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RESEARCH PAPER · Inorganic Chemistry · 2015

Is Single-4-Ring the Most Basic but Elusive Secondary Building Unit That Transforms to Larger Structures in Zinc Phosphate Chemistry?

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Is Single-4-Ring the Most Basic but Elusive Secondary Building Unit That Transforms to Larger Structures in Zinc Phosphate Chemistry?OriginalOctanuclear Zinc Phosphates with Hitherto Unknown Cluster Architectures: Ancillary Ligand and Solvent Assisted Structural Transformations Thereof33Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units11A Solvent Switch for the Stabilization of Multiple Hemiacetals on an Inorganic Platform: Role of Supramolecular Interactions15Dimensionality Alteration and Intra- versus Inter-SBU Void Encapsulation in Zinc Phosphate Frameworks29Elusive Double-Eight-Ring Zeolitic Secondary Building Unit28Five different pseudo-polymorphs of 4-aminoarylphosphate: supramolecular aggregation in organophosphates15Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates11Delineating factors that dictate the framework of a bulky phosphate derived metal complexes: Sterics of phosphate, anion of the metal salt and auxiliary N-donor ligand12Complex Structural Landscape of Titanium Organophosphonates: Isolation of Structurally Related Ti4, Ti5, and Ti6 Species and Mechanistic Insights13Dinuclear Manganese(II), Cobalt(II), and Nickel(II) Aryl Phosphates Incorporating 4′‐Chloro‐2,2′:6′,2′′‐Terpyridine Coligands – Efficient Catalysts for Alcohol Oxidation28Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper $4^{\prime }$ 4 ′ -(N-methylpyridinium)- $2{,}2^{\prime }{:}6^{\prime }{,}2^{\prime \prime }$ 2 , 2 ′ : 6 ′ , 2 ″ terpyridine complexes7A [4+2] Condensation Strategy to Imine‐Linked Single‐Crystalline Zeolite‐Like Zinc Phosphate Frameworks21Thermolabile Organotitanium Monoalkyl Phosphates: Synthesis, Structures, and Utility as Epoxidation Catalysts and Single-Source Precursors for TiP2O716A rational synthesis of ladder-like motif in zinc-methylphosphonate from a preformed coordination assembly13Hitherto unknown eight-connected frameworks formed from A 4 B 4 O 12 metal organophosphate heterocubanes7Modulation of the nuclearity of molecular Mg( ii )-phosphates: solid-state structural change involving coordinating solvents3Molecular di- and tetra-nuclear zinc(II) phosphates with sterically hindered aryl phosphate mono esters ligands2Ceramic and porous framework metal silicates and phosphates from molecular precursors: an ever-evolving ambient synthesis approach16Discrete and Polymeric Cobalt Pyrophosphates Derived from Pyrophosphoric Acid Diester Ar2H2P2O75Dinuclear group 12 metal phosphates bridged by hexadentate 2,3,5,6-tetra(2-pyridyl)-pyrazine and their supramolecular organization5Structural Features of 1,3,4-Thiadiazole-Derived Ligands and Their Zn(II) and Cu(II) Complexes Which Demonstrate Synergistic Antibacterial Effects with Kanamycin54Cyclic zinc organophosphate based expanded ditopic N,N′-metalloligands1Studies on the Genesis and Proton Conductivity of Imidazole-Based Linear and Open-Framework Zinc Phosphites11Exploration of Solid-State vs Solution-State Structure in Contact Ion Pair Systems: Synthesis, Characterization, and Solution-State Dynamics of Zinc Diphenyl Phosphate, [Zn{O2P(OPh)2}2], Donor-Base-Supported Complexes8

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  1. Octanuclear Zinc Phosphates with Hitherto Unknown Cluster Architectures: Ancillary Ligand and Solvent Assisted Structural Transformations Thereof

    Inorganic Chemistry · 2015-09-14

    Aijaz A. Dar, Saumik Sen, Sandeep K. Gupta, G. Naresh Patwari, Ramaswamy Murugavel

    Read original paper ↗ ·
  2. Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units

    Dalton Transactions · 2016-01-01

    Małgorzata Wolska‐Pietkiewicz, Adam Świerkosz, Iwona Justyniak, Agnieszka Grala, Kamil Sokołowski, Janusz Lewiński

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  3. A Solvent Switch for the Stabilization of Multiple Hemiacetals on an Inorganic Platform: Role of Supramolecular Interactions

    Chemistry - A European Journal · 2016-04-08

    Alok Ch. Kalita, Sandeep K. Gupta, Ramaswamy Murugavel

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  4. Dimensionality Alteration and Intra- versus Inter-SBU Void Encapsulation in Zinc Phosphate Frameworks

    Inorganic Chemistry · 2016-05-09

    Aijaz Ahmad Dar, Gulzar Ahmad Bhat, Ramaswamy Murugavel

    Read original paper ↗ ·
  5. Elusive Double-Eight-Ring Zeolitic Secondary Building Unit

    Journal of the American Chemical Society · 2016-12-17

    Sandeep K. Gupta, Alok Ch. Kalita, Aijaz A. Dar, Saumik Sen, G. Naresh Patwari, Ramaswamy Murugavel

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  6. Five different pseudo-polymorphs of 4-aminoarylphosphate: supramolecular aggregation in organophosphates

    CrystEngComm · 2017-01-01

    Kamna Sharma, Alok Ch. Kalita, Ramaswamy Murugavel

    Read original paper ↗ ·
  7. Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates

    CrystEngComm · 2017-01-01

    Gulzar Ahmad Bhat, Alok Ch. Kalita, Ramaswamy Murugavel

    Read original paper ↗ ·
  8. Delineating factors that dictate the framework of a bulky phosphate derived metal complexes: Sterics of phosphate, anion of the metal salt and auxiliary N-donor ligand

    Inorganica Chimica Acta · 2017-08-17

    Priya Saxena, Shyam Kumar Mandal, Kamna Sharma, Ramaswamy Murugavel

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  9. Complex Structural Landscape of Titanium Organophosphonates: Isolation of Structurally Related Ti4, Ti5, and Ti6 Species and Mechanistic Insights

    Inorganic Chemistry · 2017-10-20

    Kamna Sharma, Antony Rajendran, Alok Ch. Kalita, Sandeep K. Gupta, Paul Davis, Ramaswamy Murugavel

    Read original paper ↗ ·
  10. Dinuclear Manganese(II), Cobalt(II), and Nickel(II) Aryl Phosphates Incorporating 4′‐Chloro‐2,2′:6′,2′′‐Terpyridine Coligands – Efficient Catalysts for Alcohol Oxidation

    European Journal of Inorganic Chemistry · 2017-11-29

    Gulzar Ahmad Bhat, Antony Rajendran, Ramaswamy Murugavel

    Read original paper ↗ ·
  11. Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper $$4^{\prime }$$ 4 ′ -(N-methylpyridinium)- $$2{,}2^{\prime }{:}6^{\prime }{,}2^{\prime \prime }$$ 2 , 2 ′ : 6 ′ , 2 ″ terpyridine complexes

    Journal of Chemical Sciences · 2018-02-01

    Gulzar Ahmad Bhat, Raihana Maqbool, Ramaswamy Murugavel

    Read original paper ↗ ·
  12. A [4+2] Condensation Strategy to Imine‐Linked Single‐Crystalline Zeolite‐Like Zinc Phosphate Frameworks

    Chemistry - A European Journal · 2018-03-22

    Ritambhara Jangir, Alok Ch. Kalita, Dhananjayan Kaleeswaran, Sandeep K. Gupta, Ramaswamy Murugavel

    Read original paper ↗ ·
  13. Thermolabile Organotitanium Monoalkyl Phosphates: Synthesis, Structures, and Utility as Epoxidation Catalysts and Single-Source Precursors for TiP2O7

    Inorganic Chemistry · 2018-06-15

    Gulzar Ahmad Bhat, Sonam Verma, Antony Rajendran, Ramaswamy Murugavel

    Read original paper ↗ ·
  14. A rational synthesis of ladder-like motif in zinc-methylphosphonate from a preformed coordination assembly

    Inorganica Chimica Acta · 2018-07-10

    Ravi Shankar, Swati Mendiratta, Ekta Jakhar, Rohit Singh, Amanpreet Kaur Jassal, Gabriele I. Kociok-Köhn

    Read original paper ↗ ·
  15. Hitherto unknown eight-connected frameworks formed from A 4 B 4 O 12 metal organophosphate heterocubanes

    Chemical Communications · 2019-01-01

    Kamna Sharma, Sandeep K. Gupta, Aditya Borah, Ramaswamy Murugavel

    Read original paper ↗ ·
  16. Modulation of the nuclearity of molecular Mg( ii )-phosphates: solid-state structural change involving coordinating solvents

    Dalton Transactions · 2019-01-01

    Biswajit Santra, Ramakirushnan Suriya Narayanan, Pankaj Kalita, Vierandra Kumar, Debdeep Mandal, Vivek Gupta, Michael Zimmer, Volker Hüch, Vadapalli Chandrasekhar, David Scheschkewitz, Carola Schulzke, Anukul Jana

    Read original paper ↗ ·
  17. Molecular di- and tetra-nuclear zinc(II) phosphates with sterically hindered aryl phosphate mono esters ligands

    Polyhedron · 2019-06-20

    Biswajit Santra, Vierandra Kumar, Pankaj Kalita, Vivek Gupta, Debdeep Mandal, Amitava Chandra, Mayank Joshi, Angshuman Roy Choudhury, Anukul Jana, Vadapalli Chandrasekhar

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  18. Ceramic and porous framework metal silicates and phosphates from molecular precursors: an ever-evolving ambient synthesis approach

    Emergent Materials · 2019-09-01

    Ramaswamy Murugavel

    Read original paper ↗ ·
  19. Discrete and Polymeric Cobalt Pyrophosphates Derived from Pyrophosphoric Acid Diester Ar2H2P2O7

    European Journal of Inorganic Chemistry · 2020-05-26

    Kamna Sharma, Sandeep K. Gupta, Ramaswamy Murugavel

    Read original paper ↗ ·
  20. Dinuclear group 12 metal phosphates bridged by hexadentate 2,3,5,6-tetra(2-pyridyl)-pyrazine and their supramolecular organization

    Journal of Molecular Structure · 2020-07-25

    Gulzar Ahmad Bhat, Ramaswamy Murugavel

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  21. Structural Features of 1,3,4-Thiadiazole-Derived Ligands and Their Zn(II) and Cu(II) Complexes Which Demonstrate Synergistic Antibacterial Effects with Kanamycin

    International Journal of Molecular Sciences · 2020-08-10

    Dariusz Karcz, Arkadiusz Paweł Matwijczuk, Daniel M. Kamiński, Bernadette Sarah Creaven, Ewa Ciszkowicz, Katarzyna Lecka-Szlachta, Karolina Starzak

    Read original paper ↗ ·
  22. Cyclic zinc organophosphate based expanded ditopic N,N′-metalloligands

    Journal of Chemical Sciences · 2020-09-08

    Gulzar Ahmad Bhat, Ramaswamy Murugavel

    Read original paper ↗ ·
  23. Studies on the Genesis and Proton Conductivity of Imidazole-Based Linear and Open-Framework Zinc Phosphites

    Inorganic Chemistry · 2021-04-16

    Ravi Shankar, Ekta Jakhar, Archishmati Dubey, Priyanka Chauhan, Pankaj Tiwari, Suddhasatwa Basu

    Read original paper ↗ ·
  24. Exploration of Solid-State vs Solution-State Structure in Contact Ion Pair Systems: Synthesis, Characterization, and Solution-State Dynamics of Zinc Diphenyl Phosphate, [Zn{O2P(OPh)2}2], Donor-Base-Supported Complexes

    Inorganic Chemistry · 2023-03-14

    Andrew J. Straiton, James D. Parish, Joshua J. Smith, John P. Lowe, Andrew L. Johnson

    Read original paper ↗ ·