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RESEARCH PAPER · Nature Communications · 2016

Phase-referenced nonlinear spectroscopy of the α-quartz/water interface

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Phase-referenced nonlinear spectroscopy of the α-quartz/water interfaceOriginalHow to distinguish various components of the SHG signal recorded from the solid/liquid interface?4Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues124Surface-specific vibrational spectroscopy of the water/silica interface: screening and interference116The behavior of hydroxide and hydronium ions at the hexadecane–water interface studied with second harmonic generation and zeta potential measurements43In situ spectroscopy of ligand exchange reactions at the surface of colloidal gold and silver nanoparticles24Quantifying the Electrostatics of Polycation–Lipid Bilayer Interactions41Conformational Changes of a Surface-Tethered Polymer during Radical Growth Probed with Second-Harmonic Generation2Effects of third-order susceptibility in sum frequency generation spectra: a molecular dynamics study in liquid water106Adsorbed Dyes onto Nanoparticles: Large Wavelength Dependence in Second Harmonic Scattering8Separating the pH-Dependent Behavior of Water in the Stern and Diffuse Layers with Varying Salt Concentration113Proton Order toward the Surface of Ice Ih Revealed by Heterodyne-Detected Sum Frequency Generation Spectroscopy42Second-order spectral lineshapes from charged interfaces259Evidence for Considerable Metal Cation Concentrations from Lithium Intercalation Compounds in the Nano–Bio Interface Gap18Ion Pairing and Adsorption of Azo Dye/C16TAB Surfactants at the Air–Water Interface30Sum Frequency Generation Spectroscopy and Second Harmonics Generation0Water-water correlations in electrolyte solutions probed by hyper-Rayleigh scattering17Counting charges on membrane-bound peptides27Detecting weak signals from interfaces by high accuracy phase-resolved SFG spectroscopy33Interfacial electrostatics of poly(vinylamine hydrochloride), poly(diallyldimethylammonium chloride), poly- l -lysine, and poly- l -arginine interacting with lipid bilayers19Lyophobicity may not be the main driving force for long chain surfactants from the bulk phase to the interface11Modeling of solid–liquid interfaces using scaled charges: rutile (110) surfaces48Non-parabolic potential dependence of optical second harmonic generation from the Si(111) electrode/electrolyte interface16Other Topics1Structural definition of the BIL and DL: a new universal methodology to rationalize non-linear χ (2) ( ω ) SFG signals at charged interfaces, including χ (3) ( ω ) contributions123Water at surfaces with tunable surface chemistries22Relative permittivity in the electrical double layer from nonlinear optics69Structure from Dynamics: Vibrational Dynamics of Interfacial Water as a Probe of Aqueous Heterogeneity62Second-harmonic phonon spectroscopy of α -quartz18Second-Order Vibrational Lineshapes from the Air/Water Interface92Hydrogen-Bond Networks near Supported Lipid Bilayers from Vibrational Sum Frequency Generation Experiments and Atomistic Simulations65Electrolyte and Temperature Effects on Third-Order Susceptibility in Sum-Frequency Generation Spectroscopy of Aqueous Salt Solutions51Smart Air–Water Interfaces with Arylazopyrazole Surfactants and Their Role in Photoresponsive Aqueous Foam61Bulk Contributions Modulate the Sum-Frequency Generation Spectra of Water on Model Sea-Spray Aerosols103Binding of trivalent ions on fatty acid Langmuir monolayer: Fe3+ versus La3+26What the Diffuse Layer (DL) Reveals in Non-Linear SFG Spectroscopy38Evidence for auto-catalytic mineral dissolution from surface-specific vibrational spectroscopy50Effects of Ca2+ Ion Condensation on the Molecular Structure of Polystyrene Sulfonate at Air–Water Interfaces23Surface Potential of a Planar Charged Lipid–Water Interface. What Do Vibrating Plate Methods, Second Harmonic and Sum Frequency Measure?59Mechanism of Electric Power Generation from Ionic Droplet Motion on Polymer Supported Graphene134Spectroscopic BIL-SFG Invariance Hides the Chaotropic Effect of Protons at the Air-Water Interface24Charge-Controlled Surface Properties of Native and Fluorophore-Labeled Bovine Serum Albumin at the Air–Water Interface26Introduction of Positive Charges into Zwitterionic Phospholipid Monolayers Disrupts Water Structure Whereas Negative Charges Enhances It39Quantifying Double-Layer Potentials at Liquid–Gas Interfaces from Vibrational Sum-Frequency Generation62C n TAB/polystyrene sulfonate mixtures at air–water interfaces: effects of alkyl chain length on surface activity and charging state23Deconvolution of BIL-SFG and DL-SFG spectroscopic signals reveals order/disorder of water at the elusive aqueous silica interface58Particle adsorption at the oil–water interface studied with second harmonic generation11Development of ultrafast broadband electronic sum frequency generation for charge dynamics at surfaces and interfaces47Water structure at the interface of alcohol monolayers as determined by molecular dynamics simulations and computational vibrational sum-frequency generation spectroscopy18New Insights into χ(3) Measurements: Comparing Nonresonant Second Harmonic Generation and Resonant Sum Frequency Generation at the Silica/Aqueous Electrolyte Interface56Simple physics in and easy manipulating of the interfacial behavior of charged molecules on drug delivery vesicles33Beyond the Gouy–Chapman Model with Heterodyne-Detected Second Harmonic Generation97Perturbation of Hydrogen-Bonding Networks over Supported Lipid Bilayers by Poly(allylamine hydrochloride)20Bacterial Model Membranes Deform (resp. Persist) upon Ni2+ Binding to Inner Core (resp. O-Antigen) of Lipopolysaccharides4Surface solvation and hindered isomerization at the water/silica interface explored with second harmonic generation9DFT-MD simulations and theoretical SFG spectroscopy to characterize H-Bonded networks at aqueous interfaces : from hydrophobic to hydrophilic environments0Organic Enrichment at Aqueous Interfaces: Cooperative Adsorption of Glucuronic Acid to DPPC Monolayers Studied with Vibrational Sum Frequency Generation32Probing Charged Aqueous Interfaces Near Critical Angles: Effect of Varying Coherence Length76Specifics about Specific Ion Adsorption from Heterodyne-Detected Second Harmonic Generation47Specifics about Specific Ion Adsorption from Heterodyne-Detected Second Harmonic Generation2Molecular Dynamics Study of the Electric Double Layer and Nonlinear Spectroscopy at the Amorphous Silica–Water Interface52Energy conversion via metal nanolayers37Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface10Potassium Hydroxide Concentration-Dependent Water Structure on the Quartz Surface Studied by Combining Sum-Frequency Generation (SFG) Spectroscopy and Molecular Simulations9Direct Quantification of Water Surface Charge by Phase-Sensitive Second Harmonic Spectroscopy56Gate-Controlled Sum-Frequency Vibrational Spectroscopy for Probing Charged Oxide/Water Interfaces38Autoionization dynamics of (2P1/2) ns/d states in krypton probed by noncollinear wave mixing with attosecond extreme ultraviolet and few-cycle near infrared pulses25Cooperative Adsorption of Trehalose to DPPC Monolayers at the Water–Air Interface Studied with Vibrational Sum Frequency Generation17Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy21Electrostatics, Hydrogen Bonding, and Molecular Structure at Polycation and Peptide:Lipid Membrane Interfaces21Direct Measurement of Charge Reversal on Lipid Bilayers Using Heterodyne-Detected Second Harmonic Generation Spectroscopy41Cloud history can change water–ice–surface interactions of oxide mineral aerosols: a case study on silica10Surface Hydration and Hydroxyl Configurations of Gibbsite and Boehmite Nanoplates42Spiropyran Sulfonates for Photo- and pH-Responsive Air–Water Interfaces and Aqueous Foam51Anomalous pH-Dependent Enhancement of p-Methyl Benzoic Acid Sum-Frequency Intensities: Cooperative Surface Adsorption Effects9Ions Tune Interfacial Water Structure and Modulate Hydrophobic Interactions at Silica Surfaces94Ordering and Nonideality of Air–Ionic Liquid Interfaces in Surface Second Harmonic Generation14Wavelength-scanning second-harmonic generation for determining absolute charge density at aqueous interfaces10Electric-Field-Induced Interface Behavior of Dodecyl Sulfate with Large Organic Counterions: A Molecular Dynamics Study7The Attraction of Water for Itself at Hydrophobic Quartz Interfaces23Herzberg–Teller Effect Predominates in Sum-Frequency Vibrational Spectroscopy of Limonene Chiral Liquids1Evolution of Different Structures of the Fungicide Dodine and Changes in the Associated Water at the Air/Water Interface: Vibrational Sum Frequency Generation Study10Potential-Induced Adsorption and Structuring of Water at the Pt(111) Electrode Surface in Contact with an Ionic Liquid31Second Harmonic Generation Spectroscopy and Microscopy of Liposomes, Nanoparticles, and Cells1High-resolution phase-sensitive sum frequency generation spectroscopy by time-domain ptychography6Si(111) electrode/electrolyte interfacial studied by in-situ second harmonic generation1The Role of Ions on the Surface-Bound Water Structure at the Silica/Water Interface: Identifying the Spectral Signature of Stability4Signature of the surface hydrated proton and associated restructuring of water at model membrane interfaces: a vibrational sum frequency generation study5DNA-Induced Restructuring of Interfacial Water and the Hydrocarbon Chain of Different Forms of Fungicide at the Water Interface: Vibrational Sum Frequency Generation Study8Role of Ions on the Surface-Bound Water Structure at the Silica/Water Interface: Identifying the Spectral Signature of Stability78Molecular Fingerprints of Hydrophobicity at Aqueous Interfaces from Theory and Vibrational Spectroscopies70Observing the structural variations on binary complex vesicle surfaces and the influence on molecular transportation12Origin of Asymmetric Electric Double Layers at Electrified Oxide/Electrolyte Interfaces33Environmental Interfacial Spectroscopy7Polarity-dependent nonlinear optics of nanowires under electric field17Stern and Diffuse Layer Interactions During Ionic Strength Cycling1A New Imaginary Term in the Second-Order Nonlinear Susceptibility from Charged Interfaces61Disentangling Sum-Frequency Generation Spectra of the Water Bending Mode at Charged Aqueous Interfaces38Water at charged interfaces556Ion Pairing Mediates Molecular Organization Across Liquid/Liquid Interfaces26In Situ Label-Free Study of Protein Adsorption on Nanoparticles13Stern and Diffuse Layer Interactions during Ionic Strength Cycling40Gate Alignment of Liquid Water Molecules in Electric Double Layer0Spectral Response of Interfacial Water at Different Lipid Monolayer Interfaces upon Interaction with Charged Gold Nanoparticles11Determining the Surface Potential of Charged Aqueous Interfaces Using Nonlinear Optical Methods22Charge-Induced χ (3) Susceptibility in Interfacial Nonlinear Optical Spectroscopy Beyond the Bulk Aqueous Contributions: The Case for Silica/Water Interface12Diagrammatic theory of linear and nonlinear optics for composite systems11Nanoscale Effects on the Surfactant Adsorption and Interface Charging in Hexadecane/Water Emulsions16Sum-frequency vibrational spectroscopy of methanol at interfaces due to Fermi resonance8Chemical Potential Driven Reorganization of Anions between Stern and Diffuse Layers at the Air/Water Interface20Protonation State of Dopamine Neurotransmitter at the Aqueous Interface: Vibrational Sum Frequency Generation Spectroscopy Study13Contact Ion Pair Formation Is Not Necessarily Stronger than Solvent Shared Ion Pairing23Spectral Phase Measurements of Heterodyne Detection in Interfacial Broadband Electronic Spectroscopy17Doubly Resonant Sum-Frequency Vibrational Spectroscopy of 1,1′-Bi-2-naphthol Chiral Solutions Due to the Nonadiabatic Effect1Ion Pairing and Molecular Orientation at Liquid/Liquid Interfaces: Self-Assembly and Function18Label‐Free Imaging of Membrane Potentials by Intramembrane Field Modulation, Assessed by Second Harmonic Generation Microscopy15Surface States for Photoelectrodes of Gallium Phosphide (GaP) with Surface-Specific Electronic Spectra and Phase Measurements15Water as a contrast agent to quantify surface chemistry and physics using second harmonic scattering and imaging: A perspective17The interfacial structure of super-concentration LiNO3 aqueous electrolyte studied by second harmonic generation4Phase-Sensitive Vibrational Sum and Difference Frequency-Generation Spectroscopy Enabling Nanometer-Depth Profiling at Interfaces24Ion Depletion in the Interfacial Microenvironment from Cell–Surface Interactions3Connecting Thermodynamics of Alkali Ion Exchange on the Quartz (101) Surface with Density Functional Theory Calculations4Surface Activity and Aggregation Behavior of Polyhydroxylated Fullerenes in Aqueous Solutions4Probing Interface of Perovskite Oxide Using Surface-Specific Terahertz Spectroscopy12Elucidation of the pH-Dependent Electric Double Layer Structure at the Silica/Water Interface Using Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy74Binding and Orientation of Carbamate Pesticides on Silica Surfaces8Revealing Silica’s pH-Dependent Second Harmonic Generation Response with Overcharging12Vibrational spectroscopy of geochemical interfaces25Structure evolution at the gate-tunable suspended graphene–water interface70Quantification of Stern Layer Water Molecules, Total Potentials, and Energy Densities at Fused Silica:Water Interfaces for Adsorbed Alkali Chlorides, CTAB, PFOA, and PFAS15Relating the phase in vibrational sum frequency spectroscopy and second harmonic generation with the maximum entropy method7Variations in Proton Transfer Pathways and Energetics on Pristine and Defect-Rich Quartz Surfaces in Water: Insights into the Bimodal Acidities of Quartz12Water Film Structure and Wettability of Different Quartz Surfaces: Hydrogen Bonding Across Various Cutting Planes22Charge Regulation at the Nanoscale as Evidenced from Light-Responsive Nanoemulsions12Variable-Angle Surface Spectroscopy Reveals the Water Structure in the Stern Layer at Charged Aqueous Interfaces19Spatial and Bidirectional Work Function Modulation of Monolayer Graphene with Patterned Polymer “Fluorozwitterists”3Phase of the second-order susceptibility in vibrational sum frequency generation spectroscopy: Origins, utility, and measurement techniques9Water-Mediated Proton Hopping Mechanisms at the SnO 2 (110)/H 2 O Interface from Ab Initio Deep Potential Molecular Dynamics30Flipping Water Orientation at the Surface of Water-in-Salt and Salt-in-Water Solutions8Imaging with a twist: Three-dimensional insights of the chiral nematic phase of cellulose nanocrystals via SHG microscopy17Ultrafast dynamics of two-dimensional electron gas at Al2O3/SrTiO3 interface studied by surface terahertz spectroscopy4Second harmonic generation null angle polarization analysis for determining interfacial potential at charged interfaces2Enhanced Anisotropic Second Harmonic Generation in Type-II van der Waals Heterostructures of g-C3N4/BiVO40Chemistry at Oxide/Water Interfaces: The Role of Interfacial Water18Sum-Frequency Generation Spectroscopy of Aqueous Interfaces: The Role of Depth and Its Impact on Spectral Interpretation36Sum-Frequency Generation Spectroscopy at Aqueous Electrochemical Interfaces12Composition, Structure Characteristics and Thermal Weight Loss Behavior of Three Kinds of Gasification Coarse Slags Based on Zhundong Coal0Electrostatics, Hydration, and Chemical Equilibria at Charged Monolayers on Water24Quantifying Stern layer water alignment before and during the oxygen evolution reaction30Water structure and electric fields at the interface of oil droplets177Temperature Dependence of Proton Coverage and the Total Potential at Fused Silica:Water Interfaces from Phase-Resolved Nonlinear Optics4

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