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RESEARCH PAPER · Structure and bonding · 2005

Structural Aspects of Layered Double Hydroxides

David G. Evans, Rct Slade

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Structural Aspects of Layered Double HydroxidesOriginalMechanochemical route for synthesizing nitrate form of layered double hydroxide88Adsorption of 2,4-D on Mg/Al–NO3 layered double hydroxides with varying layer charge density89Application of layered double hydroxides for removal of oxyanions: A review1708Synthesis and anion exchange chemistry of new intercalation hosts containing lanthanide cations, Ln2(OH)5(NO3)·xH2O (Ln=Y, Gd–Lu)63Fabrication of oriented layered double hydroxide films by spin coating and their use in corrosion protection139Direct electrochemistry and electrocatalysis based on a film of horseradish peroxidase intercalated into Ni–Al layered double hydroxide nanosheets100Preparation of Co–Al layered double hydroxides by the hydrothermal urea method for controlled particle size93In situ growth of layered double hydroxide films on anodic aluminum oxide/aluminum and its catalytic feature in aldol condensation of acetone92Comparison of the evolution and growth processes of films of M/Al-layered double hydroxides with M=Ni or Zn62Emerging trends and challenges in synthetic clay-based materials and layered double hydroxides112Porphyrins Intercalated in Zn/Al and Mg/Al Layered Double Hydroxides: Properties and Structural Arrangement63Composition and microstructure of 20-year-old ordinary Portland cement–ground granulated blast-furnace slag blends containing 0 to 100% slag377Molecular dynamics computer simulations of the effects of hydrogen bonding on the properties of layered double hydroxides intercalated with organic acids62Cu−Zn−(Mn)−(Fe)−Al Layered Double Hydroxides and Their Mixed Metal Oxides: Physicochemical and Catalytic Properties in Wet Hydrogen Peroxide Oxidation of Phenol54Anion-Exchangeable Layered Materials Based on Rare-Earth Phosphors: Unique Combination of Rare-Earth Host and Exchangeable Anions203Poly l-lactide-layered double hydroxide nanocomposites via in situ polymerization of l-lactide79Removal of nitrophenol pesticides from aqueous solutions by layered double hydroxides and their calcined products71Electrochemical detection of dopamine on a Ni/Al layered double hydroxide modified carbon ionic liquid electrode116Layered double hydroxide/eggshell membrane: An inorganic biocomposite membrane as an efficient adsorbent for Cr(VI) removal80Dissolution of nano-size Mg–Al–Cl hydrotalcite in aqueous media127In situ growth of Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy172Visible-light-induced heterostructured Zn–Al–In mixed metal oxide nanocomposite photocatalysts derived from a single precursor57Corrosion in drinking water pipes: The importance of green rusts135Fabrication of Hierarchical Layered Double Hydroxide Framework on Aluminum Foam as a Structured Adsorbent for Water Treatment60Study of the in situ growth mechanism of Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy164Study of the corrosion mechanism of the in situ grown Mg–Al–CO32− hydrotalcite film on AZ31 alloy102Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides426Synthesis of Ce and Pr-promoted Ni and Co catalysts from hydrotalcite type precursors by reconstruction method81Hydration of Portland cement with additions of calcium sulfoaluminates270Electrodepositing Ag nanodendrites on layered double hydroxides modified glassy carbon electrode: Novel hierarchical structure for hydrogen peroxide detection64Influence of the nature and concentration of precursor metal ions in the brucite layer of LDHs for phosphate adsorption – a review71Synthesis of Li/Al LDH using aluminum and LiOH70Calcined graphene/MgAl-layered double hydroxides for enhanced Cr(VI) removal350Fe(II)–Al(III) layered double hydroxides prepared by ultrasound-assisted co-precipitation method for the reduction of bromate71Ternary MgO/ZnO/In2O3 heterostructured photocatalysts derived from a layered precursor and visible-light-induced photocatalytic activity131Synthesis and characterization of carboxymethyl cellulose/layered double hydroxide nanocomposites92Polymer–inorganic supramolecular nanohybrids for red, white, green, and blue applications115Release behavior and toxicity profiles towards A549 cell lines of ciprofloxacin from its layered zinc hydroxide intercalation compound56Thermodynamic properties and thermal behavior of Friedel's salt119Aqueous fluoride removal using ZnCr layered double hydroxides and their polymeric composites: Batch and column studies102Electrochemical synthesis of nickel–iron layered double hydroxide: Application as a novel modified electrode in electrocatalytic reduction of metronidazole79Copper, lead and cadmium removal by Ca Al layered double hydroxides150Intercalation of drugs in layered double hydroxides and their controlled release: A review403Adsorptive removal of phosphate by Mg–Al and Zn–Al layered double hydroxides: Kinetics, isotherms and mechanisms346Raman spectroscopy study of layered-double hydroxides containing magnesium and trivalent metals67pH sensitive nanocomposite hydrogel beads based on carboxymethyl cellulose/layered double hydroxide as drug delivery systems163Electrochemical deposition and characterization of Zn-Al layered double hydroxides (LDHs) films on magnesium alloy111Emerging applications of graphene and its derivatives in carbon capture and conversion: Current status and future prospects79A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts1440Calcined ZnAl- and Fe 3 O 4 /ZnAl–layered double hydroxides for efficient removal of Cr( vi ) from aqueous solution62Ultrathin platinum nanowires grown on single-layered nickel hydroxide with high hydrogen evolution activity974Structural and physicochemical aspects of drug release from layered double hydroxides and layered hydroxide salts55Reduced Graphene Oxide Supported CoO/MnO 2 Electrocatalysts from Layered Double Hydroxides for Oxygen Reduction Reaction56Adsorption of Cd(II) by Mg–Al–CO3- and magnetic Fe3O4/Mg–Al–CO3-layered double hydroxides: Kinetic, isothermal, thermodynamic and mechanistic studies301Porous Two-Dimensional Nanosheets Converted from Layered Double Hydroxides and Their Applications in Electrocatalytic Water Splitting298Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1,2,3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study118Hierarchical flower-like Co–Cu mixed metal oxide microspheres as highly efficient catalysts for selective oxidation of ethylbenzene89Ultrathin nanoflakes of cobalt–manganese layered double hydroxide with high reversibility for asymmetric supercapacitor318Carboxymethyl cellulose capsulated layered double hydroxides/drug nanohybrids for Cephalexin oral delivery107Ion specific effects on the stability of layered double hydroxide colloids101Flexible polyurethane foam nanocomposites with modified layered double hydroxides60Graphene/layered double hydroxide nanocomposite: Properties, synthesis, and applications203Superior flame retardant by combining high aspect ratio layered double hydroxide and graphene oxide73High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption307Synthesis and Applications164Novel Al-doped carbon nanotubes with adsorption and coagulation promotion for organic pollutant removal125Production and hydration of calcium sulfoaluminate-belite cements derived from aluminium anodising sludge118Nanostructured CeO2/MgAl-LDH composite for visible light induced water reduction reaction160Influence of surface chemistry on the formation of crystalline hydroxide coatings on Mg alloys in liquid water and steam systems67Earth-Abundant Heterogeneous Water Oxidation Catalysts1576Sorption mechanisms of arsenate on Mg-Fe layered double hydroxides: A combination of adsorption modeling and solid state analysis58Chloride ingress and steel corrosion in geopolymer concrete based on long term tests240A hierarchical CoFe-layered double hydroxide modified carbon-felt cathode for heterogeneous electro-Fenton process320Recent advances on the utilization of layered double hydroxides (LDHs) and related heterogeneous catalysts in a lignocellulosic-feedstock biorefinery scheme111Influence of Ce/Zr molar ratio on catalytic performance of hydrotalcite-derived catalysts at low temperature CO2 methane reforming97Graphitic-C 3 N 4 modified ZnAl-layered double hydroxides for enhanced photocatalytic removal of organic dye85High-stable α-phase NiCo double hydroxide microspheres via microwave synthesis for supercapacitor electrode materials143Development of dispersive micro-solid phase extraction based on micro and nano sorbents327Active protective PEO coatings on AA2024: Role of voltage on in-situ LDH growth119A Highly Active CoFe Layered Double Hydroxide for Water Splitting116Hybrid nanocomposites of layered double hydroxides: an update of their biological applications and future prospects62Heterogeneously catalyzed persulfate by CuMgFe layered double oxide for the degradation of phenol81A comparative study of the amaranth azo dye adsorption/desorption from aqueous solutions by layered double hydroxides109Photocatalytic Cr(VI) reduction by mixed metal oxide derived from ZnAl layered double hydroxide66Enhanced adsorption of bromate from aqueous solutions on ordered mesoporous Mg-Al layered double hydroxides (LDHs)139Highly selective and efficient removal and extraction of heavy metals by layered double hydroxides intercalated with the diphenylamine-4-sulfonate: A comparative study100Fundamentals and advances in magnesium alloy corrosion2073Recent advances in layered double hydroxides as electrode materials for high-performance electrochemical energy storage devices95Polyoxometalate (POM)-Layered Double Hydroxides (LDH) Composite Materials: Design and Catalytic Applications126Treatment of heavy metal ions in wastewater using layered double hydroxides: A review92A new hydrotalcite-like absorbent FeMnMg-LDH and its adsorption capacity for Pb 2+ ions in water142New insight into the preferred valency of interlayer anions in hydrotalcite-like compounds: The effect of Mg/Al ratio57Adsorption of Cd(II) from Aqueous Solutions by a Novel Layered Double Hydroxide FeMnMg-LDH60Copper-nickel catalysts from hydrotalcite precursors: The performance in NO reduction by CO57On the Natural History of Flavin-Based Electron Bifurcation58Fine Tuning the Heterostructured Interfaces by Topological Transformation of Layered Double Hydroxide Nanosheets67Facile synthesis of carbon-coated layered double hydroxide and its comparative characterisation with Zn–Al LDH: application on crystal violet and malachite green dye adsorption—isotherm, kinetics and Box-Behnken design145Hydrotalcites and hydrated Mg-carbonates as carbon sinks in serpentinite mineral wastes from the Woodsreef chrysotile mine, New South Wales, Australia: Controls on carbonate mineralogy and efficiency of CO2 air capture in mine tailings80A review on effect of synthesis conditions on the formation of layered double hydroxides414Chelating agent-assisted in situ LDH growth on the surface of magnesium alloy67Effect of Local Alkaline Microenvironment on the Behaviors of Bacteria and Osteogenic Cells180Synthesis and Characterization of ZnNiIn Layered Double Hydroxides Derived Mixed Metal Oxides with Highly Efficient Photoelectrocatalytic Activities115Recent advancements in engineering approach towards design of photo-reactors for selective photocatalytic CO2 reduction to renewable fuels287Layered double hydroxides for phosphorus recovery from acidified and non-acidified dewatered sludge72Ar Plasma-Exfoliated Ultrathin NiCo-Layered Double Hydroxide Nanosheets for Enhanced Oxygen Evolution89Enhancement corrosion resistance of Mg Al layered double hydroxides films by anion-exchange mechanism on magnesium alloys99In situ growth of a CaAl-NO 3 − -layered double hydroxide film directly on an aluminum alloy for corrosion resistance56NiCo-LDH nanowires@nanosheets core-shell structure grown on carbon fiber cloth for high performance flexible supercapacitor electrode131Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides66Preparation of Layered Double Hydroxides toward Precisely Designed Hierarchical Organization92Layered Structure Causes Bulk NiFe Layered Double Hydroxide Unstable in Alkaline Oxygen Evolution Reaction624Advances in controlled release pesticide formulations: Prospects to safer integrated pest management and sustainable agriculture537Adsorption and photocatalytic reduction of aqueous Cr(VI) by Fe3O4-ZnAl-layered double hydroxide/TiO2 composites62PPA-containing layered double hydroxide (LDH) films for corrosion protection of a magnesium alloy57Layered transition-metal hydroxides for alkaline hydrogen evolution reaction98Selective photocatalytic CO2 reduction over Zn-based layered double hydroxides containing tri or tetravalent metals346Layered Double Hydroxide Protective Films Developed on Aluminum and Aluminum Alloys: Synthetic Methods and Anti-Corrosion Mechanisms68Morphology, Thermal Stability, and Flammability Properties of Polymer-Layered Double Hydroxide (LDH) Nanocomposites: A Review120Graphene-supported organic-inorganic layered double hydroxides and their environmental applications: A review81Starch-Mg/Al layered double hydroxide composites as an efficient solid phase extraction sorbent for non-steroidal anti-inflammatory drugs as environmental pollutants77Electrocoagulation processes: A general review about role of electro-generated flocs in pollutant removal243Surface chemistry and structure evaluation of Mg/Al and Mg/Fe LDH derived from magnesite and dolomite in comparison to LDH obtained from chemicals64Boosting the electrocatalytic performance of NiFe layered double hydroxides for the oxygen evolution reaction by exposing the highly active edge plane (012)131Layered double hydroxides are still out in the bloom: Syntheses, applications and advantages of three-dimensional flower-like structures83Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review183The effect of ZnAl-LDHs-CO3 on the corrosion behaviour of Zn-5Al alloys in 3.5wt.% NaCl solution743D self-supporting heterostructure NiCo-LDH/ZnO/CC electrode for flexible high-performance supercapacitor57Electronic modulation of oxygen evolution on metal doped NiFe layered double hydroxides71Trimetallic NiFeCr-LDH/MoS2composites as novel electrocatalyst for OER90Two-dimensional layered double hydroxide nanoadjuvant: recent progress and future direction88Carbonation of calcium sulfoaluminate cement blended with blast furnace slag112Electrostatic adsorbing graphene quantum dot into nickel–based layered double hydroxides: Electron absorption/donor effects enhanced oxygen electrocatalytic activity98State-of-the-art and prospects of Zn-containing layered double hydroxides (Zn-LDH)-based materials for photocatalytic water remediation66Current advances on polymer-layered double hydroxides/metal oxides nanocomposites and bionanocomposites: Fabrications and applications in the textile industry and nanofibers67In situ stabilization of the adsorbed Co2+ and Ni2+ in rice straw biochar based on LDH and its reutilization in the activation of peroxymonosulfate65Stability-Enhanced α-Ni(OH)2 Pillared by Metaborate Anions for Pseudocapacitors69Layered double hydroxides as thermal stabilizers for Poly(vinyl chloride): A review56Recent Advances in Sample Preparation for Cosmetics and Personal Care Products Analysis67Incorporation of LDH nanocontainers into plasma electrolytic oxidation coatings on Mg alloy71Enhanced Fluoride Uptake by Layered Double Hydroxides under Alkaline Conditions: Solid-State NMR Evidence of the Role of Surface >MgOH Sites55Novel p- and n-type S-scheme heterojunction photocatalyst for boosted CO2 photoreduction activity153Advanced Two-Dimensional Materials for Green Hydrogen Generation: Strategies toward Corrosion Resistance Seawater Electrolysis─Review and Future Perspectives76Surface modification of two-dimensional layered double hydroxide nanoparticles with biopolymers for biomedical applications87A comprehensive review on LDH-based catalysts to activate persulfates for the degradation of organic pollutants169Improved cotton fabrics properties using zinc oxide-based nanomaterials: A review69Optimizing hydrogen production by alkaline water decomposition with transition metal-based electrocatalysts91Facile synthesis of magnetic ZnAl layered double hydroxides and efficient adsorption of malachite green and Congo red78Design of self-healing PEO-based protective layers containing in-situ grown LDH loaded with inhibitor on the MA8 magnesium alloy65Layered Double Hydroxides: Recent Progress and Promising Perspectives Toward Biomedical Applications136Recent advancement in synthesis and applications of layered double hydroxides (LDHs) composites78

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  49. Crystal chemistry of natural layered double hydroxides. 3. The crystal structure of Mg,Al-disordered quintinite-2H

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  50. Crystal chemistry of natural layered double hydroxides. I. Quintinite-2H-3c from the Kovdor alkaline massif, Kola peninsula, Russia

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