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RESEARCH PAPER · Chemistry of Materials · 2019

From NaZn4Sb3 to HT-Na1–xZn4–ySb3: Panoramic Hydride Synthesis, Structural Diversity, and Thermoelectric Properties

Volodymyr Gvozdetskyi, Bryan Owens‐Baird, Sangki Hong, Tori Cox, Gourab Bhaskar, Colin P. Harmer, Yang Sun, Feng Zhang, Cai‐Zhuang Wang, Kai‐Ming Ho, Julia V. Zaikina

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From NaZn4Sb3 to HT-Na1–xZn4–ySb3: Panoramic Hydride Synthesis, Structural Diversity, and Thermoelectric PropertiesOriginalSynthesis, Crystal and Electronic Structure of Layered AMSb Compounds (A = Rb, Cs; M = Zn, Cd)11Lithium nickel borides: evolution of [NiB] layers driven by Li pressure14First-principles predictions of low lattice thermal conductivity and high thermoelectric performance of AZnSb (A = Rb, Cs)17Ternary antimonide NaCd4Sb3: Hydride synthesis, crystal structure and transport properties0First-Principles Hydrothermal Synthesis Design to Optimize Conditions and Increase the Yield of Quaternary Heteroanionic Oxychalcogenides28Ternary Zinc Antimonides Unlocked Using Hydride Synthesis14Ternary ACd4P3 (A = Na, K) Nanostructures via a Hydride Solution-Phase Route8How to Look for Compounds: Predictive Screening and in situ Studies in Na−Zn−Bi System8In Situ Methods for Metal-Flux Synthesis in Inert Environments11Panoramic (in beam) studies of materials synthesis1Improved Thermoelectric Performance for β-Zn4Sb3 by Na/Zn Co-doping2Periodic TableTalks: An Oasis of Science within a Conference Desert0Ternary antimonide NaCd4Sb3: hydride synthesis, crystal structure and transport properties7Solution-Grown Ternary Semiconductors: Nanostructuring and Stereoelectronic Lone Pair Distortions in I–V–VI 2 Materials27Thermal Conductivity of Glasses and Disordered Crystals4Hydride precursors in materials synthesis9Structural phase transition and transport properties in topological material candidate NaZn4As32Rb(Zn,Cu)4As3 as a New High-Efficiency Thermoelectric Material8Exploring the A -V-Sb landscape beyond AV3Sb5 : A case study on the KV6Sb6 Kagome compound9Breaking New Ground: MBene Route toward Selective Vinyl Double Bond Hydrogenation in Nitroarenes7Application of neutron scattering to studying low lattice thermal conductivity of Zintl phase compounds3Unraveling the topological phase in Zintl semiconductors RbZn4X3 (X = P, As) through band engineering4Influence of “Non-Interacting” Flux Concentration in Metallic Flux Growth Synthesis2Combining Compositional Screening via Hydride Route, Machine Learning, and In Situ Diffraction to Discover Antimonides in the K–Cd–Sb System3Rb(Cd,Zn) 4 As 3 as a new n-type Zintl phase thermoelectric compound0Adding Another Syngony to the K–Cd–Sb System: Synthesis, Structure, and Properties of Cubic, Clathrate-Like K 3 Cd 12 Sb 101First-principles insight into the multifunctional properties of tetragonal Zintl-phase CsCd4As3: From dynamical stability to thermoelectric performance2Cation Site Ordering by Dissolution-Based Annealing during Cr2(NCN)3 Metathesis in a Molten Salt0

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  1. Synthesis, Crystal and Electronic Structure of Layered AMSb Compounds (A = Rb, Cs; M = Zn, Cd)

    Zeitschrift für anorganische und allgemeine Chemie · 2020-01-22

    Bryan Owens‐Baird, Lin‐Lin Wang, Shannon Lee, Kirill A. Kovnir

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  2. Lithium nickel borides: evolution of [NiB] layers driven by Li pressure

    Inorganic Chemistry Frontiers · 2020-11-25

    Volodymyr Gvozdetskyi, Yang Sun, Xin Zhao, Gourab Bhaskar, Scott L. Carnahan, Colin P. Harmer, Feng Zhang, Raquel A. Ribeiro, Paul C. Canfield, Aaron J. Rossini, Cai‐Zhuang Wang, Kai‐Ming Ho, Julia V. Zaikina

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  3. First-principles predictions of low lattice thermal conductivity and high thermoelectric performance of AZnSb (A = Rb, Cs)

    RSC Advances · 2021-01-01

    Enamul Haque

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  4. Ternary antimonide NaCd4Sb3: Hydride synthesis, crystal structure and transport properties

    Unknown journal · 2021-01-01

    Brittany Courteau

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  5. First-Principles Hydrothermal Synthesis Design to Optimize Conditions and Increase the Yield of Quaternary Heteroanionic Oxychalcogenides

    Chemistry of Materials · 2021-04-05

    Lauren N. Walters, Chi Zhang, Vinayak P. Dravid, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  6. Ternary Zinc Antimonides Unlocked Using Hydride Synthesis

    Inorganic Chemistry · 2021-06-28

    Volodymyr Gvozdetskyi, Shannon Lee, Bryan Owens‐Baird, Juli‐Anna Dolyniuk, Tori Cox, Renhai Wang, Zijing Lin, Kai‐Ming Ho, Julia V. Zaikina

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  7. Ternary ACd4P3 (A = Na, K) Nanostructures via a Hydride Solution-Phase Route

    ACS Materials Au · 2021-07-28

    Alan M. Medina‐Gonzalez, Philip Yox, Yunhua Chen, Marquix A. S. Adamson, Maranny Svay, Emily A. Smith, Richard D. Schaller, Aaron J. Rossini, Javier Vela

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  8. How to Look for Compounds: Predictive Screening and in situ Studies in Na−Zn−Bi System

    Chemistry - A European Journal · 2021-09-01

    Volodymyr Gvozdetskyi, Renhai Wang, Weiyi Xia, Feng Zhang, Zijing Lin, Kai‐Ming Ho, Gordon J. Miller, Julia V. Zaikina

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  9. In Situ Methods for Metal-Flux Synthesis in Inert Environments

    Chemistry of Materials · 2021-09-22

    Ashley Weiland, Matthew G. Frith, Saul H. Lapidus, Julia Y. Chan

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  10. Panoramic (in beam) studies of materials synthesis

    Elsevier eBooks · 2021-10-12

    Mercouri G. Kanatzidis, Rebecca McClain

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  11. Improved Thermoelectric Performance for β-Zn4Sb3 by Na/Zn Co-doping

    Journal of Electronic Materials · 2022-01-02

    Jie Zheng, Jiali Chen, Yu Tang, Kaiyuan Shen, Yujie Xiang, Lanxian Shen, Wen Ge, Peizhi Yang, Shukang Deng

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  12. Periodic TableTalks: An Oasis of Science within a Conference Desert

    Inorganic Chemistry · 2022-04-25

    Trevor W. Hayton, Hannah S. Shafaat

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  13. Ternary antimonide NaCd4Sb3: hydride synthesis, crystal structure and transport properties

    Zeitschrift für anorganische und allgemeine Chemie · 2022-05-03

    Brittany Courteau, Volodymyr Gvozdetskyi, Shannon Lee, Tori Cox, Julia V. Zaikina

    Read original paper ↗ ·

  14. Solution-Grown Ternary Semiconductors: Nanostructuring and Stereoelectronic Lone Pair Distortions in I–V–VI 2 Materials

    Chemistry of Materials · 2022-08-10

    Alan M. Medina‐Gonzalez, Philip Yox, Yunhua Chen, Marquix A. S. Adamson, Bryan A. Rosales, Maranny Svay, Emily A. Smith, Richard D. Schaller, Kui Wu, Aaron J. Rossini, Kirill A. Kovnir, Javier Vela

    Read original paper ↗ ·

  15. Thermal Conductivity of Glasses and Disordered Crystals

    WORLD SCIENTIFIC (EUROPE) eBooks · 2022-08-25

    Alexander I. Krivchikov, Andrzej Jezowski

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  16. Hydride precursors in materials synthesis

    Elsevier eBooks · 2022-10-15

    Adedoyin N. Adeyemi, Gourab Bhaskar, Tori Cox, Sangki Hong, Volodymyr Gvozdetskyi, Julia V. Zaikina

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  17. Structural phase transition and transport properties in topological material candidate NaZn4As3

    Chinese Physics B · 2023-02-23

    Qingxin Dong, Bin-Bin Ruan, Yifei Huang, Yiyan Wang, Libo Zhang, Jianli Bai, Qiao-Yu Liu, Jingwen Cheng, Zhi-An Ren, Genfu Chen

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  18. Rb(Zn,Cu)4As3 as a New High-Efficiency Thermoelectric Material

    ACS Omega · 2023-10-30

    Keigo Ono, Kunihiro Kihou, Hidetomo Usui, Kazuhiko Kuroki, Yosuke Goto, Chul‐Ho Lee

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  19. Exploring the A -V-Sb landscape beyond AV3Sb5 : A case study on the KV6Sb6 Kagome compound

    Physical Review Materials · 2023-11-15

    Aishwarya Mantravadi, Volodymyr Gvozdetskyi, Arka Sarkar, Yaroslav Mudryk, Julia V. Zaikina

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  20. Breaking New Ground: MBene Route toward Selective Vinyl Double Bond Hydrogenation in Nitroarenes

    Journal of the American Chemical Society · 2023-12-07

    Gourab Bhaskar, Ranjan Kumar Behera, Volodymyr Gvozdetskyi, Scott L. Carnahan, Raquel A. Ribeiro, Paul Oftedahl, Charles Ward, Paul C. Canfield, Aaron J. Rossini, Wenyu Huang, Julia V. Zaikina

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  21. Application of neutron scattering to studying low lattice thermal conductivity of Zintl phase compounds

    Acta Physica Sinica · 2024-12-31

    Cuiping Zhang, Zhu Jinfeng, Xiaoling Shen, Shu Mingfang, Qingyong REN, Jie MA

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  22. Unraveling the topological phase in Zintl semiconductors RbZn4X3 (X = P, As) through band engineering

    Journal of Physics Condensed Matter · 2025-03-17

    Ramesh Kumar, Rajesh Kumar, Antik Sihi, Mukhtiyar Singh

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  23. Influence of “Non-Interacting” Flux Concentration in Metallic Flux Growth Synthesis

    Chemistry of Materials · 2025-03-26

    Trent M. Kyrk, Melissa G. Anderson, Gregory T. McCandless, Saul H. Lapidus, Julia Y. Chan

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  24. Combining Compositional Screening via Hydride Route, Machine Learning, and In Situ Diffraction to Discover Antimonides in the K–Cd–Sb System

    Chemistry of Materials · 2026-01-26

    Tori Cox, Volodymyr Gvozdetskyi, Zeina Miari, Kaden Osborn, Arka Sarkar, Philip Yox, Balaranjan Selvaratnam, Shiya Chen, Yang Sun, Arthur Mar, Julia V. Zaikina

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  25. Rb(Cd,Zn) 4 As 3 as a new n-type Zintl phase thermoelectric compound

    Acta Materialia · 2026-01-27

    Keigo Ono, Yosuke Goto, Hidetomo Usui, Masayuki Murata, Satoshi Tsutsui, K. Kuroki, Yoichi Kamihara, Chul-Ho Lee

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  26. Adding Another Syngony to the K–Cd–Sb System: Synthesis, Structure, and Properties of Cubic, Clathrate-Like K 3 Cd 12 Sb 10

    Chemistry of Materials · 2026-02-07

    Tori Cox, Volodymyr Gvozdetskyi, Nisaga Prathibhani Wanigasekara, Zhen Zhang, Genevieve Amobi, Kaden Osborn, Zeina Miari, Julia V. Zaikina

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  27. First-principles insight into the multifunctional properties of tetragonal Zintl-phase CsCd4As3: From dynamical stability to thermoelectric performance

    Journal of Molecular Graphics and Modelling · 2026-05-05

    A. Jabar, Zakaria Fadil, S. Idrissi, L. Bahmad, M Waleed Ahmad Khan, Chaitany Jayprakash Raorane, Seong‐Cheol Kim

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  28. Cation Site Ordering by Dissolution-Based Annealing during Cr2(NCN)3 Metathesis in a Molten Salt

    Inorganic Chemistry · 2026-09-08

    Layton Rudolph, Christopher L. Rom, Gabrielle Spankus, Simon Young, Andriy Zakutayev, James Richmond Neilson

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