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RESEARCH PAPER · Chemistry of Materials · 2018

Polar-Solvent-Free Synthesis of Highly Photoluminescent and Stable CsPbBr3 Nanocrystals with Controlled Shape and Size by Ultrasonication

Longshi Rao, Yong Tang, Cun-Jiang Song, Ke Xu, Evan Thomas Vickers, Sara Bonabi Naghadeh, Xinrui Ding, Zongtao Li, Jin Zhong Zhang

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Polar-Solvent-Free Synthesis of Highly Photoluminescent and Stable CsPbBr3 Nanocrystals with Controlled Shape and Size by UltrasonicationOriginalImprovement of Optical and Thermal Properties for Quantum Dots WLEDs by Controlling Layer Location29Ultrasonication-assisted synthesis of CsPbBr 3 and Cs 4 PbBr 6 perovskite nanocrystals and their reversible transformation63Investigating the transformation of CsPbBr 3 nanocrystals into highly stable CsPbBr 3 /Cs 4 PbBr 6 nanocrystals using ethyl acetate in a microchannel reactor38A “Cocktail” Approach to Effective Surface Passivation of Multiple Surface Defects of Metal Halide Perovskites Using a Combination of Ligands34Spontane Kristallisation von Perowskit‐Nanokristallen in unpolaren organischen Lösungsmitteln: Ein vielseitiges Konzept für deren morphologiekontrollierende Synthese8Spontaneous Crystallization of Perovskite Nanocrystals in Nonpolar Organic Solvents: A Versatile Approach for their Shape‐Controlled Synthesis146Synthesis of Highly Photoluminescent All-Inorganic CsPbX3 Nanocrystals via Interfacial Anion Exchange Reactions16Polar Organic Solvent-Tolerant Perovskite Nanocrystals Permanently Ligated with Polymer Hairs via Star-like Molecular Bottlebrush Trilobe Nanoreactors84Room Temperature Synthesis of Phosphine‐Capped Lead Bromide Perovskite Nanocrystals without Coordinating Solvents42Large-Scale Synthesis of Highly Luminescent Perovskite Nanocrystals by Template-Assisted Solid-State Reaction at 800 °C87All-Inorganic Perovskite Quantum Dots: Ligand Modification, Surface Treatment and Other Strategies for Enhanced Stability and Durability4Doping and ion substitution in colloidal metal halide perovskite nanocrystals482Highly Efficient and Water‐Stable Lead Halide Perovskite Quantum Dots Using Superhydrophobic Aerogel Inorganic Matrix for White Light‐Emitting Diodes61Shape Tailoring of Iodine‐Based Cesium Lead Halide Perovskite Nanocrystals in Hot‐Injection Methods26Immobilizing perovskite CsPbBr3 nanocrystals on Black phosphorus nanosheets for boosting charge separation and photocatalytic CO2 reduction182A Database of Ionic Transport Characteristics for Over 29 000 Inorganic Compounds81Green and high yield synthesis of CdTe@Hydrotalcite nanocrystals with enhanced photoluminescence stability toward white light emitting diodes7Recent Advancements in Near-Infrared Perovskite Light-Emitting Diodes63Effect of Oleamine on Microwave-Assisted Synthesis of Cesium Lead Bromide Perovskite Nanocrystals26Recent progress in all-inorganic metal halide nanostructured perovskites: Materials design, optical properties, and application39Solution-Processed Fabrication of Light-Emitting Diodes Using CsPbBr3 Perovskite Nanocrystals18Polarization-Induced Quantum-Mechanical Charge Transfer in Perovskite–Graphene Nanocomposites with Superior Electro-optic Switching Modulation9CsPbBr 3/Cs 4PbBr 6 Heterostructure Solids with High Stability and Photoluminescence for White Light-Emitting Diodes0Solvent- and initiator-free fabrication of efficient and stable perovskite-polystyrene surface-patterned thin films for LED backlights27Recent advances and perspective on the synthesis and photocatalytic application of metal halide perovskite nanocrystals38Development of all-inorganic lead halide perovskites for carbon dioxide photoreduction42Water-stable CsPbBr 3 perovskite quantum-dot luminous fibers fabricated by centrifugal spinning for dual white light illumination and communication33Microwave-assisted synthesis of blue-emitting cesium bismuth bromine perovskite nanocrystals without polar solvent21Chemically Spiraling CsPbBr3 Perovskite Nanorods88Cost-Effective Strategy for the Synthesis of Air-Stable CH3NH3PbX3 (X = Cl, Br, and I) Quantum Dots with Bright Emission10Surface Chemistry Engineering of Perovskite Quantum Dots: Strategies, Applications, and Perspectives394A comparison of the Refrigerated Adsorption Drying of Daucus carota with fluidized bed drying14Enhanced and angle dependent blue fluorescence of perovskite nanocrystals on three typical photonic crystals2Highly Emissive Green Metal Halide Perovskite Solids: Formation Kinetics, Enhanced Heat, Light, and Polar Solvent Resistance, and Light-Emitting Application0Highly luminescent dual-phase CsPbBr 3 /Cs 4 PbBr 6 microcrystals for a wide color gamut for backlight displays22Ligand-modified synthesis of shape-controllable and highly luminescent CsPbBr 3 perovskite nanocrystals under ambient conditions18Simple and sustainable synthesis of perovskite-based optoelectronic material: CsPbBr 3 nanocrystals via laser ablation in alcohol14Structural, dynamic, and diffusion properties of a Li 6 (PS 4 )SCl superionic conductor from molecular dynamics simulations; prediction of a dramatically improved conductor12Locking Energy Transfer of Rare Earth Ions via an “Electron Jam” Caused by Vertical Photocarrier Separation of a Layered Semiconductor4Approaching high-performance light-emitting devices upon perovskite quantum dots: Advances and prospects122Highly luminescent lead bromine perovskite via fast and eco-friendly water-assisted mechanochemical method7Natural Wax-Stabilized Perovskite Nanocrystals as Pen-on-Paper Inks and Doughs11CsPbBr3/Cs4PbBr6 heterostructure solids with high stability and photoluminescence for white light-emitting diodes21Investigation of highly luminescent inorganic perovskite nanocrystals synthesized using optimized ultrasonication method10Phase Sensitivity of All-Inorganic Lead Halide Perovskite Nanocrystals8Amine-Free Synthetic Route: An Emerging Approach to Making High-Quality Perovskite Nanocrystals for Futuristic Applications39Recent progress and future prospects on halide perovskite nanocrystals for optoelectronics and beyond48Synthesis of cesium lead bromide nanoparticles by the ultrasonic bath method: A polar-solvent-free approach at room temperature6Highly emissive green CsPbBr 3 /Cs 4 PbBr 6 composites: formation kinetics, excellent heat, light, and polar solvent resistance, and flexible light-emitting application11Influence of periodic flow field on synthesis of perovskite nanocrystals: Synthetic pathway and productivity8Perovskite quantum dots: Synthesis, applications, prospects, and challenges54Strategies to Extend the Lifetime of Perovskite Downconversion Films for Display Applications47Tiny spots to light the future: advances in synthesis, properties, and application of perovskite nanocrystals in solar cells10Challenges and developments for the blue perovskite nanocrystal light-emitting diodes11Cation Exchange Synthesis of Aliovalent Doped InP QDs and Their ZnSexS1–x Shell Coating for Enhanced Fluorescence Properties16Highly Stable and Photoluminescent CsPbBr3/Cs4PbBr6 Composites for White-Light-Emitting Diodes and Visible Light Communication28Metal halide perovskite nanocrystals for biomedical engineering: Recent advances, challenges, and future perspectives81Metal halide perovskites for photocatalytic CO2 reduction: An overview and prospects100Polar-Solvent-Free Sonochemical Synthesis of Mn(II)-Doped CsPbCl3 Perovskite Nanocrystals for Dual-Color Emission37Hexahedron Symmetry and Multidirectional Facet Coupling of Orthorhombic CsPbBr3 Nanocrystals19Surface Modification of ZnO Nanocrystals with Conjugated Polyelectrolytes Carrying Different Counterions for Inverted Perovskite Light-Emitting Diodes11Multigram-Scale Synthesis of Luminescent Cesium Lead Halide Perovskite Nanobricks for Plastic Scintillators12Efficient blue CsPbBr3 perovskite nanocrystals synthesis with the assistance of zwitterionic straight chain amino acids12Photoactive composite nanomaterials for environment and energy0Recent development in metal halide perovskites synthesis to improve their charge-carrier mobility and photocatalytic efficiency22Precise regulation of the multicolor spectrum of carbon dots based on the bionic leaf vein ultrasonic microreactor12All-inorganic lead halide perovskites for photocatalysis: a review56Broadband photodetectors from silane-passivated CsPbBr 3 nanocrystals by ultrasound-mediated synthesis8Highly stable CsPbBr 3 perovskite phases from new lead β-diketonate glyme adducts2Preparation of Inorganic Perovskites1Sonochemical-assisted synthesis of CsPbBr 3 perovskite quantum dots using vegetable oils10Isostructural phase transition-induced piezoelectricity in all-inorganic perovskite CsPbBr3 for catalytic CO2 reduction26Perovskite nanocrystals (PNCs) served as an emerging optical indicator for food safety and quality assessment: progress, challenges, and opportunities14Self-Driven Photodetectors Based on Flexible Silicon Nanowires Array Surface-Passivated With Tin-Based Perovskites4Lead-free metal–halide perovskite nanocrystals: synthesis and optical properties [Review]0Efficient protection of perovskite nanoparticles in salicylic acid hollow crystal via super simple standing method5Ultrasonication synthesis of a Mn2+-doped zero-dimensional metal halide: Structure, luminescence property and display application0Zwitterions: An innovative class of additive materials for perovskite light-emitting diodes3Ligand Engineering Achieves Suppression of Temperature Quenching in Pure Green Perovskite Nanocrystals for Efficient and Thermostable Electroluminescence21Solvent‐Free Ball Milling Synthesis of Water‐Stable Tin‐Based Pseudohalide Perovskites for Photocatalytic CO 2 Reduction8Atomic-level insights into the highly conductive lithium thio-phosphate solid electrolytes with exceptional stability against lithium metal12Methods of synthesis for metal halide perovskite photocatalysts0Spectral accessibility tuning through perovskite quantum dots for up-/down-converting photovoltaic applications: a review3Low‐dimensional solid‐state single‐photon emitters5Mesoporous silica-encapsulated CsPbBr3 quantum dots for the preparation of green fiber by electrospinning6Ultrasound-assisted Zn-doped CsPbCl3 perovskite nanocrystals through Mn co-doping approach with bright luminescence and stability7Material design and optical waveguide model development for fluorescent concentrator devices to improve the performance of perovskite solar cells3Perovskite Quantum Dot-Based Memory Technologies: Insights from Emerging Trends12CsPbBr 3 Perovskite‐Based Heterostructures in Photocatalysis: Mechanisms, Stability, and Multifunctional Performance37Luminescent upconverting CsPbBr 3 nanocrystals as spectral converter having chemodynamic potential against Pseudomonas bacteria1Ultrafast Laser Irradiation Enhances Crystallinity and Photoluminescence of Colloidal CsPbBr3 Nanocrystals for High-Performance X-ray Detection2Bio-inspired ultrasonic microreactor for efficient synthesis of indigo-emitting carbon dots with tunable morphology and enhanced optical properties1Low temperature green synthesis of red emitting Pb-free CsMnBr 3 perovskite films4Powder Atomic Layer Deposition–Enabled Stable Perovskite Phosphors for UV‐Wavelength‐Discriminable Luminescent Films0SiO2-coated CsPbBr3 quantum dots for visual detection of small-molecule metabolite pyruvate0Solar cells of CsPbBr3 perovskite quantum dots from green solvent processing0Green Sonochemical Synthesis and Thin‐Film Processing of Cs 3 Bi 2 I 9 Nanocrystals0Simulation-guided biomimetic sharp-edged ultrasonic microreactor enables morphology-uniform and performance-tunable halide perovskite quantum dots0Functionalization of CsPbBr3 perovskite with a new ligand chemistry for reliable and sensitive fluorescence detection of abscisic acid plant hormone0Low‐Dimensional Perovskites for Neuromorphic Vision Computing0

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  2. Ultrasonication-assisted synthesis of CsPbBr 3 and Cs 4 PbBr 6 perovskite nanocrystals and their reversible transformation

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  7. Synthesis of Highly Photoluminescent All-Inorganic CsPbX3 Nanocrystals via Interfacial Anion Exchange Reactions

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  9. Room Temperature Synthesis of Phosphine‐Capped Lead Bromide Perovskite Nanocrystals without Coordinating Solvents

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  14. Shape Tailoring of Iodine‐Based Cesium Lead Halide Perovskite Nanocrystals in Hot‐Injection Methods

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  48. Synthesis of cesium lead bromide nanoparticles by the ultrasonic bath method: A polar-solvent-free approach at room temperature

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  50. Influence of periodic flow field on synthesis of perovskite nanocrystals: Synthetic pathway and productivity

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