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RESEARCH PAPER · Journal of Solid State Chemistry · 2018

A full palette: Crystal chemistry, polymorphism, synthetic strategies, and functional applications of lanthanide oxyhalides

Malsha Udayakantha, Parker Schofield, Gregory R. Waetzig, Sarbajit Banerjee

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A full palette: Crystal chemistry, polymorphism, synthetic strategies, and functional applications of lanthanide oxyhalidesOriginalPreface to the 50 years of solid state chemistry Anniversary Issue0Structural environment of chloride ion‐conducting solids based on lanthanum oxychloride24Efficient photoluminescence of isotropic rare-earth oxychloride nanocrystals from a solvothermal route14X-ray-Excited Optical Luminescence Imaging for On-Site Analysis of Alumina Scale13Ionic conduction mechanism in Ca-doped lanthanum oxychloride16X-ray-excited optical luminescence imaging for on-site identification of xenotime11Halide Replacement with Complete Preservation of Crystal Lattice in Mixed‐Anion Lanthanide Oxyhalides26Halide Replacement with Complete Preservation of Crystal Lattice in Mixed‐Anion Lanthanide Oxyhalides1Oxidation State and Local Structure of Chromium Ions in LaOCl6Nd3+-Doped Lanthanum Oxychloride Nanocrystals as Nanothermometers34A Panoramic Overview of Chlorination and Carbochlorination of Light Rare Earth Oxides, Including Thermodynamic, Reaction Mechanism, and Kinetic Aspects10Structure-Dependent Accessibility of Phonon-Coupled Radiative Relaxation Pathways Probed by X-ray-Excited Optical Luminescence2Thermochemistry of 3D and 2D Rare Earth Oxychlorides (REOCls)17First-principle study on the stability, mechanical, electronic, and optical properties of two-dimensional scandium oxyhalides8Deciphering competing radiative relaxation pathways observed in Pr3+-Activated yttrium-based compounds: UV emission versus visible emission5Crystal-Structure Prediction and Experimental Investigation of the Polymorphic Lanthanum Fluoride Selenides LaFSe and La 2 F 4 Se13Structure prediction via global energy landscape exploration of the ternary rare‐earth compound LaOI8Mechanisms of point defect formation and ionic conduction in divalent cation-doped lanthanum oxybromide: first-principles and experimental study3Locating anionic hydrogen in Ba3(Yb,Lu)2O5H2: A combined approach of X-ray diffraction, crystal chemistry, and DFT calculations2In search of Pca21 phase ferroelectrics3Topochemical Anionic Subunit Insertion Reaction for Constructing Nanoparticles of Layered Oxychalcogenide Intergrowth Structures9Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Ce3F10·3H2O2Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се3F10 ⋅ 3Н2О0Novel BiOI/LaOXI〈IX〉 heterojunction with enhanced visible-light driven photocatalytic performance: unveiling the mechanism of interlayer electron transition1Room-temperature continuous-wave lasing based on a two-dimensional erbium compound0Synthesis, chloride-ion diffusion mechanisms, and anisotropic sintering of 2D layered erbium oxychloride nanoplatelets6Structural and cryogenic magnetic properties of the REOCl (RE = Ho, Dy, Tb, and Gd) compounds54First-principles quantum computational study to investigate radiation energy-dependent effect on optoelectronic properties of bismuth oxyhalides BiOX (X= I, Br)17Synthetic Roadmap to a Large Library of Colloidal High-Entropy Rare Earth Oxyhalide Nanoparticles Containing up to Thirteen Metals22Quantum computational insights into electronic and optical properties of LnOIs for fundamental and technological applications9Stereochemical expression of Bi 6s 2 lone pairs mediates fluoride-ion (De)insertion in tunnel-structured Bi 2 PdO 4 and Bi 1.6 Pb 0.4 PtO 49In-Situ Thermometry Reveals Fragmentation Behavior Based on Local Temperature in α-Olefin Polymerization Catalysts7Rare-Earth Substitution of La 3 Si 2 S 8 I for Efficient and Color-Tunable Phosphor Converted White Light Emitting Diodes14Hydrothermal synthesis of BiOX and its photocatalytic performance0Automated Benchtop Synthesis of a Quadrillion-Plus Member Core@Multishell Nanoparticle Library Using a Massively Generalizable Nanochemical Reaction5Defect Structure and Anion Conduction in Lanthanum Oxychloride Solid Solutions Revealed by X-ray Excited Optical Luminescence and Auger Emission2GdOCl-modified polymeric carbon nitride heterojunction for one-photon excitation efficiently driven photocatalytic hydrogen production0New record in optical gain and room-temperature nanolasers in multiple wavelengths in 2D ErOCl single crystals0Site-Selective Modification of Lanthanum Oxychloride to Modulate Halide-Ion Conduction0Fluoride ions as charge carriers in electrochemical energy storage0Synthesis, Partial Oxidation, and Solvent-Dependent Self-Assembly of Ultrathin Cerium Fluoride Nanoplatelets0

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  1. Preface to the 50 years of solid state chemistry Anniversary Issue

    Journal of Solid State Chemistry · 2019-06-11

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  2. Structural environment of chloride ion‐conducting solids based on lanthanum oxychloride

    Journal of the American Ceramic Society · 2019-08-09

    Naoyoshi Nunotani, Muhammad Radzi Iqbal Bin Misran, Miki Inada, Tomoki Uchiyama, Yoshiharu Uchimoto, Nobuhito Imanaka

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  3. Efficient photoluminescence of isotropic rare-earth oxychloride nanocrystals from a solvothermal route

    Chemical Communications · 2020-01-01

    Guillaume Gouget, Morgane Pellerin, Lauriane Pautrot‐d'Alençon, Thierry Le Mercier, Christopher B. Murray

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  4. X-ray-Excited Optical Luminescence Imaging for On-Site Analysis of Alumina Scale

    Oxidation of Metals · 2020-05-29

    Susumu Imashuku, Kazuaki Wagatsuma

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  5. Ionic conduction mechanism in Ca-doped lanthanum oxychloride

    Dalton Transactions · 2020-11-25

    Kazuki Shitara, Akihide Kuwabara, Keisuke Hibino, Kotaro Fujii, Masatomo Yashima, James Hester, Masanori Umeda, Naoyoshi Nunotani, Nobuhito Imanaka

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  6. X-ray-excited optical luminescence imaging for on-site identification of xenotime

    Journal of Geochemical Exploration · 2021-03-10

    Susumu Imashuku, Kazuaki Wagatsuma

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  7. Halide Replacement with Complete Preservation of Crystal Lattice in Mixed‐Anion Lanthanide Oxyhalides

    Angewandte Chemie International Edition · 2021-03-30

    Malsha Udayakantha, Joseph V. Handy, Rachel D. Davidson, Jagjit Kaur, Graciela V. Villalpando, Lucia Zuin, Sudip Chakraborty, Sarbajit Banerjee

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  8. Halide Replacement with Complete Preservation of Crystal Lattice in Mixed‐Anion Lanthanide Oxyhalides

    Angewandte Chemie · 2021-03-30

    Malsha Udayakantha, Joseph V. Handy, Rachel D. Davidson, Jagjit Kaur, Graciela V. Villalpando, Lucia Zuin, Sudip Chakraborty, Sarbajit Banerjee

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  9. Oxidation State and Local Structure of Chromium Ions in LaOCl

    Materials · 2021-06-25

    Andris Antuzevičš, Guna Krieķe, Haralds Ozols, Andris Fedotovs, Anatolijs Šarakovskis, Alexei Kuzmin

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  10. Nd3+-Doped Lanthanum Oxychloride Nanocrystals as Nanothermometers

    The Journal of Physical Chemistry C · 2021-09-01

    Carlos Renero‐Lecuna, Ada Herrero, Dorleta Jiménez de Aberasturi, Miriam Martínez-Flórez, Rafael Valiente, Mikhail Mychinko, Sara Bals, Luis M. Liz‐Marzán

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  11. A Panoramic Overview of Chlorination and Carbochlorination of Light Rare Earth Oxides, Including Thermodynamic, Reaction Mechanism, and Kinetic Aspects

    Mining Metallurgy & Exploration · 2021-10-15

    Federico J. Pomiro, Juan P. Gaviría, Gastón G. Fouga, Ana Ester Bohé, Georgina De Micco

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  12. Structure-Dependent Accessibility of Phonon-Coupled Radiative Relaxation Pathways Probed by X-ray-Excited Optical Luminescence

    The Journal of Physical Chemistry Letters · 2021-11-10

    Malsha Udayakantha, S. Sameera Perera, Rachel D. Davidson, Lucia Zuin, Federico A. Rabuffetti, Sarbajit Banerjee

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  13. Thermochemistry of 3D and 2D Rare Earth Oxychlorides (REOCls)

    Inorganic Chemistry · 2022-04-29

    Shuhao Yang, Andrzej Anderko, Richard E. Riman, Alexandra Navrotsky

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  14. First-principle study on the stability, mechanical, electronic, and optical properties of two-dimensional scandium oxyhalides

    Materials Chemistry and Physics · 2022-05-30

    Bo Meng, Tao Jing, Wen‐Zhi Xiao

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  15. Deciphering competing radiative relaxation pathways observed in Pr3+-Activated yttrium-based compounds: UV emission versus visible emission

    Journal of Luminescence · 2022-10-28

    Junsang Cho

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  16. Crystal-Structure Prediction and Experimental Investigation of the Polymorphic Lanthanum Fluoride Selenides LaFSe and La 2 F 4 Se

    Crystal Growth & Design · 2022-11-24

    Constantin Buyer, Hagen Grossholz, Sarah Wolf, Dejan Zagorac, Jelena Zagorac, Johann Christian Schön, Thomas Schleid

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  17. Structure prediction via global energy landscape exploration of the ternary rare‐earth compound LaOI

    Zeitschrift für anorganische und allgemeine Chemie · 2022-12-13

    Milan Pejić, Dejan Zagorac, Jelena Zagorac, Branko Z. Matović, Johann Christian Schön

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  18. Mechanisms of point defect formation and ionic conduction in divalent cation-doped lanthanum oxybromide: first-principles and experimental study

    Dalton Transactions · 2023-01-01

    Kazuki Shitara, Akihide Kuwabara, Naoyoshi Nunotani, Muhammad Radzi Iqbal Bin Misran, Miki Inada, Tomoki Uchiyama, Yoshiharu Uchimoto, Nobuhito Imanaka

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  19. Locating anionic hydrogen in Ba3(Yb,Lu)2O5H2: A combined approach of X-ray diffraction, crystal chemistry, and DFT calculations

    Journal of Solid State Chemistry · 2023-02-20

    Tiglet Besara, Daniel Candala Ramírez, Jifeng Sun, Nathaniel W. Falb, Wangwei Lan, Jeffrey B. Whalen, David Joseph Singh, Theo Siegrist

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  20. In search of Pca21 phase ferroelectrics

    Journal of Physics Materials · 2023-02-24

    Ge‐Qi Mao, Jun‐Hui Yuan, Kan‐Hao Xue, Jinhai Huang, Shengxin Yang, Xiangshui Miao

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  21. Topochemical Anionic Subunit Insertion Reaction for Constructing Nanoparticles of Layered Oxychalcogenide Intergrowth Structures

    Journal of the American Chemical Society · 2023-08-15

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  22. Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Ce3F10·3H2O

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  23. Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се3F10 ⋅ 3Н2О

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    Е. Г. Ильин, Artemy S. Parshakov, L. D. Iskhakova, Sergey Yu. Kottsov, Arina D. Filippova, Lyudmila V. Goeva, Nikolay P. Simonenko, Alexander E. Baranchikov, Vladimir K. Ivanov

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  24. Novel BiOI/LaOXI〈IX〉 heterojunction with enhanced visible-light driven photocatalytic performance: unveiling the mechanism of interlayer electron transition

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  26. Synthesis, chloride-ion diffusion mechanisms, and anisotropic sintering of 2D layered erbium oxychloride nanoplatelets

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  28. First-principles quantum computational study to investigate radiation energy-dependent effect on optoelectronic properties of bismuth oxyhalides BiOX (X= I, Br)

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  29. Synthetic Roadmap to a Large Library of Colloidal High-Entropy Rare Earth Oxyhalide Nanoparticles Containing up to Thirteen Metals

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  30. Quantum computational insights into electronic and optical properties of LnOIs for fundamental and technological applications

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  31. Stereochemical expression of Bi 6s 2 lone pairs mediates fluoride-ion (De)insertion in tunnel-structured Bi 2 PdO 4 and Bi 1.6 Pb 0.4 PtO 4

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  32. In-Situ Thermometry Reveals Fragmentation Behavior Based on Local Temperature in α-Olefin Polymerization Catalysts

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