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RESEARCH PAPER · Journal of the American Chemical Society · 2017

Ferroelectric Polarization and Second Harmonic Generation in Supramolecular Cocrystals with Two Axes of Charge-Transfer

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Ferroelectric Polarization and Second Harmonic Generation in Supramolecular Cocrystals with Two Axes of Charge-TransferOriginalTayi et al. reply3A high temperature reversible phase transition in a supramolecular complex of 15-crown-5 with tetraphenylboron sodium7An organometallic half-sandwich supramolecular complex {K(18-Crown-6)(η n -C 6 H 5 B(C 6 H 5 ) 3 )} ( n = 1–6) exhibiting a reversible breaking-symmetry phase transition and switchable dielectric behaviour7Analysis of charge transfer transitions in stacked π-electron donor–acceptor complexes23Reversible phase transition and switchable dielectric behaviors triggered by rotation and order-disorder motions of crowns43Impact of C–H···X (X = F, N) and π–π Interactions on Tuning the Degree of Charge Transfer in F6TNAP-Based Organic Binary Compound Single Crystals47Organic 2D Optoelectronic Crystals: Charge Transport, Emerging Functions, and Their Design Perspective214A Flexible Composite Mechanical Energy Harvester from a Ferroelectric Organoamino Phosphonium Salt37A Flexible Composite Mechanical Energy Harvester from a Ferroelectric Organoamino Phosphonium Salt16Chiral to Chiral Phase Transition in a Novel Hydrogen Bond Type Molecular Ferroelectric7Ferroelectric Property, Switchable Dielectric, and Excellent Second Harmonic Generation Response in a Homochiral Organic Salt: l -Prolinammonium 1-Adamantane Carboxylate13Exploring the Relationship between Intermolecular Interactions and Solid-State Photophysical Properties of Organic Co-Crystals39Hydrogen-bonded organo-amino phosphonium halides: dielectric, piezoelectric and possible ferroelectric properties12Unravelling substitution effects on charge transfer characteristics in cocrystals of pyrene based donors and 3,5-dinitrobenzoic acid18Throwing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline One-Dimensional (1D) Columnar Rotor Array43The quest for electronic ferroelectricity in organic charge-transfer crystals0Characterization of Charge Transfer in Excited States of Extended Clusters of π-Stacked Donor and Acceptor Complexes in Lock-Arm Supramolecular Ordering9Nanoscale Effects in One‐Dimensional Columnar Supramolecular Ferroelectrics32Cocrystal Engineering: A Collaborative Strategy toward Functional Materials446All-Organic Composites of Ferro- and Piezoelectric Phosphonium Salts for Mechanical Energy Harvesting Application54Interplay between Hydrogen and Halogen Bonding in Cocrystals of Dipyridinylmethyl Oxalamides and Tetrafluorodiiodobenzenes14A Highly Stabilized Phosphonium Ylide that Forms Supramolecular Dimers in Solution and the Solid State8Quantitative analysis of intermolecular interactions in cocrystals and a pair of polymorphous cocrystal hydrates from 1,4-dihydroquinoxaline-2,3-dione and 1 H -benzo[ d ]imidazol-2(3 H )-one with 2,5-dihydroxy-1,4-benzoquinones: a combined X-ray structural and theoretical analysis12Structure of Imidazolium-N-phthalolylglycinate Salt Hydrate: Combined Experimental and Quantum Chemical Calculations Studies1Supramolecular Energy Materials181Nonadiabatic Dynamics of Charge-Transfer States Using the Anthracene–Tetracyanoethylene Complex as a Prototype21Tunable exciton binding energy in 2D hybrid layered perovskites through donor–acceptor interactions within the organic layer213Growth and THz generation in organic nonlinear optical crystal: N,N′ bis(4-nitrophenyl)-(1R,2R)-diaminocyclohexane (BNDC)7Butadiyne-Bridged (Porphinato)Zinc(II) Chromophores Assemble into Free-Standing Nanosheets6Quantum-Chemical Simulation of the Structure of Charge-Transfer Complexes of 9,10-Phenanthrenequinone Nitro-Derivatives with Phenanthrene. Crystal and Molecular Structure of 1 : 1 Complex of 2,4,7-Trinitro-9,10-phenanthrenequinone with Phenanthrene6Understanding Intermolecular Interactions in a Tetracene–F4TCNQ Cocrystal via Its Electron Density Distribution and Topology14Advancing Versatile Ferroelectric Materials Toward Biomedical Applications105Crystal Structure Landscape of a Triphenol: Polymorphism and Isostructurality in Solvates and Cocrystals, and Pentameric and Hexameric Aromatic Stacks12Soft Ferroelectrics Enabling High‐Performance Intelligent Photo Electronics81Effect of Noncovalent Interactions on the Intersystem Crossing Behavior in Charge-Transfer Cocrystals of 3,5-Dinitrobromobenzene14Attractive Organic Cocrystal Materials in Optics5CHARGE TRANSFER COMPLEXES OF NITRO DERIVATIVES OF 9,10-PHENANTHRENEQUINONE WITH ANTHRACENE. CRYSTAL AND MOLECULAR STRUCTURES OF THE (1:1) COMPLEX OF 2,4,7-TRINITRO-9,10-PHENANTHRENEQUINONE WITH ANTHRACENE5Polymorphism and Optoelectronic Properties in Crystalline Supramolecular Polymers27Creating Organic Functional Materials beyond Chemical Bond Synthesis by Organic Cocrystal Engineering233Stable room temperature ferroelectricity in hydrogen-bonded supramolecular assemblies of ambipolar π-systems25Chemical design of organic ferroelectrics using dynamics of alkylamide chains26Crystal engineering and structural diversity of 2-aminopyridinium hypodiphosphates obtained by crystallization and dehydration11Ferroelectricity in a hydrogen-bonded alternating donor–acceptor supramolecular copolymer12Ferroelectricity in organic materials: from materials characteristics to de novo design39Room temperature charge-transfer phosphorescence from organic donor–acceptor Co-crystals121Charge transfer and hydrogen bonding motifs in organic cocrystals derived from aromatic diamines and TCNB21Quantum-Chemical Simulation of Charge-Transfer Complexes of 2,4,7-Trinitro-9H-fluoren-9-one with Donor Molecules. Crystal and Molecular Structure of the 1 : 1 Complex of 2,4,7-Trinitro-9H-fluoren-9-one with Anthracene3A Hierarchical (Macro)molecular Assembly Assisted by Donor–Acceptor Charge‐Transfer Interactions Exhibiting Room‐Temperature Ferroelectricity3A Hierarchical (Macro)molecular Assembly Assisted by Donor–Acceptor Charge‐Transfer Interactions Exhibiting Room‐Temperature Ferroelectricity35Modulating Supramolecular Charge‐Transfer Interactions in the Solid State using Compressible Macrocyclic Hosts51Modulating Supramolecular Charge‐Transfer Interactions in the Solid State using Compressible Macrocyclic Hosts7Energy‐Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal1Energy‐Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal26Metallurgical alloy approach to two-dimensional supramolecular materials22QUANTUM CHEMICAL SIMULATION OF 2,4,7-TRINITRO-9H-FLUORENE-9-ONE CHARGE-TRANSFER COMPLEXES WITH NONLINEAR POLYCYCLIC AROMATIC HYDROCARBONS. CRYSTAL AND MOLECULAR STRUCTURE OF THE (1:1) 2,4,7-TRINITRO-9H- FLUORENE-9-ONE COMPLEX WITH PHENANTHRENE3A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator21A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator5A folded π-system with supramolecularly oriented dipoles: single-component piezoelectric relaxor with NLO activity16Revisiting organic charge-transfer cocrystals for wide-range tunable, ambient phosphorescence55Macrocycle‐Based Crystalline Supramolecular Assemblies Built with Intermolecular Charge‐Transfer Interactions106Macrocycle‐Based Crystalline Supramolecular Assemblies Built with Intermolecular Charge‐Transfer Interactions25Symmetry‐Broken Intermolecular Charge Separation of Cationic Radicals29Symmetry‐Broken Intermolecular Charge Separation of Cationic Radicals3Syntheses, Structures, and Magnetic Properties of Novel [3×1 + 2×1] Pentanuclear Zinc(II)-Lanthanide(III) Cocrystal Complexes: Slow Magnetic Relaxation Behavior of the Dy(III) Analogue12Multifunctional Triggering by Solid-Phase Molecular Motion: Relaxor Ferroelectricity, Modulation of Magnetic Exchange Interactions, and Enhancement of Negative Thermal Expansion17Pronounced Chirality Effect on the Ferroelectricity of Hydrogen-Bonded Supramolecular Assemblies of Ambipolar Chromophoric Systems6Unleashing Ambient Triplet Harvesting Pathways in Arylene Diimides via Modular, Noncovalent Charge Transfer Interactions52Development of a scalar-based geometric parameterization approach for the crystal structure landscape of dithienylethene-based crystalline solids4Crown‐Ether‐Ring Size Dependent Crystal Structures, Phase Transition and Dielectric Properties of [M(crown)]BF4⋅xH2O (M+=Na+, K+; crown=15‐crown‐5, 18‐crown‐6; x=0 or 1)3Grinding-induced supramolecular charge-transfer assemblies with switchable vapochromism toward haloalkane isomers60Supramolecular Organic Ferroelectric Materials from Donor–Acceptor Systems25Comprehensively understanding the distinct properties of crystal structure, phase transition and dielectrics in [M(crown) n ]ReO 4 (M + = Na + , K + , NH 4 + ; crown = 15-crown-5, 18-crown-6; n = 1 or 2)4Supramolecular-macrocycle-based functional organic cocrystals54The past 10 years of molecular ferroelectrics: structures, design, and properties173Polar Organic Charge-Transfer Complex of the Asymmetrical Component for Flexible Piezoelectric Energy Harvesting and Self-Powered Wearable Sensors21Optical Second Harmonic Generation on Ferroelectric Polarization Reversal for Ferroelectric Hf0.5Zr0.5O2 Capacitors3New frontiers in supramolecular design of materials8Ternary Cocrystal with Long‐Lived Charge‐Transfer State for Efficient Light Conversion Applications11Organic cocrystals: From high‐performance molecular materials to multi‐functional applications74Flexible Piezoelectric-Coupling Organic Transistor-Based Press Sensors with Ferroelectric Charge-Transfer Complex Integrated Dielectrics8Peptide programming of supramolecular vinylidene fluoride ferroelectric phases52Individual domain characteristics determined by second-harmonic generation diffractometer for multi-domain multiferroics2Vapochromic materials based on pillar[n]arenes17A ferroelectric helical polymer3Supramolecular Organic Frameworks Based on Cyclic Aromatic Imides Tethered to Carboxylic Acid Hosts and Aromatic N-Heterocyclic Solvent Guests5Synthesis, Structural Characterization, Hirshfeld Surface Analysis, and Evaluation of Nonlinear Optical Properties of Novel Cocrystal of Acridine with 2,4-Dihydroxybenzaldehyde4Geminiarene‐Based Charge‐Transfer Cocrystals with Dichromatic Variants and Stimuli‐Responsive Structural Interconversion2Geminiarene‐Based Charge‐Transfer Cocrystals with Dichromatic Variants and Stimuli‐Responsive Structural Interconversion26Recent Progress in Organic Cocrystal‐Based Superlattices and Their Optoelectronic Applications30Lattice arrangement induced the transition from bipolar to n -type enhancing the spin polarization and the magnetic field dependent dipole effect in organic crystals1Turning on the Heat by Cocrystal Engineering: The Rise of Organic Charge Transfer Photothermal Cocrystals as an Emerging Therapeutic Frontier in Biomedical Application14Organic cocrystals in the NIR window: functional design, controlled synthesis and frontier applications4Adaptive Co‐Crystals with Switchable Host‐Guest Stoichiometry for Dynamic Regulation of Photoluminescence15A multifunctional organic charge-transfer cocrystal for effective photothermal seawater desalination and electrocatalytic nitrate reduction0Peptide‐Induced Ferroelectricity in Charge‐Transfer Supramolecular Materials3A Tale of Two Folds: Multiorthogonal Interactions Driven Hierarchical Assembly of a Polymer with an Appended Donor–Acceptor Dyad and Prominent Piezoelectricity1Controlled Self-Assembly of Clamparene-Based Cocrystals for Tunable Supramolecular Architectures and Their Application in Photothermal Conversion3Organic donor-acceptor cocrystal ferroelectrics: advances and perspectives0Donor‐Acceptor Stacks in Flexible Porous Coordination Polymers Toward Room‐Temperature Ferroelectricity0Donor‐Acceptor Stacks in Flexible Porous Coordination Polymers Toward Room‐Temperature Ferroelectricity0Quantum coherent beating in polar disubphthalocyanine-fullerene cocrystals for ultrafast photothermal conversion1Macrocycle‐Based Charge‐Transfer Cocrystals: From Host–Guest Recognition to Multifunctional Solid‐State Materials0Multi‐Field Coupling in Organic Charge Transfer Cocrystals: Rational Design and Emerging Opto‐Electro‐Magnetic Functions0

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  1. Tayi et al. reply

    Nature · 2017-07-01

    Alok S. Tayi, Alexander K. Shveyd, Andrew C.‐H. Sue, Jodi M. Szarko, Brian S. Rolczynski, Dennis Cao, T. Jackson Kennedy, Amy A. Narducci Sarjeant, Charlotte L. Stern, Walter F. Paxton, Wei Wu, Sanjeev K. Dey, Albert C. Fahrenbach, Jeffrey R. Guest, Hooman Mohseni, Lin X. Chen, Kang L. Wang, James Fraser Stoddart, Samuel Isaac Stupp

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  2. A high temperature reversible phase transition in a supramolecular complex of 15-crown-5 with tetraphenylboron sodium

    New Journal of Chemistry · 2018-01-01

    Guo‐Jun Yuan, Shao-Xian Liu, Zhengfang Tian, Xiao‐Ming Ren

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  3. An organometallic half-sandwich supramolecular complex {K(18-Crown-6)(η n -C 6 H 5 B(C 6 H 5 ) 3 )} ( n = 1–6) exhibiting a reversible breaking-symmetry phase transition and switchable dielectric behaviour

    Dalton Transactions · 2018-01-01

    Guo‐Jun Yuan, Dong-Sheng Shao, Zhi-Yuan Yao, Wenlong Liu, Xiao‐Ming Ren

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  4. Analysis of charge transfer transitions in stacked π-electron donor–acceptor complexes

    Physical Chemistry Chemical Physics · 2018-01-01

    Zhong‐hua Cui, Adélia J. A. Aquino, Andrew C.‐H. Sue, Hans Lischka

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  5. Reversible phase transition and switchable dielectric behaviors triggered by rotation and order-disorder motions of crowns

    Dalton Transactions · 2018-01-01

    Yi Liu, Haitao Zhou, Shaopeng Chen, Yu‐Hui Tan, Changfeng Wang, Chang‐Shan Yang, He‐Rui Wen, Yun‐Zhi Tang

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  6. Impact of C–H···X (X = F, N) and π–π Interactions on Tuning the Degree of Charge Transfer in F6TNAP-Based Organic Binary Compound Single Crystals

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    Peng Hu, Shancheng Wang, Apoorva Chaturvedi, Fengxia Wei, Xiaoting Zhu, Xiaotao Zhang, Rongjin Li, Yongxin Li, Hui Jiang, Yi Long, Christian Kloc

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  7. Organic 2D Optoelectronic Crystals: Charge Transport, Emerging Functions, and Their Design Perspective

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    Sang Kyu Park, Jin Hong Kim, Soo Young Park

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  8. A Flexible Composite Mechanical Energy Harvester from a Ferroelectric Organoamino Phosphonium Salt

    Angewandte Chemie International Edition · 2018-05-31

    Thangavel Vijayakanth, Anant Kumar Srivastava, Farsa Ram, Priyangi Kulkarni, Kadhiravan Shanmuganathan, Balu Praveenkumar, Ramamoorthy Boomishankar

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  9. A Flexible Composite Mechanical Energy Harvester from a Ferroelectric Organoamino Phosphonium Salt

    Angewandte Chemie · 2018-05-31

    Thangavel Vijayakanth, Anant Kumar Srivastava, Farsa Ram, Priyangi Kulkarni, Kadhiravan Shanmuganathan, Balu Praveenkumar, Ramamoorthy Boomishankar

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  10. Chiral to Chiral Phase Transition in a Novel Hydrogen Bond Type Molecular Ferroelectric

    ChemistrySelect · 2018-07-26

    Chang‐Shan Yang, Yu‐Hui Tan, Changfeng Wang, Shaopeng Chen, He‐Rui Wen, Yun‐Zhi Tang

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  11. Ferroelectric Property, Switchable Dielectric, and Excellent Second Harmonic Generation Response in a Homochiral Organic Salt: l -Prolinammonium 1-Adamantane Carboxylate

    Crystal Growth & Design · 2018-09-14

    Shaopeng Chen, Changfeng Wang, Haitao Zhou, Yu‐Hui Tan, He‐Rui Wen, Yun‐Zhi Tang

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  12. Exploring the Relationship between Intermolecular Interactions and Solid-State Photophysical Properties of Organic Co-Crystals

    The Journal of Physical Chemistry C · 2018-12-14

    Rohit Bhowal, Suprakash Biswas, Athulbabu Thumbarathil, Apurba Lal Koner, Deepak Chopra

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  13. Hydrogen-bonded organo-amino phosphonium halides: dielectric, piezoelectric and possible ferroelectric properties

    Dalton Transactions · 2019-01-01

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  14. Unravelling substitution effects on charge transfer characteristics in cocrystals of pyrene based donors and 3,5-dinitrobenzoic acid

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  15. Throwing in a Monkey Wrench to Test and Determine Geared Motion in the Dynamics of a Crystalline One-Dimensional (1D) Columnar Rotor Array

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  16. The quest for electronic ferroelectricity in organic charge-transfer crystals

    arXiv (Cornell University) · 2019-04-16

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  17. Characterization of Charge Transfer in Excited States of Extended Clusters of π-Stacked Donor and Acceptor Complexes in Lock-Arm Supramolecular Ordering

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  18. Nanoscale Effects in One‐Dimensional Columnar Supramolecular Ferroelectrics

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  19. Cocrystal Engineering: A Collaborative Strategy toward Functional Materials

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  20. All-Organic Composites of Ferro- and Piezoelectric Phosphonium Salts for Mechanical Energy Harvesting Application

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  21. Interplay between Hydrogen and Halogen Bonding in Cocrystals of Dipyridinylmethyl Oxalamides and Tetrafluorodiiodobenzenes

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  22. A Highly Stabilized Phosphonium Ylide that Forms Supramolecular Dimers in Solution and the Solid State

    Chemistry - A European Journal · 2019-10-14

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  23. Quantitative analysis of intermolecular interactions in cocrystals and a pair of polymorphous cocrystal hydrates from 1,4-dihydroquinoxaline-2,3-dione and 1 H -benzo[ d ]imidazol-2(3 H )-one with 2,5-dihydroxy-1,4-benzoquinones: a combined X-ray structural and theoretical analysis

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  24. Structure of Imidazolium-N-phthalolylglycinate Salt Hydrate: Combined Experimental and Quantum Chemical Calculations Studies

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  25. Supramolecular Energy Materials

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  26. Nonadiabatic Dynamics of Charge-Transfer States Using the Anthracene–Tetracyanoethylene Complex as a Prototype

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  27. Tunable exciton binding energy in 2D hybrid layered perovskites through donor–acceptor interactions within the organic layer

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  28. Growth and THz generation in organic nonlinear optical crystal: N,N′ bis(4-nitrophenyl)-(1R,2R)-diaminocyclohexane (BNDC)

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  29. Butadiyne-Bridged (Porphinato)Zinc(II) Chromophores Assemble into Free-Standing Nanosheets

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  30. Quantum-Chemical Simulation of the Structure of Charge-Transfer Complexes of 9,10-Phenanthrenequinone Nitro-Derivatives with Phenanthrene. Crystal and Molecular Structure of 1 : 1 Complex of 2,4,7-Trinitro-9,10-phenanthrenequinone with Phenanthrene

    Russian Journal of General Chemistry · 2020-10-01

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  31. Understanding Intermolecular Interactions in a Tetracene–F4TCNQ Cocrystal via Its Electron Density Distribution and Topology

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  32. Advancing Versatile Ferroelectric Materials Toward Biomedical Applications

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  33. Crystal Structure Landscape of a Triphenol: Polymorphism and Isostructurality in Solvates and Cocrystals, and Pentameric and Hexameric Aromatic Stacks

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  34. Soft Ferroelectrics Enabling High‐Performance Intelligent Photo Electronics

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  35. Effect of Noncovalent Interactions on the Intersystem Crossing Behavior in Charge-Transfer Cocrystals of 3,5-Dinitrobromobenzene

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  36. Attractive Organic Cocrystal Materials in Optics

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  37. CHARGE TRANSFER COMPLEXES OF NITRO DERIVATIVES OF 9,10-PHENANTHRENEQUINONE WITH ANTHRACENE. CRYSTAL AND MOLECULAR STRUCTURES OF THE (1:1) COMPLEX OF 2,4,7-TRINITRO-9,10-PHENANTHRENEQUINONE WITH ANTHRACENE

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  38. Polymorphism and Optoelectronic Properties in Crystalline Supramolecular Polymers

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  39. Creating Organic Functional Materials beyond Chemical Bond Synthesis by Organic Cocrystal Engineering

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  40. Stable room temperature ferroelectricity in hydrogen-bonded supramolecular assemblies of ambipolar π-systems

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  41. Chemical design of organic ferroelectrics using dynamics of alkylamide chains

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  42. Crystal engineering and structural diversity of 2-aminopyridinium hypodiphosphates obtained by crystallization and dehydration

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  43. Ferroelectricity in a hydrogen-bonded alternating donor–acceptor supramolecular copolymer

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  44. Ferroelectricity in organic materials: from materials characteristics to de novo design

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  45. Room temperature charge-transfer phosphorescence from organic donor–acceptor Co-crystals

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  46. Charge transfer and hydrogen bonding motifs in organic cocrystals derived from aromatic diamines and TCNB

    Journal of Molecular Structure · 2022-01-06

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  47. Quantum-Chemical Simulation of Charge-Transfer Complexes of 2,4,7-Trinitro-9H-fluoren-9-one with Donor Molecules. Crystal and Molecular Structure of the 1 : 1 Complex of 2,4,7-Trinitro-9H-fluoren-9-one with Anthracene

    Russian Journal of General Chemistry · 2022-02-01

    Р. В. Линко, M. A. Ryabov, П. В. Страшнов, В. В. Давыдов, Павел В. Дороватовский, Natalia Yu. Chernikova, Victor Nikolaevich Khrustalev

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  48. A Hierarchical (Macro)molecular Assembly Assisted by Donor–Acceptor Charge‐Transfer Interactions Exhibiting Room‐Temperature Ferroelectricity

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  49. A Hierarchical (Macro)molecular Assembly Assisted by Donor–Acceptor Charge‐Transfer Interactions Exhibiting Room‐Temperature Ferroelectricity

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  50. Modulating Supramolecular Charge‐Transfer Interactions in the Solid State using Compressible Macrocyclic Hosts

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