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RESEARCH PAPER · Journal of Energy Chemistry · 2018

Highly efficient extraction of lithium from salt lake brine by LiAl-layered double hydroxides as lithium-ion-selective capturing material

Ying Sun, Xiaoyu Guo, Shaofang Hu, Xu Xiang

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Highly efficient extraction of lithium from salt lake brine by LiAl-layered double hydroxides as lithium-ion-selective capturing materialOriginalThe Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides25Spodumene: The Lithium Market, Resources and Processes248Highly Efficient Lithium Recovery from Pre-Synthesized Chlorine-Ion-Intercalated LiAl-Layered Double Hydroxides via a Mild Solution Chemistry Process48Determination of boundary conditions for highly efficient separation of magnesium and lithium from salt lake brine by reaction-coupled separation technology56Continuous Lithium Extraction from Aqueous Solution Using Flow-Electrode Capacitive Deionization55PVC-based hybrid membranes containing metal-organic frameworks for Li+/Mg2+ separation188Enriching lithium and separating lithium to magnesium from sulfate type salt lake brine58Photocatalytic selective oxidation of benzene to phenol in water over layered double hydroxide: A thermodynamic and kinetic perspective111Synergic and competitive adsorption of Li–Na–MgCl2 onto lithium–aluminum hydroxides29Application of concentration-dependent HSDM to the lithium adsorption from brine in fixed bed columns62Metal oxide sorbents for the sustainable recovery of lithium from unconventional resources81Microbubble-assisted pressure carbonation for preparation of high purity lithium carbonate20Quantitative Effects of Desorption Intensity on Structural Stability and Readsorption Performance of Lithium/Aluminum Layered Double Hydroxides in Cyclic Li + Extraction from Brines with Ultrahigh Mg/Li Ratio71Transport and Electrochemical Characteristics of CJMCED Homogeneous Cation Exchange Membranes in Sodium Chloride, Calcium Chloride, and Sodium Sulfate Solutions28Electrostatic‐Assembled MXene@NiAl‐LDHs Electrodes with 3D Interconnected Networks Architectures for High‐Performance Pseudocapacitor Storage31Lithium extraction from synthetic brine with high Mg2+/Li+ ratio using the polymer inclusion membrane107Recent advances in magnesium/lithium separation and lithium extraction technologies from salt lake brine681Tailoring hydrophobic deep eutectic solvent for selective lithium recovery from the mother liquor of Li2CO3142Lithium separation by growth of lithium aluminum layered double hydroxides on aluminum metal substrates26Progress in electrochemical lithium ion pumping for lithium recovery98The extraction rules investigation of mental (Li, Na, K, Mg, Ca) ion in salt lake brine by TBP-FeCl3 extraction system19Post-transition metal/polymer composites for the separation and sensing of alkali metal ions16A Nano‐Heterogeneous Membrane for Efficient Separation of Lithium from High Magnesium/Lithium Ratio Brine384Selective Lithium Adsorption of Silicon Oxide Coated Lithium Aluminum Layered Double Hydroxide Nanocrystals and Their Regeneration20Spray-drying assisted layer-structured H2TiO3 ion sieve synthesis and lithium adsorption performance31Highly Efficient Lithium Extraction from Brine with a High Sodium Content by Adsorption-Coupled Electrochemical Technology101Membranes for separation of alkali/alkaline earth metal ions: A review73Advantages of pH and Temperature Control in the Carbonation Stage for Li 2 CO 3 Production with Sulphated Liquors2Crown Ether Grafted Graphene Oxide/Chitosan/Polyvinyl Alcohol Nanofiber Membrane for Highly Selective Adsorption and Separation of Lithium Ion39Polyacrylonitrile hybrid membrane coated with aluminum hydroxide for separating lithium13Polyacrylonitrile/Crown Ether Composite Nanofibres With High Efficiency for Adsorbing Li(I): Experiments and Theoretical Calculations15High flux Mg2+/Li+ nanofiltration membranes prepared by surface modification of polyethylenimine thin film composite membranes92Extracting lithium from the H2SO4 leaching solution of bauxitic claystone via co-precipitation methods without addition of Al source26Zr-doped titanium lithium ion sieve and EP-granulated composite: Superb adsorption and recycling performance82Direct Lithium Recovery from Aqueous Electrolytes with Electrochemical Ion Pumping and Lithium Intercalation40Extraction and Separation of Li+ from High-Ratio Mg/Li Salt Lake Brines by [C2mim][Ntf2] Ionic Liquid and a Homemade Extractor38Facile strategy for the construction of a robust underbrine superoleophobic membrane for highly efficient oil-brine separation2Construction of truncated-octahedral LiMn2O4 for battery-like electrochemical lithium recovery from brine86Stable ionic liquid-based polymer inclusion membranes for lithium and magnesium separation60Synthesis of granulated Li/Al-LDHs adsorbent and application for recovery of Li from synthetic and real salt lake brines86Adsorption of Li(I) Ions through New High-Performance Electrospun PAN/Kaolin Nanofibers: A Combined Experimental and Theoretical Calculation34Recovery of Lithium Ions From Salt Lakes Using Nanofibers Containing Zeolite Carriers11Selective recovery of lithium resources in salt lakes by polyacrylonitrile/ion-imprinted polymer: Synthesis, testing, and computation20Construction of porous disc-like lithium manganate for rapid and selective electrochemical lithium extraction from brine39Hydrophilic Modification Using Polydopamine on Core–Shell Li1.6Mn1.6O4@Carbon Electrodes for Lithium Extraction from Lake Brine81Lithium intercalation and deintercalation of thermally decomposed LiAl2-layered double hydroxides27Quaternary ammonium engineered polyamide membrane with high positive charge density for efficient Li+/Mg2+separation124Double-edged role of interlayer water on Li+ extraction from ultrahigh Mg2+/Li+ ratio brines using Li/Al-LDHs68Metal-based adsorbents for lithium recovery from aqueous resources176Two-dimensional materials in enhancement of membrane-based lithium recovery from metallic-ions-rich wastewaters: A review74Phosphate Functionalized Ionic Liquid: An Efficient Li+ Migration Inhibitor and Hole Extraction Accelerator for Perovskite Solar Cells7Recent advances in lithium extraction from salt lake brine using coupled and tandem technologies194Fabrication of Fe-doped lithium-aluminum-layered hydroxide chloride with enhanced reusable stability inspired by computational theory and its application in lithium extraction75Chitosan grafted with crown ether with high selectivity and adsorption on lithium-ion8Technological tendencies for lithium production from salt lake brines: Progress and research gaps to move towards more sustainable processes75Particle size control and electrochemical lithium extraction performance of LiMn2O446Bifunctional Modification Enhances Lithium Extraction from Brine Using a Titanium-Based Ion Sieve Membrane Electrode66Synthesis and Lithium Adsorption Performance of NiFe2O4@AlLi-LDH9Anion regulation strategy of lithium-aluminum layered double hydroxides for strengthening resistance to deactivation in lithium recovery from brines109Interlayer confinement imprinting to enhance the feasibility of Li/Al-LDHs in lithium extraction from sulfate-type brines38Clean Process for Selective Recovery of Lithium Carbonate from Waste Lithium-Bearing Aluminum Electrolyte Slag23Multifunctional AlPO4 reconstructed LiMn2O4 surface for electrochemical lithium extraction from brine78A directional growth strategy for high layer charge Li / Al‐LDHs to reinforce Li+ extraction in low‐grade salt lake brines18Recent Innovations and Patents of Lithium Extraction Techniques from Various Lithium Bearing Solutions0Lithium Extraction from an Aqueous Medium through In Situ Synthesis of Aluminum Hydroxide: A Comprehensive Study on Adsorption and Desorption Processes, Kinetics, Isotherm Models, and Thermodynamic Parameters8Efficient Step-by-Step Desorption to Reduce Boron in Brine Lithium Extraction11A sustainable method for lithium recovery from waste liquids: Thermodynamic analysis and application20Synthesis and optimisation mechanism of functionalised adsorption materials for lithium-ion extraction from salt water: A review77Adsorbents for lithium extraction from salt lake brine with high magnesium/lithium ratio: From structure-performance relationship to industrial applications225Separation effect of Li+, Na+, and Mg2+ with alumina–lithium LDH doped with amorphous titanium dioxide16Enhanced lithium separation with Li1.3Al0.3Ti1.7(PO4)3 lithium superionic conductor and aided charge balance17Efficient extraction of the structural lithium from cookeite through a combined approach of roasting-leaching, co-precipitation, and elution16Instant Interlayer Restoration Strategy for Lithium Adsorption Engineering Enhancement in Sulfate-type Brines14Efficient recovery of lithium from spent lithium-ion battery raffinate by Mn and Al-based adsorbents: pretreatment, adsorption mechanism, and performance comparison24Modulating porosity and hydrophilicity of granular adsorbent by water-soluble polymers to enhance lithium extraction from ultrahigh Mg/Li ratio brine21High mixing enhancement for continuous uniformity Li/Al-LDHs in lithium extraction from low grade salt lakes16Configuring a structure self-curable lithium aluminum layered double hydroxide chloride type lithium adsorbents via a facile one-pot synergistical modification way38Study on lithium extraction from natural brine without additional energy consumption by photocatalytic technology5Uncovering fantastic synergistic lithium adsorption with manganese-titanium based composite nanospheres: Mild synthesis and molecular dynamics simulation insights16Preparation of composites of lithium-aluminum layered double hydroxides and biochar and their performance in lithium extraction from aqueous media8Self‐Oxidated Hybrid Conductive Network Enables Efficient Electrochemical Lithium Extraction Under High‐Altitude Environment12Exploring lithium extraction technologies in oil and gas field-produced waters: from waste to valuable resource23Research progress of technology of lithium extraction66Research Status and Development Trends of Inorganic Salt Lake Resource Extraction Based on Bibliometric Analysis11Direct Lithium Extraction from Spodumene Ore Via Alkali Leaching-Li/Al Co-Precipitation Method0Efficient Regeneration and Structural Transformation Pathways Observed of LiAl-LDHs Adsorbents0Efficient Regeneration and Structural Transformation Pathways Observed of LiAl-LDHs Adsorbents0Preparation of Interlayer Anion Controllable LiAl-LDHs and Lithium Adsorption Performance0Tuning Li/Al-LDHs nucleation and active sites toward enhanced lithium extraction32Enhanced lithium extraction from high-sodium brines: Modification of a manganese-based ion sieve using hydroxylated graphene and graphene oxide14Recent advances in heteroatom doping for performance optimization of inorganic metal-based lithium-ion adsorbents19Direct lithium extraction from α-spodumene ore via alkali leaching-Li/Al co-precipitation method17pH-responsive nanofiltration membrane with color monitoring for efficient Mg2+/Li+ separation9Photo-curable layered double hydroxide-hyaluronic acid-composite hydrogels with multifunctional properties for growth factor-free bone regeneration8Facile synthesis of aluminum-based adsorbents from spent lithium-ion batteries for efficient Li+ extraction3Lithium-selective extraction utilizing lithium-trap LiAlFe-LDHs/MWCNTs/QCS composite membrane within the ship lock-type ion selective permeability system6Lithium extraction from salt‐lake brines using dicationic ionic liquids: ePC ‐ SAFT modeling and molecular mechanisms11Competitive cation effects on lithium extraction: Unraveling structural variation mechanisms of butyrate@AlLi-LDHs2Preparation of a Cross-linked CTS Composite Ion Sieve and a Study of Lithium Adsorption from Oilfield Brines1Synergistic effect of polymer-ZIF-8 and γ-CDs anchored polyamide membranes for enhanced Li+/Mg2+ separation7Granulating-avoiding aluminum-based adsorbents for fast salt lake lithium extraction with low freshwater consumption7Electro-assisted functional nanofiltration membrane for enhancing Li+ enrichment and Li+/Mg2+ separation10Deep insights into LDH reconstruction for enhanced capacitive deionization4The recent advances and modification strategies of Li/Al-LDHs toward lithium extraction6Multi-dimensional regulation of the cycling stability of lithium manganese oxides: A review1Lithium Extraction from Acidic Salt Lake Brine Using Solvent Extraction to Prepare Lithium Carbonate: Process Optimization and Mechanism Analysis3Efficient regeneration and structural transformation pathways observed of LiAl-LDHs adsorbents3Extractant-functionalized LiAl-LDH membrane with synergistic sites for high permeability and selectivity for Li+/Mg2+ separation3Critical raw materials: geological perspectives, unconventional resources and disruptive opportunities0Harvesting lithium from brines via high-selectivity nanofiltration integrated with membrane distillation6Effect of SO42− anions on lithium-aluminum layered double hydroxides: Implications for Li+ recovering from brines5Secondary resources and advanced separation technologies for critical metal recovery: Progress and challenges7Industrial extraction of lithium from Urmia Lake using precipitation and evaporation methods2Controllable Synthesis of Organic-Cladding Li/Al-LDH and Its High Cycling Performance for Lithium Extraction from Salt Lakes3A review of Al-based lithium adsorbents for efficient lithium recovery from salty brine: adsorption mechanism and application progress7An Induced Li + Oriented Migration Strategy for High‐Efficiency Extremely Strong Acid Lithium Recovery2An Induced Li + Oriented Migration Strategy for High‐Efficiency Extremely Strong Acid Lithium Recovery1A paradigm of plate-pressing-driven electrode microstructure design for regulating polarization and Li+/Na+ selectivity in electrochemical deintercalation from salt-lake brines0In situ growth preparation of bio-inspired Al-based Li+ sieve membranes for sustainable Li-extraction from original brines1Direct Lithium Extraction from a Complex Acidic Brine Using Aluminum Hydroxide0Microwave-assisted synthesis of FeN Co-doped ZIF-8 derived carbon for low-concentration lithium recovery via CDI: Adsorption performance and mechanism0Synergetic effective lithium-ion adsorption and complexation by molecularly engineered Schiff base functionalized bio-composite: From molecular design to life cycle assessment1Lithium Capture in Gibbsite-Derived Layered Double Hydroxides: Molecular Insights into Intercalation and Lattice Incorporation Mechanisms3Dual-modification engineering of Al-based Li adsorbents for enhanced sulfate resistance and anion-selective lithium recovery0Lithium and magnesium removal from high Mg/Li ratio brine by electrocoagulation: Processing and mechanism2Intrinsically Lithium-Selective Nanofiltration Membranes Enabled by 1,3,5-Tris(aminomethyl)benzene1Synergistic Extraction of Lithium and Aluminum from Clay-Type Lithium Ore by Mechanical Activation and Acid Leaching0Recent progress in metal-based lithium-ion sieves for adsorption-driven direct lithium extraction0Future of lithium industry in Chile and the national lithium strategy: integration of solar evaporation, direct lithium extraction, and controlled reinjection1

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