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RESEARCH PAPER · Angewandte Chemie International Edition · 2020

Responsive Four‐Coordinate Iron(II) Nodes in FePd(CN)4

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Responsive Four‐Coordinate Iron(II) Nodes in FePd(CN)4OriginalGraphical Abstract: Angew. Chem. Int. Ed. 43/20201Theoretical investigation of tetrahedral distortion of four-coordinate iron( ii ) centres in FePd(CN) 45Coordination Geometry Changes in Amorphous Cyanide-Bridged Metal–Organic Frameworks upon Water Adsorption23Node Distortion Modulation for Anisotropic Thermal Expansions of Two‐dimensional Coordination Polymers8New family of Hofmann-like coordination polymers constructed with imidazole ligands and associated with spin crossover and anisotropic thermal expansions10The ligand field in low-crystallinity metal–organic frameworks investigated by soft X-ray core-level absorption spectroscopy3Zero area thermal expansion of honeycomb layers via double distortion relaxation in (PPh 4 )[Cu 2 (CN) 3 ]8Simultaneous magneto-dielectric transitions in a fluorescent Hofmann-type coordination polymer7Spin-Flop Transition in a Nickel–Octacyanidotungstate Chain Magnet2Colossal Anisotropic Thermal Expansion through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {FeIII4FeII2} Compound28Colossal Anisotropic Thermal Expansion through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {FeIII4FeII2} Compound3Studies on dynamic structures constructed by anisotropic assemblies of tetracyanometallate units0A NiII–WV(CN)8 layer magnet showing metamagnetic behavior1Janus-Type Mixed-Valent Copper–Cyanido Honeycomb Layers3Crystal structures and properties of Fe(H 2 O) 2 [Ni(CN) 4 ]·nH 2 O hydrates5The Synthesis and Crystal Structures of New One- and Two-Dimensional Fe(II) Coordination Polymers Using Imidazole Derivatives4A novel style of 2D Hofmann-type coordination polymer incorporated trigonal prismatic coordination geometry with bidentate co-ligands4Giant anisotropic thermal expansion of copper-cyanido flat layers with flexible copper nodes3Atomically isolated Sb(CN) 3 on sp 2 -c-COFs with balanced hydrophilic and oleophilic sites for photocatalytic C-H activation43Fe(II) coordination transition regulates reductive dechlorination: The overlooked abiotic role of lactate13Mechanistic Insights on the Formation of a Carbodiimide Ion from Urea in La2O2NCN Synthesis Based on the “Proanion” Strategy4A three-dimensional Hofmann-type metal–organic framework with switchable spin crossover and fluorescence properties3Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers2Reversible and Massive Structural Transformation in Meltable Cyanido‐bridged Coordination Polymer Crystals0Anisotropic Thermal Expansion and Asymmetric Spin-Crossover Hysteresis in [Fe III 4 Fe II 2 ] Clusters Driven by Elastic Anisotropy1Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers0

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  1. Graphical Abstract: Angew. Chem. Int. Ed. 43/2020

    Angewandte Chemie International Edition · 2020-10-12

    Read original paper ↗ ·
  2. Theoretical investigation of tetrahedral distortion of four-coordinate iron( ii ) centres in FePd(CN) 4

    Dalton Transactions · 2021-01-01

    Susumu Fujii, Ryo Ohtani, Akihide Kuwabara

    Read original paper ↗ ·
  3. Coordination Geometry Changes in Amorphous Cyanide-Bridged Metal–Organic Frameworks upon Water Adsorption

    Inorganic Chemistry · 2021-02-16

    Haruka Yoshino, Kohei Yamagami, Hiroki Wadati, Hirona Yamagishi, Hiroyuki Setoyama, Sayuri Shimoda, Akio Mishima, Benjamin Le Ouay, Ryo Ohtani, Masaaki Ohba

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  4. Node Distortion Modulation for Anisotropic Thermal Expansions of Two‐dimensional Coordination Polymers

    ChemNanoMat · 2021-03-28

    Ryo Ohtani, Junichi Yanagisawa, Benjamin Le Ouay, Masaaki Ohba

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  5. New family of Hofmann-like coordination polymers constructed with imidazole ligands and associated with spin crossover and anisotropic thermal expansions

    New Journal of Chemistry · 2022-01-01

    Takashi Kosone, Ryota Kosuge, Morie Tanaka, Takeshi Kawasaki, Naoya Adachi

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  6. The ligand field in low-crystallinity metal–organic frameworks investigated by soft X-ray core-level absorption spectroscopy

    Physical Chemistry Chemical Physics · 2022-01-01

    Kohei Yamagami, Haruka Yoshino, Hirona Yamagishi, Hiroyuki Setoyama, Arata Tanaka, Ryo Ohtani, Masaaki Ohba, Hiroki Wadati

    Read original paper ↗ ·
  7. Zero area thermal expansion of honeycomb layers via double distortion relaxation in (PPh 4 )[Cu 2 (CN) 3 ]

    CrystEngComm · 2022-01-01

    Yuudai Iwai, Manabu Nakaya, Hiroyoshi Ohtsu, Benjamin Le Ouay, Ryo Ohtani, Masaaki Ohba

    Read original paper ↗ ·
  8. Simultaneous magneto-dielectric transitions in a fluorescent Hofmann-type coordination polymer

    Dalton Transactions · 2023-01-01

    Fei‐Fei Yan, Dan Liu, Rui Cai, Liang Zhao, Pan‐Dong Mao, Hui-Ying Sun, Yin‐Shan Meng, Tao Liu

    Read original paper ↗ ·
  9. Spin-Flop Transition in a Nickel–Octacyanidotungstate Chain Magnet

    Crystal Growth & Design · 2023-02-16

    Shintaro Akagi, Junhao Wang, Kenta Imoto, Shin‐ichi Ohkoshi, Hiroko Tokoro

    Read original paper ↗ ·
  10. Colossal Anisotropic Thermal Expansion through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {FeIII4FeII2} Compound

    Angewandte Chemie International Edition · 2023-05-13

    Hui‐Ying Sun, Yin‐Shan Meng, Liang Rong Zhao, Nian‐Tao Yao, Pan‐Dong Mao, Qiang Liu, Fei‐Fei Yan, Hiroki Oshio, Tao Liu

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  11. Colossal Anisotropic Thermal Expansion through Coupling Spin Crossover and Rhombus Deformation in a Hexanuclear {FeIII4FeII2} Compound

    Angewandte Chemie · 2023-05-13

    Hui‐Ying Sun, Yin‐Shan Meng, Liang Rong Zhao, Nian‐Tao Yao, Pan‐Dong Mao, Qiang Liu, Fei‐Fei Yan, Hiroki Oshio, Tao Liu

    Read original paper ↗ ·
  12. Studies on dynamic structures constructed by anisotropic assemblies of tetracyanometallate units

    Bulletin of Japan Society of Coordination Chemistry · 2023-05-31

    Ryo Ohtani

    Read original paper ↗ ·
  13. A NiII–WV(CN)8 layer magnet showing metamagnetic behavior

    Pure and Applied Chemistry · 2023-06-01

    Shintaro Akagi, Junhao Wang, Kenta Imoto, Kunal Kumar, Shin‐ichi Ohkoshi, Hiroko Tokoro

    Read original paper ↗ ·
  14. Janus-Type Mixed-Valent Copper–Cyanido Honeycomb Layers

    Inorganic Chemistry · 2023-10-31

    Yuudai Iwai, Yuki Imamura, Manabu Nakaya, Miki Inada, Benjamin Le Ouay, Masaaki Ohba, Ryo Ohtani

    Read original paper ↗ ·
  15. Crystal structures and properties of Fe(H 2 O) 2 [Ni(CN) 4 ]·nH 2 O hydrates

    Journal of Coordination Chemistry · 2023-11-24

    Lucero Torres, Ana Adela Lemus‐Santana, Laritza Sánchez, M. Ávila, E. Reguera

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  16. The Synthesis and Crystal Structures of New One- and Two-Dimensional Fe(II) Coordination Polymers Using Imidazole Derivatives

    Crystals · 2023-11-30

    Ryota Kosuge, Takeshi Kawasaki, Kosuke Kitase, Takashi Kosone

    Read original paper ↗ ·
  17. A novel style of 2D Hofmann-type coordination polymer incorporated trigonal prismatic coordination geometry with bidentate co-ligands

    Dalton Transactions · 2024-01-01

    Yuki Imamura, Haruka Yoshino, Benjamin Le Ouay, Ryo Ohtani, Masaaki Ohba

    Read original paper ↗ ·
  18. Giant anisotropic thermal expansion of copper-cyanido flat layers with flexible copper nodes

    Chemical Communications · 2024-01-01

    Yuudai Iwai, Manabu Nakaya, Yuta Tsuji, Benjamin Le Ouay, Masaaki Ohba, Ryo Ohtani

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  19. Atomically isolated Sb(CN) 3 on sp 2 -c-COFs with balanced hydrophilic and oleophilic sites for photocatalytic C-H activation

    Science Advances · 2024-01-31

    Zhenyuan Teng, Zhenzong Zhang, Hongbin Yang, Qitao Zhang, Teruhisa Ohno, Chenliang Su

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  20. Fe(II) coordination transition regulates reductive dechlorination: The overlooked abiotic role of lactate

    Water Research · 2024-02-19

    Qianqian Jia, Xue-Jie Zhang, Liandong Zhu, Li‐Zhi Huang

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  21. Mechanistic Insights on the Formation of a Carbodiimide Ion from Urea in La2O2NCN Synthesis Based on the “Proanion” Strategy

    Inorganic Chemistry · 2024-08-05

    Oomi Sumioka, Naoki Tarutani, Kiyofumi Katagiri, Kei Inumaru, Zi Lang Goo, Kunihisa Sugimoto, Yusuke Asai, Miwa Saito, Teruki Motohashi

    Read original paper ↗ ·
  22. A three-dimensional Hofmann-type metal–organic framework with switchable spin crossover and fluorescence properties

    New Journal of Chemistry · 2025-01-01

    Fei‐Fei Yan, Ren-He Zhou, Xin-Feng Li, Liang Zhao, Yin‐Shan Meng

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  23. Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

    Advanced Materials · 2025-09-16

    Sonia Martínez‐Giménez, Alejandro Orellana‐Silla, Marta Galbiati, Efrén Navarro‐Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio‐Giménez, Sergio Tatay, Carlos Martí‐Gastaldo

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  24. Reversible and Massive Structural Transformation in Meltable Cyanido‐bridged Coordination Polymer Crystals

    Chemistry - A European Journal · 2025-10-25

    Yuudai Iwai, Saaya Kimura, Manabu Nakaya, Takanori Nakane, Akihiro Kawamoto, Genji Kurisu, Yuta Tsuji, Kenji Hirai, Koji Kimoto, Ovidiu Cretu, Fumitaka Takeiri, Kunihisa Sugimoto, Benjamin Le Ouay, Masaaki Ohba, Ryo Ohtani

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  25. Anisotropic Thermal Expansion and Asymmetric Spin-Crossover Hysteresis in [Fe III 4 Fe II 2 ] Clusters Driven by Elastic Anisotropy

    Crystal Growth & Design · 2026-03-05

    Ren-He Zhou, Du-Yong Chen, Meng-Jia Shang, Tian Wang, Jingyi Xiao, Yin‐Shan Meng, Tao Liu

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  26. Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers

    Chemistry - A European Journal · 2026-05-08

    Haruka Yoshino, Kohei Yamagami, Yuki Imamura, Hirona Yamagishi, Sayuri Shimoda, Benjamin Le Ouay, Ryo Ohtani, Hitoshi Miyasaka, Masaaki Ohba

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