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RESEARCH ARTICLE · Chemistry of Materials · 2016

Determination of Bulk and Surface Atomic Arrangement in Ni–Zn γ-Brass Phase at Different Ni to Zn Ratios

Charles S. Spanjers, Anish Dasgupta, Melanie Kirkham, Blake A. Burger, Gaurav Kumar, Michael John Janik, Robert M. Rioux

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Determination of Bulk and Surface Atomic Arrangement in Ni–Zn γ-Brass Phase at Different Ni to Zn RatiosOriginalIntermetallics in catalysis: An exciting subset of multimetallic catalysts110Generalized approach for the synthesis of silica supported Pd-Zn, Cu-Zn and Ni-Zn gamma brass phase nanoparticles18Formation of γ-brass type pseudo-binary Ni2Zn11-4δXδ (0≤δ≤~0.13) (X = In and Ga) by an exchange mechanism7Gamma-phase Zn-Ni alloy deposition by pulse-electroplating from a modified deep eutectic solution35γ-Brass type structures with I- and P-cell in the ternary Cu–Zn–In system2The role of three-dimensional bulk clusters in determining surface morphologies of intermetallic compounds: Quasicrystals to clathrates5A partly disordered 2 × 2 × 2 – superstructure of γ-brass related phase in Mn–Ni–Zn system5Biogas dry reforming using Ni–Al-LDH catalysts reconstructed with Mg and Zn50Structure and Spin-Glass Magnetism of the Mn x Ni 2 Zn 11– x Pseudobinary γ-Brasses at Low Mn Contents17Atomic Site Preference, Electronic Structures, and Magnetic Properties of Γ-Brass Type Pseudo-Binary Mn2zn11–Ni2zn11 at High Mn-Contents8Atomic control of active-site ensembles in ordered alloys to enhance hydrogenation selectivity143Structural and theoretical investigations on the “coloring” scheme of γ-brass type phase Ag5Cd88Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation42Concentration Influence of Complexing Agent on Electrodeposited Zn-Ni Alloy7Atomic distributions of Ag and In in the γ-brass type Ag9In46Understanding of magnetic behavior of the pseudo-binary Co 2− x Ni x Zn 11 : in the light of crystal and electronic structures3Site-specific substitution in the structure of Ni 2 Zn 11 by the coinage metals ( Cn = Ag and Au) to alter the magnetism1Structural chemistry of intermetallic compounds for active site design in heterogeneous catalysis23Determination of Site Occupancy in the M–Pd–Zn (M = Cu, Ag, and Au) γ-Brass Phase by CALculation of PHAse Diagrams Modeling and Rietveld Refinement2Chemical Disorder-Driven Cluster Spin Glass in Pseudobinary Co 2 Zn 10.2 Mn 0.8 : An Experimental and Theoretical Study5Post-Synthetic Transformation of High Entropy Alloy Nanoparticles into High-Entropy Intermetallics for Selective Acetylene Semi-Hydrogenation Catalysis19Solving the “Coloring Problem” in InPd 3– x Ag x ( x = 0–0.7) by Phase Diagrams Modeling and Diffraction Experiments2Understanding the Structure and Stability of a Partially Disordered “Push–Pull Alloy” Ni 2 Zn 11– x Ga x (0.4 ≤ x ≤ 1.25)0

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  1. Intermetallics in catalysis: An exciting subset of multimetallic catalysts

    Catalysis Today · 2018

    Anish Dasgupta, Robert M. Rioux

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  2. Generalized approach for the synthesis of silica supported Pd-Zn, Cu-Zn and Ni-Zn gamma brass phase nanoparticles

    Catalysis Today · 2018

    Anish Dasgupta, Eric K. Zimmerer, Randall J. Meyer, Robert M. Rioux

    Read original paper ↗ ·

  3. Formation of γ-brass type pseudo-binary Ni2Zn11-4δXδ (0≤δ≤~0.13) (X = In and Ga) by an exchange mechanism

    Journal of Solid State Chemistry · 2020

    Sivaprasad Ghanta, Rajat Kamboj, Nikhil George Mohan, Partha P. Jana

    Read original paper ↗ ·

  4. Gamma-phase Zn-Ni alloy deposition by pulse-electroplating from a modified deep eutectic solution

    Surface and Coatings Technology · 2020

    Chunhong Lei, Hasan Fisal Alesary, Farrah Khan, Andrew P. Abbott, Karl Scott Ryder

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  5. γ-Brass type structures with I- and P-cell in the ternary Cu–Zn–In system

    Zeitschrift für Kristallographie - Crystalline Materials · 2020

    Samiran Misra, Souvik Giri, Partha P. Jana

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  6. The role of three-dimensional bulk clusters in determining surface morphologies of intermetallic compounds: Quasicrystals to clathrates

    The Journal of Chemical Physics · 2021

    Émilie Gaudry, J. Ledieu, V. Fournée

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  7. A partly disordered 2 × 2 × 2 – superstructure of γ-brass related phase in Mn–Ni–Zn system

    Zeitschrift für Kristallographie - Crystalline Materials · 2021

    Sivaprasad Ghanta, Anustoop Das, Rajat Kamboj, Partha P. Jana

    Read original paper ↗ ·

  8. Biogas dry reforming using Ni–Al-LDH catalysts reconstructed with Mg and Zn

    International Journal of Hydrogen Energy · 2021

    Morgana Rosset, Liliana Amaral Féris, Oscar W. Perez‐Lopez

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  9. Structure and Spin-Glass Magnetism of the Mn x Ni 2 Zn 11– x Pseudobinary γ-Brasses at Low Mn Contents

    Inorganic Chemistry · 2021

    Sivaprasad Ghanta, Anustoop Das, Partha P. Jana, S. Vrtnik, Darja Gačnik, Jože Luzar, Andreja Jelen, Primoz Koželj, Magdalena Wencka, J. Dolinšek

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  10. Atomic Site Preference, Electronic Structures, and Magnetic Properties of Γ-Brass Type Pseudo-Binary Mn2zn11–Ni2zn11 at High Mn-Contents

    Journal of Alloys and Compounds · 2022

    Sivaprasad Ghanta, Amit Mondal, Anustoop Das, Riju Dey, Mayra D. Silva, Joyce Pham, Anup Kumar Bera, Bikash Chandra Saha, Seikh Mohammad Yusuf, J. Dolinšek, Partha P. Jana

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  11. Atomic control of active-site ensembles in ordered alloys to enhance hydrogenation selectivity

    Nature Chemistry · 2022

    Anish Dasgupta, Haoran He, Rushi Gong, Shun‐Li Shang, Eric K. Zimmerer, Randall J. Meyer, Zi‐Kui Liu, Michael John Janik, Robert M. Rioux

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  12. Structural and theoretical investigations on the “coloring” scheme of γ-brass type phase Ag5Cd8

    Journal of Solid State Chemistry · 2023

    Krishnendu Buxi, Amit Mondal, Fei Wang, Partha P. Jana

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  13. Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation

    Nature Catalysis · 2023

    Haoran He, Griffin A. Canning, Angela Nguyen, Anish Dasgupta, Randall J. Meyer, Robert M. Rioux, Michael John Janik

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  14. Concentration Influence of Complexing Agent on Electrodeposited Zn-Ni Alloy

    Applied Sciences · 2023

    Byung-Ki Son, Ji-Won Choi, Su-Byung Jeon, Injoon Son

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  15. Atomic distributions of Ag and In in the γ-brass type Ag9In4

    Journal of Solid State Chemistry · 2023

    Krishnendu Buxi, Sandip K. Kuila, Ahin Roy, Partha P. Jana

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  16. Understanding of magnetic behavior of the pseudo-binary Co 2− x Ni x Zn 11 : in the light of crystal and electronic structures

    Dalton Transactions · 2024

    Amit Mondal, Sandip K. Kuila, Rahul Pan, Shubham Patel, Krishnendu Buxi, Subhadip Saha, Sivaprasad Ghanta, Maxim Avdeev, Partha P. Jana

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  17. Site-specific substitution in the structure of Ni 2 Zn 11 by the coinage metals ( Cn = Ag and Au) to alter the magnetism

    Dalton Transactions · 2025

    Amit Mondal, Siddha Sankalpa Sethi, Jayanta Dutta, Rahul Pan, Sandip K. Kuila, Weiwei Xie, Ahin Roy, Partha P. Jana

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  18. Structural chemistry of intermetallic compounds for active site design in heterogeneous catalysis

    Chemical Science · 2025

    Nilanjan Roy, Kathryn L. MacIntosh, Mustafa Eid, Griffin A. Canning, Robert M. Rioux

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  19. Determination of Site Occupancy in the M–Pd–Zn (M = Cu, Ag, and Au) γ-Brass Phase by CALculation of PHAse Diagrams Modeling and Rietveld Refinement

    Inorganic Chemistry · 2025

    Rushi Gong, Anish Dasgupta, Shun‐Li Shang, Haoran He, Melanie Kirkham, Eric K. Zimmerer, Griffin A. Canning, Michael John Janik, Robert M. Rioux, Zi‐Kui Liu

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  20. Chemical Disorder-Driven Cluster Spin Glass in Pseudobinary Co 2 Zn 10.2 Mn 0.8 : An Experimental and Theoretical Study

    Inorganic Chemistry · 2025

    Amit Mondal, Shubham Patel, Rahul Pan, Sandip K. Kuila, Riju Dey, Lars Schumacher, Anup Kumar Bera, Rainer Pöttgen, Partha P. Jana

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  21. Post-Synthetic Transformation of High Entropy Alloy Nanoparticles into High-Entropy Intermetallics for Selective Acetylene Semi-Hydrogenation Catalysis

    Journal of the American Chemical Society · 2025

    Samuel S. Soliman, Mohamed Rabea Eid, Zachary Mitarotonda, Kathryn L. MacIntosh, Gaurav R. Dey, Robert M. Rioux, Raymond E. Schaak

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  22. Solving the “Coloring Problem” in InPd 3– x Ag x ( x = 0–0.7) by Phase Diagrams Modeling and Diffraction Experiments

    Inorganic Chemistry · 2025

    Nilanjan Roy, Sandip K. Kuila, Jin Li, Mustafa Eid, Kathryn L. MacIntosh, Parna Pramanik, Thomas E. Proffen, Michael John Janik, Robert M. Rioux, Partha P. Jana

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  23. Understanding the Structure and Stability of a Partially Disordered “Push–Pull Alloy” Ni 2 Zn 11– x Ga x (0.4 ≤ x ≤ 1.25)

    Inorganic Chemistry · 2026

    Sivaprasad Ghanta, Amit Mondal, Siddha Sankalpa Sethi, Émilie Gaudry, Rajat Kamboj, Partha P. Jana

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