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RESEARCH PAPER · Chemistry - A European Journal · 2017

Mechanistic Aspects in the Formation, Growth and Surface Functionalization of Metal Oxide Nanoparticles in Organic Solvents

Rupali Deshmukh, Markus Niederberger

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Mechanistic Aspects in the Formation, Growth and Surface Functionalization of Metal Oxide Nanoparticles in Organic SolventsOriginalMultiscale Nanoparticle Assembly: From Particulate Precise Manufacturing to Colloidal Processing73Colloidal Synthesis and Controlled 2D/3D Assemblies of Oxide Nanoparticles0Ultrasound-Assisted Synthesis of Nanostructured Oxide Materials9Ligand induced shape transformation of thorium dioxide nanocrystals20The Sol-Gel Method: Pathway to Ultrapure and Homogeneous Mixed Metal Oxide Nanoparticles41Epitaxial YBa 2 Cu 3 O 7− x nanocomposite films and coated conductors from Ba M O 3 ( M = Zr, Hf) colloidal solutions40Localized Surface Plasmon Resonance in Semiconductor Nanocrystals1014Ethers as Oxygen Donor and Carbon Source in Non‐hydrolytic Sol–Gel: One‐Pot, Atom‐Economic Synthesis of Mesoporous TiO2–Carbon Nanocomposites11Beyond the Compositional Threshold of Nanoparticle-Based Materials42Surfactant-Mediated Morphology and Photocatalytic Activity of α-Ag2WO4 Material87Cobalt-Assisted Morphology and Assembly Control of Co-Doped ZnO Nanoparticles40Design of Hollow Protein Nanoparticles with Modifiable Interior and Exterior Surfaces43Design of Hollow Protein Nanoparticles with Modifiable Interior and Exterior Surfaces2Microwave-assisted synthesis of colloidal ZnO nanocrystals and their utilization in improving polymer light emitting diodes efficiency28Following the Kinetics of Barium Titanate Nanocrystal Formation in Benzyl Alcohol Under Near‐Ambient Conditions1Polymer Nanocomposites With Decorated Metal Oxides46Role of aliphatic ligands and solvent composition in the solvothermal synthesis of iron oxide nanocrystals12Secondary Particle Formation during the Nonaqueous Synthesis of Metal Oxide Nanocrystals10Impact of the synthesis parameters on the microstructure of nano-structured LTO prepared by glycothermal routes and 7Li NMR structural investigations6Tuning Texture and Morphology of Mesoporous TiO2 by Non-Hydrolytic Sol-Gel Syntheses9Synthèse par chimie douce et étude structurale de nanocristaux d'oxydes métalliques0Effect of lithium and sodium ions on the size and morphology of ZnO nanoparticles synthesized by a glycerol–urea route18Acetic Anhydride as an Oxygen Donor in the Non‐Hydrolytic Sol–Gel Synthesis of Mesoporous TiO2 with High Electrochemical Lithium Storage Performances12One-step nonhydrolytic sol–gel synthesis of mesoporous TiO2 phosphonate hybrid materials8Decreasing Nanocrystal Structural Disorder by Ligand Exchange: An Experimental and Theoretical Analysis22Microwave-assisted synthesis of FexZn1−xO nanoparticles for use in MEH-PPV nanocomposites and their application in polymer light-emitting diodes8Phase Control in Hafnia: New Synthesis Approach and Convergence of Average and Local Structure Properties27Solvothermally-synthesized tin-doped indium oxide plasmonic nanocrystals spray-deposited onto glass as near-infrared electrochromic films23Precipitates shape up7A Comprehensive Review of Magnetic Nanomaterials Modern Day Theranostics297Exploiting the Condensation Reactions of Acetophenone to Engineer Carbon‐Encapsulated Nb2O5 Nanocrystals for High‐Performance Li and Na Energy Storage Systems65Developement of an "all-in-one" approach for the synthesis of silica-based hybrid materials0Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts132Synthèse sol-gel non hydrolytique de catalyseurs stables pour l’hydrogénation en phase aqueuse de substrats biosourcés0Designed single-phase ZrO 2 nanocrystals obtained by solvothermal syntheses21Heterometallic trinuclear oxo-centered clusters as single-source precursors for synthesis of stoichiometric monodisperse transition metal ferrite nanocrystals28Synthesizing 1D and 2D metal oxide nanostructures: using metal acetate complexes as building blocks7Solute Incorporation at Oxide–Oxide Interfaces Explains How Ternary Mixed‐Metal Oxide Nanocrystals Support Element‐Specific Anisotropic Growth3Formation of a Single‐Crystal Aluminum‐Based MOF Nanowire with Graphene Oxide Nanoscrolls as Structure‐Directing Agents51Formation of a Single‐Crystal Aluminum‐Based MOF Nanowire with Graphene Oxide Nanoscrolls as Structure‐Directing Agents3Nanosized Carbonate-Doped TiO2–x Mesocrystals for Visible-Light-Driven Photocatalytic Removal of Water Pollutants14Low-Temperature Molten Salt Synthesis for Ligand-Free Transition Metal Oxide Nanoparticles18Nanoparticle processing: Understanding and controlling aggregation946Crystallization in Confinement338Experimental Descriptors for the Synthesis of Multicationic Nickel Perovskite Nanoparticles for Oxygen Reduction9Water Formation in Non‐Hydrolytic Sol–Gel Routes: Selective Synthesis of Tetragonal and Monoclinic Mesoporous Zirconia as a Case Study9TinO2n−1 Suboxide Phases in TiO2/C Nanocomposites Engineered by Non-hydrolytic Sol–Gel with Enhanced Electrocatalytic Properties8Harnessing Composition of Iron Oxide Nanoparticle: Impact of Solvent-Mediated Ligand–Ligand Interaction and Competition between Oxidation and Growth Kinetics29Recent Advances in Zinc Oxide Nanostructures with Antimicrobial Activities182Atomically precise vanadium-oxide clusters65Co/Ni-polyoxotungstate photocatalysts as precursor materials for electrocatalytic water oxidation7Elucidating the role of precursors in synthesizing single crystalline lithium niobate nanomaterials: a study of effects of lithium precursors on nanoparticle quality9Formation and growth mechanism for niobium oxide nanoparticles: atomistic insight from in situ X-ray total scattering23Magnetic nanoparticles: synthesis and characterization8Physicochemical implications of surface alkylation of high-valent, Lindqvist-type polyoxovanadate-alkoxide clusters13Ultrasound-Assisted Synthesis of Nanostructured Oxide Materials1Porous Silica Microspheres with Immobilized Titania Nanoparticles for In‐Flow Solar‐Driven Purification of Wastewater49The forgotten chemistry of group(IV) metals: A survey on the synthesis, structure, and properties of discrete Zr(IV), Hf(IV), and Ti(IV) oxo clusters91Scalable Synthesis of Ultrasmall Metal Oxide Radio-Enhancers Outperforming Gold22Role of Alcohols in Colloidal Nanoparticle Synthesis1Colloidal Nanocrystals: A Toolbox for Materials Chemistry5Insight into the effect of green methanol functionalization of Vulcan on the catalytic activity Pt1Sn1 alloy for the Ethanol Oxidation Reaction in acid and alkaline media2Aspects of high-performance and bio-acceptable magnetic nanoparticles for biomedical application93Fast Microwave Synthesis of Phase-Pure Ni2FeS4 Thiospinel Nanosheets for Application in Electrochemical CO2 Reduction16Optical spectroscopy methods for the characterization of sol–gel materials11Magnetic properties and structural analysis on spinel MnFe2O4 nanoparticles prepared via non‐aqueous microwave synthesis38Anatase Nanocrystals Covalently Functionalized with EDTA-diol: Interaction with Aromatic Sulfur1Microstructure, composition and magnetic properties of Nd-(Fe1-xCox)-B oxide magnetic particles synthesized by Pechini-type chemical method7Tailored routes to metal-containing nanoparticles for hydrogenation reactions in solution : surface design for H2 activation0Engineering chemical pathways for phase-tuned nanocrystalline iron oxides in microwave-assisted solvothermal synthesis2New frontiers for heterogeneous catalysis1Photoelectrochemical glycerol oxidation on Mo-BiVO 4 photoanodes shows high photocharging current density and enhanced H 2 evolution22Potential of Metal Oxide Nanoparticles and Nanocomposites as Antibiofilm Agents: Leverages and Limitations7Self-boosting non-hydrolytic synthesis of Cl-passivated SnO2 nanocrystals for universal electron transport material of next-generation solar cells13Addressing Complex Transition Metal Oxides at the Nanoscale: Bottom‐Up Syntheses of Nano‐objects and Properties3Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals83Non-Aqueous One-Pot SnO2 Nanoparticle Inks and Their Use in Printable Perovskite Solar Cells20Solvothermal synthesis of zirconia nanomaterials: Latest developments and future45Manganese ferrite (MnFe2O4) nanostructures for cancer theranostics247Valence State-Controlled Synthesis of Vanadium Oxide Nanocrystals3Deciphering the role of water and a zinc-doping process in a polyol-based approach for obtaining Zn/Co/Al-based spinels: toward “green” mesoporous inorganic pigments5Nanoparticle-Based Inorganic Aerogels5Ni 2 FeS 4 as a highly efficient earth-abundant co-catalyst in photocatalytic hydrogen evolution15The hinge morphology of SnO2 as multifunctional semiconductor: What we can learn from simulations, theory, and experiments14Precursor and Surface Reactivities Influence the Early Growth of Indium Oxide Nanocrystals in a Reagent-Driven, Continuous Addition Synthesis13Gelation Mechanism Revealed in Organometallic Gels: Prevalence of van der Waals Interactions on Oligomerization by Coordination Chemistry2Ex situ and in situ functionalized Yb/Fe nanoparticles obtained by scanning pulsed laser ablation in liquids: A route to obtain biofunctionalized multiplatform contrast agents for MRI and CT imaging6Molecular‐scale hybrid membranes: Metal‐oxo cluster crosslinked benzimidazole‐linked polymer membranes for superior H2 purification14Synthesis of Anisotropic Metal Oxide Nanoparticles via Non-Aqueous and Non-Hydrolytic Routes6Functionalized Nanomaterials, Classification, Properties, and Functionalization Techniques4TRACING THE EVOLUTION OF AI AND MACHINE LEARNING APPLICATIONS IN ADVANCING MATERIALS DISCOVERY AND PRODUCTION PROCESSES53Insights into the kinetics–morphology relationship of 1-, 2-, and 3D TiNb2O7 anodes for Li-ion storage17Medium‐ and High‐Entropy Spinel Ferrite Nanoparticles via Low‐Temperature Synthesis for the Oxygen Evolution Reaction42Single-Step Formation of Metal Oxide Nanostructures Wrapped in Mesoporous Silica and Silica–Niobia Catalysts for the Condensation of Furfural with Acetone4A Concise Review on Magnetic Nanoparticles: Their Properties, Types, Synthetic Methods, and Current Trending Applications7Bulky olefin epoxidation under mild conditions over Mo-based oxide catalysts9Complexation and disproportionation of group 4 metal (alkoxy) halides with phosphine oxides8Impacts of the reactants on the synthesis of ZnO particles in glycerol-based solvents2Selective optimisation of catalytic activity by tuning the structural composition in nanoparticulate CuFe 2 O 49From Gel to Crystal: Mechanism of HfO2 and ZrO2 Nanocrystal Synthesis in Benzyl Alcohol0Non-hydrolytic sol-gel synthesis of BaTiO3 nano-powder: Effect of calcination temperature and modified titanium source on particles18Optical Properties of Correlated Metallic V2O3 and Anosovite V3O5 Nanocrystals and Nanocrystal Films3On the Fate of Lithium Ions in Sol–Gel Derived Zinc Oxide Nanocrystals20From Gel to Crystal: Mechanism of HfO 2 and ZrO 2 Nanocrystal Synthesis in Benzyl Alcohol18Effect of synthetic conditions on the structure and magnetic properties of iron oxide nanoparticles in diethylene glycol medium3Functionalization of nanostructured surfaces: From the impact on morphological control during synthesis to the effect on colloidal dispersion8Synthesis pathways of (HfZrTiCe/La/Y)O2-x nanoparticles via benzyl alcohol route at critical temperature1CoMoO4 nano-architecture-based supercapacitors: Tunable properties, performance optimization, and prospective applications15Crystallization of 2D TiO2 Nanosheets via Oriented Attachment of 1D Coordination Polymer10Metal Nanoparticles for Simultaneous Use in AC Magnetic Field Hyperthermia and Magnetic Resonance Imaging2Interlaced NiCoO 2 nanoparticle/nanosheet films for electrochromic energy storage devices with wide-band optical modulation and robust stability4Mechanistic insights into solvent-guided growth and structure of MoO 2 nanoparticles in solvothermal synthesis5Revisiting the dissolution-recrystallization mechanism of rutile growth from protonated titanate nanotubes4Surfactant-Free Synthesis of Metal and Metal Oxide Nanomaterials: Sustainable and Eco-Synthesis Methods31 min synthesis of phase pure nanocrystalline high‐entropy sulfides for efficient water electrolysis31Chemical pathways to control morphology in microwave-assisted growth of iron oxide films and their thermodynamic validation0Green Liquid–Liquid Extraction for Environmental Chemicals0Metal Oxide Particles: Green Synthesis, In Situ Methodologies, and Industrial Case Studies0Formation, Phase Transition, Surface, and Catalytic Properties of Cubic ZrO 2 Nanocrystals11Minimal water content tailoring of ZrO 2 nanocrystals via nonaqueous sol–gel synthesis0Phytotoxicity of organic nanoparticles0Extrinsic Doping and Interface Engineering of Nonaqueous Tin Oxide Nanocrystals for Efficient Perovskite Solar Cells2Recent advances in the synthesis and applications of zinc oxide nanomaterials for healthcare energy and environmental systems8In situ surface modification of cerium oxide nanoparticles with catechol derivatives during supercritical hydrothermal synthesis0Synthesis of Sr-NiO and 4-aminobenzoic acid-functionalized Sr-NiO nanoparticles - A structural, optical and surface analysis0

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