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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2016

Facile Atmospheric Pressure Synthesis of High Thermal Stability and Narrow-Band Red-Emitting SrLiAl3N4:Eu2+ Phosphor for High Color Rendering Index White Light-Emitting Diodes

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Facile Atmospheric Pressure Synthesis of High Thermal Stability and Narrow-Band Red-Emitting SrLiAl3N4:Eu2+ Phosphor for High Color Rendering Index White Light-Emitting DiodesOriginalDesign, preparation, and optimized luminescence of a dodec-fluoride phosphor Li 3 Na 3 Al 2 F 12 :Mn 4+ for warm WLED applications101Facile synthesis, morphology and photoluminescence of a novel red fluoride nanophosphor K 2 NaAlF 6 :Mn 4+115K 7 Ca 9 [Si 2 O 7 ] 4 F:Ce 3+ : a novel blue-emitting phosphor with good thermal stability for ultraviolet-excited light emitting diodes54Photoluminescence properties of a novel red fluoride K 2 LiGaF 6 :Mn 4+ nanophosphor51Realizing superior white LEDs with both high R9 and luminous efficacy by using dual red phosphors46Highly Efficient and Thermally Stable K3AlF6:Mn4+ as a Red Phosphor for Ultra-High-Performance Warm White Light-Emitting Diodes283Charge compensated derived enhanced red emission from Sr 3 (VO 4 ) 2 :Eu 3+ nanophosphors for white light emitting diodes and flat panel displays46Highly Stable Modified Phosphors of Ba2SiO4:Eu2+ by Forming a Robust Hydrophobic Inorganic Surface Layer of Silicon-Oxy-Imide-Carbide14Concentration-Driven Selectivity of Energy Transfer Channels and Color Tunability in Ba3La(PO4)3:Tb3+, Sm3+for Warm White LEDs76Controlling of Structural Ordering and Rigidity of β-SiAlON:Eu through Chemical Cosubstitution to Approach Narrow-Band-Emission for Light-Emitting Diodes Application82Critical Review—Narrow-Band Nitride Phosphors for Wide Color-Gamut White LED Backlighting91Luminescence Tuning, Thermal Quenching, and Electronic Structure of Narrow-Band Red-Emitting Nitride Phosphors62Thermal stability and reliability studies of (Sr, Ca) AlSiN3:Eu2+ phosphors for LED application11Crystal field splitting of 4fn−15d-levels of Ce3+ and Eu2+ in nitride compounds110Photoluminescent properties of Eu3+‐Eu2+ activated MAl2SixO2x + 4 (M = Mg, Ca, Sr, Ba) phosphors prepared in air8Facile synthesis of bifunctional Eu3+-activated NaBiF4 red-emitting nanoparticles for simultaneous white light-emitting diodes and field emission displays427A far-red emission (Ca,Sr)14Zn6Ga10O35:Mn4+ phosphor for potential application in plant-growth LEDs57A novel Cs 2 NbOF 5 :Mn 4+ oxyfluoride red phosphor for light-emitting diode devices83Narrow-band blue emitting nitridomagnesosilicate phosphor Sr 8 Mg 7 Si 9 N 22 :Eu 2+ for phosphor-converted LEDs28Phase-transition-induced giant enhancement of red emission in Mn 4+ -doped fluoride elpasolite phosphors63Pressure-controlled synthesis of high-performance SrLiAl 3 N 4 :Eu 2+ narrow-band red phosphors34Synthesis and improved photoluminescence of a novel red phosphor LiSrGaF 6 :Mn 4+ for applications in warm WLEDs22The electronic and optical properties of a narrow-band red-emitting nanophosphor K 2 NaGaF 6 :Mn 4+ for warm white light-emitting diodes88Thermal stabilization and energy transfer in narrow-band red-emitting Sr[(Mg 2 Al 2 ) 1−y (Li 2 Si 2 ) y N 4 ]:Eu 2+ phosphors11Two Ce 3+ centers induced broadband emission in Y 3 Si 6 N 11 :Ce 3+ yellow phosphor14Preparation and photoluminescence properties of red-emitting phosphor ZnAl2O4:Eu3+with an intense5D0→7F2transition24Vacuum Referred Binding Energy Scheme, Electron–Vibrational Interaction, and Energy Transfer Dynamics in BaMg2Si2O7:Ln (Ce3+, Eu2+) Phosphors34The Enhanced Red Emission and Improved Thermal Stability of CaAlSiN3:Eu2+ Phosphors by Using Nano-EuB6 as Raw Material29Synthesis, structure and luminescence of SrLiAl3N4:Ce3+ phosphor24NaBaY(BO 3 ) 2 :Ce 3+ ,Tb 3+ : A novel sharp green‐emitting phosphor used for WLED and FEDs63Facile Post‐Synthesis of a Ce 3+ ‐Doped Ca x Sr 1‐x Sc 2 O 4 Phosphor by Means of Cation Exchange7Disentangling Red Emission and Compensatory Defects in Sr[LiAl3N4]:Ce3+ Phosphor30Improving Quantum Efficiency and Thermal Stability in Blue-Emitting Ba 2– x Sr x SiO 4 :Ce 3+ Phosphor via Solid Solution244Controlled Morphology, Improved Photoluminescent Properties, and Application of an Efficient Non-rare Earth Deep Red-Emitting Phosphor68Room-temperature synthesis, optimized photoluminescence and warm-white LED application of a highly efficient non-rare-earth red phosphor33Preferential Neighboring Substitution-Triggered Full Visible Spectrum Emission in Single-Phased Ca10.5–xMgx(PO4)7:Eu2+ Phosphors for High Color-Rendering White LEDs122A green synthetic route to K2NbF7:Mn4+ red phosphor for the application in warm white LED devices34Blue-yellow multicolor phosphor, Eu2+-activated Li3NaSiO4: Excellent thermal stability and quenching mechanism47Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor185Significantly conquering moisture-induced luminescence quenching of red line-emitting phosphor Rb 2 SnF 6 :Mn 4+ through H 2 C 2 O 4 triggered particle surface reduction for blue converted warm white light-emitting diodes81Excellent human eye sensitivity matching, high luminous efficacy, high quantum yield and thermal stability of narrow-band red-emitting SrLiAl3N4:Eu2+ phosphor17A high-performance non-rare-earth deep-red-emitting Ca14-xSrxZn6Al10O35:Mn4+ phosphor for high-power plant growth LEDs71Novel polygonal structure Mn 4+ activated In 3+ -based Elpasolite-type hexafluorides red phosphor for warm white light-emitting diodes (WLEDs)30Carbon quantum dot-sensitized and tunable luminescence of Ca 19 Mg 2 (PO 4 ) 14 :Ln 3+ (Ln 3+ = Eu 3+ and/or Tb 3+ ) nanocrystalline phosphors with abundant colors via a sol–gel process39Electronic and optical properties of a novel fluoroaluminate red phosphor Cs 2 NaAl 3 F 12 :Mn 4+ with high color purity for white light-emitting diodes33Enhanced narrow-band green-emission and thermal stability via the introduction of Mg 2+ in ZnB 2 O 4 :Mn 2+ phosphor11Facile in situ synthesis of zeolite-encapsulating Cs 2 SiF 6 :Mn 4+ for application in WLEDs28Mn 4+ nonequivalent-doped Al 3+ -based cryolite high-performance warm WLED red phosphors20Tunable photoluminescence of apatite phosphor Ca 5.95− x Sr x La 4 (SiO 4 ) 2 (PO 4 ) 4 O 2 :0.05Eu 2+ and its application in light‐emitting diodes11New strategy for designing orangish-red-emitting phosphor via oxygen-vacancy-induced electronic localization348Structure and photoluminescence properties of Ca 0.99− x S r x AlSiN 3 :0.01Ce 3+ solid solutions21Improving moisture stability of SrLiAl3N4:Eu2+ through phosphor-in-glass approach to realize its application in plant growing LED device38Enhanced narrow green emission and thermal stability in γ-AlON: Mn2+, Mg2+ phosphor via charge compensation56Controllable Eu 2+ -Doped Orthophosphate Blue-/Red-Emitting Phosphors: Charge Compensation and Lattice-Strain Control49Implementation of high color quality, high luminous warm WLED using efficient and thermally stable Rb3AlF6:Mn4+ as red color converter40A novel Ba4Gd3K3(PO4)6F2:Eu2+ blue-white emitting phosphor for near-ultraviolet excited light-emitting diodes22Phase formation and luminescence properties of ternary solid-solution among tetragonal systems2A red-emitting Mn4+ activated phosphor with controlled morphology and two-dimensional luminescence nanofiber film: Synthesis and application for high-performance warm white light-emitting diodes (WLEDs)27A Double-Layer White Light Converter with High-Efficiency Heat Transfer Structure for High-Power NUV LEDs/LDs4White Light-Emitting Diodes With Ultrahigh Color Rendering Index by Red/Green Phosphor Layer Configuration Structure23Thermally stable Na3.6Y1.8(PO4)3:Eu3+ phosphor, luminescent properties and application in WLEDs27A deep-learning technique for phase identification in multiphase inorganic compounds using synthetic XRD powder patterns199Eu3+-doped SrGe4O9 red emitting phosphors: structural, luminescence properties, theoretical calculation and applications2Effect of Sm3+ doping on optical properties of Mg2P2O7 and Mg3P2O8 phosphors70Crystal-field splitting of Ce3+ in narrow-band phosphor SrLiAl3N413Strategies for Designing Antithermal‐Quenching Red Phosphors216Tuning the luminescence properties of Mn 4+ ‐activated CaYAlO 4 phosphor by co‐doping cations for indoor plant cultivation27Structure identification and strongly enhanced luminescence of Sr9Y2(WO6)4: Mn4+ phosphors by co-doping Mg2+ ions for plant growth LEDs21Thermally Stable and Deep Red Luminescence of Sr1–xBax[Mg2Al2N4]:Eu2+ (x = 0–1) Phosphors for Solid State and Agricultural Lighting Applications64Elimination of residual carbon in carbothermal-synthesized SrAlSi4N7:Eu2+ phosphors via non-thermal plasma oxidation3Luminescence Line Broadening of CdSe Nanoplatelets and Quantum Dots for Application in w-LEDs57Improved thermal stability of luminescence by anion modification in Na2Y(MoO4)(PO4):Tb3+,Eu3+ red-emitting phosphors29Blue-laser-diode–based high CRI lighting and high-speed visible light communication using narrowband green-/red-emitting composite phosphor film42Eu3+, Sm3+ Deep‐Red Phosphors as Novel Materials for White Light‐Emitting Diodes and Simultaneous Performance Enhancement of Organic–Inorganic Perovskite Solar Cells84Intrinsic Point Defects and Dopants Ce3+ in SrLiAl3N4: Thermodynamic and Spectral Properties from First Principles6The red-emitting phosphors of Mn4+-activated A2MgWO6 (A = Ba, Sr, Ca) for light emitting diodes30A promising red-emitting phosphor SrLiAl3N4:Eu2+ for field emission displays33Structure evolution and tunable magneto‐optical multifunctional property study of novel Ca 18 K 3 Sc 1‐x Sm x (PO 4 ) 14 phosphors7A Novel and Highly Efficient Rare-Earth Element-Free K 2Ge 1-XTi xF 6: Mn 4+ Red Phosphor for Warm White LEDs0A Novel and Highly Efficient Rare-Earth Element-Free K 2Ge 1-XTi xF 6: Mn 4+ Red Phosphor for Warm White LEDs0High partial thermal conductivity of luminescence sites: a crucial factor for reducing the heat-induced lowering of the luminescence efficiency8Structure, luminescence of Eu 2+ and Eu 3+ in CaMgSi 2 O 6 and their co-existence for the excitation-wavelength/temperature driven colour evolution32Synthesis and optical absorption properties of nanocrystalline rare earth hexaborides Nd1–xEuxB6 powders3Single phase white LED phosphor Ca3YAl3B4O15:Ce3+,Tb3+,Sm3+ with superior performance: Color-tunable and energy transfer study183Ca19Zn2(PO4)14:Dy3+, M+ (M = Li, Na, K) white-emitting phosphors: Charge compensation effect of M+ on the photoluminescence enhancement42Reduction Mechanism of Eu 3+ in Ca 2+x La 8−x (SiO 4 )6O 2–0.5x : Eu 2+ Phosphors3Robust thermal performance of red-emitting phosphor composites for white light-emitting diodes: Energy transfer and oxygen-vacancy induced electronic localization43Synthesis of narrow-band red-emitting SrLiAl3N4:Eu2+ phosphor and the study of its influencing factors on luminescence performance2Robust thermal performance and color purity of samarium based deep red emitting phosphor for near-UV chip-based high-color-rendering34Bright Red-Emitting Ca3LuAl3B4O15:Ce3+,Sm3+ Phosphors with High Thermal Stability for Elevating the Color Rendering of Near-Ultraviolet-Based White-Light-Emitting Diodes21A Novel Red-Emitting Na2NbOF5:Mn4+ Phosphor with Ultrahigh Color Purity for Warm White Lighting and Wide-Gamut Backlight Displays36Blue Laser Diode-Based Visible Light Communication and Solid-State Lighting4Structural development and luminescent enhancement of CaAlSiN3:Eu2+ phosphor via replacing Al3+ by Ga3+22Bifunctional samarium activated red-emitting and thermal resistant phosphor for simultaneous field emission displays and white light-emitting diodes32Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Correlating doping with the stability and color rendition of red phosphors10Multisite-occupation properties, spectral characteristics and energy-transfer behaviors of Ca2ZrSi4O12:Ce3+,Tb3+ phosphor for NUV-based LEDs8Simple synthetic route to Ca18.75Li10.5[Al39N55]:Ce3+ yellow-green phosphors for white LEDs4Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance24Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance1Luminescence enhancement of single-component Ca19Zn2(PO4)14:Dy3+ white-emitting phosphor powders through partial substitution of PO43− with SiO44− and BO33-19Emission color shift from green yellow to reddish orange in Eu2+-activated Ca6BaP4O17 by doping high amount of activator ion9Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca30Design of luminescence in (Sr,Gd)Li(Al,Mg)3N4:Eu2+ deep red phosphors via crystal field engineering for full-spectrum WLEDs29Accessing deep-red emission using chemical units cosubstituted LaTiSbO6:Mn4+ phosphor38A novel sulfide phosphor, BaNaAlS3:Eu2+, discovered via particle swarm optimization24Sr2BN2Cl:Eu2+-Based Narrow-Band Blue-Emitting Phosphor: A Potential Color Converter for Illumination and Displays10Na1.5Y2.5F9: Ce3+, Tb3+, Eu3+ glass-ceramics for white light9A highly efficient Mn 4+ activated Nb-based oxyfluoride red fluorescent material with excellent water stability: preparation and performance analysis6一种高效、优异的水稳定性Mn4 + 活化Nb基氧氟化物红荧光物质制备及性能分析0Photoluminescence properties of novel blue-light excited orange-red phosphors Sr3Al2Si3O12:Eu2+23Ultra-narrow-band luminescence with spectral width down to 32 nm in bismuth-activated phosphate phosphors with superior thermal stability11Realizing thermal and moisture stability in the K2Ge1-xTixF6:Mn4+ red phosphors with high efficiency for WLEDs22Photoluminescence enhancement and excellent thermal stability of Ca2ZnSi2O7:Pr3+ red-emitting phosphors through charge compensator A+ (Li+, Na+ and K+) co-doping for w-LED applications17Enhanced orange-red emission in Eu3+/Li+ co-doped Na5Lu9F32 fluoride single crystal upon excitation of 394 nm11White light emission and superior color stability in a single-component host with exceptional eminent color rendering and theoretical calculations on D uv for color quality10A Giant Stokes Shift in Wide‐Band Red Phosphor [Ca0.33(Sr1‐xBax)0.67]7(SiO3)6Cl2: Eu2+13A new yellowish‐green‐emitting phosphor: Eu 2+ ‐doped Ba 3 YAl 2 O 7.55A Strategy for the Synthesis of Oxonitridosilicate Phosphors from Anionic Condensation8Photoluminescence investigation of novel red emitting NaLa(1-x)MgTeO6: XSm3+ phosphor with high color purity for n-UV based warm WLEDS and anti-counterfeiting applications23Excellent Color Purity and Luminescence Thermometry Performance in Germanate Tellurite Glass Doped with Eu3+ and Tb3+13Optimizations of luminescent materials for white light emitting diodes toward healthy lighting27Study on the photoluminescence performance and thermal sensitivity of (Y,Gd)2O3:Tb3+,Dy3+,Tm3+ phosphors6Garnet-type cyan-green-emitting SrLu2Ga1.5Al2.5SiO12:Ce3+ phosphor with high quantum efficiency, thermal stability, and water resistance for blue-excited WLEDs14Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold11Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold10Nitride phosphors0Violet light excitable Sm/Eu activated zirconium silicate towards white light-emitting diodes7Luminescent Materials for Solid-State Lighting and Enhancement of Solar Cell Efficiency0Designing Ultra‐Narrow‐Band Red Phosphor via Oxygen Vacancy Engineering for Transparent Display Application14Synthesis and luminescence investigation of Eu3+ and Dy3+ doped NaAl(PO3)4 glass for solid state lighting applications6Narrow-band green nitride phosphor for wide color gamut backlighting11Narrow‐Band Green Phosphors for Advanced Display Technologies: Material Design, Performance Optimization, and Future Prospects6The short fluorescent lifetime and high moisture resistance K3NbOF6:Mn4+ fluorescent material for backlight display application1Narrow-band red-emitting Li6Y1-x(BO3)3:xEu3+ phosphors with high R9 for WLEDs9The Low-Temperature Heat Capacity and Thermodynamic Functions of Mg3N2, Ca3N2, and Sr3N20Ce3+-activated BaAlSi5N7O2: A novel cyan-emitting phosphor with superior thermal stability for full-visible-spectrum LED lighting2Optical enhancement of novel double perovskite Ca2Sc0.95Sb1-xW5x/6O6:0.05Sm3+ red phosphors for WLEDs applications1Spectroscopic investigation of Sr1−xCaxLiAl3N4:Eu2+ phosphor involving structural characterization, luminescence mechanism and potential LED applications0

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