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RESEARCH PAPER · Chemical Communications · 2019

A new ferroelastic hybrid material with a large spontaneous strain: (Me 3 NOH) 2 [ZnCl 4 ]

Wei Yuan, Ying Zeng, Ya-Yin Tan, Jianhua Zhou, Wei‐Jian Xu, Wei‐Xiong Zhang, Xiao‐Ming Chen

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A new ferroelastic hybrid material with a large spontaneous strain: (Me 3 NOH) 2 [ZnCl 4 ]OriginalOne-Dimensional Cadmium Thiocyanate Perovskite Ferroelastics Tuned by Halogen Substitution61Smart and efficient opto-electronic dual response material based on two-dimensional perovskite crystal/thin film22A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism38A one-dimensional switchable dielectric material with Pd uptake function: [(CH 2 ) 3 NH 2 S] 2 BiCl 518Unique Design Strategy for Dual Phase Transition That Successfully Validates Dual Switch Implementation in the Dielectric Material19A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches163A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches20Phase Transition and Band Gap Regulation by Halogen Substituents on the Organic Cation in Organic–Inorganic Hybrid Perovskite Semiconductors37Distinctive hydration dynamics around highly coordinated Cu2+/Zn2+-chloride complexes: A molecular dynamics simulation study13Temperature-Stimulus Responsive Ferroelastic Molecular–Ionic Crystal: (C8H20N)[BF4]13A Three-Dimensional Molecular Perovskite Ferroelastic with Two-Step Switching of Quadratic Nonlinear Optical Properties Tuned by Molecular Chiral Design35Successive Phase Transitions and Dual Dielectric Switching in an Organic–Inorganic Hybrid Perovskite37A high-temperature halide perovskite molecular ferroelastic with evident dielectric switching30A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking40An unprecedented hexagonal double perovskite organic–inorganic hybrid ferroelastic material: (piperidinium) 2 [KBiCl 6 ]43Competing hydrogen-bonding interactions in a high- T c organic molecular-ionic crystal with evident nonlinear optical response2Enantiomeric perovskite with a dual phase transition at high temperature22Emergent Chirality and Nonlinear Optical Switching in a Ferroelastic Molecular Perovskite Solid Solution31A Photoluminescent Lead Bromide Hybrid Perovskite Molecular Ferroelastic Semiconductor with Sequential High-Tc Phase Transitions33Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu(HCOO)2Cl4High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me3NCH2CH2OH)4[Ni(NCS)6]24Metal ion modulation triggers dielectric double switching and green fluorescence in A 2 MX 4 -type compounds40Dual-channel control of ferroelastic domains in a host–guest inclusion compound17Ferroelastic phase transition with large spontaneous strain caused by freezing the conformational dynamics of ammonium8Ferroic phase transition molecular crystals45H/F Substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic51High temperature hybrid perovskite multifunctional switching materials constructed through precise molecular design20Metal regulated organic–inorganic hybrid ferroelastic materials: [(CH 3 ) 3 CN(CH 3 ) 2 CH 2 F] 2 [MBr 4 ] (M = Cd and Zn)24Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic22Insights into the Molecular Dynamics of Quasi-Spherical (Chloromethyl)triethylammonium Confined in a Weakly Bound Ionic Cocrystal9Ammonium Sulfate Structure-Type Hybrid Metal Halide Ferroelectric with Giant Uniaxial Spontaneous Strain21Ferroelasticity in Organic–Inorganic Hybrid Perovskites63Above room-temperature dielectric switching in a new Zn-halide hybrid crystal based on pyrrolidine-derivative4A New Zn(II) Metal Hybrid Material of 5-Nitrobenzimidazolium Organic Cation (C7H6N3O2)2[ZnCl4]: Elaboration, Structure, Hirshfeld Surface, Spectroscopic, Molecular Docking Analysis, Electric and Dielectric Properties10Solid-state molecular dynamics of a torsion-variable ammonium embedded in a deformable supramolecular framework4A chiral two-dimensional perovskite-like lead-free bismuth( iii ) iodide hybrid with high phase transition temperature15A photoluminescent chiral lead-free hybrid ferroelastic semiconductor with switchable second-harmonic generation23An anomalous ferroelastic phase transition arising from an unusual cis -/ anti -conformational reversal of polar organic cations15Pressure-Induced Ferroelastic Transition Drives a Large Shape Change in a Ni(II) Complex Single Crystal4Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system16Temperature-Tuned Variable Confined Space for Modulating Dipolar Polarization of a Disc-Shaped Ammonium Ion5Novel High-Tc, Broadband-Emission Multifunctional Hybrid Compound: (4,4-DCA)2CdCl4 with Sb Doping Enhances Fluorescence Emission4An organic–inorganic hybrid photoluminescent ferroelastic with high phase transition temperature10Designing dynamic coordination bonds in polar hybrid crystals for a high-temperature ferroelastic transition15Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH 3 ) 3 NOH] 2 [CoCl 4 ]3Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]6Switchable K–O bonds unveiling anomalous ferroelastic transitions in a polar hybrid crystal4Characterization of a New Hybrid Compound (C3H8N6)2ZnCl4·2Cl: X-ray Structure, Hirshfeld Surface, Vibrational, Thermal Stability, Dielectric Relaxation, and Electrical Conductivity17Crystal structure of catena-poly[bis(N,O-dimethylhydroxylammonium) [di-μ-bromido-dibromidostannate(II)]]1Hot-pressing boosted nonlinear optical properties in a new ferroelectric plastic crystalline material3Hydrogen-Bonding-Driven Design of Organic–Inorganic Hybrid Ferroelastics with Reversible Photoisomerization6Zero-Dimensional Plastic Phase Transition Iron-Based Compounds with High T c and Switchable SHG Responses5Spin-ferroelasticity coupling in nonrelativistic spin-split antiferromagnetic-ferroelastic systems1A zero-dimensional zinc-based hybrid showing switchable dielectric constant, inverse symmetry breaking and fluorescence property0(C6H16N)3Sb2I9: thermally switchable dielectric and semiconducting hybrid with structural phase transition0

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  1. One-Dimensional Cadmium Thiocyanate Perovskite Ferroelastics Tuned by Halogen Substitution

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  2. Smart and efficient opto-electronic dual response material based on two-dimensional perovskite crystal/thin film

    Journal of Materials Chemistry C · 2019-12-20

    Jie Li, Chang Xu, Wan‐Ying Zhang, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  3. A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism

    Chemical Communications · 2020-01-01

    Wei‐Jian Xu, Ying Zeng, Wei Yuan, Wei‐Xiong Zhang, Xiao‐Ming Chen

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  4. A one-dimensional switchable dielectric material with Pd uptake function: [(CH 2 ) 3 NH 2 S] 2 BiCl 5

    Chemical Communications · 2020-01-01

    Yuting Liu, Lei He, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  5. Unique Design Strategy for Dual Phase Transition That Successfully Validates Dual Switch Implementation in the Dielectric Material

    Inorganic Chemistry · 2020-03-12

    Chang‐Yuan Su, Zhi‐Xu Zhang, Wan‐Ying Zhang, Ping‐Ping Shi, Da‐Wei Fu, Qiong Ye

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  6. A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches

    Angewandte Chemie International Edition · 2020-04-18

    Ren‐Gen Xiong, Siqi Lu, Zhi‐Xu Zhang, Hao Cheng, Peng‐Fei Li, Wei‐Qiang Liao

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  7. A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches

    Angewandte Chemie · 2020-04-18

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  8. Phase Transition and Band Gap Regulation by Halogen Substituents on the Organic Cation in Organic–Inorganic Hybrid Perovskite Semiconductors

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    Yingjie Cao, Lin Zhou, Lei He, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  9. Distinctive hydration dynamics around highly coordinated Cu2+/Zn2+-chloride complexes: A molecular dynamics simulation study

    Journal of Molecular Liquids · 2020-06-17

    Ying-Ying Li, Mei Wang, Chunchang Wang, Qingwen Zhang, Haibo Yi

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  10. Temperature-Stimulus Responsive Ferroelastic Molecular–Ionic Crystal: (C8H20N)[BF4]

    The Journal of Physical Chemistry C · 2020-07-27

    Marcin Moskwa, Emilia Ganczar, Paweł Sobieszczyk, W. Medycki, Piotr Zieliński, R. Jakubas, G. Bator

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  11. A Three-Dimensional Molecular Perovskite Ferroelastic with Two-Step Switching of Quadratic Nonlinear Optical Properties Tuned by Molecular Chiral Design

    The Journal of Physical Chemistry Letters · 2020-09-01

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  12. Successive Phase Transitions and Dual Dielectric Switching in an Organic–Inorganic Hybrid Perovskite

    Inorganic Chemistry · 2020-12-09

    Lin Zhou, Ruixia Li, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  13. A high-temperature halide perovskite molecular ferroelastic with evident dielectric switching

    Inorganic Chemistry Frontiers · 2020-12-14

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  14. A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking

    Inorganic Chemistry Frontiers · 2021-01-01

    Le‐Ping Miao, Lin-Lin Chu, Xiang‐Bin Han, Bei‐Dou Liang, Chao‐Yang Chai, Chang‐Chun Fan, Xiao‐Xu Wang, Ye‐Feng Yao, Wen Zhang

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  15. An unprecedented hexagonal double perovskite organic–inorganic hybrid ferroelastic material: (piperidinium) 2 [KBiCl 6 ]

    Chemical Communications · 2021-01-01

    Qian-Ru Meng, Wei‐Jian Xu, Wang‐Hua Hu, Hui Ye, Xiao‐Xian Chen, Wei Yuan, Wei‐Xiong Zhang, Xiao‐Ming Chen

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  16. Competing hydrogen-bonding interactions in a high- T c organic molecular-ionic crystal with evident nonlinear optical response

    CrystEngComm · 2021-01-01

    Wentao Xu, Jun‐Chao Liu, Yu‐Ling Zeng, Hua Zhang, Zhong‐Xia Wang

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  17. Enantiomeric perovskite with a dual phase transition at high temperature

    Journal of Materials Chemistry C · 2021-01-01

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  18. Emergent Chirality and Nonlinear Optical Switching in a Ferroelastic Molecular Perovskite Solid Solution

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  19. A Photoluminescent Lead Bromide Hybrid Perovskite Molecular Ferroelastic Semiconductor with Sequential High-Tc Phase Transitions

    The Journal of Physical Chemistry Letters · 2021-05-27

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  20. Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu(HCOO)2Cl

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  21. High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me3NCH2CH2OH)4[Ni(NCS)6]

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  22. Metal ion modulation triggers dielectric double switching and green fluorescence in A 2 MX 4 -type compounds

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  23. Dual-channel control of ferroelastic domains in a host–guest inclusion compound

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  24. Ferroelastic phase transition with large spontaneous strain caused by freezing the conformational dynamics of ammonium

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  25. Ferroic phase transition molecular crystals

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  26. H/F Substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic

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  27. High temperature hybrid perovskite multifunctional switching materials constructed through precise molecular design

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  28. Metal regulated organic–inorganic hybrid ferroelastic materials: [(CH 3 ) 3 CN(CH 3 ) 2 CH 2 F] 2 [MBr 4 ] (M = Cd and Zn)

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  29. Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic

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  30. Insights into the Molecular Dynamics of Quasi-Spherical (Chloromethyl)triethylammonium Confined in a Weakly Bound Ionic Cocrystal

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  31. Ammonium Sulfate Structure-Type Hybrid Metal Halide Ferroelectric with Giant Uniaxial Spontaneous Strain

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  32. Ferroelasticity in Organic–Inorganic Hybrid Perovskites

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  33. Above room-temperature dielectric switching in a new Zn-halide hybrid crystal based on pyrrolidine-derivative

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  34. A New Zn(II) Metal Hybrid Material of 5-Nitrobenzimidazolium Organic Cation (C7H6N3O2)2[ZnCl4]: Elaboration, Structure, Hirshfeld Surface, Spectroscopic, Molecular Docking Analysis, Electric and Dielectric Properties

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  35. Solid-state molecular dynamics of a torsion-variable ammonium embedded in a deformable supramolecular framework

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  36. A chiral two-dimensional perovskite-like lead-free bismuth( iii ) iodide hybrid with high phase transition temperature

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  37. A photoluminescent chiral lead-free hybrid ferroelastic semiconductor with switchable second-harmonic generation

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  38. An anomalous ferroelastic phase transition arising from an unusual cis -/ anti -conformational reversal of polar organic cations

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  39. Pressure-Induced Ferroelastic Transition Drives a Large Shape Change in a Ni(II) Complex Single Crystal

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  40. Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system

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  41. Temperature-Tuned Variable Confined Space for Modulating Dipolar Polarization of a Disc-Shaped Ammonium Ion

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  42. Novel High-Tc, Broadband-Emission Multifunctional Hybrid Compound: (4,4-DCA)2CdCl4 with Sb Doping Enhances Fluorescence Emission

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  43. An organic–inorganic hybrid photoluminescent ferroelastic with high phase transition temperature

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  44. Designing dynamic coordination bonds in polar hybrid crystals for a high-temperature ferroelastic transition

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  45. Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH 3 ) 3 NOH] 2 [CoCl 4 ]

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  46. Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]

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  47. Switchable K–O bonds unveiling anomalous ferroelastic transitions in a polar hybrid crystal

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  48. Characterization of a New Hybrid Compound (C3H8N6)2ZnCl4·2Cl: X-ray Structure, Hirshfeld Surface, Vibrational, Thermal Stability, Dielectric Relaxation, and Electrical Conductivity

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  49. Crystal structure of catena-poly[bis(N,O-dimethylhydroxylammonium) [di-μ-bromido-dibromidostannate(II)]]

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  50. Hot-pressing boosted nonlinear optical properties in a new ferroelectric plastic crystalline material

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