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RESEARCH PAPER · Inorganic Chemistry · 2018

Anderson-Type Polyoxometalates Functionalized by Tetrathiafulvalene Groups: Synthesis, Electrochemical Studies, and NLO Properties

Amandine Boulmier, Antoine Vacher, Dejin Zang, Yang Shu, Ali Saad, Jérôme Marrot, Olivier Oms, Pierre Mialane, Isabelle N. Ledoux-Rak, Laurent Ruhlmann, Dominique Lorcy, Anne Dolbecq

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Anderson-Type Polyoxometalates Functionalized by Tetrathiafulvalene Groups: Synthesis, Electrochemical Studies, and NLO PropertiesOriginalThree hybrid tungstosilicates: Confinement of SiW12O404− anions in rigid concave surfaces with excellent nonlinear optical performance and interesting magnetic properties3Poly (dithienylpyrrole) / Keggin type (nBu4N)3[PW9O34(tBuSiOH)3] hybrid material: Enhanced optical and electrical properties of conjugated polymers via polyoxometalates13Two Keggin-Based Isostructural POMOF Hybrids: Synthesis, Crystal Structure, and Catalytic Properties82Synthesis and characterization of hybrid Anderson hexamolybdoaluminates(III) functionalized with indometacin or cinnamic acid5Redox-switching of ternary Ni( ii ) and Cu( ii ) complexes: synthesis, experimental and theoretical studies along with second-order nonlinear optical properties17Cu dendrites induced by the Anderson-type polyoxometalate NiMo6O24 as a promising electrocatalyst for enhanced hydrogen evolution86Theoretical Assessment of the Second-Order Nonlinear Optical Responses of Lindqvist-Type Organoimido Polyoxometalates49Highly stable polyoxometalate‐resorcin[4]arene‐based inorganic‐organic complexes for catalytic oxidation desulfurization8Direct Syntheses of Nanocages and Frameworks Based on Anderson-Type Polyoxometalates via One-Pot Reactions20Two isolated Zn-ε-Keggin decorated by pyridine-imidazole with excellent electrocatalytic and third-order NLO properties7Five-Membered Ring Systems: With O and S (Se, Te) Atoms2Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications444Two polyoxometalate-based inorganic-organic hybrids and one coordination polymer assembled with a functionalized calix[4]arene: Catalytic and electrochemical properties13Four octamolybdate complexes constructed from a quinoline–imidazole–monoamide ligand: structures and electrochemical, photocatalytic and magnetic properties31Palladium( ii ) complexes of tetradentate donor–acceptor Schiff base ligands: synthesis and spectral, structural, thermal and NLO properties23A Chemically Soldered Polyoxometalate Single‐Molecule Transistor80A Chemically Soldered Polyoxometalate Single‐Molecule Transistor22Twisted chromophore assist to tetrathiafulvalene-spiropyran hybrid driving four-state molecular switch2In Situ Ligand-Transformation-Involved Synthesis of Inorganic–Organic Hybrid Polyoxovanadates as Efficient Heterogeneous Catalysts for the Selective Oxidation of Sulfides53Anderson-type polyoxometalate-based complexes constructed from a new ‘V’-like bis-pyridine–bis-amide ligand for selective adsorption of organic dyes and detection of Cr( vi ) and Fe( iii ) ions42Anderson-type polyoxometalates: from structures to functions104Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties10Matériaux composites poreux pour la conversion du CO2 : synthèse, caractérisation et modélisation01,3-Dithioles4Density Functional Theory Study of Substitution Effects on the Second-Order Nonlinear Optical Properties of Lindquist-Type Organo-Imido Polyoxometalates15Polyoxometalates with tunable third-order nonlinear optical and superbroadband optical limiting properties26Two POM-based compounds containing Zn-capped Keggin anions as decent heterogeneous catalysts for sulfur oxidation and CO 2 cycloaddition reactions23Cations Modulated Assembly of Triol-Ligand Modified Cu-Centered Anderson-Evans Polyanions11Energy Level Engineering: Ru Single Atom Anchored on Mo-MOF with a [Mo 8 O 26 (im) 2 ] 4– Structure Acts as a Biomimetic Photocatalyst83Synthesis of α-Anderson Polyoxometalates-Porphyrin polymeric hybrid as an efficient photosensitizer11Self-assembly of Hybrid Solids {Hpz}2[H7CrMo6O24]·6H2O and [Co(2-Hampz)2Cl4] (pz = pyrazole, 2-ampz = 2-aminopyrazine) from Aqueous Solution1Experimental and Theoretical Evaluation of Four NLO‐Active Divalent Transition‐Metal Complexes Supported by an Enantiomerically Pure Tetradentate Schiff Base Ligand9Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials92Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance86Bis-TTF-Ge derivatives: promising linear and nonlinear optical properties, a theoretical investigation37Asymmetric modification of Anderson-type polyoxometalates towards organic–inorganic homo- and hetero-cluster oligomers13A bifunctional molecular catalyst built up of l -proline grafted polyoxometalate for one-pot three-component green synthesis of heterocycles67Latest progress in asymmetrically functionalized Anderson-type polyoxometalates37A Modern Look at Spiropyrans: From Single Molecules to Smart Materials107A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications22Covalent synthesis, structural characterization and biological behavioral study of tin captured porphyrin-polyoxometalate based polymeric hybrid2Photoelectrochemical biosensor based on SiW12@CdS quantum dots for the highly sensitive detection of HPV 16 DNA13Synthesis of multi fluorine containing polyoxometalate sandwich type compound with drug delivery, DNA interaction and protein binding studies5Catalytic oxidative desulfurization of thio-compounds by employing χ-Anderson-type polyoxometalates-porphyrin covalent organic framework (COF)13Synthesis of POM@Porphyrin COF heterogeneous catalyst for oxidative desulfurization of thio compounds17An innovative approach for the synthesis of 4Tris@Porphyrin and anderson polyoxometalate based covalent organic framework to reveal its potential for photocatalytic properties9The catalytic epimerization of glucose to mannose over an organic–inorganic hybrid based on Keggin-type phosphomolybdate9Polyoxometalate-based materials against environmental pollutants: A review67Synthesis, Characterization, and Properties of a Titanium(IV)-Tetrathiafulvalene-Based Complex0Lanthanide compounds with Anderson POM ligands: a route to multifunctional wide bandgap single molecule magnets0Quantitative cation exchange in Anderson-type polyoxometalate hybrid polyelectrolytes: Structural evolution and ion-transport mechanism transition0

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  1. Three hybrid tungstosilicates: Confinement of SiW12O404− anions in rigid concave surfaces with excellent nonlinear optical performance and interesting magnetic properties

    Polyhedron · 2018-05-24

    Wei Jiang, Lu Chen, Weiwei Cheng, Yayu Dong, Jun-Jie Gong, Haochen Shen, Yan Xu

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  2. Poly (dithienylpyrrole) / Keggin type (nBu4N)3[PW9O34(tBuSiOH)3] hybrid material: Enhanced optical and electrical properties of conjugated polymers via polyoxometalates

    Synthetic Metals · 2018-07-17

    Tuğba Soğancı, Yasemin Torlak, Metin Ak, Mustafa Ersöz

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  3. Two Keggin-Based Isostructural POMOF Hybrids: Synthesis, Crystal Structure, and Catalytic Properties

    Inorganic Chemistry · 2018-09-18

    Soumyabrata Roy, Vamseedhara Vemuri, Sthitadhi Maiti, Kaja Sai Manoj, Udumula Subbarao, Sebastian Chirambatte Peter

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  4. Synthesis and characterization of hybrid Anderson hexamolybdoaluminates(III) functionalized with indometacin or cinnamic acid

    Acta Crystallographica Section C Structural Chemistry · 2018-10-24

    Nadiia I. Gumerova, Amir Blazevic, Tania Caldera Fraile, Alexander Roller, Gerald Giester, Annette Rompel

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  5. Redox-switching of ternary Ni( ii ) and Cu( ii ) complexes: synthesis, experimental and theoretical studies along with second-order nonlinear optical properties

    New Journal of Chemistry · 2019-01-01

    Néstor Novoa, Carolina Manzur, Thierry Roisnel, Vincent Dorcet, Nolwenn Cabon, Françoise Robin‐Le Guen, Isabelle N. Ledoux-Rak, Samia Kahlal, Jean‐Yves Saillard, David Carrillo, Jean‐René Hamon

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  6. Cu dendrites induced by the Anderson-type polyoxometalate NiMo6O24 as a promising electrocatalyst for enhanced hydrogen evolution

    Applied Catalysis B: Environmental · 2019-02-23

    Dejin Zang, Yichao Huang, Qi Li, Yajie Tang, Yongge Wei

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  7. Theoretical Assessment of the Second-Order Nonlinear Optical Responses of Lindqvist-Type Organoimido Polyoxometalates

    Inorganic Chemistry · 2019-08-07

    Emna Rtibi, Manef Abderrabba, Sameh Ayadi, Benoît R. Champagne

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  8. Highly stable polyoxometalate‐resorcin[4]arene‐based inorganic‐organic complexes for catalytic oxidation desulfurization

    Applied Organometallic Chemistry · 2019-08-14

    Ming‐Yue Yu, Jin Zhong Yang, Xianxiu Xu, Jian‐Fang Ma, Zhenxing Wang

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  9. Direct Syntheses of Nanocages and Frameworks Based on Anderson-Type Polyoxometalates via One-Pot Reactions

    Inorganic Chemistry · 2019-09-03

    Min Cheng, Zicheng Xiao, Longbo Yu, Xinjun Lin, Yu Wang, Pingfan Wu

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  10. Two isolated Zn-ε-Keggin decorated by pyridine-imidazole with excellent electrocatalytic and third-order NLO properties

    Inorganica Chimica Acta · 2019-09-23

    Ye‐Min Han, Weiwei Cheng, Jia‐Peng Cao, Mu‐Xiu Yang, Ya-Lin Hong, Run‐Kun Kang, Yan Xu

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  11. Five-Membered Ring Systems: With O and S (Se, Te) Atoms

    Progress in heterocyclic chemistry · 2019-10-14

    R. A. Aitken

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  12. Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

    Chemical Society Reviews · 2019-12-03

    Alexander V. Anyushin, Aleksandar Kondinski, Tatjana N. Parac‐Vogt

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  13. Two polyoxometalate-based inorganic-organic hybrids and one coordination polymer assembled with a functionalized calix[4]arene: Catalytic and electrochemical properties

    Polyhedron · 2019-12-23

    Zhuo Li, Ying‐Ying Liu, Guohai Xu, Jian‐Fang Ma

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  14. Four octamolybdate complexes constructed from a quinoline–imidazole–monoamide ligand: structures and electrochemical, photocatalytic and magnetic properties

    CrystEngComm · 2020-01-01

    Lei Li, Xiang Wang, Na Xu, Zhihan Chang, Guo‐Cheng Liu, Hong‐Yan Lin, Xiuli Wang

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  15. Palladium( ii ) complexes of tetradentate donor–acceptor Schiff base ligands: synthesis and spectral, structural, thermal and NLO properties

    New Journal of Chemistry · 2020-01-01

    Salvador Celedón, Thierry Roisnel, Vania Artigas, Mauricio Fuentealba, David Carrillo, Isabelle N. Ledoux-Rak, Jean‐René Hamon, Carolina Manzur

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  16. A Chemically Soldered Polyoxometalate Single‐Molecule Transistor

    Angewandte Chemie International Edition · 2020-04-09

    Chuanli Wu, Xiaohang Qiao, Craig M. Robertson, Simon J. Higgins, Chenxin Cai, Richard John Nichols, Andrea Vezzoli

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  17. A Chemically Soldered Polyoxometalate Single‐Molecule Transistor

    Angewandte Chemie · 2020-04-09

    Chuanli Wu, Xiaohang Qiao, Craig M. Robertson, Simon J. Higgins, Chenxin Cai, Richard John Nichols, Andrea Vezzoli

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  18. Twisted chromophore assist to tetrathiafulvalene-spiropyran hybrid driving four-state molecular switch

    Computational and Theoretical Chemistry · 2020-06-27

    Guochen Zhao, Chun‐Guang Liu

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  19. In Situ Ligand-Transformation-Involved Synthesis of Inorganic–Organic Hybrid Polyoxovanadates as Efficient Heterogeneous Catalysts for the Selective Oxidation of Sulfides

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    Xiang Wang, Tong Zhang, Yunhui Li, Jia-Feng Lin, Huan Li, Xiuli Wang

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  20. Anderson-type polyoxometalate-based complexes constructed from a new ‘V’-like bis-pyridine–bis-amide ligand for selective adsorption of organic dyes and detection of Cr( vi ) and Fe( iii ) ions

    Inorganic Chemistry Frontiers · 2021-01-01

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  21. Anderson-type polyoxometalates: from structures to functions

    Nanoscale · 2021-01-01

    Pingfan Wu, Yu Wang, Bo Huang, Zicheng Xiao

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  22. Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties

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    Xiuli Wang, Xiuli Wang, Lei Li, Xiang Wang, Xiang Wang, Yuqing Zhang

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  23. Matériaux composites poreux pour la conversion du CO2 : synthèse, caractérisation et modélisation

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  24. 1,3-Dithioles

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  25. Density Functional Theory Study of Substitution Effects on the Second-Order Nonlinear Optical Properties of Lindquist-Type Organo-Imido Polyoxometalates

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  26. Polyoxometalates with tunable third-order nonlinear optical and superbroadband optical limiting properties

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  27. Two POM-based compounds containing Zn-capped Keggin anions as decent heterogeneous catalysts for sulfur oxidation and CO 2 cycloaddition reactions

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  28. Cations Modulated Assembly of Triol-Ligand Modified Cu-Centered Anderson-Evans Polyanions

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  29. Energy Level Engineering: Ru Single Atom Anchored on Mo-MOF with a [Mo 8 O 26 (im) 2 ] 4– Structure Acts as a Biomimetic Photocatalyst

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  30. Synthesis of α-Anderson Polyoxometalates-Porphyrin polymeric hybrid as an efficient photosensitizer

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  31. Self-assembly of Hybrid Solids {Hpz}2[H7CrMo6O24]·6H2O and [Co(2-Hampz)2Cl4] (pz = pyrazole, 2-ampz = 2-aminopyrazine) from Aqueous Solution

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  32. Experimental and Theoretical Evaluation of Four NLO‐Active Divalent Transition‐Metal Complexes Supported by an Enantiomerically Pure Tetradentate Schiff Base Ligand

    European Journal of Inorganic Chemistry · 2022-10-04

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  33. Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

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  34. Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance

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  35. Bis-TTF-Ge derivatives: promising linear and nonlinear optical properties, a theoretical investigation

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  36. Asymmetric modification of Anderson-type polyoxometalates towards organic–inorganic homo- and hetero-cluster oligomers

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  37. A bifunctional molecular catalyst built up of l -proline grafted polyoxometalate for one-pot three-component green synthesis of heterocycles

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  38. Latest progress in asymmetrically functionalized Anderson-type polyoxometalates

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  39. A Modern Look at Spiropyrans: From Single Molecules to Smart Materials

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  40. A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications

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  41. Covalent synthesis, structural characterization and biological behavioral study of tin captured porphyrin-polyoxometalate based polymeric hybrid

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  42. Photoelectrochemical biosensor based on SiW12@CdS quantum dots for the highly sensitive detection of HPV 16 DNA

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  43. Synthesis of multi fluorine containing polyoxometalate sandwich type compound with drug delivery, DNA interaction and protein binding studies

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  44. Catalytic oxidative desulfurization of thio-compounds by employing χ-Anderson-type polyoxometalates-porphyrin covalent organic framework (COF)

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  45. Synthesis of POM@Porphyrin COF heterogeneous catalyst for oxidative desulfurization of thio compounds

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  46. An innovative approach for the synthesis of 4Tris@Porphyrin and anderson polyoxometalate based covalent organic framework to reveal its potential for photocatalytic properties

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  47. The catalytic epimerization of glucose to mannose over an organic–inorganic hybrid based on Keggin-type phosphomolybdate

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  48. Polyoxometalate-based materials against environmental pollutants: A review

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  49. Synthesis, Characterization, and Properties of a Titanium(IV)-Tetrathiafulvalene-Based Complex

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  50. Lanthanide compounds with Anderson POM ligands: a route to multifunctional wide bandgap single molecule magnets

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