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RESEARCH PAPER · ACS Applied Nano Materials · 2018

Mithrene Is a Self-Assembling Robustly Blue Luminescent Metal–Organic Chalcogenolate Assembly for 2D Optoelectronic Applications

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Mithrene Is a Self-Assembling Robustly Blue Luminescent Metal–Organic Chalcogenolate Assembly for 2D Optoelectronic ApplicationsOriginalTarnishing Silver Metal into Mithrene69Competing Roles of Crystallization and Degradation of a Metal–Organic Chalcogenolate Assembly under Biphasic Solvothermal Conditions27Metallo‐Hydrogel‐Assisted Synthesis and Direct Writing of Transition Metal Dichalcogenides15Metal Nanoclusters Stabilized by Selenol Ligands76Structural and photophysical studies of coordination polymers of coinage metals thiolates0Transparent and luminescent glasses of gold thiolate coordination polymers54Corrosion of Late- and Post-Transition Metals into Metal–Organic Chalcogenolates and Implications for Nanodevice Architectures20Anisotropic 2D excitons unveiled in organic–inorganic quantum wells60Two-Dimensional Layered Materials Offering Expanded Applications in Flatland43Understanding the Synthetic Pathway to Large Area, High Quality [AgSePh] Nanocrystal Films0Understanding the Synthetic Pathway to Large-Area, High-Quality [AgSePh]∞ Nanocrystal Films30Strongly Quantum-Confined Blue-Emitting Excitons in Chemically Configurable Multiquantum Wells504D-STEM of Beam-Sensitive Materials145Investigation of Nucleation and Growth at a Liquid–Liquid Interface by Solvent Exchange and Synchrotron Small-Angle X-Ray Scattering12Size and Quality Enhancement of 2D Semiconducting Metal–Organic Chalcogenolates by Amine Addition58General introduction—luminescent metal nanoclusters1Chemical crystallography by serial femtosecond X-ray diffraction125Morphological Control of 2D Hybrid Organic–Inorganic Semiconductor AgSePh46Layered Organic Metal Chalcogenides (OMCs): From Bulk to Two‐Dimensional Materials69Layered Organic Metal Chalcogenides (OMCs): From Bulk to Two‐Dimensional Materials9Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation10Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies25Light Emission in 2D Silver Phenylchalcogenolates34Dual-Emission 2D Blue Luminescent Organic Silver Chalcogenide for Highly Selective Pb2+ Detection in an Aqueous Medium71D Hybrid Semiconductor Silver 2,6-Difluorophenylselenolate37Microwave-assisted synthesis of metal-organic chalcogenolate assemblies as electrocatalysts for syngas production35XFEL Microcrystallography of Self-Assembling Silver n -Alkanethiolates31Dimensionality Engineering of Lead Organic Chalcogenide Semiconductors35Tunable Synthesis of Metal–Organic Chalcogenide Semiconductor Nanocrystals25Engineering Supramolecular Hybrid Architectures with Directional Organofluorine Bonds9Coherent exciton-lattice dynamics in a 2D metal organochalcogenolate semiconductor20Inorganic–Organic Hybrid Layered Semiconductor AgSePh: Quasi-Solution Synthesis, Optical Properties, and Thermolysis Behavior10Heterocyclic Modification Leading to Luminescent 0D Metal Organochalcogenide with Stable X-ray Scintillating Properties21Mechanochemistry: Fundamental Principles and Applications92Giant Optical Anisotropy in 2D Metal–Organic Chalcogenates26Synthesis and Structural Anisotropy of Single-Crystalline 2D AgEPh (E = S, Se, Te)22Nucleophilic Displacement Reactions of Silver-Based Metal–Organic Chalcogenolates11Slow Dephasing of Coherent Optical Phonons in Two-Dimensional Lead Organic Chalcogenides13Ligand‐Mediated Quantum Yield Enhancement in 1‐D Silver Organothiolate Metal–Organic Chalcogenolates12Mixed-Chalcogen 2D Silver Phenylchalcogenides (AgE1–xExPh; E = S, Se, Te)15Birefringent Color Filter by Layered Metal‐Organic Chalcogenides: In‐Plane Anisotropy and Odd/Even Effect10Area-scalable film preparation and blue excitonic photoluminescence of organic–inorganic hybrid 2D semiconductor AgSePh (Ph = C 6 H 5 )2Low-dimensional AgTePh disordered aggregation versus directed coalescence for shortwave-IR to visible semiconductors0Ultrastrong light–matter coupling in two-dimensional metal–organic chalcogenolates33Hot‐Injection Synthesis of Metal Organochalcogenide Nanocrystals with Tunable Compositions and Competitive Hole Mobility9Layered Metal–Organic Chalcogenides: 2D Optoelectronics in 3D Self-Assembled Semiconductors26Design and application of two-dimensional organic metal chalcogenides0Selenolated Copper Hydride Clusters for Visible-Light Photocatalytic Iodofluoroalkylation of Alkynes3Supramolecular Support of Cuprophilic Network Bonding in 2-D Copper n -Alkanethiolates2Systematic Bandgap Engineering of a 2D Organic–Inorganic Chalcogenide Semiconductor via Ligand Modification8Electroluminescence From a 1D Metal–Organic Chalcogenide Enabled by a Minute‐Scale Facile Synthesis2Wafer‐Scale Synthesis of Mithrene and its Application in UV Photodetectors3Chelation-Driven Dissolution and Single-Crystal Growth of Hybrid Metal Organochalcogenide Semiconductors by Polydentate Amines51D Silver Organochalcogenide Semiconductors: Color Tunable Luminescence, Polarized Emission, and Long-Range Exciton Diffusion2Excitonic Anisotropy in Single‐Crystalline 2D Silver Phenylchalcogenides0Kinetics Control of Mithrene Formation in a High-Pressure Inert Environment: A Robust Solvent-Free Route to Superior-Quality Films2Ambient Tunneling Microscopy of Surface Annealing and Ligand Exchange Reactions on Metal–Organic Chalcogenolates0Stabilizing Structural Transitional States between 1- and 2-Dimensional Topologies via Hydrogen Bond-Mediated Crystal Engineering1Pressure-Induced Luminescence Evolution Mediated by Phase Transition of a One-Dimensional Metal–Organic Chalcogenolate0In-situ surface reconstruction of silver-based MOCHAs via chalcogen depletion for durable CO₂-to-CO electrocatalysis0Structural Insights into AgBi(SC 12 H 25 ) 4 Mixed-Metal n -Alkanethiolate: Heterometallic Thiolate Bridging and Metallophilic Interaction-Directed Self-Assembly0High color purity deep-blue light-emitting diodes with CIE coordinates of (0.134, 0.066) based on covalently bonded metal-organic chalcogenolates0

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  1. Tarnishing Silver Metal into Mithrene

    Journal of the American Chemical Society · 2018-09-28

    Brittany Trang, Matthew Yeung, Derek Popple, Elyse A. Schriber⧓, Michael A. Brady, Tevye Kuykendall, J. Nathan Hohman

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  2. Competing Roles of Crystallization and Degradation of a Metal–Organic Chalcogenolate Assembly under Biphasic Solvothermal Conditions

    Langmuir · 2018-10-29

    Derek Popple, Elyse A. Schriber⧓, Matthew Yeung, J. Nathan Hohman

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  3. Metallo‐Hydrogel‐Assisted Synthesis and Direct Writing of Transition Metal Dichalcogenides

    Advanced Functional Materials · 2019-05-09

    Xining Zang, J. Nathan Hohman, Kaiyuan Yao, Penghong Ci, Aiming Yan, Minsong Wei, Takeshi Hayasaka, Alex K. Zettl, Peter James Schuck, Junqiao Wu, Liwei Lin

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  4. Metal Nanoclusters Stabilized by Selenol Ligands

    Small · 2019-09-04

    Xi Kang, Manzhou Zhu

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  5. Structural and photophysical studies of coordination polymers of coinage metals thiolates

    Unknown journal · 2019-10-17

    Oleksandra Veselska

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  6. Transparent and luminescent glasses of gold thiolate coordination polymers

    Chemical Science · 2020-01-01

    Shefali Vaidya, Oleksandra Veselska, Antonii Zhadan, Maria Diaz‐Lopez, Yves Joly, P. Bordet, Nathalie Guillou, Christophe Dujardin, Gilles Ledoux, François Toche, Rodica Chiriac, Alexandra Fateeva, Satoshi Horike, Aude Demessence

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  7. Corrosion of Late- and Post-Transition Metals into Metal–Organic Chalcogenolates and Implications for Nanodevice Architectures

    ACS Applied Nano Materials · 2020-03-17

    Matthew Yeung, Derek Popple, Elyse A. Schriber⧓, Simon J. Teat, Christine M. Beavers, Aude Demessence, Tevye Kuykendall, J. Nathan Hohman

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  8. Anisotropic 2D excitons unveiled in organic–inorganic quantum wells

    Materials Horizons · 2020-07-06

    Lorenzo Maserati, Sivan Refaely‐Abramson, Christoph Kastl, Christopher T. Chen, Nicholas J. Borys, Carissa N. Eisler, Mary S. Collins, Tess Smidt, Edward S. Barnard, Matthew Strasbourg, Elyse A. Schriber⧓, Brian Shevitski, Kaiyuan Yao, J. Nathan Hohman, Peter James Schuck, Shaul Aloni, Jeffrey B. Neaton, Adam M. Schwartzberg

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  9. Two-Dimensional Layered Materials Offering Expanded Applications in Flatland

    ACS Applied Nano Materials · 2020-07-24

    Humberto R. Gutiérrez

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  10. Understanding the Synthetic Pathway to Large Area, High Quality [AgSePh] Nanocrystal Films

    arXiv (Cornell University) · 2020-07-30

    Lorenzo Maserati, Stefano Pecorario, Mirko Prato, Mario Caironi

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  11. Understanding the Synthetic Pathway to Large-Area, High-Quality [AgSePh]∞ Nanocrystal Films

    The Journal of Physical Chemistry C · 2020-09-23

    Lorenzo Maserati, Stefano Pecorario, Mirko Prato, Mario Caironi

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  12. Strongly Quantum-Confined Blue-Emitting Excitons in Chemically Configurable Multiquantum Wells

    ACS Nano · 2020-11-09

    Kaiyuan Yao, Mary S. Collins, Kara M. Nell, Edward S. Barnard, Nicholas J. Borys, Tevye Kuykendall, J. Nathan Hohman, Peter James Schuck

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  13. 4D-STEM of Beam-Sensitive Materials

    Accounts of Chemical Research · 2021-05-12

    Karen C. Bustillo, Steven E. Zeltmann, Min Chen, Jennifer Donohue, Jim Ciston, Colin Ophus, Andrew M. Minor

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  14. Investigation of Nucleation and Growth at a Liquid–Liquid Interface by Solvent Exchange and Synchrotron Small-Angle X-Ray Scattering

    Frontiers in Chemistry · 2021-07-20

    Elyse A. Schriber⧓, Daniel J. Rosenberg, Ryan P. Kelly, Anita Ghodsi, J. Nathan Hohman

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  15. Size and Quality Enhancement of 2D Semiconducting Metal–Organic Chalcogenolates by Amine Addition

    Journal of the American Chemical Society · 2021-11-21

    Watcharaphol Paritmongkol, Tomoaki Sakurada, Woo Seok Lee, Ruomeng Wan, Péter Müller, William A. Tisdale

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  16. General introduction—luminescent metal nanoclusters

    Elsevier eBooks · 2022-01-01

    Jitha Santhakumari Jayan, Kitty Joseph Kuruvilla, Appukuttan Saritha, Meegle S. Mathew, Kuruvilla Joseph, Sabu Thomas

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  17. Chemical crystallography by serial femtosecond X-ray diffraction

    Nature · 2022-01-19

    Elyse A. Schriber⧓, Daniel W. Paley⧓, Robert Bolotovsky, Daniel J. Rosenberg, Raymond G. Sierra, Andrew Aquila, Derek A. Mendez, Frédéric Poitevin, Johannes Blaschke, Asmit Bhowmick, Ryan P. Kelly, Mark S. Hunter, Brandon Hayes, Derek Popple, Matthew Yeung, Carina Pareja‐Rivera, Stella Lisova, Kensuke Tono, Michihiro Sugahara, Shigeki Owada, Tevye Kuykendall, Kaiyuan Yao, Peter James Schuck, Diego Solís-Ibarra, Nicholas K. Sauter, Aaron S. Brewster, J. Nathan Hohman

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  18. Morphological Control of 2D Hybrid Organic–Inorganic Semiconductor AgSePh

    ACS Nano · 2022-01-31

    Watcharaphol Paritmongkol, Woo Seok Lee, Wenbi Shcherbakov-Wu, Seung Kyun Ha, Tomoaki Sakurada, Soong Ju Oh, William A. Tisdale

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  19. Layered Organic Metal Chalcogenides (OMCs): From Bulk to Two‐Dimensional Materials

    Angewandte Chemie International Edition · 2022-04-20

    Guan‐E Wang, Shaozhen Luo, Tuo Di, Zhihua Fu, Gang Xu

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  20. Layered Organic Metal Chalcogenides (OMCs): From Bulk to Two‐Dimensional Materials

    Angewandte Chemie · 2022-04-20

    Guan‐E Wang, Shaozhen Luo, Tuo Di, Zhihua Fu, Gang Xu

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  21. Lead(II)-Azido Metal–Organic Coordination Polymers: Synthesis, Structure and Application in PbO Nanomaterials Preparation

    Nanomaterials · 2022-06-30

    Jaber Dadashi, Mohammad Khaleghian, Younes Hanifehpour, Babak Mirtamizdoust, Sang‐Woo Joo

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  22. Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies

    Chemistry of Materials · 2022-07-18

    Harrison A. Mills, Christopher G. Jones, Kierstyn P. Anderson, Austin D. Ready, Peter I. Djurovich, Saeed I. Khan, J. Nathan Hohman, Hosea M. Nelson, Alexander M. Spokoyny

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  23. Light Emission in 2D Silver Phenylchalcogenolates

    ACS Nano · 2022-11-23

    Woo Seok Lee, Yeongsu Cho, Eric R. Powers, Watcharaphol Paritmongkol, Tomoaki Sakurada, Heather J. Kulik, William A. Tisdale

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  24. Dual-Emission 2D Blue Luminescent Organic Silver Chalcogenide for Highly Selective Pb2+ Detection in an Aqueous Medium

    Inorganic Chemistry · 2023-01-25

    Chunhui Ye, Ze Li, Zixin Chang, Sha Sha Wu, Yimeng Sun, Wei Xu

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  25. 1D Hybrid Semiconductor Silver 2,6-Difluorophenylselenolate

    Journal of the American Chemical Society · 2023-02-22

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  26. Microwave-assisted synthesis of metal-organic chalcogenolate assemblies as electrocatalysts for syngas production

    Communications Chemistry · 2023-03-01

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  27. XFEL Microcrystallography of Self-Assembling Silver n -Alkanethiolates

    Journal of the American Chemical Society · 2023-07-31

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  28. Dimensionality Engineering of Lead Organic Chalcogenide Semiconductors

    Journal of the American Chemical Society · 2023-10-28

    Hanjun Yang, Sagarmoy Mandal, Yoon Ho Lee, Jee Yung Park, Han Zhao, Chongli Yuan, Libai Huang, Ming Chen, Letian Dou

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  29. Tunable Synthesis of Metal–Organic Chalcogenide Semiconductor Nanocrystals

    Chemistry of Materials · 2023-10-31

    Alexander C. Hernandez Oendra, Maximilian A. Aspect, Julia L. Jaeggi, Janik Baumann, Carin R. Lightner, Andrew B. Pun, David J. Norris

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  30. Engineering Supramolecular Hybrid Architectures with Directional Organofluorine Bonds

    Small Science · 2023-12-13

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  31. Coherent exciton-lattice dynamics in a 2D metal organochalcogenolate semiconductor

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  32. Inorganic–Organic Hybrid Layered Semiconductor AgSePh: Quasi-Solution Synthesis, Optical Properties, and Thermolysis Behavior

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  33. Heterocyclic Modification Leading to Luminescent 0D Metal Organochalcogenide with Stable X-ray Scintillating Properties

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  34. Mechanochemistry: Fundamental Principles and Applications

    Advanced Science · 2024-08-29

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  35. Giant Optical Anisotropy in 2D Metal–Organic Chalcogenates

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  36. Synthesis and Structural Anisotropy of Single-Crystalline 2D AgEPh (E = S, Se, Te)

    Chemistry of Materials · 2024-09-30

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  37. Nucleophilic Displacement Reactions of Silver-Based Metal–Organic Chalcogenolates

    Journal of the American Chemical Society · 2024-10-23

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  38. Slow Dephasing of Coherent Optical Phonons in Two-Dimensional Lead Organic Chalcogenides

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  39. Ligand‐Mediated Quantum Yield Enhancement in 1‐D Silver Organothiolate Metal–Organic Chalcogenolates

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  40. Mixed-Chalcogen 2D Silver Phenylchalcogenides (AgE1–xExPh; E = S, Se, Te)

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  41. Birefringent Color Filter by Layered Metal‐Organic Chalcogenides: In‐Plane Anisotropy and Odd/Even Effect

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  42. Area-scalable film preparation and blue excitonic photoluminescence of organic–inorganic hybrid 2D semiconductor AgSePh (Ph = C 6 H 5 )

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  43. Low-dimensional AgTePh disordered aggregation versus directed coalescence for shortwave-IR to visible semiconductors

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  44. Ultrastrong light–matter coupling in two-dimensional metal–organic chalcogenolates

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  46. Layered Metal–Organic Chalcogenides: 2D Optoelectronics in 3D Self-Assembled Semiconductors

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  47. Design and application of two-dimensional organic metal chalcogenides

    Chinese Science Bulletin (Chinese Version) · 2025-06-12

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  48. Selenolated Copper Hydride Clusters for Visible-Light Photocatalytic Iodofluoroalkylation of Alkynes

    Inorganic Chemistry · 2025-07-17

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  49. Supramolecular Support of Cuprophilic Network Bonding in 2-D Copper n -Alkanethiolates

    Inorganic Chemistry · 2025-08-12

    Maggie C. Willson, Daniel W. Paley⧓, Elyse A. Schriber⧓, Daniel J. Rosenberg, Daniel Tchoń, Patience A. Kotei, Komal Rani, Cynthia Melendrez, Mat­thias Zeller, Tarun Kaushik, Qiaoling Fan, Chamathka Dehiwala Liyanage, Jungmin Kang, Ichiro Inoue, Kensuke Tono, Yuichi Inubushi, Aaron S. Brewster, J. Nathan Hohman

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  50. Systematic Bandgap Engineering of a 2D Organic–Inorganic Chalcogenide Semiconductor via Ligand Modification

    Journal of the American Chemical Society · 2025-08-19

    Tomoaki Sakurada, Watcharaphol Paritmongkol, Yeongsu Cho, Woo Seok Lee, Petcharaphorn Chatsiri, Julius J. Oppenheim, Ruomeng Wan, Annlin Su, Nicholas Samulewicz, Khemika Wannakan, Péter Müller, Mircea Dincă, Heather J. Kulik, William A. Tisdale

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