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RESEARCH PAPER · Chemical Communications · 2019

One-step synthesis and growth mechanism of nitrate intercalated ZnAl LDH conversion coatings on zinc

Aliaksandr Mikhailau, Hanna M. Maltanava, Sergey K. Poznyak, Andrei N. Salak, Mikhail L. Zheludkevich, Kiryl A. Yasakau, M.G.S. Ferreira

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One-step synthesis and growth mechanism of nitrate intercalated ZnAl LDH conversion coatings on zincOriginalZn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: Comparison of crystal structure and kinetics73Enhanced corrosion protection by Al surface immobilization of in-situ grown layered double hydroxide films co-intercalated with inhibitors and low surface energy species80In situ kinetics studies of Zn-Al LDH intercalation with corrosion related species0In situ kinetics studies of Zn–Al LDH intercalation with corrosion related species33The catalytic degradation of nitrobenzene by the Cu–Co–Fe-LDH through activated oxygen under ambient conditions38Chlorides Entrapment Capability of Various In-Situ Grown NiAl-LDHs: Structural and Corrosion Resistance Properties27Layered Double Hydroxide Protective Films Developed on Aluminum and Aluminum Alloys: Synthetic Methods and Anti-Corrosion Mechanisms68Zn-Al Layered Double Hydroxide Thin Film Fabricated by the Sputtering Method and Aqueous Solution Treatment12Z–Scheme heterojunction ZnO-Au-ZnAl2O4: Bridge-type hot carrier transfer and reaction kinetics in the photodegradation of catechol44Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review183Chemical modification of LDH conversion coating with diethyldithiocarbamate as a novel anti-corrosive film for AA2024-T332Properties of ZnO/ZnAl2O4 composite PEO coatings on zinc alloy Z116Nanoscale ZrRGOCuFe layered double hydroxide composites for enhanced photocatalytic degradation of dye contaminant54One-pot scalable in situ growth of highly corrosion-resistant MgAl-LDH/MBT composite coating on magnesium alloy under mild conditions131Construction of ecofriendly anticorrosive composite film ZnAl‐LDH by modification of lignin on AA 7075 surface12Mechanism of LDH Direct Growth on Aluminum Alloy Surface: A Kinetic and Morphological Approach30Layered double hydroxide (LDH) for multi-functionalized corrosion protection of metals: A review279A comparative study of the structure and corrosion resistance of ZnAl hydrotalcite conversion layers at different Al3+/Zn2+ ratios on electrogalvanized steel20Environmentally Friendly Layered Double Hydroxide Conversion Layers: Formation Kinetics on Zn–Al–Mg-Coated Steel40Improved SERS detection of anionic pollutant with Ag Nanoparticles-decorated ZnAl layered double hydroxide nanosheets array8The Role of an In-Situ Grown Zn-Al Layered Double Hydroxide Conversion Coating in the Protective Properties of Epoxy Coating on Galvanized Steel24In situ synergistic strategy of sacrificial intermedium for scalable-manufactured and controllable layered double hydroxide film15Layered materials as nanocontainers for active corrosion protection: A brief review34Supported Ru nanocatalyst over phosphotungstate intercalated Zn-Al layered double hydroxide derived mixed metal oxides for efficient hydrodeoxygenation of guaiacol27Study of the formation and anti-corrosion properties of Zn Al hydrotalcite conversion films grown “in situ” on different zinc alloys coated steel14Self-healing and corrosion-sensing coatings based on pH-sensitive MOF-capped microcontainers for intelligent corrosion control93Layered double hydroxides for corrosion-related applications—Main developments from 20 years of research at CICECO24LDH has been grown: What is next? Overview on methods of post-treatment of LDH conversion coatings56Nanocontainers: A comprehensive review on their application in the stimuli-responsive smart functional coatings55Functional Regulation of ZnAl-LDHs and Mechanism of Photocatalytic Reduction of CO2: A DFT Study23Corrosion Inhibitors Intercalated into Layered Double Hydroxides Prepared In Situ on AZ91 Magnesium Alloys: Structure and Protection Ability42Enhanced corrosion resistance and biofunctionality of Zn–Al layered double hydroxide coating on micro-arc oxidized ZK60 Mg alloy via ion exchange22Methodology for development of smart epoxy coatings incorporated with Ethylenediamine-N, N'-disuccinic ac-id (EDDS) layered double hydroxides (LDHs) for corrosion protection of XC38 carbon steel0Zinc-aluminum layered double hydroxide and double oxide for room-temperature oxidation of sulfur dioxide gas9Benzotriazole modified Zn-Al layered double hydroxide conversion coating on galvanized steel for improved corrosion resistance31Influence of solution pH on the structure formation and protection properties of ZnAlCe hydrotalcites layers on hot-dip galvanized steel9Development of superhydrophobic layered double hydroxide directly on zinc substrate: structural and corrosion resistance properties6Corrosion protection of zinc by LDH conversion coatings54Surface Hydroxyl and Oxygen Vacancies Engineering in ZnSnAl LDH: Synergistic Promotion of Photocatalytic Oxidation of Aromatic VOCs71An Inhibitor-Loaded LDH- and MOF-Based Bilayer Hybrid System for Active Corrosion Protection of Aluminum Alloys47Revolutionizing corrosion protection in seawater using innovative layered double hydroxide/polyvinylidene fluoride LDH@PVDF composite coatings12MoO42−-LDH films for active protection of steel substrates by Electrodeposition–Hydrothermal method14A review: Hydrotalcite layers as protective coatings on zinc and zinc alloys4The influence of reaction-time-determined surface morphology on corrosion resistance of Zn-Al LDH coatings on zinc surfaces3Study on a facile method of in-situ fabricating enhanced corrosion protection LDH/PEO composites coating on Mg alloy and its growth behavior16Advances in LDHs for corrosion-resistant protection of Mg and Al alloys: A review55Active corrosion protection of AA2024T3 by the synergy of flash-PEO/Ce coating and epoxy coating loaded with LDH/eco-friendly gluconate4Synergy of consecutive PEO and LDH surface treatments on the corrosion protection and adhesion strength of organic coatings on AA2024T35Study on the adsorption mechanism of heavy metal ions by Thiosulfate-Intercalated ZnAl-LDH13Effects of anions in a physiological environment on corrosion behavior of pure zinc1Recent Developments in Layered Double Hydroxides as Anticorrosion Coatings8Graphene oxide/chitosan-layered double hydroxides for dye decolorization, oxygen evolution reaction and bactericidal inactivation1In-situ chemical conversion approach for growth of magnesium-aluminium-layered double hydroxide thin films: Room temperature NO2 sensing1The role of ZnAl hydrotalcite conversion layers in corrosion protection of acrylic coating on electrogalvanized steel3In-situ intercalation of ZnAl LDH materials: Multidimensional regulation of zinc behavior toward stable and reversible zinc anodes2Picolinoyl N4-Phenylthiosemicarbazide-Modified ZnAl and ZnAlCe Layered Double Hydroxide Conversion Films on Hot-Dip Galvanized Steel for Enhancing Corrosion Protection in Saline Solution0Temperature-regulated microstructure and corrosion resistance of Zn-Al LDH coatings on biomedical Zn0

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  1. Zn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: Comparison of crystal structure and kinetics

    Applied Surface Science · 2019-10-01

    Anissa C. Bouali, Mariia H. Iuzviuk, Maria Serdechnova, Kiryl A. Yasakau, D. C. Florian Wieland, Gleb Dovzhenko, Hanna M. Maltanava, I.A. Zobkalo, M.G.S. Ferreira, Mikhail L. Zheludkevich

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  2. Enhanced corrosion protection by Al surface immobilization of in-situ grown layered double hydroxide films co-intercalated with inhibitors and low surface energy species

    Corrosion Science · 2019-11-12

    Yanhui Cao, Dajiang Zheng, Jingsong Luo, Fan Zhang, Cheng Wang, Shigang Dong, Yan Long Ma, Zhaoyuan Liang, Changjian Lin

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  3. In situ kinetics studies of Zn-Al LDH intercalation with corrosion related species

    PubMed · 2020-01-01

    Mariia H. Iuzviuk, Anissa C. Bouali, Maria Serdechnova, Kiryl A. Yasakau, D. C. Florian Wieland, Gleb Dovzhenko, Aliaksandr Mikhailau, Carsten Blawert, I.A. Zobkalo, M.G.S. Ferreira, Mikhail L. Zheludkevich

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  4. In situ kinetics studies of Zn–Al LDH intercalation with corrosion related species

    Physical Chemistry Chemical Physics · 2020-01-01

    Mariia H. Iuzviuk, Anissa C. Bouali, Maria Serdechnova, Kiryl A. Yasakau, D. C. Florian Wieland, Gleb Dovzhenko, Aliaksandr Mikhailau, Carsten Blawert, I.A. Zobkalo, M.G.S. Ferreira, Mikhail L. Zheludkevich

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  5. The catalytic degradation of nitrobenzene by the Cu–Co–Fe-LDH through activated oxygen under ambient conditions

    Dalton Transactions · 2020-01-01

    Shaohong Wang, Jiayi Zhu, Sisi Zhang, Xiwang Zhang, Fei Ge, Yin Xu

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  6. Chlorides Entrapment Capability of Various In-Situ Grown NiAl-LDHs: Structural and Corrosion Resistance Properties

    Coatings · 2020-04-14

    Muhammad Ahsan Iqbal, Luyi Sun, Humaira Asghar, Michele Fedel

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  7. Layered Double Hydroxide Protective Films Developed on Aluminum and Aluminum Alloys: Synthetic Methods and Anti-Corrosion Mechanisms

    Coatings · 2020-04-25

    Muhammad Ahsan Iqbal, Luyi Sun, Allyson T. Barrett, Michele Fedel

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  8. Zn-Al Layered Double Hydroxide Thin Film Fabricated by the Sputtering Method and Aqueous Solution Treatment

    Coatings · 2020-07-13

    Jae-Hwan Shin, Kyunghwan Kim, Jeongsoo Hong

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  9. Z–Scheme heterojunction ZnO-Au-ZnAl2O4: Bridge-type hot carrier transfer and reaction kinetics in the photodegradation of catechol

    Applied Surface Science · 2020-08-06

    Guanhua Zhang, Tiantian Dai, Yue Zhong Meng, Lianyang Zhang, Chao Yang, Guoxiang Pan, Zheming Ni, Shengjie Xia

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  10. Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review

    Applied Materials Today · 2020-10-28

    Anissa C. Bouali, Maria Serdechnova, Carsten Blawert, João Tedim, M.G.S. Ferreira, Mikhail L. Zheludkevich

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  11. Chemical modification of LDH conversion coating with diethyldithiocarbamate as a novel anti-corrosive film for AA2024-T3

    Journal of Industrial and Engineering Chemistry · 2020-12-24

    Iman Mohammadi, Taghi Shahrabi, Mohammad Mahdavian, Mazdak Izadi

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  12. Properties of ZnO/ZnAl2O4 composite PEO coatings on zinc alloy Z1

    Surface and Coatings Technology · 2021-02-05

    Maria Serdechnova, Carsten Blawert, Карпушенков Сергей Александрович, Larisa S. Karpushenkava, Tatsiana Shulha, Polina Karlova, Rastko Vasilić, Stevan Stojadinović, Srna Stojanović, Ljiljana Damjanović-Vasilić, Volker Heitmann, S.M. Rabchynski, Mikhail L. Zheludkevich

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  13. Nanoscale ZrRGOCuFe layered double hydroxide composites for enhanced photocatalytic degradation of dye contaminant

    Materials Science in Semiconductor Processing · 2021-03-07

    Ome Parkash Kumar, Muhammad Naeem Ashiq, Syed Shoaib Ahmad Shah, Shahbaz Akhtar, Mudhar Abdul Alwahab Al-Obaidi, Iqbal Mohammed Mujtaba, Aziz ur Rehman

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  14. One-pot scalable in situ growth of highly corrosion-resistant MgAl-LDH/MBT composite coating on magnesium alloy under mild conditions

    Journal of Material Science and Technology · 2021-04-28

    Ting Hu, Yuejun Ouyang, Zhihui Xie, Liang Wu

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  15. Construction of ecofriendly anticorrosive composite film ZnAl‐LDH by modification of lignin on AA 7075 surface

    Materials and Corrosion · 2021-05-13

    Yanhui Cao, Dajiang Zheng, Changjian Lin

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  16. Mechanism of LDH Direct Growth on Aluminum Alloy Surface: A Kinetic and Morphological Approach

    The Journal of Physical Chemistry C · 2021-05-19

    Anissa C. Bouali, Mariia H. Iuzviuk, Maria Serdechnova, Kiryl A. Yasakau, Daria Drozdenko, Alexander Lutz, Klaudia Fekete, Gleb Dovzhenko, D. C. Florian Wieland, Herman Albert Terryn, M.G.S. Ferreira, I.A. Zobkalo, Mikhail L. Zheludkevich

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  17. Layered double hydroxide (LDH) for multi-functionalized corrosion protection of metals: A review

    Journal of Material Science and Technology · 2021-08-26

    Yanhui Cao, Dajiang Zheng, Fan Zhang, Jinshan Pan, Changjian Lin

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  18. A comparative study of the structure and corrosion resistance of ZnAl hydrotalcite conversion layers at different Al3+/Zn2+ ratios on electrogalvanized steel

    Surface and Coatings Technology · 2021-11-27

    Thu Thuy Pham, Thuy Duong Nguyen, Anh Son Nguyen, Yoann Paint, Maurice Gonon, Thi Xuan Hang To, Marie‐Georges Olivier

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  19. Environmentally Friendly Layered Double Hydroxide Conversion Layers: Formation Kinetics on Zn–Al–Mg-Coated Steel

    ACS Applied Materials & Interfaces · 2022-01-20

    Tobias Holzner, Gerald H. Luckeneder, Bernhard Strauß, Markus Valtiner

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  20. Improved SERS detection of anionic pollutant with Ag Nanoparticles-decorated ZnAl layered double hydroxide nanosheets array

    Materials Letters · 2022-02-09

    Kexi Sun, Zihui Tang, Qiangsheng Zhao, Quan Deng, Xiujuan Wang, Haibin Tang

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  21. The Role of an In-Situ Grown Zn-Al Layered Double Hydroxide Conversion Coating in the Protective Properties of Epoxy Coating on Galvanized Steel

    Journal of The Electrochemical Society · 2022-03-01

    Sima Amanian, Reza Naderi, Mohammad Mahdavian

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  22. In situ synergistic strategy of sacrificial intermedium for scalable-manufactured and controllable layered double hydroxide film

    Science China Materials · 2022-03-25

    Yixing Zhu, Guang‐Ling Song, Dajiang Zheng, Maria Serdechnova, Carsten Blawert, Mikhail L. Zheludkevich

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  23. Layered materials as nanocontainers for active corrosion protection: A brief review

    Applied Clay Science · 2022-05-17

    Débora Abrantes Leal, Alena I. Kuznetsova, Gabriel Machado Silva, João Tedim, Fernando Wypych, Cláudia Eliana Bruno Marino

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  24. Supported Ru nanocatalyst over phosphotungstate intercalated Zn-Al layered double hydroxide derived mixed metal oxides for efficient hydrodeoxygenation of guaiacol

    Molecular Catalysis · 2022-07-13

    Zihang Wang, An Wang, Lan Yang, Guoli Fan, Feng Li

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  25. Study of the formation and anti-corrosion properties of Zn Al hydrotalcite conversion films grown “in situ” on different zinc alloys coated steel

    Progress in Organic Coatings · 2022-09-29

    Thu Thuy Pham, Thuy Duong Nguyen, Anh Son Nguyen, Maurice Gonon, Xavier Noirfalise, Yoann Paint, Thi Xuan Hang To, Marie‐Georges Olivier

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  26. Self-healing and corrosion-sensing coatings based on pH-sensitive MOF-capped microcontainers for intelligent corrosion control

    Chemical Engineering Journal · 2022-11-15

    Tong Liu, Dawei Zhang, Rongjun Zhang, Jinke Wang, Lingwei Ma, Patrick Keil, J.M.C. Mol, Xiaogang Li

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  27. Layered double hydroxides for corrosion-related applications—Main developments from 20 years of research at CICECO

    Frontiers in Chemistry · 2022-11-17

    João Tedim, Tiago L. P. Galvão, Kiryl A. Yasakau, Alexandre Cunha Bastos, José R. B. Gomes, M.G.S. Ferreira

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  28. LDH has been grown: What is next? Overview on methods of post-treatment of LDH conversion coatings

    Applied Clay Science · 2022-12-09

    Valeryia I. Kasneryk, Maria Serdechnova, Carsten Blawert, Mikhail L. Zheludkevich

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  29. Nanocontainers: A comprehensive review on their application in the stimuli-responsive smart functional coatings

    Progress in Organic Coatings · 2023-01-10

    Saman Zehra, Mohammad Mobin, Ruby Aslam, Shahidul Islam Bhat

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  30. Functional Regulation of ZnAl-LDHs and Mechanism of Photocatalytic Reduction of CO2: A DFT Study

    Molecules · 2023-01-11

    Dongcun Xu, Gang Fu, Zhong‐Ming Li, Wenqing Zhen, Hongyi Wang, Meiling Liu, Jianmin Sun, Jiaxu Zhang, Li Yang

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  31. Corrosion Inhibitors Intercalated into Layered Double Hydroxides Prepared In Situ on AZ91 Magnesium Alloys: Structure and Protection Ability

    ACS Applied Materials & Interfaces · 2023-01-23

    Tatsiana Shulha, Maria Serdechnova, Sviatlana V. Lamaka, Xiaopeng Lu, Christian Feiler, Carsten Blawert, Mikhail L. Zheludkevich

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  32. Enhanced corrosion resistance and biofunctionality of Zn–Al layered double hydroxide coating on micro-arc oxidized ZK60 Mg alloy via ion exchange

    Materials Chemistry and Physics · 2023-02-10

    Zheng-Yi Zhang, Sheng Lu, Wei-Gang Lv, Junjie Gu, Shu-Fan Zhou, Jinwei Zhang, Dubovyy Oleksandr, Zexin Wang, Liang‐Yu Chen

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  33. Methodology for development of smart epoxy coatings incorporated with Ethylenediamine-N, N'-disuccinic ac-id (EDDS) layered double hydroxides (LDHs) for corrosion protection of XC38 carbon steel

    Unknown journal · 2023-07-03

    Gata Joseph Ayemi

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  34. Zinc-aluminum layered double hydroxide and double oxide for room-temperature oxidation of sulfur dioxide gas

    Chemosphere · 2023-07-13

    Nishesh Kumar Gupta, Carolina Leyva, Herlys Viltres, Rushikesh P. Dhavale, Kwang Soo Kim, Adolfo Romero-Galarza, Hyung‐Ho Park

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  35. Benzotriazole modified Zn-Al layered double hydroxide conversion coating on galvanized steel for improved corrosion resistance

    Journal of the Taiwan Institute of Chemical Engineers · 2023-07-29

    Sima Amanian, Reza Naderi, Mohammad Mahdavian

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  36. Influence of solution pH on the structure formation and protection properties of ZnAlCe hydrotalcites layers on hot-dip galvanized steel

    Surface and Coatings Technology · 2023-08-25

    Thu Thuy Pham, Thuy Duong Nguyen, Anh Son Nguyen, Maurice Gonon, Alice Belfiore, Yoann Paint, Thi Xuan Hang To, Marie‐Georges Olivier

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  37. Development of superhydrophobic layered double hydroxide directly on zinc substrate: structural and corrosion resistance properties

    Bulletin of Materials Science · 2023-11-10

    Muhammad Ahsan Iqbal, Humaira Asghar, M. Mohedano, Michele Fedel

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  38. Corrosion protection of zinc by LDH conversion coatings

    Corrosion Science · 2024-02-02

    Kiryl A. Yasakau, Alena I. Kuznetsova, Hanna M. Maltanava, Sergey K. Poznyak, M.G.S. Ferreira, Mikhail L. Zheludkevich

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  39. Surface Hydroxyl and Oxygen Vacancies Engineering in ZnSnAl LDH: Synergistic Promotion of Photocatalytic Oxidation of Aromatic VOCs

    Environmental Science & Technology · 2024-02-04

    Biyuan Liu, Boge Zhang, Biying Liu, Zhuofeng Hu, Wenjing Dai, Jiarui Zhang, Fada Feng, Bang Lan, Tao Zhang, Haibao Huang

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  40. An Inhibitor-Loaded LDH- and MOF-Based Bilayer Hybrid System for Active Corrosion Protection of Aluminum Alloys

    ACS Applied Materials & Interfaces · 2024-02-26

    Zhe Zhang, Juping Wang, Maria Serdechnova, Valeryia I. Kasneryk, Zheng Zhang, Carsten Blawert, Hao Wang, Mikhail L. Zheludkevich, Fei Chen, You Zhang

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  41. Revolutionizing corrosion protection in seawater using innovative layered double hydroxide/polyvinylidene fluoride LDH@PVDF composite coatings

    Arabian Journal of Chemistry · 2024-04-05

    Jwaher M. AlGhamdi, Hissah A. Alqahtani, Nuhu Dalhat Mu’azu, Mukarram Zubair, Shamsuddeen A. Haladu, Mohammad Saood Manzar

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  42. MoO42−-LDH films for active protection of steel substrates by Electrodeposition–Hydrothermal method

    Applied Surface Science · 2024-05-20

    Qingrui Yang, Wenjie Liu, Xiang Wang, Biqin Dong, Dongshuai Hou, Feng Xing, Qi Luo, Shuxian Hong

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  43. A review: Hydrotalcite layers as protective coatings on zinc and zinc alloys

    Vietnam Journal of Science and Technology/Science and Technology · 2024-12-23

    Tô Thị Xuân Hằng, Thu Thuy Pham, Thuy-Duong Nguyen, Marie‐Georges Olivier

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  44. The influence of reaction-time-determined surface morphology on corrosion resistance of Zn-Al LDH coatings on zinc surfaces

    Materials Letters · 2024-12-31

    Baoe Li, Xiaopeng Fu, Peihang Zhao, Feng Peng, Donghui Wang, Haipeng Li, Chunyong Liang, Hongshui Wang

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  45. Study on a facile method of in-situ fabricating enhanced corrosion protection LDH/PEO composites coating on Mg alloy and its growth behavior

    Surface and Coatings Technology · 2025-02-12

    Wenyi Qiu, Xinglong Ye, Yan Liu, Bin Lin, Junfeng Chen, Lei Xiao, Chen Wang, Bingshu Wang, Xiping Cui, Linchi Zou

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  46. Advances in LDHs for corrosion-resistant protection of Mg and Al alloys: A review

    Journal of Magnesium and Alloys · 2025-03-01

    Lin Wang, Fen Zhang, Zuo-Jun Jiao, Lan‐Yue Cui, Yuan-Ding Huang, Shuo‐Qi Li, Cheng‐Bao Liu, Rong‐Chang Zeng

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  47. Active corrosion protection of AA2024T3 by the synergy of flash-PEO/Ce coating and epoxy coating loaded with LDH/eco-friendly gluconate

    Progress in Organic Coatings · 2025-05-08

    Muhammad Ahsan Iqbal, Frederico Maia, Endzhe Matykina, Raul Arrabal, M. Mohedano, Jesús Manuel Vega

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  48. Synergy of consecutive PEO and LDH surface treatments on the corrosion protection and adhesion strength of organic coatings on AA2024T3

    Progress in Organic Coatings · 2025-05-28

    Muhammad Ahsan Iqbal, Humaira Asghar, Endzhe Matykina, Raul Arrabal, M. Mohedano, Jesús Manuel Vega

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  49. Study on the adsorption mechanism of heavy metal ions by Thiosulfate-Intercalated ZnAl-LDH

    Inorganic Chemistry Communications · 2025-05-29

    Jinhui Li, Yuming Wei, Laixi Zou, Luo Yue, Yaozong Liu, Shuaidong Li

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  50. Effects of anions in a physiological environment on corrosion behavior of pure zinc

    Materials Today Communications · 2025-06-10

    Suqin Wang, Rui Yue, Yusong Pan, Xiancai Meng, Ruotong Zhu, Yu Bo Zuo, Dunfeng Zeng, Shaoding Sheng

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