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RESEARCH PAPER · Inorganic Chemistry · 2003

Synthesis and Characterization of Zirconogermanates

Jacques Plévert, Rebeca Sanchez‐Smith, Travis M. Gentz, Hailian Li, Thomas L. Groy, Omar M. Yaghi, Michael O'Keeffe

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Synthesis and Characterization of ZirconogermanatesOriginalSynthesis and Characterization of a Novel Organically Templated Open Framework Zirconogermanate with Three- and Seven-Membered Rings20Synthesis and Characterization of Zirconogermanates.022 New compounds and structures in the solid state2A germanium zeotype with a three-dimensional net of interconnected 14-, 12- and 12-ring channels. Ge 13 O 26 (OH) 4 [C 6 N 2 H 16 ] 2 (H 2 O) 1.540Crystallization of Sodium Titanium Silicate with Sitinakite Topology: Evolution from the Sodium Nonatitanate Phase3920 New compounds and structures in the solid state5Topology of Microporous Structures51Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.6Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.2In situ type study of hydrothermally prepared titanates and silicotitanates25Synthesis, Characterization, and Separation Properties of Sn− and Ti−Silicate Umbite Membranes30In2Ge6O15(OH)2(H2dien): An Open‐Framework Indate Germanate with One‐Dimensional 12‐Ring Channels58In2Ge6O15(OH)2(H2dien): An Open‐Framework Indate Germanate with One‐Dimensional 12‐Ring Channels8Reconstruction of umbite framework variants by atomistic simulations using XRD and sorption data9Synthesis and Characterization of Protonated Zirconium Trisilicate and Its Exchange Phases with Strontium9GeB4O9⋅H2en: An Organically Templated Borogermanate with Large 12‐Ring Channels Built by B4O9 Polyanions and GeO4 Units: Host–Guest Symmetry and Charge Matching in Triangular‐Tetrahedral Frameworks78Formation of Micro/Macroporous Hierarchical Spheres of Titanosilicate Umbite9Spheres of Microporous Titanosilicate Umbite with Hierarchical Pore Systems17Improved Ti-silicate umbite membranes for the separation of H215Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0Zn2+-exchange kinetics and antimicrobial properties of synthetic zirconium umbite (K2ZrSi3O9·H2O)4The Fluoride Route: A Good Opportunity for the Preparation of 2D and 3D Inorganic Microporous Frameworks8Germanate Frameworks Constructed from Oxo Germanium Cluster Building Units40Deeping into the microporosity of porous silicates Ti- and Sn-umbite4In Situ X-ray Diffraction Study of Cesium Exchange in Synthetic Umbite16(C8H22N4Zn)2Ge7O14(OH)F3: A One-Dimensional Zinc Germanate Containing Hollow Columns with an 18-Membered Window9The Structure of a Complex Open-Framework Germanate Obtained by Combining Powder Charge-Flipping and Simulated Annealing10Crystal structure, thermal flexibility and structural transformations of tin umbite and copper exchanged tin umbite prepared from clear solution2Two Tetra-CdII-Substituted Vanadogermanate Frameworks94Experimental measurement and modeling of ion exchange equilibrium and kinetics of cadmium(II) solutions over microporous stannosilicate AV-611Lanthanide Germanate Cluster Organic Frameworks Based on {Ln8Ge12} Clusters: From One-Dimensional Chains to Two-Dimensional Layers and Three-Dimensional Frameworks20Umbite Type Zirconium Germanates for Cs Removal2Synthesis and ion exchange properties of zirconogermanates0

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  1. Synthesis and Characterization of a Novel Organically Templated Open Framework Zirconogermanate with Three- and Seven-Membered Rings

    Inorganic Chemistry · 2003-08-16

    Zhicheng Liu, Linhong Weng, Zhenxia Chen, Dongyuan Zhao

    Read original paper ↗ ·

  2. Synthesis and Characterization of Zirconogermanates.

    ChemInform · 2003-11-26

    Jacques Plévert, Rebeca Sanchez‐Smith, Travis M. Gentz, Hailian Li, Thomas L. Groy, Omar M. Yaghi, M. O’Keeffe

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  3. 22 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2004-01-01

    Gary B. Hix

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  4. A germanium zeotype with a three-dimensional net of interconnected 14-, 12- and 12-ring channels. Ge 13 O 26 (OH) 4 [C 6 N 2 H 16 ] 2 (H 2 O) 1.5

    Chemical Communications · 2004-01-01

    Manuela E. Medina, Enrique Gutiérrez‐Puebla, Ángeles Monge, Natalia Snejko

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  5. Crystallization of Sodium Titanium Silicate with Sitinakite Topology: Evolution from the Sodium Nonatitanate Phase

    Chemistry of Materials · 2004-08-13

    Dmitri Medvedev, Akhilesh Tripathi, Abraham Clearfield, Aaron J. Celestian, John B. Parise, Jonathan C. Hanson

    Read original paper ↗ ·

  6. 20 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2005-01-01

    Gary B. Hix

    Read original paper ↗ ·

  7. Topology of Microporous Structures

    Reviews in Mineralogy and Geochemistry · 2005-01-01

    Sergey V. Krivovichev

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  8. Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2005-09-07

    Chao Qin, Lei Gao, Enbo Wang

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  9. Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

    Encyclopedia of Inorganic Chemistry · 2005-09-07

    Chao Qin, Lei Gao, Enbo Wang

    Read original paper ↗ ·

  10. In situ type study of hydrothermally prepared titanates and silicotitanates

    Journal of Materials Science · 2006-03-01

    Abraham Clearfield, A. Tripathi, Dmitri Medvedev, Aaron J. Celestian, John B. Parise

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  11. Synthesis, Characterization, and Separation Properties of Sn− and Ti−Silicate Umbite Membranes

    Chemistry of Materials · 2006-04-18

    Víctor Sebastián, Zhi Lin, João Rocha, Carlos Téllez, Jesús Santamarı́a, Joaquı́n Coronas

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  12. In2Ge6O15(OH)2(H2dien): An Open‐Framework Indate Germanate with One‐Dimensional 12‐Ring Channels

    Angewandte Chemie International Edition · 2007-03-13

    Guang‐Zhen Liu, Shou‐Tian Zheng, Guo‐Yu Yang

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  13. In2Ge6O15(OH)2(H2dien): An Open‐Framework Indate Germanate with One‐Dimensional 12‐Ring Channels

    Angewandte Chemie · 2007-03-13

    Guang‐Zhen Liu, Shou‐Tian Zheng, Guo‐Yu Yang

    Read original paper ↗ ·

  14. Reconstruction of umbite framework variants by atomistic simulations using XRD and sorption data

    Chemical Engineering and Processing - Process Intensification · 2007-06-23

    Nuria Navascués, Eugene D. Skouras, Vladimiros A. Nikolakis, Vasilis N. Burganos, Carlos Téllez, Joaquı́n Coronas

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  15. Synthesis and Characterization of Protonated Zirconium Trisilicate and Its Exchange Phases with Strontium

    The Journal of Physical Chemistry A · 2008-02-29

    Christopher S. Fewox, Abraham Clearfield

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  16. GeB4O9⋅H2en: An Organically Templated Borogermanate with Large 12‐Ring Channels Built by B4O9 Polyanions and GeO4 Units: Host–Guest Symmetry and Charge Matching in Triangular‐Tetrahedral Frameworks

    Chemistry - A European Journal · 2008-04-08

    Chun‐Yang Pan, Guang‐Zhen Liu, Shou‐Tian Zheng, Guo‐Yu Yang

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  17. Formation of Micro/Macroporous Hierarchical Spheres of Titanosilicate Umbite

    European Journal of Inorganic Chemistry · 2008-04-11

    Víctor Sebastián, Carlos Téllez, Joaquı́n Coronas, Jesús Santamarı́a

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  18. Spheres of Microporous Titanosilicate Umbite with Hierarchical Pore Systems

    Advanced Functional Materials · 2008-04-15

    Víctor Sebastián, Isabel Dı́az, Carlos Téllez, Joaquı́n Coronas, Jesús Santamarı́a

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  19. Improved Ti-silicate umbite membranes for the separation of H2

    Journal of Membrane Science · 2008-06-21

    Víctor Sebastián, Zhi Lin, João Rocha, Carlos Téllez, J. Santamaria, Joaquı́n Coronas

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  20. Alternative approaches to structure description

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  21. Anion-topology approach

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  22. Basic concepts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  23. Copyright Page

    Unknown journal · 2009-01-22

    Read original paper ↗ ·

  24. Dedication

    Unknown journal · 2009-01-22

    Read original paper ↗ ·

  25. Dimensional reduction in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  26. Graph theory applied to low-dimensional structural units in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  27. Preface

    Unknown journal · 2009-01-22

    Read original paper ↗ ·

  28. Structural Crystallography of Inorganic Oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  29. Topology of framework structures in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  30. Zn2+-exchange kinetics and antimicrobial properties of synthetic zirconium umbite (K2ZrSi3O9·H2O)

    Journal of Porous Materials · 2009-12-21

    Nichola Jayne Coleman, Samantha P. Lewis, Andrew P. Mendham, Vivek Trivedi

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  31. The Fluoride Route: A Good Opportunity for the Preparation of 2D and 3D Inorganic Microporous Frameworks

    Unknown journal · 2010-04-16

    Jean‐Louis Paillaud, Philippe Caullet, Jocelyne Brendlé, Angélique Simon‐Masseron, Joël Patarin

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  32. Germanate Frameworks Constructed from Oxo Germanium Cluster Building Units

    European Journal of Inorganic Chemistry · 2010-06-01

    Zhien Lin, Guo‐Yu Yang

    Read original paper ↗ ·

  33. Deeping into the microporosity of porous silicates Ti- and Sn-umbite

    Microporous and Mesoporous Materials · 2011-01-24

    Víctor Sebastián, Jorge Bosque, Izumi Kumakiri, Rune Bredesen, Alejandro Ansón‐Casaos, Juan Antonio Maciá-Agulló, Angel Linares-Solano, Carlos Téllez, Joaquı́n Coronas

    Read original paper ↗ ·

  34. In Situ X-ray Diffraction Study of Cesium Exchange in Synthetic Umbite

    Inorganic Chemistry · 2011-03-04

    Christopher S. Fewox, Abraham Clearfield, Aaron J. Celestian

    Read original paper ↗ ·

  35. (C8H22N4Zn)2Ge7O14(OH)F3: A One-Dimensional Zinc Germanate Containing Hollow Columns with an 18-Membered Window

    Inorganic Chemistry · 2012-08-10

    Quang Bac Nguyen, Kwang‐Hwa Lii

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  36. The Structure of a Complex Open-Framework Germanate Obtained by Combining Powder Charge-Flipping and Simulated Annealing

    Crystal Growth & Design · 2012-08-28

    A. Ken Inge, Shiliang Huang, Hong Chen, Francisca Moraga, Junliang Sun, Xiaodong Zou

    Read original paper ↗ ·

  37. Crystal structure, thermal flexibility and structural transformations of tin umbite and copper exchanged tin umbite prepared from clear solution

    Journal of Porous Materials · 2013-04-12

    Miguel A. R. Peixoto, Stanislav Ferdov

    Read original paper ↗ ·

  38. Two Tetra-CdII-Substituted Vanadogermanate Frameworks

    Journal of the American Chemical Society · 2014-03-18

    Jian Zhou, Jun-Wei Zhao, Qi Wei, Jie Zhang, Guo‐Yu Yang

    Read original paper ↗ ·

  39. Experimental measurement and modeling of ion exchange equilibrium and kinetics of cadmium(II) solutions over microporous stannosilicate AV-6

    Chemical Engineering Journal · 2016-03-09

    Simão P. Cardoso, Ivo S. Azenha, Zhi Lin, Inês Portugal, Alírio Egídio Rodrigues, Carlos M. Silva

    Read original paper ↗ ·

  40. Lanthanide Germanate Cluster Organic Frameworks Based on {Ln8Ge12} Clusters: From One-Dimensional Chains to Two-Dimensional Layers and Three-Dimensional Frameworks

    Inorganic Chemistry · 2016-05-24

    Lei-Lei Li, Gao-Juan Cao, Junwei Zhao, Huan He, Bai‐Feng Yang, Guo‐Yu Yang

    Read original paper ↗ ·

  41. Umbite Type Zirconium Germanates for Cs Removal

    MRS Advances · 2017-02-13

    Ryan George, Joseph A. Hriljac

    Read original paper ↗ ·

  42. Synthesis and ion exchange properties of zirconogermanates

    MRS Advances · 2018-12-27

    Ryan George, Joseph A. Hriljac

    Read original paper ↗ ·
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