterbium on potassium titanate for enhanced photocatalytic degradation of Acid red 10Revealing the role of individual components in the high performance photocatalytic mineralization of mixtures of organohalogen pollutants3Applications of Antimony in Catalysis21A zinc titanate-based floatable composite for photocatalytic degradation of azophloxine2Sol–Gel Synthesis of Porous Na2Ti6O13: Effects of Polyethylene Glycol on Photocatalytic Degradation of Ofloxacin1Enhanced photocatalytic activity of Na2Ti6O13/Al2O3 fibres synthesised by sol-gel method for degradation of azophloxine3Combined Catalytic Conversion of NOx and VOCs: Present Status and Prospects16Fabrication of Moldable Self-Bonding Bamboo Fiberboard Using a Dual-Coordination Network Enhancement Strategy10Heterostructure Based of Ti-TiO2(NW)/rGO Hybrid Materials for Electrochemical Applications5Continuous fabrication of hollow photocatalytic CNT/TiO2/calcium alginate microfibers via needle-based microfluidic device for environmental remediation in NO removal2Graphene-modified g-C3N4/ α-Fe2O3 systems for light-induced hydrogen generation5Harnessing 1D TiO 2 nanostructures: insights into synthesis, properties and photocatalytic applications for pollution control5Engineering CuMn2O4 via waste activated carbon incorporation for low-temperature toluene oxidation: Coupling oxygen vacancies and hierarchical porosity4Advancing Air Sustainability: Light-induced Removal of Airborne Pollutants0Construction of a Novel Solar‐Light‐Driven Bismuth Titanate/Barium Titanate Photocatalyst for Significantly Enhanced Purification of Nitric Oxide1Photocatalyst deactivation in gaseous VOCs photooxidation: Mechanisms, stability enhancement, and regeneration strategies17Core-shell structured GCS@MnO2 enables light-driven self-heating photothermal synergistic catalytic oxidation of toluene8Green-synthesized metal oxide nanostructures for solar-driven photocatalysis: Advances, challenges, and environmental applications11The application of multifunctional biochar materials in mitigating atmospheric environmental issues: Influencing factors, mechanisms of action, and application prospects2Density functional theory insights to VOCs adsorption mechanism on Ce/CuO modified TiO2(001) surface: A comparative study on toluene and dichloromethane1Computational analysis of solar light harvesting properties of TiO2-BiVO4 inverse opals for applications in photocatalysis8Carbon nanostructures for photocatalytic degradation of organic pollutants: Synthesis strategies and functionalization techniques6Using TiO2 in photocatalytic reactors: VOCs, NOx, CO2 removal and H2 production12Flexible polyurethane foam supported ZnO nanorods-graphene hybrids for efficient broad-spectrum photodegradation of toluene3Zinc titanate hollow microspheres synthesised via the sol–gel method for photocatalytic degradation of Acid Red 10Association between indoor ventilation frequency and frailty among Chinese older adults0Prospective insights into the emerging strategies of metal oxides and chalcogenides for elimination of volatile organic compounds for environmental sustainability0Suspensible ZnTiO 3 /FAC Microspheres Facilitate Photocatalytic Degradation of Acid Red 1 and Recycling1Synergistic ring-opening of toluene by porous carbon and high-exposure Ag/TiO 2 : preventing benzoate poisoning for enhanced stability0

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  41. Constructing S-scheme CeO2/CN heterojunction for high efficiency light-induced photothermal synergistic catalytic degradation of gaseous formaldehyde under visible light irradiation

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