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RESEARCH PAPER · ACS Nano · 2020

Highly Crystalline Hollow Toroidal Copper Phosphosulfide via Anion Exchange: A Versatile Cation Exchange Nanoplatform

Yongju Hong, Taekyung Kim, Jinhyoung Jo, Byeongyoon Kim, Haneul Jin, Hionsuck Baik, Kwangyeol Lee

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Highly Crystalline Hollow Toroidal Copper Phosphosulfide via Anion Exchange: A Versatile Cation Exchange NanoplatformOriginalThe rational design of hierarchical CoS 2 /CuCo 2 S 4 for three-dimensional all-solid-state hybrid supercapacitors with high energy density, rate efficiency, and operational stability61Transformations of Ionic Nanocrystals via Full and Partial Ion Exchange Reactions75Novel core-shell CuMo-oxynitride@N-doped graphene nanohybrid as multifunctional catalysts for rechargeable zinc-air batteries and water splitting182Crystal structure dependent cation exchange reactions in Cu 2− x S nanoparticles16Sequential galvanic replacement mediated Pd-doped hollow Ru–Te nanorods for enhanced hydrogen evolution reaction mass activity in alkaline media16Two-dimensional copper based colloidal nanocrystals: synthesis and applications36Modulating the Local Coordination Environment of Single‐Atom Catalysts for Enhanced Catalytic Performance in Hydrogen/Oxygen Evolution Reaction129Successive Anion/Cation Exchange Enables the Fabrication of Hollow CuCo2S4 Nanorods for Advanced Oxygen Evolution Reaction Electrocatalysis19Chemical Fields: Directing Atom Migration in the Multiphasic Nanocrystal13Manipulating Cation Exchange Reactions in Cu 2– x S Nanoparticles via Crystal Structure Transformation13Transition‐metal‐incorporated molybdenum phosphide nanocatalysts synthesized through post‐synthetic transformation for the hydrogen evolution reaction12Galvanic replacement reaction to prepare catalytic materials27Regiospecific Cation Exchange in Nanocrystals and Its Potential in Diversifying the Nanostructural Library18Formation of Unprecedented Nanocrystals by Element Substitution Reactions0Engineering nickel phosphides for electrocatalytic hydrogen evolution: A doping perspective108Morphology Engineering in Multicomponent Hollow Metal Chalcogenide Nanoparticles27Region-Controlled Framework Interface Mediated Anion Exchange Chemical Transformation to Designed Metal Phosphosulfide Heteronanostructures10Constructing Fe‐N4 Sites through Anion Exchange‐mediated Transformation of Fe Coordination Environments in Hierarchical Carbon Support for Efficient Oxygen Reduction77Constructing Fe‐N4 Sites through Anion Exchange‐mediated Transformation of Fe Coordination Environments in Hierarchical Carbon Support for Efficient Oxygen Reduction11A multiple Kirkendall strategy for converting nanosized zero-valent iron to highly active Fenton-like catalyst for organics degradation159Controlled Surface Modification of Cobalt Phosphide with Sulfur Tunes Hydrogenation Catalysis25Pre-phase transition of a Cu 2− x S template enables polymorph selective synthesis of MS (M = Zn, Cd, Mn) nanocrystals via cation exchange reactions8Nanoporous CeO2-Decorated Cu-SmMn2O5 Composite Mullite Oxide Catalyst for Toluene Oxidation10Double‐Walled Tubular Heusler‐Type Platinum–Ruthenium Phosphide as All‐pH Hydrogen Evolution Reaction Catalyst Outperforming Platinum and Ruthenium41Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction26Copper Phosphosulfide Nanosheets on Cu-Coated Graphene Fibers as Asymmetric Supercapacitor Electrodes12Ru 2 P/Ir 2 P Heterostructure Promotes Hydrogen Spillover for Efficient Alkaline Hydrogen Evolution Reaction62Cation-exchange-induced structural and chemical modulation of transition metal spinel sulfides to enhance their oxygen evolution performance16Kirkendall Effect-Driven Reversible Chemical Transformation for Reconfigurable Nanocrystals32Anion-driven enabled functional nanomaterials from metal and metal oxide nanoparticles8Determinants of regioselectivity of heterostructures in cation exchange reactions9Anion-Exchange-Mediated Synthesis of Hollow 2D Layered Materials and Heterostructures: Mechanism and Room-Temperature Gas-Sensing Properties9Sustainable and selective upgrade of Cu(II) to High-Value HKUST-1 from acidic electroplating wastewater21Precise synthesis of hollow IrCu alloy nanoparticles for hydrogenation of substituted nitroaromatics8Se‐Assisted Modulation of Electronic Structure of Ruthenium Phosphide Nanotubes for Efficient Alkaline Hydrogen Evolution Reaction15A Novel Method for Continuous Deep Removal of Copper Citrate from Saline Wastewater: Synergy of Nano-Zirconium Loaded Resin and Optimized Electric Field0Electrocatalytic and Magnetic Properties of Porous Iron Phosphide Nanorods3Carbon disulfide-modified polyvinyl alcohol/sodium alginate adsorbent for removing Cu(II) from electroplating wastewaters1Tailoring metal-organic frameworks for water decontamination: From pore structure engineering to mechanistic insights2Cation-Exchange-Induced Enhanced Capacitive Performance of Ternary ZnCoNi Carbonate Hydroxides for High-Energy-Density Hybrid Supercapacitors0Elucidating TCE removal and process regulation in the 1O2-mediated S-nZVI/PMS system: Integrated contributions of S/Fe ratio and mineral phases0

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  1. The rational design of hierarchical CoS 2 /CuCo 2 S 4 for three-dimensional all-solid-state hybrid supercapacitors with high energy density, rate efficiency, and operational stability

    Sustainable Energy & Fuels · 2020-12-22

    Yogesh Kumar Sonia, Mahesh Kumar Paliwal, Sumanta Kumar Meher

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  2. Transformations of Ionic Nanocrystals via Full and Partial Ion Exchange Reactions

    Accounts of Chemical Research · 2021-02-03

    Masaki Saruyama, Ryota Sato, Toshiharu Teranishi

    Read original paper ↗ ·

  3. Novel core-shell CuMo-oxynitride@N-doped graphene nanohybrid as multifunctional catalysts for rechargeable zinc-air batteries and water splitting

    Nano Energy · 2021-03-18

    Jayaraman Balamurugan, Thanh Tuan Nguyen, Nam Hoon Kim, Do Hwan Kim, Joong Hee Lee

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  4. Crystal structure dependent cation exchange reactions in Cu 2− x S nanoparticles

    Nanoscale · 2022-01-01

    Lihui Chen, Zhenzhen Kong, Hengcong Tao, Haifeng Hu, Jing Gao, Guohua Li

    Read original paper ↗ ·

  5. Sequential galvanic replacement mediated Pd-doped hollow Ru–Te nanorods for enhanced hydrogen evolution reaction mass activity in alkaline media

    Nanoscale · 2022-01-01

    Hojung Ahn, Sanghyuk Cho, Jung Tae Park, Hongje Jang

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  6. Two-dimensional copper based colloidal nanocrystals: synthesis and applications

    Nanoscale · 2022-01-01

    Nilotpal Kapuria, Niraj Nitish Patil, Kevin Michael Ryan, Shalini Singh

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  7. Modulating the Local Coordination Environment of Single‐Atom Catalysts for Enhanced Catalytic Performance in Hydrogen/Oxygen Evolution Reaction

    Small · 2022-01-31

    Gracita M. Tomboc, Taekyung Kim, Sangmin Jung, Hyo Jae Yoon, Kwangyeol Lee

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  8. Successive Anion/Cation Exchange Enables the Fabrication of Hollow CuCo2S4 Nanorods for Advanced Oxygen Evolution Reaction Electrocatalysis

    Inorganic Chemistry · 2022-02-10

    Qing Wang, Hui Jie Xu, Xingyue Qian, Bingji Huang, Kun Wang, Lei Jin, Guangyu He, Haiqun Chen

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  9. Chemical Fields: Directing Atom Migration in the Multiphasic Nanocrystal

    Accounts of Chemical Research · 2022-03-09

    Minki Jun, Taehyun Kwon, Yunchang Son, Byeongyoon Kim, Kwangyeol Lee

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  10. Manipulating Cation Exchange Reactions in Cu 2– x S Nanoparticles via Crystal Structure Transformation

    Inorganic Chemistry · 2022-06-07

    Lihui Chen, Zhenzhen Kong, Haifeng Hu, Hengcong Tao, Yuhua Wang, Jing Gao, Guohua Li

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  11. Transition‐metal‐incorporated molybdenum phosphide nanocatalysts synthesized through post‐synthetic transformation for the hydrogen evolution reaction

    International Journal of Energy Research · 2022-07-13

    Minyoung Kim, Yoonsu Park, Taegyeom Lee, Yun‐Kun Hong, Don‐Hyung Ha

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  12. Galvanic replacement reaction to prepare catalytic materials

    Bulletin of the Korean Chemical Society · 2022-11-02

    Yongju Hong, Sandhya Venkateshalu, Sangyeon Jeong, Gracita M. Tomboc, Jinhyoung Jo, Jong‐Sik Park, Kwangyeol Lee

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  13. Regiospecific Cation Exchange in Nanocrystals and Its Potential in Diversifying the Nanostructural Library

    Small Science · 2022-12-03

    Yongju Hong, Sandhya Venkateshalu, Sangyeon Jeong, Jong‐Sik Park, Kwangyeol Lee

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  14. Formation of Unprecedented Nanocrystals by Element Substitution Reactions

    Bulletin of Japan Society of Coordination Chemistry · 2022-12-25

    Toshiharu Teranishi

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  15. Engineering nickel phosphides for electrocatalytic hydrogen evolution: A doping perspective

    Chemical Engineering Journal · 2023-02-13

    Lutfi Kurnianditia Putri, Boon‐Junn Ng, Ryan Yow Zhong Yeo, Wee‐Jun Ong, Abdul Rahman Mohamed, Siang‐Piao Chai

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  16. Morphology Engineering in Multicomponent Hollow Metal Chalcogenide Nanoparticles

    ACS Nano · 2023-02-17

    Bo Shen, Liliang Huang, Jiahong Shen, Xiaobing Hu, Peichen Zhong, Cindy Y. Zheng, Chris M. Wolverton, Chad Alexander Mirkin

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  17. Region-Controlled Framework Interface Mediated Anion Exchange Chemical Transformation to Designed Metal Phosphosulfide Heteronanostructures

    Nano Letters · 2023-05-01

    Wanhong Li, Hou‐Ming Xu, Lei Shi, Zheng Dong, Chao Gu, Shikui Han

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  18. Constructing Fe‐N4 Sites through Anion Exchange‐mediated Transformation of Fe Coordination Environments in Hierarchical Carbon Support for Efficient Oxygen Reduction

    Angewandte Chemie International Edition · 2023-08-04

    Lingbo Zong, Kaicai Fan, Lixiu Cui, Fenghong Lu, Porun Liu, Bin Li, Shouhua Feng, Lei Wang

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  19. Constructing Fe‐N4 Sites through Anion Exchange‐mediated Transformation of Fe Coordination Environments in Hierarchical Carbon Support for Efficient Oxygen Reduction

    Angewandte Chemie · 2023-08-04

    Lingbo Zong, Kaicai Fan, Lixiu Cui, Fenghong Lu, Porun Liu, Bin Li, Shouhua Feng, Lei Wang

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  20. A multiple Kirkendall strategy for converting nanosized zero-valent iron to highly active Fenton-like catalyst for organics degradation

    Proceedings of the National Academy of Sciences · 2023-09-19

    Jianhua Qu, Zhuoran Li, Fuxuan Bi, Xiubo Zhang, Bo Zhang, Kaige Li, Siqi Wang, Mingze Sun, Jun Ma, Ying Zhang

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  21. Controlled Surface Modification of Cobalt Phosphide with Sulfur Tunes Hydrogenation Catalysis

    Journal of the American Chemical Society · 2023-10-24

    Nina A. Arnosti, Vanessa Wyss, Murielle F. Delley

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  22. Pre-phase transition of a Cu 2− x S template enables polymorph selective synthesis of MS (M = Zn, Cd, Mn) nanocrystals via cation exchange reactions

    Nanoscale · 2023-12-08

    Yan Zhang, Shaobo He, Qingxia Zhang, Hong‐Tao Zhang, Jinchen Zhou, Xing Yang, Qinhong Wei, Lihui Chen

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  23. Nanoporous CeO2-Decorated Cu-SmMn2O5 Composite Mullite Oxide Catalyst for Toluene Oxidation

    ACS Applied Nano Materials · 2024-01-11

    Yaohui Dun, Xiangyu Ma, Yanfei Liu, Lihong Xie, Qingbo Wang, Aimin Zhang, Chun Du, Bin Shan

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  24. Double‐Walled Tubular Heusler‐Type Platinum–Ruthenium Phosphide as All‐pH Hydrogen Evolution Reaction Catalyst Outperforming Platinum and Ruthenium

    Advanced Energy Materials · 2024-02-02

    Yongju Hong, Seong Chan Cho, Soobean Kim, Haneul Jin, Jae Hun Seol, Tae Kyung Lee, Jong‐kyeong Ryu, Gracita M. Tomboc, Taekyung Kim, Hionsuck Baik, Changhyeok Choi, Jinhyoung Jo, Sangyeon Jeong, Eunsoo Lee, Yousung Jung, Docheon Ahn, Yong‐Tae Kim, Sung Jong Yoo, Sang Uck Lee, Kwangyeol Lee

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  25. Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

    Chemical Research in Chinese Universities · 2024-05-16

    Chengbin Wang, Ping Li, Dehong Chen, Ruiyong Zhang, Lei Wang, Lingbo Zong

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  26. Copper Phosphosulfide Nanosheets on Cu-Coated Graphene Fibers as Asymmetric Supercapacitor Electrodes

    ACS Applied Nano Materials · 2024-05-20

    Bing Bai, Jiaxin Shui, Yong Wang, Zhiqin Su, Linlin Qiu, Pingfan Du

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  27. Ru 2 P/Ir 2 P Heterostructure Promotes Hydrogen Spillover for Efficient Alkaline Hydrogen Evolution Reaction

    Advanced Energy Materials · 2024-05-25

    Yongju Hong, Sangyeon Jeong, Jae Hun Seol, Taekyung Kim, Seong Chan Cho, Tae Kyung Lee, Chaeyoen Yang, Hionsuck Baik, Hyun S. Park, Eunsoo Lee, Sung Jong Yoo, Sang Uck Lee, Kwangyeol Lee

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  28. Cation-exchange-induced structural and chemical modulation of transition metal spinel sulfides to enhance their oxygen evolution performance

    Chemical Engineering Journal · 2024-06-06

    Eunseo Hwang, Min-Young Kim, Wooseok Lee, Yoonsu Park, WooSeok Jeong, Yun Jae Hwang, Yeongbin Lee, Shinhyo Bang, Goohwan Kim, Liane M. Moreau, Hyungbin Son, Seoin Back, Don‐Hyung Ha

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  29. Kirkendall Effect-Driven Reversible Chemical Transformation for Reconfigurable Nanocrystals

    Journal of the American Chemical Society · 2024-10-25

    Hou‐Ming Xu, Chao Gu, Gang Wang, Pengfei Nan, Jian-Ding Zhang, Lei Shi, Shikui Han, Binghui Ge, Yang‐Gang Wang, Jun Li, Shu‐Hong Yu

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  30. Anion-driven enabled functional nanomaterials from metal and metal oxide nanoparticles

    Materials Today · 2024-11-07

    Yi Zhou, Jun Li, Long Liu, Cuifang Wang, Reilly P. Lynch, Bing Bai, Hsien‐Yi Hsu, Zongyou Yin, Andreu Cabot, Richard D. Robinson, Ido Hadar, Zongping Shao, Mark A. Buntine, Xuyong Yang, Guohua Jia

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  31. Determinants of regioselectivity of heterostructures in cation exchange reactions

    Chemical Science · 2024-12-12

    Xuelian Qu, Huisheng Zhang, Tianyi Gao, Fei Zhang, Ying Zhang, Ding‐Jiang Xue, Yang Liu

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  32. Anion-Exchange-Mediated Synthesis of Hollow 2D Layered Materials and Heterostructures: Mechanism and Room-Temperature Gas-Sensing Properties

    Chemistry of Materials · 2025-01-03

    Rajeev Kumar, Naveen Goyal, Deepak Sharma, Ranit Ram, Koushik Jagadish, Navakanta Bhat, Narayanan Ravishankar

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  33. Sustainable and selective upgrade of Cu(II) to High-Value HKUST-1 from acidic electroplating wastewater

    Chemical Engineering Journal · 2025-02-07

    Lin Ding, Qiang Wang, Yu Luo, Yu Luo, Yunxia Luo, Yunxia Luo, Wei Ren, Hui Shi, Penghui Shao, Xubiao Luo

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  34. Precise synthesis of hollow IrCu alloy nanoparticles for hydrogenation of substituted nitroaromatics

    Journal of Colloid and Interface Science · 2025-03-04

    Peijian Yan, Siyu Wang, LI Hong-xi, Jiuyuan Xu, Yali Jiang, Wei Yu, Ning Zhang, Xiangjin Kong, Shenghu Zhou

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  35. Se‐Assisted Modulation of Electronic Structure of Ruthenium Phosphide Nanotubes for Efficient Alkaline Hydrogen Evolution Reaction

    Small Science · 2025-03-13

    Yongju Hong, Eunsoo Lee, Jae Hun Seol, Tae Kyung Lee, Songa Choi, Seong Chan Cho, Taekyung Kim, Hionsuck Baik, Sangyeon Jeong, Sung Jong Yoo, Sang Uck Lee, Kwangyeol Lee

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  36. A Novel Method for Continuous Deep Removal of Copper Citrate from Saline Wastewater: Synergy of Nano-Zirconium Loaded Resin and Optimized Electric Field

    ACS ES&T Water · 2025-10-22

    Xin Li, Yongyan Zhou, Lu Lv, Weiming Zhang, Bingcai Pan, Ming Hua

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  37. Electrocatalytic and Magnetic Properties of Porous Iron Phosphide Nanorods

    ACS Applied Energy Materials · 2025-11-05

    Shubham Kumar Sharma, Sharad Puri, Resham Shrestha, David N. McIlroy, Julius de Rojas, A. Kaan Kalkan, Yolanda Vasquez

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  38. Carbon disulfide-modified polyvinyl alcohol/sodium alginate adsorbent for removing Cu(II) from electroplating wastewaters

    Desalination and Water Treatment · 2026-03-11

    Heyuan Zhang, Cuiling Zhang, Changchun Deng, Ningyi Yang, Saihua Dai, Haiping Luo, Wenbo Huang

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  39. Tailoring metal-organic frameworks for water decontamination: From pore structure engineering to mechanistic insights

    Journal of environmental chemical engineering · 2026-04-12

    Chang Sun, Yandi Wang, Zhengying Chang, Zixuan Ma, Wen Yao, Zhongshan Chen

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  40. Cation-Exchange-Induced Enhanced Capacitive Performance of Ternary ZnCoNi Carbonate Hydroxides for High-Energy-Density Hybrid Supercapacitors

    Langmuir · 2026-05-19

    Shuqing Liao, Qingqing Wu, Xuehan Yu, Bifeng Wang, Xuetang Xu, Fan Wang

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  41. Elucidating TCE removal and process regulation in the 1O2-mediated S-nZVI/PMS system: Integrated contributions of S/Fe ratio and mineral phases

    Journal of environmental chemical engineering · 2026-09-09

    Yan Xu, Huixiang Xu

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