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RESEARCH PAPER · Inorganic Chemistry · 2018

Red Phosphor Rb2NbOF5:Mn4+ for Warm White Light-Emitting Diodes with a High Color-Rendering Index

Zhengliang Wang, Zhiyu Yang, Zhaofeng Yang, Qianwen Wei, Qiang Zhou, Li Ma, Xiaojun Wang

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Red Phosphor Rb2NbOF5:Mn4+ for Warm White Light-Emitting Diodes with a High Color-Rendering IndexOriginalA highly luminescent Mn 4+ activated LaAlO 3 far-red-emitting phosphor for plant growth LEDs: charge compensation induced Mn 4+ incorporation31An ultra-high yield of spherical K 2 NaScF 6 :Mn 4+ red phosphor and its application in ultra-wide color gamut liquid crystal displays95Electronic and optical properties of a novel fluoroaluminate red phosphor Cs 2 NaAl 3 F 12 :Mn 4+ with high color purity for white light-emitting diodes33Red-emitting phosphors APF 6 :Mn 4+ (A = Cs + , Rb + , K + ): synthesis, luminescence properties and application in solid-state lighting5Review—Tanabe−Sugano Energy-Level Diagram and Racah Parameters in Mn4+-Activated Red and Deep Red-Emitting Phosphors78Luminescence of red-emitting phosphor Rb5Nb3OF18:Mn4+ for warm white light-emitting diodes28Structure and Luminescence Properties of Mn4+-Activated K3TaO2F4 Red Phosphor for White LEDs85Improving the moisture resistance and luminescent properties of K2TiF6:Mn4+ by coating with CaF250Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7:Mn4+ (M: Nb, Ta)21Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation89HF‐Free Solid‐State Synthesis of the Oxyfluoride Phosphor K3MoOF7:Mn4+21Impact of solvents on energy gap, photophysical, photometric properties for a new class of 4-HCM coumarin derivative: Nonlinear optical studies and optoelectronic applications38K3WOF7:Mn4+ ‒ A red oxyfluoride phosphor16Review—Mn 4+ -Activated Red and Deep Red-Emitting Phosphors193Spray pyrolysis synthesis and characterization of Mg1-xSrxMoO4 heterostructure with white light emission24A red-emitting phosphor K2[MoO2F4]•H2O:Mn4+ for warm white light-emitting diodes with a high color rendering index17Cs2MnF6 Red Phosphor with Ultrahigh Absorption Efficiency51Synthesis, photoluminescence properties and potential applications of Eu3+ and Mn4+ activated SrLaMgNbO6 phosphors37Comparative investigation on luminescence properties of Mn4+ doped Ba6Y2W3O18 and Ba6Gd2W3O18 phosphors24Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting220Near-infrared emission of CaAl 6 Ga 6 O 19 :Cr 3+ ,Ln 3+ (Ln = Yb, Nd, and Er) via energy transfer for c-Si solar cells33A new far-red emission from Zn2SnO4 powder synthesized by modified solid state reaction method33Luminescent properties of a red-emitting oxyfluoride phosphor Rb2WO2F4:Mn4+22A new double perovskite CaY0.5Ta0.5O3:Mn4+ deep-red phosphor: Synthesis, optical properties, and potential applications in plant-growth LEDs53Microsized Red Luminescent MgAl2O4:Mn4+ Single-Crystal Phosphor Grown in Molten Salt for White LEDs36A Guanidinium-Based Mn4+-Doped Red-Emitting Hybrid Phosphor with High Stability35Co-Substitution Strategy to Achieve a Novel Efficient Deep-Red-Emitting SrKYTeO 6:Mn 4+ Phosphor for Plant Cultivation Lighting0Novel SrGd 2 Al 2 O 7 :Mn 4+ , Nd 3+ , and Yb 3+ phosphors for c-Si solar cells14Perovskite tungstate Ba2La2ZnW2O12:Mn4+ phosphor: Synthesis, energy transfer and tunable emission53Towards green synthesis of Mn4+-doped fluoride phosphors: a review43Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph31Surface modification of K 2 TiF 6 :Mn 4+ phosphor with SrF 2 coating to enhance water resistance36Research on high luminous efficiency, high color rendering index chips on board light emitting diode and excitation and excitation saturation effect of phosphor2Relationship between photoluminescence intensity, Mn ion oxidation, and crystal structure of new phosphors Li-M-Ti-O:Mn4+ (M = Nb or Ta)4Review on deep red-emitting rare-earth free germanates and their efficiency as well as adaptability for various applications27Enhanced red emission from Mn4+ activated phosphor induced by fluoride to oxyfluoride phase transformation19Coupling strong photoluminescence and narrow band gap in a new tetranuclear copper cluster: Copper(I) iodide with dimethylamine10An efficient far‐red emission Sr 2 InSbO 6 :Mn 4+ , M (M = Li + , Na + , and K + ) phosphors for plant cultivation LEDs46A Novel Red-Emitting Na2NbOF5:Mn4+ Phosphor with Ultrahigh Color Purity for Warm White Lighting and Wide-Gamut Backlight Displays36Mn4+-doped La(CaZr)0.5O3 phosphors for plant grow LEDs: Ab initio site occupy and photoluminescence properties9Chemical unit co-substitution for a new far-red-emitting phosphor Ca3-6(NaLu)3LiSbO6:Mn4+ to achieve high quantum efficiency and superb thermal stability12Defect-related luminescence behavior of a Mn 4+ non-equivalently doped fluoroantimonate red phosphor13Co-Substitution Strategy to Achieve a Novel Efficient Deep-Red-Emitting SrKYTeO 6:Mn 4+ Phosphor for Plant Cultivation Lighting0Locally-ordered A-site vacancy assisted photoluminescence enhancement in simply rare-earth doped perovskite oxide13Hydrothermal synthesis and crystal structure of a new rubidium sodium niobium fluoride, RbNaNbF73Shining Mn 4+ in 0D Organometallic Fluoride Hosts towards Highly Efficient Photoluminescence45Luminescent properties of Mn4+ in an oxyfluoride complex with ultra-high thermal stability10A novel K3WO2F5·2H2O:Mn4+ phosphor with excellent hydrophobic stability by coating paraffin wax for the application of WLEDs13Cation-exchange reaction to prepare Na2WO2F4:Mn4+ with intense zero phonon line at 619 nm avoiding disproportionation reaction17A Na 2 MoO 2 F 4 :Mn 4+ phosphor with red luminescence peaking at 625 nm and a ZPL/ v 6 intensity ratio of 243%23Synthesis and characterization of narrow band emitting phosphors for plant growth and display applications2New double perovskite Cd2MgTeO6:Sm3+, Na+ tellurate phosphors with abnormal thermal quenching for applications in white and plant growth lighting25Site occupancy strategy for emission tunable K3HF2W1-xOF6:xMn4+ nanophosphor via ions exchange0Novel Mn4+-Activated K2Nb1−xMoxF7 (0 ≤ x ≤ 0.15) Solid Solution Red Phosphors with Superior Moisture Resistance and Good Thermal Stability13Investigation of Oxygen Partial Pressure to Improve Photoluminescence Intensity for Li-Ta-Ti-O:Mn4+ Phosphors Using Air-pressure Control Atmosphere Furnace0Oxyfluoride K3MoO2F5·2H2O:Mn4+ red phosphor with enhanced luminescence and moisture resistance for WLED indoor lighting and wide gamut display applications16Light Harvesting Materials: A Study on Förster Resonance Energy Transfer and Optoelectronic Properties of Potential Nerium Oleander Flowers2Light Harvesting Materials: A Study on Förster Resonance Energy Transfer and Optoelectronic Properties of Potential Nerium Oleander Flowers0Non-equivalent Mn 4+ doping in mixed-anion host of K 3 Na(MoO 2 F 4 ) 2 ·H 2 O achieving short fluorescence lifetime and intense zero phonon line8Mn4+-activated (K1-Cs )2NbF7 red phosphors with high color purity and excellent moisture resistance for WLEDs19Anthocyanins of Delonix Regia Floral Petals: A Novel Approach on Fluorescence Enhancement, Forster Resonance Energy Transfer Mechanism and Photostability Studies for Optoelectronic Applications11A novel fluorescent material K3NbOF6: Mn4+ for light-emitting diode devices4Light Harvesting Materials: A Study on Förster Resonance Energy Transfer and Optoelectronic Properties of Potential Nerium oleander Flowers10The structure transition and luminescence performance of a high moisture resistant KNaNbOF 5 :Mn 4+ red phosphor2Preparation and photoluminescence characterization of novel red emitting Ba4CaB4O10F2:xEu3+ fluorescent materials3Unlocking the Photoluminescence Potential of Tabebuia Rosea Dyes: A Novel Natural Source of Broadband Visible Spectral Fluorescence for OLED Technologies12Mn4+-Activated Oxyfluoride CsNaWO2F4 Phosphor: Enhancement in the Water Stability and Thermal-Quenching Resistance13A highly fluorescent violet hue natural dye from Lagerstroemia speciosa: Excellent optical and photoluminescent properties for OLED and antioxidant activity applications3Defect engineering in Mn4 + -doped Li4Mg2TaO6F oxyfluoride phosphors via NaF charge compensation for broadband far-red agricultural lighting10Theoretical Prediction‐Assisted Synthesis of Narrow‐Band Red‐Emitting Fluoride Phosphors with High Film‐Forming Ability for Mini Light‐Emitting Diode Displays1Preparation and Luminescence Properties of Mn4+ Ions Doped CaAl12O19 Red Phosphors1A K₃HF₂WO₂F₄: Mn⁴⁺ oxyfluoride red phosphor with high quantum efficiency for backlight display2Solvent-orchestrated intramolecular exciton reordering and π–π∗ transition engineering in tannin matrices: A comprehensive spectro-electrochemical mapping of Terminalia-based chromophores4Simultaneous enhancement of zero-phonon line emission and thermal stability in ALiSiF6:Mn4+ (A = Rb, Cs) red-emitting fluoride phosphors0Enhancing the emission intensity and improving the thermal stability of Mn4+ based on anion substitution through F− regulation1Structure, luminescent properties and local symmetry evolution of Eu3+ doped Sr2MgB2O6 phosphor0

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  1. A highly luminescent Mn 4+ activated LaAlO 3 far-red-emitting phosphor for plant growth LEDs: charge compensation induced Mn 4+ incorporation

    Dalton Transactions · 2019-01-01

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  2. An ultra-high yield of spherical K 2 NaScF 6 :Mn 4+ red phosphor and its application in ultra-wide color gamut liquid crystal displays

    Journal of Materials Chemistry C · 2019-01-01

    Hong Ming, Lili Liu, Shengan He, Jiaqing Peng, Fu Du, Junxiang Fu, Fengli Yang, Xinyu Ye

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  3. Electronic and optical properties of a novel fluoroaluminate red phosphor Cs 2 NaAl 3 F 12 :Mn 4+ with high color purity for white light-emitting diodes

    Dalton Transactions · 2019-01-01

    Zibo Liang, Zhaofeng Yang, Xiaoling Xie, Haiqi Pu, Dongxin Shi, Qiang Zhou, Zhengliang Wang, Junming Guo, Mingmei M. Wu

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  4. Red-emitting phosphors APF 6 :Mn 4+ (A = Cs + , Rb + , K + ): synthesis, luminescence properties and application in solid-state lighting

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    Yu Chen, Zhaofeng Yang, Qin Wang, Meizhu Rong, Qiang Zhou, Zhengliang Wang

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  5. Review—Tanabe−Sugano Energy-Level Diagram and Racah Parameters in Mn4+-Activated Red and Deep Red-Emitting Phosphors

    ECS Journal of Solid State Science and Technology · 2019-01-01

    Sadao Adachi

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  6. Luminescence of red-emitting phosphor Rb5Nb3OF18:Mn4+ for warm white light-emitting diodes

    Journal of Luminescence · 2019-03-04

    Zhiyu Yang, Zhaofeng Yang, Qianwen Wei, Qiang Zhou, Zhengliang Wang

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  7. Structure and Luminescence Properties of Mn4+-Activated K3TaO2F4 Red Phosphor for White LEDs

    Inorganic Chemistry · 2019-03-19

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  8. Improving the moisture resistance and luminescent properties of K2TiF6:Mn4+ by coating with CaF2

    Materials Research Bulletin · 2019-03-23

    Qizheng Dong, Chengjin Guo, Ling He, Xuefeng Lu, Jianbo Yin

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  9. Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7:Mn4+ (M: Nb, Ta)

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  10. Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation

    Inorganic Chemistry · 2019-05-07

    Jinquan Chen, Conghua Yang, Yibo Chen, Jin He, Zhao‐Qing Liu, Jing Wang, Jilin Zhang

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  11. HF‐Free Solid‐State Synthesis of the Oxyfluoride Phosphor K3MoOF7:Mn4+

    European Journal of Inorganic Chemistry · 2019-07-12

    Christiane Stoll, Markus Seibald, Dominik Baumann, Hubert Huppertz

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  12. Impact of solvents on energy gap, photophysical, photometric properties for a new class of 4-HCM coumarin derivative: Nonlinear optical studies and optoelectronic applications

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  13. K3WOF7:Mn4+ ‒ A red oxyfluoride phosphor

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  14. Review—Mn 4+ -Activated Red and Deep Red-Emitting Phosphors

    ECS Journal of Solid State Science and Technology · 2019-08-16

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  15. Spray pyrolysis synthesis and characterization of Mg1-xSrxMoO4 heterostructure with white light emission

    Journal of Alloys and Compounds · 2019-09-10

    A.A.G. Santiago, R.L. Tranquilin, Pablo Botella, Francisco Javier Manjon, Daniel Errandonea, C. A. Paskocimas, F.V. Motta, Mauricio R. D. Bomio

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  16. A red-emitting phosphor K2[MoO2F4]•H2O:Mn4+ for warm white light-emitting diodes with a high color rendering index

    Materials Research Bulletin · 2019-10-24

    Yan Liu, Hong Li, Shu Tang, Qiang Zhou, Kaimin Wang, Huaijun Tang, Zhengliang Wang

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  17. Cs2MnF6 Red Phosphor with Ultrahigh Absorption Efficiency

    Inorganic Chemistry · 2019-10-25

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  18. Synthesis, photoluminescence properties and potential applications of Eu3+ and Mn4+ activated SrLaMgNbO6 phosphors

    Materials Research Bulletin · 2019-11-05

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  19. Comparative investigation on luminescence properties of Mn4+ doped Ba6Y2W3O18 and Ba6Gd2W3O18 phosphors

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  20. Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting

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  21. Near-infrared emission of CaAl 6 Ga 6 O 19 :Cr 3+ ,Ln 3+ (Ln = Yb, Nd, and Er) via energy transfer for c-Si solar cells

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  22. A new far-red emission from Zn2SnO4 powder synthesized by modified solid state reaction method

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  23. Luminescent properties of a red-emitting oxyfluoride phosphor Rb2WO2F4:Mn4+

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  24. A new double perovskite CaY0.5Ta0.5O3:Mn4+ deep-red phosphor: Synthesis, optical properties, and potential applications in plant-growth LEDs

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  25. Microsized Red Luminescent MgAl2O4:Mn4+ Single-Crystal Phosphor Grown in Molten Salt for White LEDs

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  26. A Guanidinium-Based Mn4+-Doped Red-Emitting Hybrid Phosphor with High Stability

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  27. Co-Substitution Strategy to Achieve a Novel Efficient Deep-Red-Emitting SrKYTeO 6:Mn 4+ Phosphor for Plant Cultivation Lighting

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  28. Novel SrGd 2 Al 2 O 7 :Mn 4+ , Nd 3+ , and Yb 3+ phosphors for c-Si solar cells

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  29. Perovskite tungstate Ba2La2ZnW2O12:Mn4+ phosphor: Synthesis, energy transfer and tunable emission

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  30. Towards green synthesis of Mn4+-doped fluoride phosphors: a review

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  31. Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph

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  32. Surface modification of K 2 TiF 6 :Mn 4+ phosphor with SrF 2 coating to enhance water resistance

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  33. Research on high luminous efficiency, high color rendering index chips on board light emitting diode and excitation and excitation saturation effect of phosphor

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  34. Relationship between photoluminescence intensity, Mn ion oxidation, and crystal structure of new phosphors Li-M-Ti-O:Mn4+ (M = Nb or Ta)

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  35. Review on deep red-emitting rare-earth free germanates and their efficiency as well as adaptability for various applications

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  36. Enhanced red emission from Mn4+ activated phosphor induced by fluoride to oxyfluoride phase transformation

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  37. Coupling strong photoluminescence and narrow band gap in a new tetranuclear copper cluster: Copper(I) iodide with dimethylamine

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  38. An efficient far‐red emission Sr 2 InSbO 6 :Mn 4+ , M (M = Li + , Na + , and K + ) phosphors for plant cultivation LEDs

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  39. A Novel Red-Emitting Na2NbOF5:Mn4+ Phosphor with Ultrahigh Color Purity for Warm White Lighting and Wide-Gamut Backlight Displays

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  40. Mn4+-doped La(CaZr)0.5O3 phosphors for plant grow LEDs: Ab initio site occupy and photoluminescence properties

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  41. Chemical unit co-substitution for a new far-red-emitting phosphor Ca3-6(NaLu)3LiSbO6:Mn4+ to achieve high quantum efficiency and superb thermal stability

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  42. Defect-related luminescence behavior of a Mn 4+ non-equivalently doped fluoroantimonate red phosphor

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  43. Co-Substitution Strategy to Achieve a Novel Efficient Deep-Red-Emitting SrKYTeO 6:Mn 4+ Phosphor for Plant Cultivation Lighting

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  44. Locally-ordered A-site vacancy assisted photoluminescence enhancement in simply rare-earth doped perovskite oxide

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  45. Hydrothermal synthesis and crystal structure of a new rubidium sodium niobium fluoride, RbNaNbF7

    Journal of the Ceramic Society of Japan · 2022-01-31

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  46. Shining Mn 4+ in 0D Organometallic Fluoride Hosts towards Highly Efficient Photoluminescence

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  47. Luminescent properties of Mn4+ in an oxyfluoride complex with ultra-high thermal stability

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  48. A novel K3WO2F5·2H2O:Mn4+ phosphor with excellent hydrophobic stability by coating paraffin wax for the application of WLEDs

    Journal of Alloys and Compounds · 2022-05-21

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  49. Cation-exchange reaction to prepare Na2WO2F4:Mn4+ with intense zero phonon line at 619 nm avoiding disproportionation reaction

    Ceramics International · 2022-11-15

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  50. A Na 2 MoO 2 F 4 :Mn 4+ phosphor with red luminescence peaking at 625 nm and a ZPL/ v 6 intensity ratio of 243%

    Journal of Materials Chemistry C · 2023-01-01

    Qiao Qu, Konglan Chen, Yayun Zhou, Jinsheng Li, Haipeng Ji

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