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RESEARCH PAPER · Advanced Materials · 2018

N‐Doped C@Zn3B2O6 as a Low Cost and Environmentally Friendly Anode Material for Na‐Ion Batteries: High Performance and New Reaction Mechanism

Sai Wang, Xinbo Zhang

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N‐Doped C@Zn3B2O6 as a Low Cost and Environmentally Friendly Anode Material for Na‐Ion Batteries: High Performance and New Reaction MechanismOriginalElectrochemical and thermal characterization of Li4Ti5O12||Li3V2(PO4)3 lithium ion battery11Robust Polyimide Nanofibrous Membrane with Bonding Microstructures Fabricated via Dipping Process for Lithium‐Ion Battery Separators32Inhibiting Grain Pulverization and Sulfur Dissolution of Bismuth Sulfide by Ionic Liquid Enhanced Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) for High-Performance Zinc-Ion Batteries113Carbon coated transition metal borates as anode materials for Na-ion batteries382D Metal–Organic Framework Derived CuCo Alloy Nanoparticles Encapsulated by Nitrogen‐Doped Carbonaceous Nanoleaves for Efficient Bifunctional Oxygen Electrocatalyst and Zinc–Air Batteries54Pseudo‐Zn–Air and Zn‐Ion Intercalation Dual Mechanisms to Realize High‐Areal Capacitance and Long‐Life Energy Storage in Aqueous Zn Battery153Conjugated System of PEDOT:PSS-Induced Self-Doped PANI for Flexible Zinc-Ion Batteries with Enhanced Capacity and Cyclability140In Situ Derivatization for Boosted Lithium Storage Performance of Fe7S8/C Hollow Nanospheres9The morphology and electrochemical properties of porous Fe2O3@C and FeS@C nanofibers as stable and high-capacity anodes for lithium and sodium storage23PPy‐Derived Sandwich‐Structured Hollow Carbon Fiber Anchoring Sn4P3 as Anode Materials with Improved Na+ Storage15An ultraviolet polymerized 3D gel polymer electrolyte based on multi-walled carbon nanotubes doped double polymer matrices for lithium-sulfur batteries57Highly reversible electrochemical reaction of insoluble 3D nanoporous polyquinoneimines with stable cycle and rate performance40Uniform yolk−shell Fe7S8@C nanoboxes as a general host material for the efficient storage of alkali metal ions89Tetragonal MF2 (M=Ni, Co) micro/nanocrystals anodes for lithium/sodium-ion capacitors33Encapsulating Red Phosphorus in Ultralarge Pore Volume Hierarchical Porous Carbon Nanospheres for Lithium/Sodium-Ion Half/Full Batteries114A Flexible Dual‐Ion Battery Based on Sodium‐Ion Quasi‐Solid‐State Electrolyte with Long Cycling Life145Tailoring the Pore Size of a Polypropylene Separator with a Polymer Having Intrinsic Nanoporosity for Suppressing the Polysulfide Shuttle in Lithium–Sulfur Batteries102π-Conjugated polyimide-based organic cathodes with extremely-long cycling life for rechargeable magnesium batteries122Growth of LiNi0.5Mn1.5O4 crystals on reduced graphene oxide sheets for high energy and power density charge storage9Modeling of Zinc Bromine redox flow battery with application to channel design45Nickel‐Catalyzed Synthesis of 3D Edge‐Curled Graphene for High‐Performance Lithium‐Ion Batteries55Highly microporous SbPO 4 /BC x hybrid anodes for sodium-ion batteries18Recent progress on metallic Sn- and Sb-based anodes for sodium-ion batteries141Structure-controlled SnSe2 nanosheets as high performance anode material for lithium ion batteries27Synthesis of hierarchical Mn3O4 nanowires on reduced graphene oxide nanoarchitecture as effective pseudocapacitive electrodes for capacitive desalination application99Cylindroid‐Like Li4Ti5O12 Mesocrystals for High‐Rate and Long‐Life Lithium‐Ion Battery Anodes5Flexible Interface Design for Stress Regulation of a Silicon Anode toward Highly Stable Dual‐Ion Batteries188Empowering organic‐based negative electrode material based on conjugated lithium carboxylate through molecular design8Two-dimensional materials as anodes for sodium-ion batteries104High-Voltage Flexible Aqueous Zn-Ion Battery with Extremely Low Dropout Voltage and Super-Flat Platform64Co 2 B 2 O 5 as an anode material with high capacity for sodium ion batteries28PbTe nanodots confined on ternary B2O3/BC2O/C nanosheets as electrode for efficient sodium storage21Hydrangea‐Like CuS with Irreversible Amorphization Transition for High‐Performance Sodium‐Ion Storage97Manipulating the stress of Sn in carbon structure to realize long-life high performance sodium ion battery anode material14Buckwheat derived nitrogen-rich porous carbon material with a high-performance Na-storage27Tailoring the mesoporous ZnMn2O4 spheres as anode materials with excellent cycle stability for sodium-ion batteries24Electrospinning‐Based Strategies for Battery Materials302Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review427Interlayer Doping in Layered Vanadium Oxides for Low‐cost Energy Storage: Sodium‐ion Batteries and Aqueous Zinc‐ion Batteries66Recent Advances and Optimization Strategies on the Electrolytes for Hard Carbon and P‐Based Sodium‐Ion Batteries91Borates as promising electrode materials for rechargeable batteries92Three-Phase Borate Solid Solution With Low Sintering Temperature, High Quality Factor, and Low Dielectric Constant: Experimental and DFT Study1Recent Advances and Perspectives on Calcium‐Ion Storage: Key Materials and Devices191Bond characteristics and microwave dielectric properties of high‐Q materials in li‐doped Zn 3 B 2 O 6 systems57A facile method to stabilize sodium metal anodes towards high-performance sodium batteries69A renewable future: a comprehensive perspective from materials to systems for next-generation batteries23An overview on Sb-based intermetallics and alloys for sodium-ion batteries: trends, challenges and future prospects from material synthesis to battery performance76Defect induced nitrogen reduction reaction of carbon nanomaterials15Flexible electrodes with high areal capacity based on electrospun fiber mats22Multi-length scale microstructural design of lithium-ion battery electrodes for improved discharge rate performance106Nanostructured intermetallic InSb as a high-capacity and high-performance negative electrode for sodium-ion batteries12Synthesis and characterization of metal–organic framework/biomass-derived CoSe/C@C hierarchical structures with excellent sodium storage performance30Pseudocapacitive MoOx anode material with super-high rate and ultra-long cycle properties for aqueous zinc ion batteries31Recent Advances in Heterostructured Anode Materials with Multiple Anions for Advanced Alkali‐Ion Batteries99Three‐phase borate solid solution with low sintering temperature, high‐quality factor, and low dielectric constant25Recent Progress and Challenges in Multivalent Metal‐Ion Hybrid Capacitors31A detailed study of the substitution mechanism for improved zinc-borate: High-performance and its crystal structure variation2Eco‐Friendly Electronics—A Comprehensive Review172Recent Progress in Polyanionic Anode Materials for Li (Na)-Ion Batteries172Upcycling of spent carbon cathode (SCC) into SCC-2600@rGO facilitates ultrastable and fast lithium storage15High Oxidation Potential ≈6.0 V of Concentrated Electrolyte toward High‐Performance Dual‐Ion Battery97Surface modification of manganese monoxide through chemical vapor deposition to attain high energy storage performance for aqueous zinc–ion batteries31Incorporating quantum-sized boron dots into 3D cross-linked rGO skeleton to enable the activity of boron anode for favorable lithium storage28Liquid Ammoniates as Efficient Electrolytes for Room-Temperature Rechargeable Sodium-Metal Batteries Based on an Organic Cathode5Structural Evaluation of Coal-Tar-Pitch-Based Carbon Materials and Their Na+ Storage Properties19Enhanced performance of NiF2/BiVO4 photoanode for photoelectrochemical water splitting9Atomically Thin Materials for Next-Generation Rechargeable Batteries169Defect‐Selectivity and “Order‐in‐Disorder” Engineering in Carbon for Durable and Fast Potassium Storage310Richly electron-deficient BC x O 3− x anodes with enhanced reaction kinetics for sodium/potassium-ion batteries8Liquefied-Natural-Gas-Derived Vertical Carbon Layer Deposited on SiO as Cost-Effective Anode for Li-Ion Batteries19Converting spent carbon cathode (SCC) into SCC-2600@rGO for superior Li+ storage performance11Perspective: Design of cathode materials for sustainable sodium-ion batteries86Detection of the UV-vis silent biomarker trimethylamine-N-oxide via outer-sphere interactions in a lanthanide metal-organic framework67Expeditious Electrochemical Synthesis of Mesoporous Chalcogenide Flakes: Mesoporous Cu 2 Se as a Potential High‐Rate Anode for Sodium‐Ion Battery25SnO2 nanoparticles composited with biomass N-doped carbon microspheres as low cost, environmentally friendly and high-performance anode material for sodium-ion and lithium-ion batteries60Rational Screening of Artificial Solid Electrolyte Interphases on Zn for Ultrahigh‐Rate and Long‐Life Aqueous Batteries216A Low Cost, High Electrochemical Performance Carbon Coated Zinc Borate Anode Material for Sodium-ion Batteries1A stable anthraquinone-derivative cathode to develop sodium metal batteries: The role of ammoniates as electrolytes6Combustion Activation Induced Solid‐State Synthesis for N, B Co‐Doped Carbon/Zinc Borate Anode with a Boosting of Sodium Storage Performance75Efficient Preparation of BNNSs and Their Performance Study of Reinforced Porous Si3N4 Composites by Gel Casting1Bi Nanospheres Embedded in N‐Doped Carbon Nanowires Facilitate Ultrafast and Ultrastable Sodium Storage30Structural engineering of Sb‐based electrode materials to enhance advanced sodium‐ion batteries20Enhancing the sodium-ion storage performance of two-dimensional layered Ti3CN with a molecular riveting strategy12Spatial structure and influencing factors of China’s energy storage technology transfer network4Boron quantum dot powered anthracite-derived carbon anode achieving enhanced reaction kinetics and superior sodium storage capability10Scalable Preparation and Precise Control of Carbon Materials via Molten Salt Liquid Seal Strategy in Air5Solution combustion synthesis of zinc borate nanoparticles: Its flame-retardant properties10Solvent-assisted ligand exchange induces the epitaxial growth of VSe 2 on the surface of a 3D nitrogen-doped carbon network for ultra-long-life lithium/sodium-ion batteries2Dysprosium-doped molybdenum oxide nano-ceramic with impressive performances for zinc metal-free zinc-ion batteries4Organic molecular pillaring strategy for Nb2C MXene toward fast and stable sodium-ion storage0Boron-tailored starbon for fast-charging and stable-cycling lithium-ion batteries0

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