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RESEARCH PAPER · Chemical Communications · 2019

Stabilization of a 4.5 V Cr 4+ /Cr 3+ redox reaction in NASICON-type Na 3 Cr 2 (PO 4 ) 3 by Ti substitution

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Stabilization of a 4.5 V Cr 4+ /Cr 3+ redox reaction in NASICON-type Na 3 Cr 2 (PO 4 ) 3 by Ti substitutionOriginalFull Activation of Mn4+/Mn3+ Redox in Na4MnCr(PO4)3 as a High‐Voltage and High‐Rate Cathode Material for Sodium‐Ion Batteries155Revisiting the Stability of the Cr4+/Cr3+ Redox Couple in Sodium Superionic Conductor Compounds17Symmetric Sodium-Ion Battery Based on Dual-Electron Reactions of NASICON-Structured Na 3 MnTi(PO 4 ) 3 Material115A facilely-synthesized polyanionic cathode with impressive long-term cycling stability for sodium-ion batteries12Designing positive electrodes with high energy density for lithium-ion batteries844.7 V Operation of the Cr4+/Cr3+ Redox Couple in Na3Cr2(PO4)2F325Elevating Energy Density for Sodium-Ion Batteries through Multielectron Reactions116First-principles study of electronic structure, sodium diffusion, and (de)intercalation in NASICON NaMR(MoO4)3 (M = Mg, Ni; R = Cr, Fe)11Crystal Structures and Local Environments of NASICON-Type Na 3 FeV(PO 4 ) 3 and Na 4 FeV(PO 4 ) 3 Positive Electrode Materials for Na-Ion Batteries100Buckwheat derived N-doped carbon coated Na3V2(PO4)2F3 enwrapping in graphene as enhanced cathode material for high performance sodium ion batteries31Advanced characterizations and measurements for sodium-ion batteries with NASICON-type cathode materials294NASICON-structured Na 3 Fe 2 PO 4 (SO 4 ) 2 : a potential cathode material for rechargeable sodium-ion batteries27Similarity between the redox potentials of 3d transition-metal ions in polyanionic insertion materials and aqueous solutions4Vanadium-free NASICON-type electrode materials for sodium-ion batteries41Rational Design of Mixed Polyanion Electrodes Na x V 2 P 3– i (Si/S) i O 12 for Sodium Batteries42Rationally Designed Sodium Chromium Vanadium Phosphate Cathodes with Multi‐Electron Reaction for Fast‐Charging Sodium‐Ion Batteries194Towards high-performance phosphate-based polyanion-type materials for sodium-ion batteries125Crystal chemistry of V-based NASICON-type positive electrode materials for Na-ion batteries0Emerging characterization techniques for delving polyanion-type cathode materials of sodium-ion batteries121Recent progress and prospects of NASICON framework electrodes for Na-ion batteries204Low‐Cost Polyanion‐Type Cathode Materials for Sodium‐Ion Battery36Recent progress on advanced high energy electrode materials for sodium ion batteries59Doping engineering of phosphorus-based polyanion-type cathodes for sodium storage: a review47Structurally Modulated Na 4– x Fe 3– x V x (PO 4 ) 2 P 2 O 7 by Vanadium Doping for Long-Life Sodium-Ion Batteries83Enhancing Kinetics in Sodium Super Ion Conductor Na3MnTi(PO4)3 through Microbe-Assisted and Structural Optimization19Stabilizing NASICON-type Na4MnCr(PO4)3 by Ti-substitution toward a high-voltage cathode material for sodium ion batteries15Enhancing Voltage Output in Polyanion‐Type Cathode Materials for Sodium Ion Batteries11Realizing Three-Electron Redox Reactions in NASICON-Type NaCrNb(PO4)3 for Sodium Ion Battery Applications17Obtaining V2(PO4)3 by sodium extraction from single-phase NaxV2(PO4)3 (1 < x < 3) positive electrode materials73Elucidation of the Co 4+ state with strong charge-transfer effects in charged LiCoO 2 by resonant soft X-ray emission spectroscopy at the Co L 3 edge7Chromium-containing polyanionic cathode materials for sodium-ion batteries: progress, challenges and opportunities9A novel NASICON-Na3.4MnV0.2Cr0.2Ti0.6(PO4)3 cathode with ultrahigh energy density and remarkable cycling stability toward practical Na-ion batteries21Element Optimization in NASICON Phosphates Enhances Sodium Storage Performance7Synergistic role of transition metals and polyanionic frameworks in phosphate-based cathode materials for sodium-ion batteries34Recent Progress of Na 3 MnTi(PO 4 ) 3 Cathode for Sodium‐Ion Batteries: Mechanism, Synthesis, and Optimization Strategy6Structural innovation and electrochemical progress in phosphate-based polyanionic oxide cathodes for high-performance sodium-ion batteries12Insights on novel carbon-coated NaSICON-type structure Na3FeCr(PO4)3@C as positive electrode material for sodium-ion batteries3Investigation on the electrochemical properties of NaSICon-type Na3Fe1+xCr1-x(PO4)3 as positive electrode materials for sodium-ion batteries0

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  2. Revisiting the Stability of the Cr4+/Cr3+ Redox Couple in Sodium Superionic Conductor Compounds

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    Jiansheng Zhang, Guisheng Liang, Chao Wang, Chunfu Lin, Jiajia Chen, Zhongru Zhang, Xin Zhao

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  3. Symmetric Sodium-Ion Battery Based on Dual-Electron Reactions of NASICON-Structured Na 3 MnTi(PO 4 ) 3 Material

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  4. A facilely-synthesized polyanionic cathode with impressive long-term cycling stability for sodium-ion batteries

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  5. Designing positive electrodes with high energy density for lithium-ion batteries

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    Masashi Okubo, Seongjae Ko, Debasmita Dwibedi, Atsuo Yamada

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  6. 4.7 V Operation of the Cr4+/Cr3+ Redox Couple in Na3Cr2(PO4)2F3

    Chemistry of Materials · 2021-02-11

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  7. Elevating Energy Density for Sodium-Ion Batteries through Multielectron Reactions

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    Yongjie Zhao, Xiangwen Gao, Hongcai Gao, Andrei Dolocan, John Bannister Goodenough

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  8. First-principles study of electronic structure, sodium diffusion, and (de)intercalation in NASICON NaMR(MoO4)3 (M = Mg, Ni; R = Cr, Fe)

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    A. V. Serdtsev, I. Yu. Kotova, N. I. Medvedeva

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  9. Crystal Structures and Local Environments of NASICON-Type Na 3 FeV(PO 4 ) 3 and Na 4 FeV(PO 4 ) 3 Positive Electrode Materials for Na-Ion Batteries

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  10. Buckwheat derived N-doped carbon coated Na3V2(PO4)2F3 enwrapping in graphene as enhanced cathode material for high performance sodium ion batteries

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  11. Advanced characterizations and measurements for sodium-ion batteries with NASICON-type cathode materials

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    Yukun Liu, Yukun Liu, Jie Li, Qiuyu Shen, Jian Zhang, Pingge He, Xuanhui Qu, Yongchang Liu, Yongchang Liu

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  12. NASICON-structured Na 3 Fe 2 PO 4 (SO 4 ) 2 : a potential cathode material for rechargeable sodium-ion batteries

    Dalton Transactions · 2022-01-01

    Saurabh Kumar, R. Ranjeeth, Neeraj Kumar Mishra, Rajiv Prakash, Preetam Singh

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  13. Similarity between the redox potentials of 3d transition-metal ions in polyanionic insertion materials and aqueous solutions

    Physical Chemistry Chemical Physics · 2022-01-01

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  14. Vanadium-free NASICON-type electrode materials for sodium-ion batteries

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    Ye-Chao Wu, Xianhe Meng, Lijing Yan, Qiaoling Kang, Huiwei Du, ChuBin Wan, Meiqiang Fan, Tingli Ma

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  15. Rational Design of Mixed Polyanion Electrodes Na x V 2 P 3– i (Si/S) i O 12 for Sodium Batteries

    Chemistry of Materials · 2022-03-29

    Vishakha Kapoor, Baltej Singh, Gopalakrishnan Sai Gautam, Anthony Kevin Cheetham, Pieremanuele Canepa

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  16. Rationally Designed Sodium Chromium Vanadium Phosphate Cathodes with Multi‐Electron Reaction for Fast‐Charging Sodium‐Ion Batteries

    Advanced Energy Materials · 2022-05-08

    Wei Zhang, Yulun Wu, Zhenming Xu, Huangxu Li, Ming Fei Xu, Jianwei Li, Yuhang Dai, Wei Zong, Ruwei Chen, Liang Hua He, Zhian Zhang, Dan J. L. Brett, Guanjie He, Yanqing Lai, Ivan Paul Parkin

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  17. Towards high-performance phosphate-based polyanion-type materials for sodium-ion batteries

    Energy storage materials · 2022-06-07

    Yong Yuan, Qingyuan Wei, Shaokang Yang, Xiaoyu Zhang, Min Jia, Jiaren Yuan, Xiaohong Yan

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  18. Crystal chemistry of V-based NASICON-type positive electrode materials for Na-ion batteries

    Unknown journal · 2022-07-12

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  19. Emerging characterization techniques for delving polyanion-type cathode materials of sodium-ion batteries

    Materials Today · 2023-04-06

    Jin‐Zhi Guo, Zhen‐Yi Gu, Miao Du, Xin-Xin Zhao, Xiaotong Wang, Xing‐Long Wu

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  20. Recent progress and prospects of NASICON framework electrodes for Na-ion batteries

    Progress in Materials Science · 2023-04-14

    Raghunayakula Thirupathi, Vandana Kumari, Sumanta Chakrabarty, Shobit Omar

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  21. Low‐Cost Polyanion‐Type Cathode Materials for Sodium‐Ion Battery

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  22. Recent progress on advanced high energy electrode materials for sodium ion batteries

    Green Energy and Resources · 2023-09-01

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  23. Doping engineering of phosphorus-based polyanion-type cathodes for sodium storage: a review

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  24. Structurally Modulated Na 4– x Fe 3– x V x (PO 4 ) 2 P 2 O 7 by Vanadium Doping for Long-Life Sodium-Ion Batteries

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  25. Enhancing Kinetics in Sodium Super Ion Conductor Na3MnTi(PO4)3 through Microbe-Assisted and Structural Optimization

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  26. Stabilizing NASICON-type Na4MnCr(PO4)3 by Ti-substitution toward a high-voltage cathode material for sodium ion batteries

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  27. Enhancing Voltage Output in Polyanion‐Type Cathode Materials for Sodium Ion Batteries

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  28. Realizing Three-Electron Redox Reactions in NASICON-Type NaCrNb(PO4)3 for Sodium Ion Battery Applications

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  29. Obtaining V2(PO4)3 by sodium extraction from single-phase NaxV2(PO4)3 (1 < x < 3) positive electrode materials

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  30. Elucidation of the Co 4+ state with strong charge-transfer effects in charged LiCoO 2 by resonant soft X-ray emission spectroscopy at the Co L 3 edge

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  31. Chromium-containing polyanionic cathode materials for sodium-ion batteries: progress, challenges and opportunities

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  32. A novel NASICON-Na3.4MnV0.2Cr0.2Ti0.6(PO4)3 cathode with ultrahigh energy density and remarkable cycling stability toward practical Na-ion batteries

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  33. Element Optimization in NASICON Phosphates Enhances Sodium Storage Performance

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