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RESEARCH PAPER · ACS Central Science · 2020

Facet-Specific Photocatalytic Activity Enhancement of Cu2O Polyhedra Functionalized with 4-Ethynylanaline Resulting from Band Structure Tuning

Tzu-Ning Chen, Jui‐Cheng Kao, Xin-Yan Zhong, Shang-Ju Chan, Anindya Sundar Patra, Yu-Chieh Lo, Michael H. Huang

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Facet-Specific Photocatalytic Activity Enhancement of Cu2O Polyhedra Functionalized with 4-Ethynylanaline Resulting from Band Structure TuningOriginalA review: Synthesis, modification and photocatalytic applications of ZnIn2S4359Well-defined Cu 2 O photocatalysts for solar fuels and chemicals175Formation of size-tunable CuI tetrahedra showing small band gap variation and high catalytic performance towards click reactions18Novel Structures and Applications of Graphene-Based Semiconductor Photocatalysts: Faceted Particles, Photonic Crystals, Antimicrobial and Magnetic Properties26Inactive Cu2O Cubes Become Highly Photocatalytically Active with Ag2S Deposition68Single-Particle Imaging of Anion Exchange Reactions in Cuprous Oxide9Defective cuprous oxide as a selective surface‐enhanced Raman scattering sensor of dye adulteration in Chinese herbal medicines22Facile synthesis of Cu2O/TiO2 (P25) composites with enhanced photocatalytic H2 evolution activity11Benzylic Csp3–H Bond Oxidation on the (111) Facets of Octahedral Cu2O Nanocrystals10Effect of aqueous inorganic anions on the photocatalytic activity of CuO–Cu2O nanocomposite on MB and MO dyes degradation1404-Nitrophenylacetylene-modified Cu 2 O cubes and rhombic dodecahedra showing superior photocatalytic activity through surface band structure modulation17Elucidating Facet Dependent Electronic and Electrochemical Properties of Cu2o Nanocrystals Using Afm/Scem and Dft43Facet-controlled synthesis and morphological evolution of Cu 2 O microcrystals11Facet-dependent electrical conductivity properties of a 4H-SiC wafer38Morphological evolution of cadmium oxide crystals showing color changes and facet-dependent conductivity behavior29P25-induced polydopamine conformal assembly on Cu 2 O polyhedra for hydrophilic and stable photoelectrochemical performance3Photocatalytic activity enhancement of Cu 2 O cubes functionalized with 2-ethynyl-6-methoxynaphthalene through band structure modulation27ZnIn2S4 and ZnIn2S4 based advanced hybrid materials: Structure, morphology and applications in environment and energy87Surface facets dependent oxygen evolution reaction of single Cu2O nanoparticles48Improving the p–type conductivity of Cu2O thin films by Ni doping and their heterojunction with n–ZnO22Surface-Terminated Hydroxyl Groups for Deciphering the Facet-Dependent Photocatalysis of Anatase TiO246Simultaneously tailor band structure and accelerate charge separation by constructing novel In(OH)3-TiO2 heterojunction for enhanced photocatalytic water reduction14Integrated p-n/Schottky junctions for efficient photocatalytic hydrogen evolution upon Cu@TiO2-Cu2O ternary hybrids with steering charge transfer156Origin and manifestation of semiconductor facet effects11Single-particle exciton-initiated photo-catalytic reaction mapping on defective cuprous oxide6Crystal Facet Dependent Energy Band Structures of Polyhedral Cu 2 O Nanocrystals and Their Application in Solar Fuel Production25Differentiating the {100} surfaces of Cu2O nanocrystals from {111} and {110} for benzylic Csp3-H bond oxidation: Oxidations of diphenyl methane to benzophenone and cumene to cumene hydroperoxide under mild conditions12Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface56Sunlight-driven photocatalytic oxidation of 5-hydroxymethylfurfural over a cuprous oxide-anatase heterostructure in aqueous phase74Oscillatory Reaction Activity of Single Cuprous Oxide Microparticles with NO21Cu2O/SrTi1–xCrxO3 Heterojunction Photocatalyst for the Efficient Degradation of Isopropanol under Visible Light Irradiation6Photocatalytic activity enhancement with 4-cyanophenylacetylene-modified Cu2O cubes and rhombic dodecahedra and use in arylboronic acid hydroxylation16Photocatalytic oxidative amine coupling using polyhedral SrTiO 3 crystals14Size- and facet-dependent photoelectrochemical properties of Cu 2 O crystals32Photocatalytic Aryl Sulfide Oxidation Using 4-Nitrophenylacetylene-Modified Cu 2 O Crystals31Aqueous Phase Photocatalytic Hydroxylation of Arylboronic Acids Using Polyhedral Cu2O Crystals23Optimization of p-Type Cu2O Nanocube Photocatalysts Based on Electronic Effects36Carbon Nitrides from Supramolecular Crystals: From Single Atoms to Heterojunctions and Advanced Photoelectrodes11Using adatoms to tune the band structures of Cu2O surfaces for photocatalytic applications20Photocatalytic Oxidative Amine Coupling with 4-Nitrophenylacetylene-Modified Cu2O Polyhedra46Multiple Strategies Enhance Visible-Light Photocatalytic Degradation Levofloxacin of Fe-Doped Mof/Agcl Z-Scheme Heterojunction Composites Based on Pyrazole Carboxylic Ligand0Performance Enhancement Through the Interface Passivation Effect of Potassium Hydrogen Phthalate in Perovskite Solar Cells0Photocatalytic activity enhancement with 4-trifluoromethylphenylacetylene-functionalized Cu 2 O cubes and rhombic dodecahedra from band structure modulation and use in boronic acid hydroxylation11Photocatalyzed dimethylacrylamide polymerization in an aqueous solution using 4-nitrophenylacetylene-modified Cu 2 O crystals7Density‐Functional Theory Studies on Photocatalysis and Photoelectrocatalysis: Challenges and Opportunities77Embedding ZnCo2O4 quantum dots onto graphdiyne (g-CnH2n-2) nanosheets as a 0D/2D S-scheme heterojunction for highly efficient photocatalytic H2 evolution24In Situ Synthesis of Cu2O Nanoparticles Using Eucalyptus globulus Extract to Remove a Dye via Advanced Oxidation6Biogenic Synthesis Based on Cuprous Oxide Nanoparticles Using Eucalyptus globulus Extracts and Its Effectiveness for Removal of Recalcitrant Compounds2Metallic engineering in metal-porphyrin frameworks for highly efficient CO2 photoreduction10Heterostructured S-Scheme BiOBr/Cu2O Nanocomposite for Photocatalytic Degradation of Glyphosate11Highly efficient stable pyroglutamic acid-modified Cu2O/Cu catalysts with reconstruction-resistant interfaces for CO2-to-C2 conversion at high current density21Surface Functionalization of Cu2O Polyhedra with Different Halide-Substituted Phenylacetylenes for Photocatalytic Activity Comparison8Orientational-growth of Cu2O {111} or {110} facets induced by frustules for CO2-H2O specific photo(electro)chemical conversion into methanol/ethanol under visible-light4Sonoamplified catalytic activation of potassium peroxydisulfate on the Ti2AlC MAX phase for the removal of pharmaceutical contaminants9Enhanced Photocatalytic Performance of Halogenated Phenylacetylene-Decorated Cu2O Surfaces via Electronic Structure Modulation: A DFT and Experimental Study3Work-function-mediated unidirectional charge flow enables 139-fold enhanced photocatalytic hydrogen evolution on g-C3N47Enhanced perovskite solar cells using Co3O4/NiOX composite hole transport layers for air-stable fabrication1Fabrication of Cu/Cu2O nanoparticles by banana peel extract for 4-nitrophenol degradation1Ligand-field engineered NiCo2O4 hole transport layers: defect suppression and efficiency enhancement in all-inorganic perovskite solar cells0Rational synthesis of Cu/Cu2O/Ag nanomaterials to develop photoelectrochemical and SERS dual-signal sensors for reliable and accurate quantitative determination of pesticide residues0Synergistic Schottky and blackbody effects in Au-Cu2O Janus structures for highly efficient photocatalytic CO2 reduction0

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  2. Well-defined Cu 2 O photocatalysts for solar fuels and chemicals

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  3. Formation of size-tunable CuI tetrahedra showing small band gap variation and high catalytic performance towards click reactions

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  4. Novel Structures and Applications of Graphene-Based Semiconductor Photocatalysts: Faceted Particles, Photonic Crystals, Antimicrobial and Magnetic Properties

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  5. Inactive Cu2O Cubes Become Highly Photocatalytically Active with Ag2S Deposition

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  6. Single-Particle Imaging of Anion Exchange Reactions in Cuprous Oxide

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  7. Defective cuprous oxide as a selective surface‐enhanced Raman scattering sensor of dye adulteration in Chinese herbal medicines

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  8. Facile synthesis of Cu2O/TiO2 (P25) composites with enhanced photocatalytic H2 evolution activity

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  9. Benzylic Csp3–H Bond Oxidation on the (111) Facets of Octahedral Cu2O Nanocrystals

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  10. Effect of aqueous inorganic anions on the photocatalytic activity of CuO–Cu2O nanocomposite on MB and MO dyes degradation

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  11. 4-Nitrophenylacetylene-modified Cu 2 O cubes and rhombic dodecahedra showing superior photocatalytic activity through surface band structure modulation

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  12. Elucidating Facet Dependent Electronic and Electrochemical Properties of Cu2o Nanocrystals Using Afm/Scem and Dft

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  13. Facet-controlled synthesis and morphological evolution of Cu 2 O microcrystals

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  14. Facet-dependent electrical conductivity properties of a 4H-SiC wafer

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  15. Morphological evolution of cadmium oxide crystals showing color changes and facet-dependent conductivity behavior

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  16. P25-induced polydopamine conformal assembly on Cu 2 O polyhedra for hydrophilic and stable photoelectrochemical performance

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  17. Photocatalytic activity enhancement of Cu 2 O cubes functionalized with 2-ethynyl-6-methoxynaphthalene through band structure modulation

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  18. ZnIn2S4 and ZnIn2S4 based advanced hybrid materials: Structure, morphology and applications in environment and energy

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  19. Surface facets dependent oxygen evolution reaction of single Cu2O nanoparticles

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  20. Improving the p–type conductivity of Cu2O thin films by Ni doping and their heterojunction with n–ZnO

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  22. Simultaneously tailor band structure and accelerate charge separation by constructing novel In(OH)3-TiO2 heterojunction for enhanced photocatalytic water reduction

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  23. Integrated p-n/Schottky junctions for efficient photocatalytic hydrogen evolution upon Cu@TiO2-Cu2O ternary hybrids with steering charge transfer

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