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RESEARCH PAPER · Accounts of Chemical Research · 2018

Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries

Seung‐Ho Yu, Xinran Feng, Na Zhang, Jeesoo Seok, Héctor D. Abruña

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Understanding Conversion-Type Electrodes for Lithium Rechargeable BatteriesOriginalPorous Fe3O4Nanospheres as Effective Sulfur Hosts for Li-S Batteries25CuS Microspheres with Tunable Interlayer Space and Micropore as a High‐Rate and Long‐Life Anode for Sodium‐Ion Batteries282Remedies of capacity fading in room-temperature sodium-sulfur batteries60Conversion reaction of vanadium sulfide electrode in the lithium-ion cell: Reversible or not reversible?67Morphology-dependent electrochemical performance of spinel-cobalt oxide nanomaterials towards lithium-ion batteries33Strongly Surface‐Bonded MoO2@Carbon Nanocomposites by Nitrogen‐Doping with Outstanding Capability for Fast and Stable Li Storage273-Dimensional hierarchically porous ZnFe2O4/C composites with stable performance as anode materials for Li-ion batteries85Nanostructured Conversion‐Type Negative Electrode Materials for Low‐Cost and High‐Performance Sodium‐Ion Batteries189Understanding the electrochemical reaction mechanism of VS 2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy18Recent progress in metal–organic frameworks for lithium–sulfur batteries84Structure‐Controllable Binary Nanoporous‐Silicon/Antimony Alloy as Anode for High‐Performance Lithium‐Ion Batteries18Recent advances of polar transition-metal sulfides host materials for advanced lithium–sulfur batteries48Atomic Structure of 2 nm Size Metallic Cobalt Prepared by Electrochemical Conversion: An in Situ Pair Distribution Function Study19Study on Electrochemical Processes of NiO Model Electrode during the First Lithiation/delithiation Cycle via Electrochemical Impedance Spectroscopy5Revisiting Conversion Reaction Mechanisms in Lithium Batteries: Lithiation-Driven Topotactic Transformation in FeF 264K+ storage in porous red blood cell-like hollow carbon8Construction of carbon-coated nickel phosphide nanoparticle assembled submicrospheres with enhanced electrochemical properties for lithium/sodium-ion batteries38Multifunctional porous VN nanowires interlayer as polysulfides barrier for high performance lithium sulfur batteries29Enhanced electrochemical properties of Mn3O4/graphene nanocomposite as efficient anode material for lithium ion batteries73Antimony‐Doped Lithium Phosphate Artificial Solid Electrolyte Interphase for Dendrite‐Free Lithium‐Metal Batteries362D few-layer iron phosphosulfide: a self-buffer heterophase structure induced by irreversible breakage of P–S bonds for high-performance lithium/sodium storage73Binder-free C@NiCo 2 O 4 on Ni foam with ultra-stable pseudocapacitive lithium ion storage8In-situ sulfuration synthesis of N,S-doped carbon nanosheet encapsulated Fe-doped Co9S8 as anodes for tunable lithium storage43ALL-SOLID LITHIUM-ION BATTERIES FOR HIGH SAFETY AND STABILITY0Conclusions and Perspectives on New Opportunities of Nanostrucutres and Nanomaterials in Batteries1Recent Developments in Electrode Materials for Lithium-Ion Batteries for Energy Storage Application3Sawing Angles on Property of Lithium-Sulfur Battery Interlayer Prepared withBirch Derived Orientedly Microchannel Biochar1Sulfur encapsulation by MOF-derived CoS 2 embedded in carbon hosts for high-performance Li–S batteries108Understanding the electrochemical potential and diffusivity of MnO/C nanocomposites at various charge/discharge states45Uniform lithium deposition on N-doped carbon-coated current collectors32Beyond Intercalation Chemistry for Rechargeable Mg Batteries: A Short Review and Perspective117Toward Environmentally Friendly Lithium Sulfur Batteries: Probing the Role of Electrode Design in MoS2-Containing Li–S Batteries with a Green Electrolyte30Pseudocapacitive P-doped NiCo2O4 microspheres as stable anode for lithium ion batteries27Surface Chemistry of Alkali‐Ion Battery Cathode Materials0Current Li-Ion Battery Technologies in Electric Vehicles and Opportunities for Advancements873A novel Li3P-VP nanocomposite fabricated by pulsed laser deposition as anode material for high-capacity lithium ion batteries8Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics15Facile synthesis of Mn2.1V0.9O4/rGO: A novel high-rate anode material for lithium-ion batteries28Recent Advances and Perspectives of Carbon-Based Nanostructures as Anode Materials for Li-ion Batteries156Multi-electron transfer enabled by topotactic reaction in magnetite39Oxyvanite V 3 O 5 : A new intercalation‐type anode for lithium‐ion battery141Recent progress in the application of in situ atomic force microscopy for rechargeable batteries38Hetero-layered MoS2/C composites enabling ultrafast and durable Na storage57Pulsed Laser Deposited Films for Microbatteries63Operando X-ray absorption spectroscopy applied to battery materials at ICGM: The challenging case of BiSb's sodiation18Energy-Dispersive X-ray Diffraction: Operando Visualization of Electrochemical Activity of Thick Electrodes16Porous carbon encapsulated Mn3O4 for stable lithium storage and its ex-situ XPS study68Rapid Assemble of MnC2O4 Microtubes Using a Microchannel Reactor and Their Use as an Anode Material for Lithium-ion Batteries35Li-free Cathode Materials for High Energy Density Lithium Batteries390Constructing enhanced pseudocapacitive Li+ intercalation via multiple ionically bonded interfaces toward advanced lithium storage37Oxygen-defective Co3O4 for pseudo-capacitive lithium storage68Recent progress of surface coating on cathode materials for high-performance lithium-ion batteries479Flower-Like MoSe2/MoO2 Composite with High Capacity and Long-Term Stability for Lithium-Ion Battery34Enabling Full Conversion Reaction with High Reversibility to Approach Theoretical Capacity for Sodium Storage42Multiple Anionic Transition-Metal Oxycarbide for Better Lithium Storage and Facilitated Multielectron Reactions36Self-Assembled Nanoparticle Supertubes as Robust Platform for Revealing Long-Term, Multiscale Lithiation Evolution60Structural Reorganization–Based Nanomaterials as Anodes for Lithium‐Ion Batteries: Design, Preparation, and Performance43Facile Synthesis of a Tin Oxide-Carbon Composite Lithium-Ion Battery Anode with High Capacity Retention27Prussian blue analogs (PBA) derived porous bimetal (Mn, Fe) selenide with carbon nanotubes as anode materials for sodium and potassium ion batteries207The keys for effective distribution of intergranular voids of peapod-like MnO@C core-shell for lithium ion batteries7Promoting Transport Kinetics in Li-Ion Battery with Aligned Porous Electrode Architectures135Atomic‐Scale Visualization of Electrochemical Lithiation Processes in Monolayer MoS2 by Cryogenic Electron Microscopy40Energy storage: The future enabled by nanomaterials1918Regulating lithium nucleation and growth by zinc modified current collectors41Metal carbodiimides and cyanamides, a new family of electrode materials for Li-ion batteries1Voltage issue of aqueous rechargeable metal-ion batteries782Effects of the Inherent Tubular Structure and Graphene Coating on the Lithium Ion Storage Performances of Electrospun NiO/Co3O4 Nanotubes19Binary graphene-based cathode structure for high-performance lithium-sulfur batteries17Copper sulfide nanostructures and their sodium storage properties26Electrochemical performance of Li + insertion/extraction in Ni-substituted ZnCo 2 O 4 as an emerging highly efficient anode material11Exploring the origin of electrochemical performance of Cr-doped LiNi 0.5 Mn 1.5 O 422Identifying different states of lithiation of Li 4 Ti 5 O 12 spinel by energy-dispersive inelastic X-ray scattering (EDIXS) spectroscopy6Ni–Sn intermetallics as an efficient buffering matrix of Si anodes in Li-ion batteries22Recent Developments in Electrode Materials for Lithium-Ion Batteries for Energy Storage Application5Sn(salen)-derived SnS nanoparticles embedded in N-doped carbon for high performance lithium-ion battery anodes33Synthesis, modular composition, and electrochemical properties of lamellar iron sulfides15Unraveling atomic-scale lithiation mechanisms in a NiO thin film electrode12Perspective—Enhancing Active Anode Material Performance for Lithium-Ion Batteries via Manipulation of Interfacial Chemistry8Review—Towards Efficient Energy Storage Materials: Lithium Intercalation/Organic Electrodes to Polymer Electrolytes—A Road Map (Tribute to Michel Armand)22Lithiation of Sulfur-Graphene Compounds Using Reactive Force-Field Molecular Dynamics Simulations12Effect of Continuous Capacity Rising Performed by FeS/Fe3C/C Composite Electrodes for Lithium‐Ion Batteries33Reversible High Capacity and Reaction Mechanism of Cr2(NCN)3 Negative Electrodes for Li‐Ion Batteries22Hollow CuS Nanoboxes as Li‐Free Cathode for High‐Rate and Long‐Life Lithium Metal Batteries77On battery materials and methods214Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction41Development of Novel Cathode with Large Lithium Storage Mechanism Based on Pyrophosphate‐Based Conversion Reaction for Rechargeable Lithium Batteries7Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage206MoS2 Nanoflower-Derived Interconnected CoMoO4 Nanoarchitectures as a Stable and High Rate Performing Anode for Lithium-Ion Battery Applications63Engineering of Sn and Pre‐Lithiated Sn as Negative Electrode Materials Coupled to Garnet Ta‐LLZO Solid Electrolyte for All‐Solid‐State Li Batteries16Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode55Hybrid Nanostructured Ni(OH)2/NiO for High-Capacity Lithium-Ion Battery Anodes7Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds4Multiscalar Investigation of FeVO 4 Conversion Cathode for a Low Concentration Zn(CF 3 SO 3 ) 2 Rechargeable Zn‐Ion Aqueous Battery27Effects of Atmospheric Gases on Li Metal Cyclability and Solid-Electrolyte Interphase Formation48A Trip to Oz and a Peak Behind the Curtain of Magnesium Batteries128Thermodynamic analysis of high energy density conversion type cathode materials for Na‐ and K‐ion batteries5An Innovative Lithium Ion Battery System Based on a Cu2S Anode Material38Role of silicon and carbon on the structural and electrochemical properties of Si-Ni3.4Sn4-Al-C anodes for Li-ion batteries4Electrochemical Performance of (MgCoNiZn) 1– x Li x O High-Entropy Oxides in Lithium-Ion Batteries171Macroporous Mn3O4 microspheres as a conversion-type anode material morphology for Li-ion batteries12Flexible Electrocatalytic Nanofiber Membrane Reactor for Lithium/Sulfur Conversion Chemistry58Structural engineering of porous N-doped carbon-coated Fe3O4 framework by controlling coordination for superior lithium-ion full-cell12A general anion exchange strategy to transform metal-organic framework embedded nanofibers into high-performance lithium-ion capacitors50Tunable structure and dynamics of solid electrolyte interphase at lithium metal anode70Novel Skutterudite CoP3–Based Asymmetric Supercapacitor with Super High Energy Density92Electrochemical Performance of B‐Type Vanadium Dioxide as a Sodium‐Ion Battery Cathode: A Combined Experimental and Theoretical Study6Hydrogels and Hydrogel-Derived Materials for Energy and Water Sustainability1395CTAB-modified Ni2P@ACNT composite with enhanced supercapacitive and lithium/sodium storage performance28Reaction mechanism and structural evolution of fluorographite cathodes in Li/Na/K batteries0Review of current progress in non-aqueous aluminium batteries98Unique Structure-Induced Magnetic and Electrochemical Activity in Nanostructured Transition Metal Tellurates Co1 – x Ni x TeO4 ( x = 0, 0.5, and 1)19Graphene oxide coated nanosheet‐like γ‐MnS @ KB‐S fabricated by spray drying for high energy density Li‐S batteries9Effects of Film Formation on the Electrodeposition of Lithium17Decoding of Oxygen Network Distortion in a Layered High-Rate Anode by In Situ Investigation of a Single Microelectrode13Macroscopic Displacement Reaction of Copper Sulfide in Lithium Solid‐State Batteries62Understanding the high capacity contributions of Cu3PS4 towards lithium storage20Rational design on materials for developing next generation lithium-ion secondary battery147Lithium–sulfur redox: challenges and opportunities24Lithiation mechanism of W18O49 anode material for lithium-ion batteries: Experiment and first-principles calculations14Cotton cloth templated in situ encapsulation of sulfur into carbon fibers for lithium–sulfur batteries19Reaction Mechanism and Structural Evolution of Fluorographite Cathodes in Solid‐State K/Na/Li Batteries77CuCo2S4: Versatile anode for high capacity and high rate for lithium and sodium ion battery application17High stability graphene oxide aerogel supported ultrafine Fe3O4 particles with superior performance as a Li-ion battery anode100Hollow opening nanoflowers MoS2-CuS-EG cathodes for high-performance hybrid Mg/Li-ion batteries49Advanced Anode and Cathode Materials for Li-ion Batteries: Application to Printing Methodology3Advanced cathodes and electrolytes for rechargeable zinc-ion batteries0Fabrication and characterization of silicon based electrodes for Li-ion batteries0Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries0Insight into the charging–discharging of magnetite electrodes: in situ XAS and DFT study11Interfacial modulation achieving a flexible anode of FeP/N-doped C@carbon cloth with a robust structure for high areal capacity lithium storage6Nitro Group Reduction for Use in Organic, Cathodic Materials0The role of polymers in lithium solid-state batteries with inorganic solid electrolytes112Battery Energy Transformation and Unravelling the Thermodynamics of Energy Storage and Conversion16N,S co-doped carbon confined MnO/MnS heterostructures derived from a one-step pyrolysis of Mn-methionine frameworks for advanced lithium storage29In-situ constructing uniform polymer network for iron oxide microspheres: A novel approach to improve the cycling stability of the conversion electrodes through chemical interaction12Recent Advances in Heterostructured Anode Materials with Multiple Anions for Advanced Alkali‐Ion Batteries99Hierarchical goethite nanoparticle and tin dioxide quantum dot anchored on reduced graphene oxide for long life and high rate lithium-ion storage11Frontiers in Hybrid Ion Capacitors: A Review on Advanced Materials and Emerging Devices107From binary to multinary copper based nitrides – Unlocking the potential of new applications42In Situ Synchrotron X‐Ray Absorption Spectroscopy Studies of Anode Materials for Rechargeable Batteries47Electrochemical grinding-induced metallic assembly exploiting a facile conversion reaction route of metal oxides toward Li ions20Improving the electrochemical performances of organo-palladium (II) complex as promising anode material for Li-ion batteries: Effect of double emulsion preparation2Engineering of yolk-shelled FeSe2@nitrogen-doped carbon as advanced cathode for potassium-ion batteries23A Review on the Current Progress and Challenges of 2D Layered Transition Metal Dichalcogenides as Li/Na‐ion Battery Anodes70The effect of hydrogen induced point defects on lithiation kinetics in manganese niobate anode10Crosslinked polyacrylonitrile precursor for S@pPAN composite cathode materials for rechargeable lithium batteries25Influence of Iron Sulfide Nanoparticle Sizes in Solid‐State Batteries**45Influence of Iron Sulfide Nanoparticle Sizes in Solid‐State Batteries**13Iron Phosphide Confined in Carbon Nanofibers as a Free-Standing Flexible Anode for High-Performance Lithium-Ion Batteries38Multiple anionic Ni(SO4)0.3(OH)1.4 nanobelts/reduced graphene oxide enabled by enhanced multielectron reactions with superior lithium storage capacity14

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  1. Porous Fe3O4Nanospheres as Effective Sulfur Hosts for Li-S Batteries

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  2. CuS Microspheres with Tunable Interlayer Space and Micropore as a High‐Rate and Long‐Life Anode for Sodium‐Ion Batteries

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  3. Remedies of capacity fading in room-temperature sodium-sulfur batteries

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  4. Conversion reaction of vanadium sulfide electrode in the lithium-ion cell: Reversible or not reversible?

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  5. Morphology-dependent electrochemical performance of spinel-cobalt oxide nanomaterials towards lithium-ion batteries

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  6. Strongly Surface‐Bonded MoO2@Carbon Nanocomposites by Nitrogen‐Doping with Outstanding Capability for Fast and Stable Li Storage

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  7. 3-Dimensional hierarchically porous ZnFe2O4/C composites with stable performance as anode materials for Li-ion batteries

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  8. Nanostructured Conversion‐Type Negative Electrode Materials for Low‐Cost and High‐Performance Sodium‐Ion Batteries

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  9. Understanding the electrochemical reaction mechanism of VS 2 nanosheets in lithium-ion cells by multiple in situ and ex situ x-ray spectroscopy

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  10. Recent progress in metal–organic frameworks for lithium–sulfur batteries

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  12. Recent advances of polar transition-metal sulfides host materials for advanced lithium–sulfur batteries

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  13. Atomic Structure of 2 nm Size Metallic Cobalt Prepared by Electrochemical Conversion: An in Situ Pair Distribution Function Study

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  14. Study on Electrochemical Processes of NiO Model Electrode during the First Lithiation/delithiation Cycle via Electrochemical Impedance Spectroscopy

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  15. Revisiting Conversion Reaction Mechanisms in Lithium Batteries: Lithiation-Driven Topotactic Transformation in FeF 2

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  16. K+ storage in porous red blood cell-like hollow carbon

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  17. Construction of carbon-coated nickel phosphide nanoparticle assembled submicrospheres with enhanced electrochemical properties for lithium/sodium-ion batteries

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  18. Multifunctional porous VN nanowires interlayer as polysulfides barrier for high performance lithium sulfur batteries

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  19. Enhanced electrochemical properties of Mn3O4/graphene nanocomposite as efficient anode material for lithium ion batteries

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  20. Antimony‐Doped Lithium Phosphate Artificial Solid Electrolyte Interphase for Dendrite‐Free Lithium‐Metal Batteries

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  21. 2D few-layer iron phosphosulfide: a self-buffer heterophase structure induced by irreversible breakage of P–S bonds for high-performance lithium/sodium storage

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  22. Binder-free C@NiCo 2 O 4 on Ni foam with ultra-stable pseudocapacitive lithium ion storage

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  23. In-situ sulfuration synthesis of N,S-doped carbon nanosheet encapsulated Fe-doped Co9S8 as anodes for tunable lithium storage

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  33. Pseudocapacitive P-doped NiCo2O4 microspheres as stable anode for lithium ion batteries

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  35. Current Li-Ion Battery Technologies in Electric Vehicles and Opportunities for Advancements

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  36. A novel Li3P-VP nanocomposite fabricated by pulsed laser deposition as anode material for high-capacity lithium ion batteries

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  37. Interphases in Electroactive Suspension Systems: Where Chemistry Meets Mesoscale Physics

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  38. Facile synthesis of Mn2.1V0.9O4/rGO: A novel high-rate anode material for lithium-ion batteries

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  39. Recent Advances and Perspectives of Carbon-Based Nanostructures as Anode Materials for Li-ion Batteries

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  40. Multi-electron transfer enabled by topotactic reaction in magnetite

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  41. Oxyvanite V 3 O 5 : A new intercalation‐type anode for lithium‐ion battery

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  43. Hetero-layered MoS2/C composites enabling ultrafast and durable Na storage

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  44. Pulsed Laser Deposited Films for Microbatteries

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  45. Operando X-ray absorption spectroscopy applied to battery materials at ICGM: The challenging case of BiSb's sodiation

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  46. Energy-Dispersive X-ray Diffraction: Operando Visualization of Electrochemical Activity of Thick Electrodes

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  47. Porous carbon encapsulated Mn3O4 for stable lithium storage and its ex-situ XPS study

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  48. Rapid Assemble of MnC2O4 Microtubes Using a Microchannel Reactor and Their Use as an Anode Material for Lithium-ion Batteries

    Electrochimica Acta · 2019-08-12

    Yang Yang, Liang Ming He, Jianfang Lü, Ziying Liu, Ningying Wang, Jing Su, Yunfei Long, Xiaoyan Lv, Yanxuan Wen

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  49. Li-free Cathode Materials for High Energy Density Lithium Batteries

    Joule · 2019-08-14

    Liping Wang, Zhenrui Wu, Jian Zou, Peng Dong Gao, Xiaobin Niu, Hong Li, Liquan Chen

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  50. Constructing enhanced pseudocapacitive Li+ intercalation via multiple ionically bonded interfaces toward advanced lithium storage

    Energy storage materials · 2019-08-30

    Zhikang Liu, Jing Huang, Bin Liu, Dong Fang, Tao Wang, Quanling Yang, Lijie Dong, Guo‐Hua Hu, Chuanxi Xiong

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