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RESEARCH PAPER · Advanced Functional Materials · 2016

Aggregation Induced Enhancement of Linear and Nonlinear Optical Emission from a Hexaphenylene Derivative

Yulong Duan, Chenggong Ju, Guang Yang, Eduard Fron, Eduardo Coutiño‐González, Sergey V. Semin, Chencheng Fan, Ryan S. Balok, Jonathan Cremers, Paul Tinnemans, Yaqing Feng, Yuliang Li, Johan Hofkens, Alan E. Rowan, Th. Rasing, Jialiang Xu

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Aggregation Induced Enhancement of Linear and Nonlinear Optical Emission from a Hexaphenylene DerivativeOriginalHigh-Efficiency Second-Harmonic Generation from Hybrid Light-Matter States116Synthesis and properties of tetraphenylethylene derivatived diarylethene with photochromism and aggregation-induced emission79Relating the Structure of Geminal Amido Esters to their Molecular Hyperpolarizability8Molecular engineering of organic chromophores and polymers for enhanced bulk second-order optical nonlinearity112Third- and high-order nonlinear optical properties of an intramolecular charge-transfer compound22Functionalized azo-based iminopyridine rhenium complexes for nonlinear optical performance87Solvatochromic benzo[h] coumarins: Synthesis, solvatochromism, NLO and DFT study23Controlling the Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties13Triethylammonium picrate: An above-room-temperature phase transition material to switch quadratic nonlinear optical properties39Optical second harmonic generation and two-photon luminescence in organic microstructures0Strong optical nonlinearities of self-assembled polymorphic microstructures of phenylethynyl functionalized fluorenones28Functionalized twistacenes for solid state nonlinear optical materials15Malonitrile‐Functionalized Tetraphenylpyrazine: Aggregation‐Induced Emission, Ratiometric Detection of Hydrogen Sulfide, and Mechanochromism170A comparison of optical, electrochemical and self-assembling properties of two structural isomers based on 1,6- and 1,8-pyrenedione chromophores2Wavelength dependent nonlinear optical response of tetraphenylethene aggregation-induced emission luminogens52THz Generation and Detection by Fluorenone Based Organic Crystals60Multi-Stimuli-Responsive Fluorescence Switching from a Pyridine-Functionalized Tetraphenylethene AIEgen200Synthesis, optoelectronic properties and third-order nonlinear optical behaviors of the functionalized acene derivatives27Synthesis and photophysical investigation of 2-hydroxyquinoline-3-carbaldehyde: AIEE phenomenon, fluoride optical sensing and BSA interaction study14Plasmonic Nanoantenna Arrays as Efficient Etendue Reducers for Optical Detection35Third-order optical nonlinearities of 1,5-Diaminoanthraquinone for optical limiting application71Chiral Lead Halide Perovskite Nanowires for Second-Order Nonlinear Optics379The influence of nanocrystal size on optical second harmonic generation by para-nitroanaline embedded in electro-spun polymeric fibers9Multi-stimuli responsive emissive NLOphoric colorants – A recent trend in research28Aggregation-induced emission-based competitive lateral flow immunoassay for rapid detection of sulfamethazine in honey27Drastic photoluminescence modulation of an organic molecular crystal with high pressure28Monopyridyl-linked unsymmetrical anthracenyl π-conjugate as a platform for acid-pen and base-eraser19Design and synthesis of novel H-Shaped chromophore for enhanced nonlinear optical properties27Nonlinear optical properties (NLO) and metal ions sensing responses of a polymer containing 1,3,4-oxadiazole and bisphenol A units38Polymorph dependent linear and nonlinear optical properties of naphthalenyl functionalized fluorenones24Synthesis of a novel pyrene derived perimidine and exploration of its aggregation induced emission, aqueous copper ion sensing, effective antioxidant and BSA interaction properties17A fluorescent responsive tetraphenylethene based metal–organic framework22Phosphorescent Molecules That Resist Concentration Quenching in the Solution State: Concentration-Driven Emission Enhancement of Vaulted trans-Bis[2-(iminomethyl)imidazolato]platinum(II) Complexes18Fluorine-Mediated Benzothiadiazole Derivatives for Second-Order Nonlinear Optics2Enhanced deep-red emission in donor-acceptor molecular architecture: The role of ancillary acceptor of cyanophenyl14Robust thermoelastic microactuator based on an organic molecular crystal93Photophysics and photoreactivity of cross-conjugated enediynyl aggregates: Applications to multi-parametric sensing of microheterogeneity and reversible fluorescence switching32D organic‐inorganic hybrid perovskite materials for nonlinear optics131Competition between radiative and nonradiative excited state processes in photoluminescent organic molecular crystals0The role of conical intersections on the efficiency of fluorescent organic molecular crystals0Consecutive and Extensive Transition of Luminescent Color of an Organic Solid Material by Applying High Pressure7The inspiration and challenge for through-space charge transfer architecture: from thermally activated delayed fluorescence to non-linear optical properties36Bioapplications Manipulated by AIEgens with Nonlinear Optical Effect15Role of Conical Intersections on the Efficiency of Fluorescent Organic Molecular Crystals21Aggregation‐induced emission materials for nonlinear optics86Developmental trend of immunoassays for monitoring hazards in food samples: A review160Fully Controllable Structural Phase Transition in Thermomechanical Molecular Crystals with a Very Small Thermal Hysteresis28Design, synthesis and structure-property relationship of fluorenone-based derivatives for fluorescent OLEDs5Aggregation Induced Emission and Nonlinear Optical Properties of an Intramolecular Charge-Transfer Compound11Fluorescence Quenching in J-Aggregates through the Formation of Unusual Metastable Dimers252D organic single crystals: Synthesis, novel physics, high-performance optoelectronic devices and integration59Energy Conversion in Single‐Crystal‐to‐Single‐Crystal Phase Transition Materials86Nonlinear Optical Properties and Applications of Fluorenone Molecular Materials161Tin‐Based Chiral Perovskites with Second‐Order Nonlinear Optical Properties51Synthesis of pyrene-based materials with third-order nonlinearity optical property by click chemistry modification4Second harmonic generation from tetraphenylethylene functionalized graphdiyne5Three-primary-color molecular cocrystals showing white-light luminescence, tunable optical waveguide and ultrahigh polarized emission33Aligned chromophores in a host–guest MOF crystal for switchable polarized nonlinear optical response24Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window112Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window13Ferrocene appended 1,8-naphthalimide chromophores: Synthesis, theoretical, the effect of phenyl substitution on aggregation-induced enhanced emission and second-order nonlinear optical studies20Self-Assembled Nonlinear Optical Crystals Based on an Asymmetric Fluorenone Derivative17Benzofuro[2,3-c]isoquinolines as novel AIEgens: Modulation of AIE characteristics by a single methoxy group5Thickness‐Dependent High‐Temperature Piezo‐ and Ferro‐Electricity in a Fluorenone‐Based Molecular Crystal4Stereochemically Active Lone Pairs and Nonlinear Optical Properties of Two-Dimensional Multilayered Tin and Germanium Iodide Perovskites116Charge Transfer as Bridging Correlator for DSSC Efficiency and NLO Property16PEG修饰的硅量子点应用于细胞的二次谐波成像0Second-order nonlinear optical organic crystals based on a “click” compound8Self-assembled organic nonlinear optical crystals based on pyridine derived fluorenone202,7-Bis(pyridin-3-ylethynyl)fluoren-9-one3Resonant Second Harmonic Generation in Proline Hybrid Lead Halide Perovskites56Growth of single-crystals and microstructures using benzothiadiazole derivatives for efficient optical waveguide and nonlinearity31D Diisopropylammonium Lead Iodide Perovskite Shows Exceptional Optical Stability and Third‐Order Nonlinearity16Controllable shape deformation of an organic single crystal actuated by anisotropic thermal expansion19Density Functional Theory Study of the Secondorder Nonlinear Optical Properties of Novel Fluorenone Derivatives0Achiral Fluorinated Aromatic Ligands Based Chiral Hybrid Antimony Halides with High‐Efficiency Second‐Harmonic Generation18Enhancement of Fluorescence Emission Intensity in a Sulfonyl Hydrazide Derivative of tri(biphenyl‐4‐yl)amine via Solid‐state Grinding with Various Metal Salts: Combined Experimental and Computational Studies5Aggregation induced emission-active dimethoxy phenyl conjugated cyanoacetates with significant second order-nonlinear optical properties: Experimental and theoretical calculations3Theoretical investigation of substitution effect on the sixth and seventh positions of coumarin derivatives9Click on the Chemically Modified New Third-Order Nonlinear Organic Materials0Functional Graphdiyne for Emerging Applications: Recent Advances and Future Challenges107Effect of the phenyl group on the non-linear optical (NLO) and aggregation induced emission (AIE) properties of ferrocene conjugated linear D–π–A/D–π–A–π–A chromophores8Synthesis of 2,7-Diaryl Substituted Fluorenes and Fluorenones3Remarkable enhancement of the nonlinear optical absorption of W18O49 by Cu doping15Breaking of J-Aggregates in Fluorescent Covalent Organic Cage Molecular Materials Through Solid State Grinding with Metal Salts: Chemo-Sensing and Light-Emitting Diode Applications7Boosted Second Harmonic Generation of a Chiral Hybrid Lead Halide Resonant to Charge Transfer Exciton from Metal Halide Octahedra to Ligand11Boosted Second Harmonic Generation of a Chiral Hybrid Lead Halide Resonant to Charge Transfer Exciton from Metal Halide Octahedra to Ligand48Third-order nonlinear optics and optical limiting of phenanthrenone derivatives14Two‐Photon Excited Magneto‐Photoluminescence in Exciplex Material for 3D Mapping of Magnetic Field4Exploring charge transfer effects on linear, non‐linear optical, and dye‐sensitized solar cell properties: A DFT and TD‐DFT investigation of carbazole and aniline‐based dyes16Theoretical Investigation of Substitution Effect on the First Position of Coumarin Derivatives1Identifying and controlling the order parameter for ultrafast photoinduced phase transitions in thermosalient materials7Theoretical Study on Second-Order Nonlinear Optical Responses of Pyrazine-carbazole Derivatives in Gas, Solution, and Crystal States7Side Chain Vibration Triggers the Thermosalient Effect in an Organic Crystal of Asymmetric Fluorenone Derivatives4A photoluminescent second-order nonlinear optical molecular crystal with cold crystallization1Mechanical Twisting-Induced Enhancement of Second-Order Optical Nonlinearity in a Flexible Molecular Crystal36AIE‐Active Cyano Substituted Dimethoxy–Phenyl Derivatives for Nonlinear Optics: Spectral, Structural, and DFT Studies3Fluorescence Enhancement in a Tri(biphenyl‐4‐yl)amine Derivative via Solid‐State Grinding with Metal Salts: Chemosensing and White Light‐Emitting Diode Applications3Nonlinear Optical Properties of 0D Chiral Hybrid Bismuth Iodides35Alkoxybenzoyl-containing Tetraphenylethylene-based aggregation-induced emissive compound: Synthesis, mechanofluorochromism, doping study and thermo-responsive luminescence3Symmetry breaking induced second harmonic generation from 4-methoxy-2-nitroaniline: PMMA electro-spun fibers0Substituent effect in D-π-A based AIE-active ferrocene conjugated 2-cyanovinylnaphthalene chromophores for second-order nonlinear optics2Engineering Isolated Molecules to Optoelectronic Nanohybrids: One- and Two-Photon Excited Aggregation-Induced Enhanced Emission in ( Z )-2-([1,1′-Biphenyl]-4-yl)-3-(4-(3-aminopropoxy)phenyl)acrylonitrile and Laponite Nanoclay0Tuning Second‐Order Nonlinear Optical Properties via Electronic Interaction Engineering: Distinct Roles of Nonconjugation, σ–π Conjugation, and Intramolecular Charge Transfer in Chalcogen‑Functionalized Closo ‐Carborane Hybrids0Solid‐State Fluorescence Emission Enhancement in H‐Type Aggregate of Single Benzene Fluorophore via Grinding With Metal Salts: Importance of Dipole‐Metal Ion Interactions0

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  1. High-Efficiency Second-Harmonic Generation from Hybrid Light-Matter States

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    Thibault Chervy, Jialiang Xu, Yulong Duan, Chunliang Wang, L. Mager, Maurice Frerejean, Joris A. W. Münninghoff, Paul Tinnemans, James Andell Hutchison, Cyriaque Genet, Alan E. Rowan, Th. Rasing, Thomas W. Ebbesen

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  2. Synthesis and properties of tetraphenylethylene derivatived diarylethene with photochromism and aggregation-induced emission

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  3. Relating the Structure of Geminal Amido Esters to their Molecular Hyperpolarizability

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  4. Molecular engineering of organic chromophores and polymers for enhanced bulk second-order optical nonlinearity

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  9. Triethylammonium picrate: An above-room-temperature phase transition material to switch quadratic nonlinear optical properties

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  10. Optical second harmonic generation and two-photon luminescence in organic microstructures

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  11. Strong optical nonlinearities of self-assembled polymorphic microstructures of phenylethynyl functionalized fluorenones

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  13. Malonitrile‐Functionalized Tetraphenylpyrazine: Aggregation‐Induced Emission, Ratiometric Detection of Hydrogen Sulfide, and Mechanochromism

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  14. A comparison of optical, electrochemical and self-assembling properties of two structural isomers based on 1,6- and 1,8-pyrenedione chromophores

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  15. Wavelength dependent nonlinear optical response of tetraphenylethene aggregation-induced emission luminogens

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  16. THz Generation and Detection by Fluorenone Based Organic Crystals

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  17. Multi-Stimuli-Responsive Fluorescence Switching from a Pyridine-Functionalized Tetraphenylethene AIEgen

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  18. Synthesis, optoelectronic properties and third-order nonlinear optical behaviors of the functionalized acene derivatives

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  21. Third-order optical nonlinearities of 1,5-Diaminoanthraquinone for optical limiting application

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  48. Design, synthesis and structure-property relationship of fluorenone-based derivatives for fluorescent OLEDs

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  49. Aggregation Induced Emission and Nonlinear Optical Properties of an Intramolecular Charge-Transfer Compound

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  50. Fluorescence Quenching in J-Aggregates through the Formation of Unusual Metastable Dimers

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