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RESEARCH PAPER · ACS Catalysis · 2019

Unraveling the Origins of the Synergy Effect between ZrO 2 and CrO x in Supported CrZrO x for Propene Formation in Nonoxidative Propane Dehydrogenation

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Unraveling the Origins of the Synergy Effect between ZrO 2 and CrO x in Supported CrZrO x for Propene Formation in Nonoxidative Propane DehydrogenationOriginalElucidating the Nature of Active Sites and Fundamentals for their Creation in Zn-Containing ZrO 2 –Based Catalysts for Nonoxidative Propane Dehydrogenation124Current status and perspectives in oxidative, non-oxidative and CO 2 -mediated dehydrogenation of propane and isobutane over metal oxide catalysts366Ga speciation in Ga/H-ZSM-5 by in-situ transmission FTIR spectroscopy59Highly Active Nanosized Anatase TiO2–x Oxide Catalysts In Situ Formed through Reduction and Ostwald Ripening Processes for Propane Dehydrogenation77Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application244Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies895Propane to olefins tandem catalysis: a selective route towards light olefins production285Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane435High‐Density Lewis Acid Sites in Porous Single‐Crystalline Monoliths to Enhance Propane Dehydrogenation at Reduced Temperatures44High‐Density Lewis Acid Sites in Porous Single‐Crystalline Monoliths to Enhance Propane Dehydrogenation at Reduced Temperatures10Non-oxidative propane dehydrogenation over alumina-supported Co-V oxide catalysts31Understanding the origin for propane non-oxidative dehydrogenation catalysed by d2-d8 transition metals19Impact of Heteroatom Speciation on the Activity and Stability of Carbon‐Based Catalysts for Propane Dehydrogenation13Assessment and comparison of ordered & non-ordered supported metal oxide catalysts for upgrading propane to propylene37The effect of oxygen vacancies on the coordinatively unsaturated Al-O acid-base pairs for propane dehydrogenation64Theory-Aided Discovery of Metallic Catalysts for Selective Propane Dehydrogenation to Propylene42Three-phase electrochemistry for green ethylene production15Stabilizing Oxygen Vacancies in ZrO 2 by Ga 2 O 3 Boosts the Direct Dehydrogenation of Light Alkanes38Fabrication of Isolated VOx Sites on Alumina for Highly Active and Stable Non-Oxidative Dehydrogenation11Full life cycle characterization strategies for spatiotemporal evolution of heterogeneous catalysts4A review on the structure-performance relationship of the catalysts during propane dehydrogenation reaction90Influence of Cr/Zr Ratio on Activity of Cr–Zr Oxide Catalysts in Non-Oxidative Propane Dehydrogenation5Highly Dispersed Low-Polymeric VOx/Silica Gel Catalyst for Efficient Catalytic Dehydrogenation of Propane to Propylene8Advanced design and development of catalysts in propane dehydrogenation66On-purpose design of dual active sites in single V atom anchored C 2 N nanosheets for propane dehydrogenation catalysis8Single Co Sites in Ordered SiO2 Channels for Boosting Nonoxidative Propane Dehydrogenation124Role of Ni species in ZnO supported on Silicalite-1 for efficient propane dehydrogenation20Promoting Propane Dehydrogenation with CO 2 over the PtFe Bimetallic Catalyst by Eliminating the Non-selective Fe(0) Phase73Effects of the metal ionic radius at lattice site on surface active oxygen and reducibility over doped mesoporous ZSM-5 for catalytic oxidation VOC18Synergistic Mechanism of Platinum‐GaO x Catalysts for Propane Dehydrogenation73Synergistic Mechanism of Platinum‐GaOx Catalysts for Propane Dehydrogenation23Recent progress on the traditional and emerging catalysts for propane dehydrogenation56NiO and CrO x interaction promoting in situ generation of the coordinatively unsaturated Cr–O acid–base for oxygen-lean propane dehydrogenation6CexZr1–xO2-Supported CrOx Catalysts for CO2-Assisted Oxidative Dehydrogenation of Propane─Probing the Active Sites and Strategies for Enhanced Stability60Closed-Loop Optimization of Catalysts for Oxidative Propane Dehydrogenation with Co2 Using Artificial Intelligence0Redox MoO3/CaMnO3 catalysts for chemical-looping oxidative dehydrogenation of propane: A greener approach of propylene production22Site Diversity and Mechanism of Metal‐Exchanged Zeolite Catalyzed Non‐Oxidative Propane Dehydrogenation59Design Strategies of Stable Catalysts for Propane Dehydrogenation to Propylene185Amorphous silica-alumina as robust support for catalytic dehydrogenation of propane: Effect of Si/Al ratio on nature and dispersion of Cr active sites30CrO /Ce1−Zr O2 for chemical looping propane oxidative dehydrogenation: The redox interaction between CrO and the support19Regulating the C–H Bond Activation Pathway over ZrO 2 via Doping Engineering for Propane Dehydrogenation34Comparison of direct and CO2-oxidative dehydrogenation of propane39Identifying the active site and structure–activity relationship in propane dehydrogenation over Ga2O3/ZrO2 catalysts20Closed-loop optimization of catalysts for oxidative propane dehydrogenation with CO2 using artificial intelligence7Morphology Effect of ZrO 2 on Tuning the C–H Bond Activation in Propane Dehydrogenation25The enhancing effect of Co2+ on propane non-oxidative dehydrogenation over supported Co/ZrO2 catalysts24Metal–Site Dispersed Zinc–Chromium Oxide Derived from Chromate–Intercalated Layered Hydroxide for Highly Selective Propane Dehydrogenation4Defective TiO x overlayers catalyze propane dehydrogenation promoted by base metals232The promotion effects of alkaline earth metals on the properties of Cr/η-Al2O3 catalysts for propane dehydrogenation11The new developments of the design and application of novel propane dehydrogenation catalysts0Advanced metal oxide catalysts for propane dehydrogenation: from design strategy to dehydrogenation performance16Boosting the C–H bond activation in propane dehydrogenation via Fe 2 O 3 /GaZrO x interface engineering0Design of a CrZrO x –Cu 2 MnO x @Na 2 WO 4 catalyst–oxygen carrier system for efficient chemical looping oxidative dehydrogenation of propane5Lattice-Confined single cobalt atom in ZrO2 for propane non-oxidative dehydrogenation10A state-of-the-art review of propane dehydrogenation over well-defined non-noble metal cobalt catalysts27Zr-Doped TiO 2– x Nano-Oxide with Coordinatively Unsaturated Ti(Zr)–O Acid–Base Pairs for Efficient Propane Dehydrogenation12The Fundamentals for Efficient Non-oxidative Propane Dehydrogenation over ZrO2-Based Catalysts15Developing a supported metal oxide catalyst for direct dehydrogenation of propane to propene7Coordinatively unsaturated Cr3+ species in CrOx/oCNT with enhanced catalytic activity in oxidative dehydrogenation of propane with CO23Synergy principle of single active centers and microenvironment for Cr-MFI-catalyzed alkane dehydrogenation16Breaking symmetry: enhanced propane dehydrogenation via asymmetric oxygen vacancies from vanadium doped ZrO2 catalysts4The Promoting Effect of Mg on Propane Dehydrogenation over Co/Silicalite-1 Catalysts1Co‐tuning the content of hydroxyl nests and b ‐axis thickness of ZnO x /Silicalite‐1 for efficient propane dehydrogenation0

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  2. Current status and perspectives in oxidative, non-oxidative and CO 2 -mediated dehydrogenation of propane and isobutane over metal oxide catalysts

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  3. Ga speciation in Ga/H-ZSM-5 by in-situ transmission FTIR spectroscopy

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  4. Highly Active Nanosized Anatase TiO2–x Oxide Catalysts In Situ Formed through Reduction and Ostwald Ripening Processes for Propane Dehydrogenation

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  7. Propane to olefins tandem catalysis: a selective route towards light olefins production

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  9. High‐Density Lewis Acid Sites in Porous Single‐Crystalline Monoliths to Enhance Propane Dehydrogenation at Reduced Temperatures

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  10. High‐Density Lewis Acid Sites in Porous Single‐Crystalline Monoliths to Enhance Propane Dehydrogenation at Reduced Temperatures

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  11. Non-oxidative propane dehydrogenation over alumina-supported Co-V oxide catalysts

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  12. Understanding the origin for propane non-oxidative dehydrogenation catalysed by d2-d8 transition metals

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  13. Impact of Heteroatom Speciation on the Activity and Stability of Carbon‐Based Catalysts for Propane Dehydrogenation

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  14. Assessment and comparison of ordered & non-ordered supported metal oxide catalysts for upgrading propane to propylene

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  15. The effect of oxygen vacancies on the coordinatively unsaturated Al-O acid-base pairs for propane dehydrogenation

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  16. Theory-Aided Discovery of Metallic Catalysts for Selective Propane Dehydrogenation to Propylene

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  18. Stabilizing Oxygen Vacancies in ZrO 2 by Ga 2 O 3 Boosts the Direct Dehydrogenation of Light Alkanes

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  19. Fabrication of Isolated VOx Sites on Alumina for Highly Active and Stable Non-Oxidative Dehydrogenation

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  20. Full life cycle characterization strategies for spatiotemporal evolution of heterogeneous catalysts

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  22. Influence of Cr/Zr Ratio on Activity of Cr–Zr Oxide Catalysts in Non-Oxidative Propane Dehydrogenation

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  25. On-purpose design of dual active sites in single V atom anchored C 2 N nanosheets for propane dehydrogenation catalysis

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  27. Role of Ni species in ZnO supported on Silicalite-1 for efficient propane dehydrogenation

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  46. The enhancing effect of Co2+ on propane non-oxidative dehydrogenation over supported Co/ZrO2 catalysts

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  48. Defective TiO x overlayers catalyze propane dehydrogenation promoted by base metals

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  49. The promotion effects of alkaline earth metals on the properties of Cr/η-Al2O3 catalysts for propane dehydrogenation

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  50. The new developments of the design and application of novel propane dehydrogenation catalysts

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