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RESEARCH PAPER · ACS Applied Energy Materials · 2020

Investigation on Cu2O Surface Reconstruction and Catalytic Performance of NH3-SCO by Experimental and DFT Studies

Xiaoyu Zhang, Hui Wang, Linlin Meng, Xiaowa Nie, Zhenping Qu

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Investigation on Cu2O Surface Reconstruction and Catalytic Performance of NH3-SCO by Experimental and DFT StudiesOriginalFirst principles probes of electronic and optical behaviours of zinc doped cuprous oxide for catalysis applications8A facile strategy for synthesis of porous Cu 2 O nanospheres and application as nanozymes in colorimetric biosensing37Adsorption and photocatalytic performance of Au nanoparticles decorated porous Cu2O nanospheres under simulated solar light irradiation62New insights into the NH 3 -selective catalytic reduction of NO over Cu-ZSM-5 as revealed by operando spectroscopy20Rationally Engineered Reox -Cuso4/Tio2 Catalyst with Superior Nh3-Sco Efficiency and Remarkably Boosted So2 Tolerance: Synergy of Acid Sites and Surface Adsorbed Oxygen72Investigation of the promotion effect of Mo doped CuO catalysts for the low-temperature performance of NH3-SCR reaction55Unraveling the Promotion Effects of Dynamically Constructed CuO x -OH Interfacial Sites in the Selective Catalytic Oxidation of Ammonia93A Copper-Based Biosensor for Dual-Mode Glucose Detection17Interface Molecular Functionalization of Cu 2 O for Synchronous Electrocatalytic Generation of Formate27Surface/Lattice Oxygen Synergism of Durable CuO Catalysts for Tandem Dehydrogenation–Oxidation of Glycerol to Carboxylic Acids in Oxygen-Free Medium6Surface Oxidation of Cu2O Nanoparticles by Adsorbed Ammonia3Origin of Ammonia Selective Oxidation Activity of SmMn2O5 Mullite: A First-Principles-Based Microkinetic Study12Construction of CuO/CeO 2 Catalysts via the Ceria Shape Effect for Selective Catalytic Oxidation of Ammonia296Multifunctional hierarchical tree-like ZnO@CuxO mesh for oily wastewater treatment9Unraveling the effect of surfactant on the preparation of 40 nm Cu2O nanofluids for enhanced thermal conductivity6Insight into the low-temperature DeNOx performance of copper-based oxides: Perspective from the valence state distribution22Unraveling the Lattice O Assisted Internal Selective Catalytic Reduction Mechanism on High N2 Selectivity of CuOx/PtCu Catalysts in NH3-SCO69Low-temperature NH3 abatement via selective oxidation over a supported copper catalyst with high Cu+ abundance10Fabrication of highly dispersed carbon doped Cu-based oxides as superior selective catalytic oxidation of ammonia catalysts via employing citric acid-modified carbon nanotubes doping CuAl-LDHs4A photoelectrochemical sensor for Hg2+ detection with enhanced cathodic photocurrent via BiOI/Bi2S3 photoanode of self-sacrifice10Reasonable design of Sm-modified Cu-based catalyst for NH3-SCO: Role of the amide intermediates47Artificial Neural Network-Based Prediction and Morphological Evolution of Cu2O Crystal Surface Energy5Review of the Catalytic System, Synthetic Process, and Support Morphological Research in Selective Catalytic Oxidation of Ammonia20Nh3-Sco Performance-Boosting for Ag-Based Catalysts at Low Temperature: Insight into Ldhs-Derived Mgal-Ldo with Low Ag Loading0Novel insights for simultaneous NOx and CO Removal: Cu+-Sm3+-Ov-Ti4+ asymmetric active site promoting NH3-SCR coupled with CO oxidation reaction58Progress of ammonia selective catalytic oxidation research and performance improvement strategy16Temperature-driven dynamic evolution process of Ag species on silver-loaded Zr0.2Sn0.8O2 catalyst for selective catalytic oxidation of ammonia12Insight into the performance-boosting mechanism of Ag/MgAlOx for NH3 selective catalytic oxidation: Perspective from the support crystalline phase structures18Removing ammonia from exhaust gas through selective catalytic oxidation reaction: Research status and future perspectives15Unraveling the Mechanistic Origin of High N 2 Selectivity in Ammonia Selective Catalytic Oxidation on CuO-Based Catalyst32Influence of Catalyst Structural Remodelling on The Performance of NH3‐SCR Reactions: A Mini Review9Redox-acidity dual modification of CuO by niobium-incorporation for enhanced selective catalytic oxidation of NH312Investigation of the NH3-SCO performance and reaction mechanism of Ag/ZnAlOx catalysts derived from LDHs0NH3-SCO performance-boosting for Ag-based catalysts at low temperature: Insight into LDHs-derived MgAl-LDO with low Ag loading12Plasma-enhanced low-temperature SCO of NH3 over Cu-Mn/SAPO-34 catalyst under oxygen-rich conditions2Modification of the W/CeZrO x Catalyst with Transition Metal Cu for Selective Catalytic Oxidation of NH 33Enhancing NH3-SCO performance of Ag-based catalysts via the optimization of MgAl supports derived from LDHs1Study on the effect of metal synergy on Ag/TiO2 catalyst for low-temperature selective catalytic oxidation of ammonia2Unlocking the Potential of Isolated Pt Atoms for NH3–SCO Reactions via Modulating Orbital Coupling in Heteroatom Ensembles12In-situ impedance-infrared spectroscopy reveals the role of Brønsted acid sites in NO reduction during high-concentration NH3 combustion0Rational design strategy for high-performance NH3-SCO catalysts: Synergy of acid sites and surface adsorbed oxygen on Ru/CeSnO -S catalyst6Tandem confinement of sub-nanometer Pt–Cu sites in USY zeolite enables high NH3-SCO selectivity across an ultra-wide temperature window3Tuning the Surface State and Zeta Potential of Aged CuO Nanoparticles by Additive‐Free Surface Treatments as Guided by XPS20Facile Sulfation strategy for acidity modulation of Ru/CeO2 catalysts toward improved N2 selectivity in NH3-SCO reaction0Self-adaptive synchronous modulation of multi-junctions within immobilized CuOx mesh for durable photocatalysis-coupled sulfite-based AOPs2Influence of Pt-Cu synergistic action and TiO2 core–shell structure on NH3-SCO and anti-aging performance1Sm-induced modulation of active Cu species and amide intermediates over Cu/ZSM-5 for enhanced low-temperature NH3-SCO performance2Breakthroughs in low-loading Ag catalysis for NH3-SCO: Dimension engineering of metal-support interaction regulates elementary steps0Interfacial Active-Oxygen Transport in Inverse CuO x /Perovskite Catalysts for Low-Temperature CO Oxidation0Surfactantless Electrophoretic Deposition of Nonaqueous CuO Nanoparticle Dispersions by Tailoring Their Surface Defectiveness0

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  2. A facile strategy for synthesis of porous Cu 2 O nanospheres and application as nanozymes in colorimetric biosensing

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  3. Adsorption and photocatalytic performance of Au nanoparticles decorated porous Cu2O nanospheres under simulated solar light irradiation

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  4. New insights into the NH 3 -selective catalytic reduction of NO over Cu-ZSM-5 as revealed by operando spectroscopy

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  6. Investigation of the promotion effect of Mo doped CuO catalysts for the low-temperature performance of NH3-SCR reaction

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  7. Unraveling the Promotion Effects of Dynamically Constructed CuO x -OH Interfacial Sites in the Selective Catalytic Oxidation of Ammonia

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  8. A Copper-Based Biosensor for Dual-Mode Glucose Detection

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  9. Interface Molecular Functionalization of Cu 2 O for Synchronous Electrocatalytic Generation of Formate

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  10. Surface/Lattice Oxygen Synergism of Durable CuO Catalysts for Tandem Dehydrogenation–Oxidation of Glycerol to Carboxylic Acids in Oxygen-Free Medium

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  11. Surface Oxidation of Cu2O Nanoparticles by Adsorbed Ammonia

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  12. Origin of Ammonia Selective Oxidation Activity of SmMn2O5 Mullite: A First-Principles-Based Microkinetic Study

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  13. Construction of CuO/CeO 2 Catalysts via the Ceria Shape Effect for Selective Catalytic Oxidation of Ammonia

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  14. Multifunctional hierarchical tree-like ZnO@CuxO mesh for oily wastewater treatment

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  15. Unraveling the effect of surfactant on the preparation of 40 nm Cu2O nanofluids for enhanced thermal conductivity

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  16. Insight into the low-temperature DeNOx performance of copper-based oxides: Perspective from the valence state distribution

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  17. Unraveling the Lattice O Assisted Internal Selective Catalytic Reduction Mechanism on High N2 Selectivity of CuOx/PtCu Catalysts in NH3-SCO

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  18. Low-temperature NH3 abatement via selective oxidation over a supported copper catalyst with high Cu+ abundance

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  19. Fabrication of highly dispersed carbon doped Cu-based oxides as superior selective catalytic oxidation of ammonia catalysts via employing citric acid-modified carbon nanotubes doping CuAl-LDHs

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  21. Reasonable design of Sm-modified Cu-based catalyst for NH3-SCO: Role of the amide intermediates

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  23. Review of the Catalytic System, Synthetic Process, and Support Morphological Research in Selective Catalytic Oxidation of Ammonia

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