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RESEARCH PAPER · ACS Catalysis · 2020

Highly Selective Catalysts for the Hydrogenation of Unsaturated Aldehydes: A Review

Xiaocheng Lan, Tiefeng Wang

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Highly Selective Catalysts for the Hydrogenation of Unsaturated Aldehydes: A ReviewOriginalA sustainable natural nanofibrous confinement strategy to obtain ultrafine Co 3 O 4 nanocatalysts embedded in N-enriched carbon fibers for efficient biomass-derivative in situ hydrogenation14Layered double hydroxide derived NiAl-oxide hollow nanospheres for selective transfer hydrogenation with improved stability21Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols79Pd catalysts supported on dual-pore monolithic silica beads for chemoselective hydrogenation under batch and flow reaction conditions10Synthesis of Intermetallic Pt-Based Catalysts by Lithium Naphthalenide-Driven Reduction for Selective Hydrogenation of Cinnamaldehyde44Recent Progress in Continuous‐Flow Hydrogenation89Synthesis of Pt@MAF-6 as a Steric Effect Catalyst for Selective Hydrogenation of Cinnamaldehyde23Electrocatalytic hydrogenation of cinnamaldehyde in a PEM cell: The role of sodium hydroxide and platinum loading15MOF-derived AgCo alloy nanoparticle protected by mesoporous carbon as chemoselective catalyst for hydrogenation of citral27NiBi intermetallic compounds catalyst toward selective hydrogenation of unsaturated aldehydes118ZrO2-x modified Cu nanocatalysts with synergistic catalysis towards carbon-oxygen bond hydrogenation146Au 3 Pd 1 Nanodendrites with Hyperbranched Architectures: Green Synthesis at Room Temperature and Highly Selective Hydrogenation for 4-Nitrophenylacetylene25One-pot production of dioctyl ether from 1,2-octanediol over rutile-titania-supported palladium-tungsten catalyst1Guidelines to Achieving High Selectivity for the Hydrogenation of α,β-Unsaturated Aldehydes with Bimetallic and Dilute Alloy Catalysts: A Review286Hydrogenation on Palladium Nanoparticles Supported by Graphene Nanoplatelets26Differentiation of Pt−Fe and Pt−Ni3 Surface Catalytic Mechanisms towards Contrasting Products in Chemoselective Hydrogenation of α,β‐Unsaturated Aldehydes21Chemoselective hydrogenation of α,β-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP15Metal-Free Ceria Catalysis for Selective Hydrogenation of Crotonaldehyde116Synergistic effect between Ni single atoms and acid–base sites: Mechanism investigation into catalytic transfer hydrogenation reaction63Efficient single-atom Ni for catalytic transfer hydrogenation of furfural to furfuryl alcohol169Selective Hydrogenation on a Highly Active Single-Atom Catalyst of Palladium Dispersed on Ceria Nanorods by Defect Engineering57Pt–Carbon interaction-determined reaction pathway and selectivity for hydrogenation of 5-hydroxymethylfurfural over carbon supported Pt catalysts44Synergy of steric, electronic, and bifunctional effects for the design of highly selective metal catalysts promoted by non-metallic elements0Selective Hydrogenation of C=C bond in Cinnamaldehyde on Pd Step Sites of Pd/Al2O34Chemoselective hydrogenation of cinnamaldehyde over a tailored oxygen-vacancy-rich Pd@ZrO 2 catalyst24Factors controlling oxophilicity and carbophilicity of transition metals and main group metals69Hydrogenation of pentenal over supported Pt nanoparticles: influence of Lewis-acid sites in the conversion pathway10Indirect reduction of CO2and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes73Metal-doped mesoporous ZrO 2 catalyzed chemoselective synthesis of allylic alcohols from Meerwein–Ponndorf–Verley reduction of α,β-unsaturated aldehydes17Engineering the interface of Au nanocatalysts with FeOx for enhanced selective hydrogenation of cinnamaldehyde14Highly Selective Catalysis at the Liquid–Liquid Interface Microregion56Tracking the chemical active species to unravel the photocatalytic activity evolution of structure modified polymeric carbon nitride2Direct Heterogenization of the Ru-Macho Catalyst for the Chemoselective Hydrogenation of α,β-Unsaturated Carbonyl Compounds39Rationally Constructing A Nano MOF-Derived Ni and CQD Embedded N-Doped Carbon Nanosphere for the Hydrogenation of Petroleum Resin at Low Temperature59Adsorption of crotonaldehyde on metal surfaces: Cu vs Pt17Edge‐Confined Pt1/MoS2 Single‐Atom Catalyst Promoting the Selective Activation of Carbon‐Oxygen Bond35Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands16Highly Selective Vapor and Liquid Phase Transfer Hydrogenation of Diaryl and Polycyclic Ketones with Secondary Alcohols in the Presence of Magnesium Oxide as Catalyst6Chemoselective NADH Regeneration: the Synergy Effect of TiOx and Pt in NAD+ Hydrogenation47Heterogeneous additive‐free highly selective synthesis of 2,5‐bis(hydroxymethyl)furan over catalysts with ultra‐low Pt content18Nanoglobular carbon and palladium–nanoglobular carbon catalysts for liquid-phase hydrogenation of organic compounds26Perspectives on Multifunctional Catalysts Derived from Layered Double Hydroxides toward Upgrading Reactions of Biomass Resources85Mechanistic Insights into the Selective Electroreduction of Crotonaldehyde to Crotyl Alcohol and 1‐Butanol15Boosting selective hydrogenation through hydrogen spillover on supported-metal catalysts at room temperature127Low-Temperature Synthesis of Single Palladium Atoms Supported on Defective Hexagonal Boron Nitride Nanosheet for Chemoselective Hydrogenation of Cinnamaldehyde122The effects of TiO2 crystal-plane-dependent Ir-TiO interactions on the selective hydrogenation of crotonaldehyde over Ir/TiO2 catalysts18Hydrogenation of Cinnamaldehyde on Cu(110) Single-Crystal Surfaces13Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis369Rhenium – A Tuneable Player in Tailored Hydrogenation Catalysis67Cinnamaldehyde adsorption and thermal decomposition on copper surfaces6Highly selective synthesis of citronellal in water at multigram scale by Pd nanoparticles-catalyzed hydrogenation of citral0Identification and Insight into the Role of Ultrathin LDH‐Induced Dual‐Interface Sites for Selective Cinnamaldehyde Hydrogenation9The Roles of Precursor-Induced Metal–Support Interaction on the Selective Hydrogenation of Crotonaldehyde over Ir/TiO2 Catalysts5Spatial Location and Microenvironment Engineering of Pt-CeO2 Nanoreactors for Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol24Advances in Electrochemical Hydrogenation Since 201089Catalytic Activity of High-Surface-Area Amorphous MgO Obtained from Upsalite5Insight into the role of iron in platinum-based bimetallic catalysts for selective hydrogenation of cinnamaldehyde12Zeolite-Encaged Isolated Platinum Ions Enable Heterolytic Dihydrogen Activation and Selective Hydrogenations196Model Catalysis with HOPG-Supported Pd Nanoparticles and Pd Foil: XPS, STM and C2H4 Hydrogenation12Single palladium atoms stabilized by β-FeOOH nanorod with superior performance for selective hydrogenation of cinnamaldehyde49Defect engineering and spilt-over hydrogen in Pt/(WO 3 –TH 2 ) for selective hydrogenation of CO bonds7Direct conversion of glycerol to n -propanol over a tandem catalytic dehydration–hydrogenation system7Efficient electrocatalytic hydrogenation of cinnamaldehyde to value-added chemicals35Efficiently Catalytic Transfer Hydrogenation and Fast Separation of Unsaturated Alkene Compounds Over Pd/Uio-66 Under Green Conditions20Exploring the Zn-regulated function in Co–Zn catalysts for efficient hydrogenation of ethyl levulinate to γ-valerolactone20Fe 2 O 3 supported Pt single atom catalysts for the selective hydrogenation of cinnamaldehyde8Highly active heterogeneous hydrogenation catalysts prepared from cobalt complexes and rice husk waste14Inert metal induces the modulation of unsaturated aldehyde absorption mode for enhanced selective hydrogenation9Microenvironment engineering of supported metal nanoparticles for chemoselective hydrogenation27Ni@C catalyzed hydrogenation of acetophenone to phenylethanol under industrial mild conditions in a flow reactor10Oxygen vacancy regulated selective hydrogenation of α,β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts17Pdru Nanocages as the Switcher for the Production of Hydrogenation Reaction Toward 4-Nitrostyrene0Photo Enhanced Catalytic Activity for Hydrogenation of Nitrobenzene Over Pt-Au/Tio2 Heterojunction9Semi-hydrogenation of α,β-unsaturated aldehydes over sandwich-structured nanocatalysts prepared by phase transformation of thin-film Al 2 O 3 to Al-TCPP13Studies of adsorption of α,β-unsaturated carbonyl compounds on heterogeneous Au/CeO 2 , Au/TiO 2 and Au/SiO 2 catalysts during reduction by hydrogen3Vapor-phase hydrothermal construction of defective MoS 2 for highly selective electrocatalytic hydrogenation of cinnamaldehyde8Synthesis of aluminum doped MIL-100(Fe) compounds for the one-pot photocatalytic conversion of cinnamaldehyde and benzyl alcohol to the corresponding alcohol and aldehyde under anaerobic conditions28Insights into the interfacial effects in Cu-Co/CeOx catalysts on hydrogenolysis of 5-hydroxymethylfurfural to biofuel 2,5-dimethylfuran59Highly stable Pt–Co bimetallic catalysts prepared by atomic layer deposition for selective hydrogenation of cinnamaldehyde11Synergistic effects of PtFe/CeO2 catalysts afford high catalytic performance in selective hydrogenation of cinnamaldehyde28Cu–Ga 2 O 3 nanoparticles supported on ordered mesoporous silica for the catalytic hydrogenation of cinnamaldehyde1High‐Performance Heterogeneous Thermocatalysis Caused by Catalyst Wettability Regulation13Epsilon Cobalt Nanoparticles as Highly Performant Catalysts in Cinnamaldehyde Selective Hydrogenation13Precise control of selective hydrogenation of α,β-unsaturated aldehydes in water mediated by ammonia borane19Selective photocatalytic hydrogenation of citral over pure TiO 2 nanoparticle5Highly Selective and Multigram Hydrogenation of Citral into Citronellal by Palladium Nanoparticles in Water11Pickering Emulsion Catalysis: Interfacial Chemistry, Catalyst Design, Challenges, and Perspectives63Pickering Emulsion Catalysis: Interfacial Chemistry, Catalyst Design, Challenges, and Perspectives223Chemoselective hydrogenation of cinnamaldehyde over amorphous coordination polymer supported Pt-Co bimetallic nanocatalyst8Synergetic effect of Cu0 −Cu+ derived from layered double hydroxides toward catalytic transfer hydrogenation reaction163Influence of the defects on selective hydrogenation of cinnamaldehyde to cinnamyl alcohol over UiO-66 supported Pt catalysts14Geometrically embedding dispersive Pt nanoparticles within silicalite-1 framework for highly selective ɑ, β-unsaturated aldehydes hydrogenation via oriented C = O adsorption configuration36Dual Interface Synergistic Catalysis: The Selective Hydrogenation of Crotonaldehyde Over Pt/Co3O4@PDA6Breaking the Activity-Selectivity Trade-Off of Pt Nanoparticles Encapsulated in UiO-66 for Hydrogenation by Constructing Suitable Hierarchical Structure30Engineering electrophilic atomic Ir sites on CeO2 colloidal spheres for selectivity control in hydrogenation of α,β-unsaturated carbonyl compounds17CuO–Ru0.3@Co3O4 nanocomposites act as a tandem catalyst for dehydrogenation of ammonia borane and hydrogenation of nitrobenezene8Combining shell confinement and outside decoration to boost the selectivity of Pt nanocatalysts in hollow-flower like Zr-MOFs double shell micro-reactor for hydrogenation cinnamaldehyde to unsaturated alcohol38High-Performance Ni 3 P Catalyst for C═O Hydrogenation of Ethyl Levulinate: Ni δ+ as Outstanding Adsorption Sites65Synthesis of Dual-Active-Sites Ni-Ni2In catalysts for selective hydrogenation of furfural to furfuryl alcohol41Exploring the confined space and active sites of Ni@OCNTs catalyst for chemoselective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde20Selective Hydrogenation of Crotonaldehyde on SiO2‐Supported Pt Clusters: A DFT Study4Tuning electrochemical environment enables unexpected C=O selectivity for cinnamaldehyde hydrogenation over self-standing palladium cathode6Excellent chemoselective hydrogenation of nitroaromatics and unsaturated aldehyde at the confined silver nanospace10Improving selective hydrogenation of carbonyls bond in α, β-unsaturated aldehydes over Pt nanoparticles encaged within the amines-functionalized MIL-101-NH233Single Atom Catalysts in Liquid Phase Selective Hydrogenations9The importance of interdiscipline in heterogeneous asymmetric catalysis10Hydrogenation and hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran via synergistic catalysis of Ni2In and acid-base sites35Photocatalytic selective hydrogenation of α,β-unsaturated aldehydes over oxygen vacancies enriched layered double hydroxide supported Co3O4 nanoparticles photocatalyst11Direct Bonding of CpCo- Fragments on Pt Nanoparticles and their Electronic Effect for Alkyne Semihydrogenation23Zero-oxidation state precursor assisted fabrication of highly dispersed and stable Pt catalyst for chemoselective hydrogenation of α,β-unsaturated aldehydes20Tuning the catalytic performance of Pt/SiO2 catalysts by CoOx modification for selective hydrogenations of unsaturated carbonyl compounds16Adsorption, thermal conversion, and catalytic hydrogenation of acrolein on Cu surfaces11Mechanistic and Atomic-Level Insights into Semihydrogenation Catalysis to Light Olefins43Highly selective electrocatalytic hydrogenation of cinnamaldehyde over tin dioxide-supported palladium nanocatalysts14Recent Advances on Confining Noble Metal Nanoparticles Inside Metal-Organic Frameworks for Hydrogenation Reactions16Efficient catalytic selective hydrogenation of furfural to furfuryl alcohol over Pt-supported on surface amino functionalized hexagonal BN nanosheets25Enhanced Chemoselective Hydrogenation of Cinnamaldehyde via Pt-Fe/Fe-NTA Nanocatalysts Under Low Temperature6Effect of boron nitride overlayers on Co@BNNSs/BN-Catalyzed aqueous phase selective hydrogenation of cinnamaldehyde25PtMx/SBA-15 (M = Co, Cu, Ni and Zn) bimetallic catalysts for crotonaldehyde selective hydrogenation9Promoting electrocatalytic hydrogenation of 5-hydroxymethylfurfural using buffer electrolytes as proton-donating motifs: Theoretical predictions and experimental validations42Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review99Targeted Intermetallic Nanocatalysts for Sustainable Biomass and CO2 Valorization21State-of-the-art and perspectives in transition metal-based heterogeneous catalysis for selective hydrogenation of cinnamaldehyde37PdRu nanocages as the switcher for the production of hydrogenation reaction toward 4-nitrostyrene6Heterogeneous Hydrogenation with Hydrogen Spillover Enabled by Nitrogen Vacancies on Boron Nitride‐Supported Pd Nanoparticles52Heterogeneous Hydrogenation with Hydrogen Spillover Enabled by Nitrogen Vacancies on Boron Nitride‐Supported Pd Nanoparticles16In-situ reconstruction of single-atom Pt on Co3O4 for hydrogenation22Geometric and Electronic Effects in Hydrogenation Reactions62A perspective on catalytic production of olefinic compounds from biomass29Catalytic Hydrogenation Reactions of Lignocellulosic Biomass-derived Compounds as a Strategy to Obtain Value-added Products2Continuous flow hydrogenolysis of 5-hydroxymethylfurfural into 2,5-dimethylfuran over alumina-supported nickel–iron alloy catalysts25Electrochemical reduction of 5-benzylidene thiazolidine-2,4-diones: a greener approach to the preparation of glitazone APIs5Ethanol as Hydrogen Donor: An Efficient Transfer Hydrogenation of Aldehydes, Ketones, and Nitroarenes with H-Bonded Ru(Ii)-N-Heterocyclic Iminium Complex1Recent advances of Cp*Ir complexes for transfer hydrogenation: focus on formic acid/formate as hydrogen donors39Selective Hydrogenation of 5-Hydroxymethyl Furfural to 5-Methyl Furfural Over Graphene Oxide Supported Mn Nanoparticles1Thermocatalytic and photocatalytic chemoselective reduction of cinnamaldehyde to cinnamyl alcohol and hydrocinnamaldehyde over Ru@ZnO/CN29Unravelling synergistic effects in bi-metallic catalysts: deceleration of palladium–gold nanoparticle coarsening in the hydrogenation of cinnamaldehyde14A Career in Catalysis: Laura Prati4Citral Hydrogenation over Dilute Alloy Catalysts7Synergistic Effect of Fe and Zn Doping on Multimetallic Catalysts for the Catalytic Hydrogenation of Furfural to Furfuryl Alcohol2Highly dispersed Pt on partial deligandation of Ce-MOFs for furfural selective hydrogenation60Enhanced Activity of Alkali-Treated ZSM-5 Zeolite-Supported Pt-Co Catalyst for Selective Hydrogenation of Cinnamaldehyde10Highly efficient chemoselective hydrogenation of unsaturated aldehydes catalyzed by hydrophobically modified core-shell defective ZIFs: Frustrated Lewis pair catalysis28Promoting Electrocatalytic Hydrogenation of Oxalic Acid to Glycolic Acid via an Al3+ Ion Adsorption Strategy Coupled with Ethylene Glycol Oxidation36Material-based generation, storage, and utilisation of hydrogen142Current trends and prospects in catalytic upgrading of lignocellulosic biomass feedstock into ultrapure biofuels13Electrochemical Reduction of Diarylketones and Aryl Alkenes5Synthesis of highly efficient Nano- Ni-Pt catalyst in a rotating packed bed for cinnamaldehyde hydrogenation13Recent advances in thermocatalytic hydrogenation of unsaturated organic compounds with Metal-Organic Frameworks-based materials: Construction strategies and related mechanisms73Peripheral Coordination-Dependent Descriptor for Selective Interactions between Near-Frontier Molecular Orbitals and Single-Atom Catalysts11

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  42. Perspectives on Multifunctional Catalysts Derived from Layered Double Hydroxides toward Upgrading Reactions of Biomass Resources

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    ChemSusChem · 2021-05-21

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  44. Boosting selective hydrogenation through hydrogen spillover on supported-metal catalysts at room temperature

    Applied Catalysis B: Environmental · 2021-06-04

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  45. Low-Temperature Synthesis of Single Palladium Atoms Supported on Defective Hexagonal Boron Nitride Nanosheet for Chemoselective Hydrogenation of Cinnamaldehyde

    ACS Nano · 2021-06-08

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  46. The effects of TiO2 crystal-plane-dependent Ir-TiO interactions on the selective hydrogenation of crotonaldehyde over Ir/TiO2 catalysts

    CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · 2021-06-22

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  47. Hydrogenation of Cinnamaldehyde on Cu(110) Single-Crystal Surfaces

    The Journal of Physical Chemistry C · 2021-07-02

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  48. Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis

    ACS Catalysis · 2021-07-17

    Xiubing Huang, Kaiyue Zhang, Baoxiang Peng, Ge Wang, Martin Muhler, Feng Wang

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  49. Rhenium – A Tuneable Player in Tailored Hydrogenation Catalysis

    European Journal of Inorganic Chemistry · 2021-07-22

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  50. Cinnamaldehyde adsorption and thermal decomposition on copper surfaces

    Journal of Vacuum Science & Technology A Vacuum Surfaces and Films · 2021-08-02

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