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RESEARCH PAPER · Chemistry of Materials · 2018

Synthesis and Size-Dependent Optical Properties of Intermediate Band Gap Cu3VS4 Nanocrystals

Valeria Mantella, Silviya Ninova, Seryio Saris, Anna Loiudice, Ulrich Aschauer, Raffaella Buonsanti

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Synthesis and Size-Dependent Optical Properties of Intermediate Band Gap Cu3VS4 NanocrystalsOriginalExploring improvement of photocatalytic and catalytic performance in Nd-doped BiYO3 nanotube systems14Iron-incorporated chalcopyrite of an intermediate band for improving solar wide-spectrum absorption4Insights into Reaction Intermediates to Predict Synthetic Pathways for Shape-Controlled Metal Nanocrystals82Defect-induced abnormal enhanced upconversion luminescence in BiOBr:Yb 3+ /Er 3+ ultrathin nanosheets and its influence on visible-NIR light photocatalysis60Tuning Intermediate-Band Cu3VS4 Nanocrystals from Plasmonic-like to Excitonic via Shell-Coating20Shaping non-noble metal nanocrystals via colloidal chemistry28Manipulation of Precursor Reactivity for the Facile Synthesis of Heterostructured and Hollow Metal Selenide Nanocrystals15Synthesis and optoelectronic properties of Cu3VSe4 nanocrystals30Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization6Atomic Control in Multicomponent Nanomaterials: when Colloidal Chemistry Meets Atomic Layer Deposition18Semiconductor nanocrystals possessing broadly size‐ and facet‐dependent optical properties26Colloidal Synthesis of Cu–M–S (M = V, Cr, Mn) Nanocrystals by Tuning the Copper Precursor Reactivity24Cascade synthesis and optoelectronic applications of intermediate bandgap Cu3VSe4 nanosheets32Colloidal Nanocrystals as Precursors and Intermediates in Solid State Reactions for Multinary Oxide Nanomaterials19Iron-Content-Dependent, Quasi-Static Dielectric Resonances and Oxidative Transitions in Bornite and Chalcopyrite Copper Iron Sulfide Nanocrystals33Sulvanites: The Promise at the Nanoscale21Tailoring hydrophily and composition of BiOI for an ultrafast photodegradation of tetracycline hydrochloride13Binary Cu2– x S Templates Direct the Formation of Quaternary Cu2ZnSnS4 (Kesterite, Wurtzite) Nanocrystals29Growth and photovoltaic device using Cu3VS4 films prepared via co-sputtering from Cu–V and V targets13Microspherical Copper Tetrathiovanadate with Stable Binding Site as Ultra-Rate and Extended Longevity Anode for Sodium-Ion Half/Full Batteries37Solution-phase controlled synthesis of Cu 3 NbSe 4 nanocrystals for optoelectronic applications4Giant Enhancement in Upconversion Luminescence of β-Ba2ScAlO5:Yb3+/Er3+ Phosphor by the Intermediate Band through Ca2+ Doping78Polyoxovanadates as Precursors for the Synthesis of Colloidal Multi-Metal Oxide Nanocrystals9Reaction intermediates in the synthesis of colloidal nanocrystals40Subsuming the Metal Seed to Transform Binary Metal Chalcogenide Nanocrystals into Multinary Compositions18Colloidal Synthesis and Photocatalytic Properties of Cu3NbS4 and Cu3NbSe4 Sulvanite Nanocrystals16Cu–V bimetallic selenide with synergistic effect for high-rate and long-life sodium storage11Effective Mass for Holes in Paramagnetic, Plasmonic Cu5FeS4 Semiconductor Nanocrystals9Flexible optical limiters based on Cu 3 VSe 4 nanocrystals19Solution-phase synthesis of group 3–5 transition metal chalcogenide inorganic nanomaterials14DFT + U study of electronic and optical properties of Cu3TMTe4: TM = V, Nb, Ta with incorporation of SOC4Copper Iron Chalcogenide Semiconductor Nanocrystals in Energy and Optoelectronics Applications—State of the Art, Challenges, and Future Potential31First-Principles Prediction of Potential Candidate Materials MCu3X4 ( M = V,Nb,Ta;X=S,Se,Te ) for Neuromorphic Computing5Colloidal Synthesis of Multinary Alkali-Metal Chalcogenides Containing Bi and Sb: An Emerging Class of I–V–VI 2 Nanocrystals with Tunable Composition and Interesting Properties18Enhanced upconversion luminescence and single-band red emission in β-Ba2ScAlO5: Yb3+/Er3+ phosphor through doping Cu2+16Intrinsic defects in sulvanite compounds: The case of transparent Cu3TaS4 and absorbing Cu3VSe45Visible‐Light‐Driven Selective Hydrogenation of Nitrostyrene over Layered Ternary Sulfide Nanostructures8Mitochondria-targeting Cu 3 VS 4 nanostructure with high copper ionic mobility for photothermoelectric therapy104Size-Controlled Cu3VSe4 Nanocrystals as Cathode Material in Platinum-Free Dye-Sensitized Solar Cells11Large enhancement of red upconversion luminescence in beta Ba2Sc0.67Yb0.3Er0.03AlO5 phosphor via Mn2+ ions doping for thermometry5Solution-processed Cu3V(S, Se)4 absorbers for thin films solar cells4Tutorial on Describing, Classifying, and Visualizing Common Crystal Structures in Nanoscale Materials Systems20Investigating the preparation process of excellent Cu3VSe4 absorption layer prepared by amine-thiol system2Enhancing Efficiency in Dye-Sensitized Solar Cells: Incorporation of Cu3VSe4 Nanocrystals into TiO2 Photoanodes9Stable Cu+/Cu2+ species derived from in-situ growing Cu-S-V bonds in CuVxS electrocatalysts enables high efficiency CO2 electroreduction to methanol32Cu3VSe4 Cathode for Rechargeable Magnesium Batteries: Favorable Chemical and Electronic Structures Inducing Intercalation and Displacement Reactions163D Tunnel Copper Tetrathiovanadate Nanocube Cathode Achieving Ultrafast Magnesium Storage Reactions through a Charge Delocalization and Displacement Mechanism23Effect of Cu Concentration on Optimizing the Optical, Morphological, and Structural Characteristics of ZnIn 2 S 4 Nanosheets for Photoresponse Applications21Enhanced optical and thermoelectric properties of Cu 3 Nb 1− X V X S 4 through chemical substitution: a DFT approach2Enhancing Near-Infrared Absorption by Modulation the Intermediate Band of Cu–Fe–S Semiconductors for Boosting Photocatalytic Hydrogenation of Nitroarenes3Hydrothermal Synthesis of Phase-Pure Sulvanite Cu3VS4 Nanoparticles6Controlled Synthesis of Core–Shell–Shell Structured Sulvanite-Based Nanocomposites with Luminescent Property2Synthesis of Cu3VS4 quantum dots and their use in quantum dot sensitized solar cells0Quantum‐Dot Intermediate Band Semiconductors: From Materials to Applications6Size-controlled synthesis of ultrasmall Cu 3 VS 4 nanocrystals via direct ternary nucleation0Intermediate Bandgap (IB) Cu3VSxSe4−x Nanocrystals as a New Class of Light Absorbing Semiconductors2Vibrational Entropic Stabilization of Layered Chalcogenides: From Ordered Vacancy Compounds to Two-Dimensional Layers0Achieving uniform elemental distribution and high crystallinity in Cu3V(S,Se)4 solar cells via optimizing selenization engineering0Enhanced Photoresponse of Solution-Processed Copper Tetrathiovandate (Cu 3 VS 4 ): Toward Efficient Nanostructured Photovoltaics0The Thickness and Crystal Phase Engineering of Copper Vanadate Nanosheets for Broadband Nonlinear Optical Limiting Glass Devices0Defect Passivation and Carrier Transport Modulation of Excellent Cu3V(S,Se)4 Solar Cells via Introducing Cd2+ Ions0

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  1. Exploring improvement of photocatalytic and catalytic performance in Nd-doped BiYO3 nanotube systems

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  2. Iron-incorporated chalcopyrite of an intermediate band for improving solar wide-spectrum absorption

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  3. Insights into Reaction Intermediates to Predict Synthetic Pathways for Shape-Controlled Metal Nanocrystals

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  4. Defect-induced abnormal enhanced upconversion luminescence in BiOBr:Yb 3+ /Er 3+ ultrathin nanosheets and its influence on visible-NIR light photocatalysis

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  5. Tuning Intermediate-Band Cu3VS4 Nanocrystals from Plasmonic-like to Excitonic via Shell-Coating

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  6. Shaping non-noble metal nanocrystals via colloidal chemistry

    Chemical Science · 2020-01-01

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  7. Manipulation of Precursor Reactivity for the Facile Synthesis of Heterostructured and Hollow Metal Selenide Nanocrystals

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  8. Synthesis and optoelectronic properties of Cu3VSe4 nanocrystals

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  9. Intermediate band induced by p-block metalloid antimony in SnS2 for higher solar energy utilization

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  10. Atomic Control in Multicomponent Nanomaterials: when Colloidal Chemistry Meets Atomic Layer Deposition

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  11. Semiconductor nanocrystals possessing broadly size‐ and facet‐dependent optical properties

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  12. Colloidal Synthesis of Cu–M–S (M = V, Cr, Mn) Nanocrystals by Tuning the Copper Precursor Reactivity

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  13. Cascade synthesis and optoelectronic applications of intermediate bandgap Cu3VSe4 nanosheets

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  14. Colloidal Nanocrystals as Precursors and Intermediates in Solid State Reactions for Multinary Oxide Nanomaterials

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  15. Iron-Content-Dependent, Quasi-Static Dielectric Resonances and Oxidative Transitions in Bornite and Chalcopyrite Copper Iron Sulfide Nanocrystals

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  16. Sulvanites: The Promise at the Nanoscale

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  17. Tailoring hydrophily and composition of BiOI for an ultrafast photodegradation of tetracycline hydrochloride

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  18. Binary Cu2– x S Templates Direct the Formation of Quaternary Cu2ZnSnS4 (Kesterite, Wurtzite) Nanocrystals

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  19. Growth and photovoltaic device using Cu3VS4 films prepared via co-sputtering from Cu–V and V targets

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  20. Microspherical Copper Tetrathiovanadate with Stable Binding Site as Ultra-Rate and Extended Longevity Anode for Sodium-Ion Half/Full Batteries

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  21. Solution-phase controlled synthesis of Cu 3 NbSe 4 nanocrystals for optoelectronic applications

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  22. Giant Enhancement in Upconversion Luminescence of β-Ba2ScAlO5:Yb3+/Er3+ Phosphor by the Intermediate Band through Ca2+ Doping

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  34. Colloidal Synthesis of Multinary Alkali-Metal Chalcogenides Containing Bi and Sb: An Emerging Class of I–V–VI 2 Nanocrystals with Tunable Composition and Interesting Properties

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