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RESEARCH PAPER · Ferroelectrics · 2017

A brief review on perovskite multiferroics

Hongbo Liu, Xue Yang

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A brief review on perovskite multiferroicsOriginalEffect of Nd Substitution on Properties of Multiferroic Bismuth Ferrite Synthesized by Sol-Gel Auto-combustion Method22Influence of Thickness on the Structural, Optical and Magnetic Properties of Bismuth Ferrite Thin Films14MgFe2O4phase effect on magnetic properties of BiFeO3in ceramic composites of (1-x) BiFeO3–xMgFe2O40Dielectrics under Electric Field4The Polar/Antipolar Phase Boundary of BiMnO3–BiFeO3–PbTiO3: Interplay among Crystal Structure, Point Defects, and Multiferroism19Low field manifestation of spiral ordering in sheet like BiFeO3 nanostructures8The role of B-site substitution on the structural and dielectric properties of samarium orthoferrite polycrystals4Strain Effect on Oxygen Evolution Reaction Activity of Epitaxial NdNiO 3 Thin Films92Crystal structure of LaSr3Fe3O9 and its phase relation with LaSr3Fe3O109Mott insulator behavior in the yttrium-based antimoniate oxide Ba2YSbO67Cation ordering, ferrimagnetism and ferroelectric relaxor behavior in Pb(Fe1−xScx)2∕3W1∕3O3 solid solutions6Room temperature ferrimagnetism in Yb-doped relaxor ferroelectric PbFe2/3W1/3O37Antiferroelectric Phase Transition in a Proton-Transfer Salt of Squaric Acid and 2,3-Dimethylpyrazine10Optical spectroscopy on the photo-response in multiferroic BiFeO3 at high pressure3Bi-doped suppression of antisite disordering and associated magnetic properties of La 2− x Bi x MnNiO 6 ( x = 0 and 1)7Influence of Addition of Nanoparticles of Magnetic Phase on Structural, Microstructural and Dielectric Properties of Multiferroic Composites1Squids, fits and other magnetic bits1High dielectric permittivity of BiFeO3–SrTiO3–CaTiO3 ternary solid solution ceramics31Formate-mediated magnetic superexchange in the model hybrid perovskite [(CH 3 ) 2 NH 2 ]Cu(HCOO) 317Interfacial strain driven magnetoelectric coupling in (111)-oriented self-assembled BiFeO 3 –CoFe 2 O 4 thin films13Analytical solution of spontaneous polarization based on a Landau-Devonshire eight-order potential0Crystal structure effect on the phase transition of (Ca0.28Ba0.72)x(Sr0.61Ba0.39)1−xNb2O6 ceramics9Organic Donor‐Acceptor Cocrystals for Multiferroic Applications30Effect of cobalt-doping on dielectric, magnetic and optical properties of BiFeO3 nanocrystals synthesized by sol – gel technique41Tunable ferrimagnetic-antiferromagnetic response by the inclusion of Fe in the gadolinium-based manganite GdMnO30Polar magnetic oxides from chemical ordering: A new class of multiferroics33Structural, Dielectric and Electrical investigation of Zirconium and Tin modified 0.5BFO-0.5BST5Spin dynamics, antiferrodistortion and magnetoelectric interaction in multiferroics. The case of BiFeO38Nanoporous Composites With Converse Magnetoelectric Effects for Energy-Efficient Applications3Hysteresis and Capacitive Features of Perovskite Solar Cells1Structural, dielectric, thermal and electrical characteristics of lead-free double perovskite: BiHoZnCeO625Structure of Pb(Fe2/3W1/3)O3 single crystals with partial cation order14Thermally stable dielectric properties of 0.5Na0.5Bi0.5TiO3–0.4SrTiO3–0.1BiFeO3 ceramics at high temperature0Peierls versus Holstein models for describing electron-phonon coupling in perovskites21Pbnm to R3-c phase transformation in (1-x)LaFeO3.xLaMnO3 solid solution due to modifications in structure, octahedral tilt and valence states of Fe-Mn1Coexistence of magnetic and electric orderings in a divalent Cr 2+ -based multiaxial molecular ferroelectric58Two-dimensional multiferroic FeCl with room temperature ferromagnetism and tunable magnetic anisotropy via ferroelectricity14Correlation between structural asymmetry and magnetization in Bi-doped LaFeO3 perovskite: a combined XRD and synchrotron radiation XAS study33Functional Perovskites: Structure-Properties Correlations3Hybrid organic-inorganic perovskites: a spin-off of oxidic perovskites6Thermally stable dielectric properties of 0.5Na0.5Bi0.5TiO3–0.4SrTiO3–0.1BiFeO3 ceramics at high temperature18Chemical Solution Deposition of La-Substituted BiFe0.5Sc0.5O3 Perovskite Thin Films on Different Substrates1Effect of B-Site Order–Disorder in the Structure and Magnetism of the New Perovskite Family La2MnB′O6 with B′ = Ti, Zr, and Hf13Tuning of electric and magnetic properties of BiFeO3-SrTiO3 solid solution ceramics by site-specific doping of Mn24Scrutinizing the stability and exploring the dependence of thermoelectric properties on band structure of 3d-3d metal-based double perovskites Ba2FeNiO6 and Ba2CoNiO671Ice Bath Assisted BiMn 2 O 5 (Mullite) Phase Synthesis, Structural and Compositional Analysis under Different Bi Concentration2Ferroelectric and magnetic domain mapping of magneto-dielectric Ce doped BiFeO3 thin films8Structural change from Pbnm to R3c phase with varying Fe/Mn content in (1-x) LaFeO3.xLaMnO3 solid solution leading to modifications in octahedral tilt and valence states27Low-energy spin dynamics in rare-earth perovskite oxides17Nanostructured perovskite oxides for dye-sensitized solar cells7Giant conventional and rotating magnetocaloric effects in TbScO3 single crystal18Pressure induced phase transitions in Sm-doped BiFeO3 in the morphotropic phase boundary19Nanostructured LaFeO3/Si thin films grown by pulsed laser deposition2Multiferroic Nanocrystals and Diluted Magnetic Semiconductors as a Base for Designing Magnetic Materials9Low-pressure air plasma induced modification of structural and electrical properties of Gd1−xSrxMnO3 manganites4Magnetoelectric heterostructures for next-generation MEMS magnetic field sensing applications59Ferromagnetic half-metallicity of the cubic NaMgO 3 perovskite: from bulk to (001) surfaces5Lattice Dynamics and Spin-Phonon Coupling in the Noncollinear Antiferromagnetic Antiperovskite Mn3nin0Studies on the structural and dielectric properties of chromium doped samarium ferrite0The Spontaneous Exchange Bias Effect in La2-Xcaxcomno6 Series0Effects of Mn doping on electrical properties of BiFeO3–SrTiO3 solid solution13Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics12Crystal Structure and Concentration-Driven Phase Transitions in Lu(1−x)ScxFeO3 (0 ≤ x ≤ 1) Prepared by the Sol–Gel Method19Multiferroic properties and magnetoelectric coupling observed in nanocrystalline HoFeO328Review—State of the Art of the Multifunctional Bismuth Ferrite: Synthesis Method and Applications18Ca Solubility in a BiFeO3-Based System with a Secondary Bi2O3 Phase on a Nanoscale7The spontaneous exchange bias effect in La 2 − x Ca x CoMnO6 series11Influence of γ Radiation on the Crystal Structure of BiFeO310Ferroelectric HfO2 and the importance of strain17Unprecedented Ferroelectricity and Ferromagnetism in a Cr 2+ ‐Based Two‐Dimensional Hybrid Perovskite9Unprecedented Ferroelectricity and Ferromagnetism in a Cr 2+ ‐Based Two‐Dimensional Hybrid Perovskite83Room-temperature multiferroic behaviour in Co/Fe co-substituted layer-structured Aurivillius phase ceramics24Ferromagnetic Ordering with High Curie Temperature in a New Pr2FeNiO6 Double Perovskite Material1Superconductivity in antiperovskites44Optical, ferroelectric, and magnetic properties of NiTiO3–CoFe2O4 composites prepared by one-step sol–gel method7Lattice dynamics and spin–phonon coupling in the noncollinear antiferromagnetic antiperovskite Mn 3 NiN18Progress of Perovskites as Electrodes for Symmetrical Solid Oxide Fuel Cells67Anomalous Hall conductivity control in Mn3NiN antiperovskite by epitaxial strain along the kagome plane25Electrical energy storage properties of AgNbO3-based antiferroelectric ceramics prepared without an oxygen atmosphere by using hydrothermally synthesized powders2Comprehensive analysis of novel cubic HgCrO 3 perovskite: a first principles, structural, thermodynamic, and magnetic properties study for spintronic applications23Evidence of half-metallicity at the BiFeO 3 (001) surface2BaTiO3/NixZn1−xFe2O4 (x = 0, 0.5, 1) Composites Synthesized by Thermal Decomposition: Magnetic, Dielectric and Ferroelectric Properties4La-Doped Alumina, Lanthanum Aluminate, Lanthanum Hexaaluminate, and Related Compounds: A Review Covering Synthesis, Structure, and Practical Importance26Effect of grain size and orthorhombic phase of La doped BiFeO3 on thermoelectric properties33Strong Ferromagnetic Manipulation of SrTiO3 from CO2‐Straining Effect on Electronic Structure Modulation17Incorporation of Co (x), Al (y) into Bi (0.99) Ba (0.1) Fe (1-x-y) O3 and its effect on the microstructural, magnetic, and dielectric properties2Influence of Bi3+ substitution on the structural and magnetic properties of Pr0.6Sr0.4MnO3 ceramics3First-principles calculations to investigate role of 4d electrons spin (Mo/Tc) in half metallic ferromagnetism, and thermoelectric characteristics of Rb2(Tc, Mo)X6 (X =Cl, Br)21Novel multiferroic nanoparticles Sm1−xHoxFeO3 as a heavy metal Cr6+ ion removal from water8Vibrational, mechanical, electronic and thermodynamic properties of rhenium-based perovskites XReO3(X = Li, Be) by an ab-initio computation30A review of cement-based materials as electroceramics55Strain-Induced Structural Phase Transitions in Epitaxial (001) BiCoO3 Films: A First-Principles Study2Quantum mechanical simulation of polarization switching in HfO2 crystals0Optimizing experimental parameters for orbital mapping1Impedance spectroscopic study of temperature and frequency dependent conduction behaviour of xBa(Zr0.2Ti0.8)O3-(1-x)(Ba0.7Ca0.3)TiO3 , x = 0.50, 0.55, 0.70, 0.85 ceramic13Temperature-driven magnetic and structural transitions in multiferroic Lu(1-)Sc FeO38First-principles calculations to investigate structural, elastic, thermodynamic, electronic, and optical properties of AgXCl3 (X = Fe, Co & Mn)15Thermoelectric properties of M 2 AgAlBr 6 (M = K, Rb, Cs) double perovskites: A first principles study8Quantum Mechanical Simulation of Polarization Switching in HfO2 Crystals2Rhenium substitution effects on the structural, morphological and magnetic properties of bismuth ferrite BiFe(1-x)RexO37Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Development and investigation of transition metal oxides having controllable ferroic properties0Enhanced photocatalytic hydrogen evolution from cation modified single perovskite niobates in the absence of noble metal cocatalysts1Exploring the Potential of Nitrogen-Based Anti-Perovskite Compounds for Solar Cells: A Theoretical Investigation of Their Structural and Optoelectronic Properties Using Density Functional Theory (Dft)"1Tuning the Physical Properties of Perovskite Multiferroic Nanoparticles for Green Energy Applications1In situ study on enhanced plastic deformability of Lanthanum-doped Bismuth ferrite processed by flash sintering6Cationic order-related magnetoresistivity and half-metallicity in bulk Pb2FeMoO6 grown by high pressure synthesis1State-of-art review on smart perovskites materials: properties and applications66First-principles study of ferroelectric, dielectric, and piezoelectric properties in the nitride perovskites CeBN3 ( B=Nb , Ta)13Phase Stability and Magnetic Properties of Compositionally Complex n = 2 Ruddlesden–Popper Perovskites9Sintering-induced multiferroicity in 0.93(Na0.5Bi0.5)TiO3–0.07BaTiO3 ceramics1Structural, optical and multiferroic properties of (1-x)BiFeO3-xNa0.5Bi0.5TiO3, x = 0.00, 0.05, 0.10 and 0.152Laser-enhanced magnetism in SmFeO 39Synergistic energy harvesting and humidity sensing with single electrode triboelectric nanogenerator38Structural, optical and electrical properties study of (Na0.5La0.5)CaTi2O6 for possible industrial applications10A comprehensive review of bismuth, lanthanum and strontium based double perovskites − Unravelling structural, magnetic, and dielectric properties11Structural, optical and multiferroic properties of (1−x)BiFeO3–(x)Pb(Fe2/3W1/3)O3 solid solution1Structural phase diagram for Sm-substituted BiFeO 3 multiferroics4The effect of manganese doping and calcination temperature on polarization, structural and magnetic properties of multiferroic LuFe(1-)Mn O3 system1Lead-Free Multiferroic Materials for Perovskite-Based Solar Cells: Recent Advancements and Future Insights0Perovskite Multiferroics as Energy Harvesters: Exploring the Multidimensional Properties for Energy Harvesting Applications0Quantum Criticality in the Sustainable Perovskite Multiferroic Materials0Spontaneous polarization, n-type half-metallicity, low lattice thermal conductivity, and high structure stabilities in F@O-doped PbTiO 30Interplay between the B -sites’ valence states and phonon dynamics in the Ca 3 B O ( B = Si, Ge, Sn, and Pb) antiperovskites2Investigating Magnetic, Magnetodielectric, and Structural Properties of Sc-Substituted Hexagonal LuFeO33Unveiling the multifunctional potential of K2YCuX6 (X=Cl,Br): Structural, mechanical and optical insights for renewable energy frontiers5Modulation of multiferroic properties of h-YMnO3 due to lattice distortion caused by Yb doping3Perovskite ABO 3 Multiferroics: Mechanisms, Advancements, and Challenges15Magnetic ground state of the new perovskite variant Ba3CoSn2O90GGA +U+ mBJ amended electronic structure, multiferroicity, and thermoelectric response in Bi@Pb-doped PbTiO 3 : Strain engineering0Magnetostriction as the origin of the magnetodielectric effect in La 2 CoMnO 64Overcoming the metamagnetic phase transition by epitaxial strain and its impact on magnetocaloric effect in Dy 2 NiMnO 6 thin films0Development of core–shell nanofibers in magnetoelectric sensors, fuel cells, and drug-delivery applications: a review5Magnetic Thin Films for Spintronics0A-site dependent metastable polar phases from polarization compatible octahedral rotations in perovskite AZrO3 (A = Ca, Sr)1Persistent structural distortion for anticipated improper ferroelectricity in ultrathin h-Lu 1− x Ca x MnO 3 films0Lattice distortion-induced modulation of antiferromagnetism and weak ferroelectricity in indium-doped YCrO30Improved dielectric response of SrAʺLiTeO6 double perovskites through Aʺ-site substitution0Quasi-two-dimensionality driven by Jahn-Teller distortion in the ferromagnetic insulator CsMnF 4 : Structural and magnetic insights from experiment and theory0Optical, and Electronic Properties of Ni-Doped BiFeO3 Nanoparticles0Pioneering computational insights into KZrS 3 and KZrSe 3 for future optoelectronics0Critical structural parameter determining magnetic phases in the F e 2 M o 3 O 8 altermagnet system0Study of Mn substitution on the structural distortion, vibrational, electronic and morphological properties of GdInO30Magnetic and Thermal Behavior of Hydrothermally Synthesized Bi0.2Ni0.8-yGdyFeO3 (y=0.2-0.8) Nanorods0Investigation of electronic and optical properties in bismuth/antimony co-doped methylammonium lead bromide1Relaxor study in high-entropy ferroelectrics and Vogel-Fulcher analysis of composition-dependent symmetry0

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  1. Effect of Nd Substitution on Properties of Multiferroic Bismuth Ferrite Synthesized by Sol-Gel Auto-combustion Method

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  3. MgFe2O4phase effect on magnetic properties of BiFeO3in ceramic composites of (1-x) BiFeO3–xMgFe2O4

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  4. Dielectrics under Electric Field

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  5. The Polar/Antipolar Phase Boundary of BiMnO3–BiFeO3–PbTiO3: Interplay among Crystal Structure, Point Defects, and Multiferroism

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  6. Low field manifestation of spiral ordering in sheet like BiFeO3 nanostructures

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  7. The role of B-site substitution on the structural and dielectric properties of samarium orthoferrite polycrystals

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  8. Strain Effect on Oxygen Evolution Reaction Activity of Epitaxial NdNiO 3 Thin Films

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  9. Crystal structure of LaSr3Fe3O9 and its phase relation with LaSr3Fe3O10

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  10. Mott insulator behavior in the yttrium-based antimoniate oxide Ba2YSbO6

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  11. Cation ordering, ferrimagnetism and ferroelectric relaxor behavior in Pb(Fe1−xScx)2∕3W1∕3O3 solid solutions

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  12. Room temperature ferrimagnetism in Yb-doped relaxor ferroelectric PbFe2/3W1/3O3

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  13. Antiferroelectric Phase Transition in a Proton-Transfer Salt of Squaric Acid and 2,3-Dimethylpyrazine

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  14. Optical spectroscopy on the photo-response in multiferroic BiFeO3 at high pressure

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  15. Bi-doped suppression of antisite disordering and associated magnetic properties of La 2− x Bi x MnNiO 6 ( x = 0 and 1)

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  16. Influence of Addition of Nanoparticles of Magnetic Phase on Structural, Microstructural and Dielectric Properties of Multiferroic Composites

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  17. Squids, fits and other magnetic bits

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  18. High dielectric permittivity of BiFeO3–SrTiO3–CaTiO3 ternary solid solution ceramics

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  19. Formate-mediated magnetic superexchange in the model hybrid perovskite [(CH 3 ) 2 NH 2 ]Cu(HCOO) 3

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  20. Interfacial strain driven magnetoelectric coupling in (111)-oriented self-assembled BiFeO 3 –CoFe 2 O 4 thin films

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  21. Analytical solution of spontaneous polarization based on a Landau-Devonshire eight-order potential

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  22. Crystal structure effect on the phase transition of (Ca0.28Ba0.72)x(Sr0.61Ba0.39)1−xNb2O6 ceramics

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  23. Organic Donor‐Acceptor Cocrystals for Multiferroic Applications

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  24. Effect of cobalt-doping on dielectric, magnetic and optical properties of BiFeO3 nanocrystals synthesized by sol – gel technique

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  25. Tunable ferrimagnetic-antiferromagnetic response by the inclusion of Fe in the gadolinium-based manganite GdMnO3

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  26. Polar magnetic oxides from chemical ordering: A new class of multiferroics

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  28. Spin dynamics, antiferrodistortion and magnetoelectric interaction in multiferroics. The case of BiFeO3

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  29. Nanoporous Composites With Converse Magnetoelectric Effects for Energy-Efficient Applications

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  30. Hysteresis and Capacitive Features of Perovskite Solar Cells

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  31. Structural, dielectric, thermal and electrical characteristics of lead-free double perovskite: BiHoZnCeO6

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  32. Structure of Pb(Fe2/3W1/3)O3 single crystals with partial cation order

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  33. Thermally stable dielectric properties of 0.5Na0.5Bi0.5TiO3–0.4SrTiO3–0.1BiFeO3 ceramics at high temperature

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  34. Peierls versus Holstein models for describing electron-phonon coupling in perovskites

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  35. Pbnm to R3-c phase transformation in (1-x)LaFeO3.xLaMnO3 solid solution due to modifications in structure, octahedral tilt and valence states of Fe-Mn

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  36. Coexistence of magnetic and electric orderings in a divalent Cr 2+ -based multiaxial molecular ferroelectric

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  37. Two-dimensional multiferroic FeCl with room temperature ferromagnetism and tunable magnetic anisotropy via ferroelectricity

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  38. Correlation between structural asymmetry and magnetization in Bi-doped LaFeO3 perovskite: a combined XRD and synchrotron radiation XAS study

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  39. Functional Perovskites: Structure-Properties Correlations

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  40. Hybrid organic-inorganic perovskites: a spin-off of oxidic perovskites

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  41. Thermally stable dielectric properties of 0.5Na0.5Bi0.5TiO3–0.4SrTiO3–0.1BiFeO3 ceramics at high temperature

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  42. Chemical Solution Deposition of La-Substituted BiFe0.5Sc0.5O3 Perovskite Thin Films on Different Substrates

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  43. Effect of B-Site Order–Disorder in the Structure and Magnetism of the New Perovskite Family La2MnB′O6 with B′ = Ti, Zr, and Hf

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  44. Tuning of electric and magnetic properties of BiFeO3-SrTiO3 solid solution ceramics by site-specific doping of Mn

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  45. Scrutinizing the stability and exploring the dependence of thermoelectric properties on band structure of 3d-3d metal-based double perovskites Ba2FeNiO6 and Ba2CoNiO6

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