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RESEARCH PAPER · Journal of Power Sources · 2016

A comparative study on electrochemical cycling stability of lithium rich layered cathode materials Li 1.2 Ni 0.13 M 0.13 Mn 0.54 O 2 where M = Fe or Co

C.P. Laisa, A.K. Nanda Kumar, S. Selva Chandrasekaran, P. Murugan, Narayanan Lakshminarasimhan, Ramanujan Govindaraj, Kannadka Ramesha

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A comparative study on electrochemical cycling stability of lithium rich layered cathode materials Li 1.2 Ni 0.13 M 0.13 Mn 0.54 O 2 where M = Fe or CoOriginalIrregular micro-sized Li1.2Mn0.54Ni0.13Co0.13O2 particles as cathode material with a high volumetric capacity for Li-ion batteries24New insights into low temperature properties of Li-rich layered cathode materials24Synthesis and characterization of Fe-doped vanadium oxide nanorods and their electrochemical performance34Improving Electrochemical Stability by Transition Metal Cation Doping for Manganese in Lithium-rich Layered Cathode, Li 1.2 Ni 0.13 Co 0.13 Mn 0.54-x M x O 2 (M = Co, Cr and Fe)44Structural and electrochemical properties of iron- and nickel-substituted Li 2 MnO 3 cathodes in charged and discharged states18Effect of Aluminum Doping on the Stability of Lithium-Rich Layered Oxide Li[Li0.23Ni0.15Mn0.52Al0.10]O2 as Cathode Material15Enhanced electrochemical performance of lithium rich layered cathode materials by Ca2+ substitution52A Convenient Synthesis Route for Co3O4 Hollow Microspheres and Their Application as a High Performing Anode in Li-Ion Batteries21Role of transition metals in a charge transfer mechanism and oxygen removal in Li 1.17 Ni 0.17 Mn 0.5 Co 0.17 O 2 : experimental and first-principles analysis8Electrochemical activation, voltage decay and hysteresis of Li-rich layered cathode probed by various cobalt content48Improving rate performance of cathode material Li1.2Mn0.54Co0.13Ni0.13O2 via niobium doping17Influence of Li substitution on the structure and electrochemical performance of P2-type Na0.67Ni0.2Fe0.15Mn0.65O2 cathode materials for sodium ion batteries37Optimizing the Structural Evolution of Li-Rich Oxide Cathode Materials via Microwave-Assisted Pre-Activation33Co-regulating the surface and bulk structure of Li-rich layered oxides by a phosphor doping strategy for high-energy Li-ion batteries79Li/Fe substitution in Li-rich Ni, Co, Mn oxides for enhanced electrochemical performance as cathode materials43A Cobalt‐Free Li(Li0.16Ni0.19Fe0.18Mn0.46)O2 Cathode for Lithium‐Ion Batteries with Anionic Redox Reactions28A Cobalt‐Free Li(Li0.17Ni0.17Fe0.17Mn0.49)O2 Cathode with More Oxygen‐Involving Charge Compensation for Lithium‐Ion Batteries25Improving the electrochemical properties of Mn-rich Li1.20[Mn0.54Ni0.13Co0.13]O2 by Nb and F co-doping20Towards improved structural stability and electrochemical properties of a Li-rich material by a strategy of double gradient surface modification67Oxygen Release Degradation in Li‐Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches532Surface modification using Sm-oxide of Fe- and Ni-substituted Li2MnO3 cathodes9In situ thermally reduced graphene oxide enhancing lithium storage of 0.3Li2MnO3•0.7LiNi1/3Co1/3Mn1/3O2 cathode material4Elucidating the Effect of Iron Doping on the Electrochemical Performance of Cobalt‐Free Lithium‐Rich Layered Cathode Materials135AxIrO3 (A = Li, Na or H) for the electrochemical storage and conversion of energy0Co-Free Layered Cathode Materials for High Energy Density Lithium-Ion Batteries176Morphology and Interconnected Microstructure-Driven High-Rate Capability of Li-Rich Layered Oxide Cathodes17Inhibition of transition metals dissolution in cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte281Flower-like hierarchical Li1.2Ni0.13Co0.13Mn0.54O2 by architectural design for lithium-ion batteries with superior capacity retention1Reducing Capacity and Voltage Decay of Co‐Free Li1.2Ni0.2Mn0.6O2 as Positive Electrode Material for Lithium Batteries Employing an Ionic Liquid‐Based Electrolyte70Effects of chelators on the structure and electrochemical properties of Li-rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials12Roles of Mn and Ni in Li-rich Mn-Ni-Fe oxide cathodes2Enhancing the electrochemical performance of Li-rich cathode material by a flexible precursor treatment method4Synergistic effect of bulk phase doping and layered-spinel structure formation on improving electrochemical performance of Li-Rich cathode material20Enhanced electrochemical performances of cerium-doped Li-Rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials49Charge Compensation Mechanism and Structural Change of Li-Rich Layered Oxide Li 1.23 Mn 0.46 Fe 0.15 Ni 0.15 O 2 Electrode during Charging and Discharging5Direct Observation of Reductive Coupling Mechanism between Oxygen and Iron/Nickel in Cobalt‐Free Li‐Rich Cathode Material: An in Operando X‐Ray Absorption Spectroscopy Study42Superior Rate Capability and Cycling Stability in Partially Cation-Disordered Co-Free Li-Rich Layered Materials Enabled by an Initial Activation Process13Understanding Li roles in chemical reversibility of O2-type Li-rich layered cathode materials40Valence Effects of Fe Impurity for Recovered LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode Materials32Revealing the Thermodynamics and Kinetics of In-Plane Disordered Li2MnO3 Structure in Li-Rich Cathodes81Sb@Ni6 Superstructure Units Stabilize Li-Rich Layered Cathode in the Wide Voltage Window10Cobalt‐Free Cathode Materials: Families and their Prospects208Correlating the initial gas evolution and structural changes to cycling performance of Co-free Li-rich layered oxide cathode29Modulating the Voltage Decay and Cationic Redox Kinetics of Li‐Rich Cathodes via Controlling the Local Electronic Structure48Combination of Li-rich layered-oxide with O2 cathodes for high-energy Li-ion/Li-O2 hybrid batteries7Cycling-Driven Electrochemical Activation of Li-Rich NMC Positive Electrodes for Li-Ion Batteries53Recent progress in Mn and Fe-rich cathode materials used in Li-ion batteries82Enhanced cathode materials for advanced lithium-ion batteries using nickel-rich and lithium/manganese-rich LiNi Mn Co O228Formation of Rocksalt Domains by Dual Substitution to Boost Electrochemical Capability of Co-Free Li-Rich Layered Cathodes17Revealing Li-ion diffusion kinetic limitations in micron-sized Li-rich layered oxides106Understanding and Control of Activation Process of Lithium-Rich Cathode Materials59Limiting voltage and capacity fade of lithium-rich, low cobalt Li 1.2 Ni 0.13 Mn 0.54 Fe 0.1 Co 0.03 O 2 by controlling the upper cut-off voltage7Li-Rich Layered Oxides: Structure and Doping Strategies to Enable Co-Poor/Co-Free Cathodes for Li-Ion Batteries18First-Principles Study of the Doping Effect in Half Delithiated LiNiO2 Cathodes8Optimized synthesis conditions and electrochemical performances for novel quaternary cobalt-free spherical cathodes2Impact of Synthesis Chelation on the Crystallography and Capacity of Li-Rich Li1.2Ni0.13Mn0.54Fe0.13O2 Cathode Particles2Lattice Oxygen Redox Reversibility Modulation in Enhancing the Cycling Stability of Li‐Rich Cathode Materials79Correlating concerted cations with oxygen redox in rechargeable batteries41Highly structural stability from small-sized Li2MnO3-like domains in Co-free Li-rich layered oxide cathodes3Cobalt-free spinel–layered structurally integrated Li0.8Mn0.64Ni0.183Fe0.091O2 cathodes for lithium-ion batteries5Operating-temperature Dependence of the Average and Electronic Structures of 0.4Li2MnO3–0.6Li(Mn1/3Ni1/3Co1/3)O20Surface Oxygen Vacancy Modulation of Nanostructured Li-Rich Mn-Based Oxides for Lithium-Ion Batteries5Synthesis of PO43−-doped hierarchical microsphere Li1.1Mn0.55Ni0.3Co0.05O2 by the solvothermal-molten salt method for enhanced lithium storage performance1Achieving Reversible Anionic Redox via Homogeneous Transition Metal‐Oxygen Coordination in Li‐Rich Layered Oxides2Pre-Disordering for Preserving Transition Metal–Oxygen Covalency in Lithium-Rich Layered Oxide Cathodes3Mechanism study of Fe penetration behavior on structural stability of lithium-rich layered co-free cathode materials0Bipolar selenium doping mitigates the lattice oxygen loss in O2-type Li-rich Mn-based layered cathode materials0Correlation between Fe/Mn/Ni Ratio and Structural Properties in P2-Na2/3Mn2/3Fe1/3– x Ni x O2 ( x = 0, 0.02, 0.05, 0.1, and 1/3)0

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  1. Irregular micro-sized Li1.2Mn0.54Ni0.13Co0.13O2 particles as cathode material with a high volumetric capacity for Li-ion batteries

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  2. New insights into low temperature properties of Li-rich layered cathode materials

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  3. Synthesis and characterization of Fe-doped vanadium oxide nanorods and their electrochemical performance

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  4. Improving Electrochemical Stability by Transition Metal Cation Doping for Manganese in Lithium-rich Layered Cathode, Li 1.2 Ni 0.13 Co 0.13 Mn 0.54-x M x O 2 (M = Co, Cr and Fe)

    Electrochimica Acta · 2017-08-09

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  5. Structural and electrochemical properties of iron- and nickel-substituted Li 2 MnO 3 cathodes in charged and discharged states

    Journal of Power Sources · 2017-08-30

    Ryota Yuge, Sadanori Kuroshima, Akio Toda, Takashi Miyazaki, Mitsuharu Tabuchi, Kyosuke Doumae, Hideka Shibuya, Noriyuki Tamura

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  6. Effect of Aluminum Doping on the Stability of Lithium-Rich Layered Oxide Li[Li0.23Ni0.15Mn0.52Al0.10]O2 as Cathode Material

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    Yunpeng Zhang, Er-Qian Liang, Jin-Xia Wang, Baojun Yu, Chengyang Wang, Mingwei Li

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  7. Enhanced electrochemical performance of lithium rich layered cathode materials by Ca2+ substitution

    Electrochimica Acta · 2017-10-11

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  8. A Convenient Synthesis Route for Co3O4 Hollow Microspheres and Their Application as a High Performing Anode in Li-Ion Batteries

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  9. Role of transition metals in a charge transfer mechanism and oxygen removal in Li 1.17 Ni 0.17 Mn 0.5 Co 0.17 O 2 : experimental and first-principles analysis

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  10. Electrochemical activation, voltage decay and hysteresis of Li-rich layered cathode probed by various cobalt content

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  11. Improving rate performance of cathode material Li1.2Mn0.54Co0.13Ni0.13O2 via niobium doping

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  12. Influence of Li substitution on the structure and electrochemical performance of P2-type Na0.67Ni0.2Fe0.15Mn0.65O2 cathode materials for sodium ion batteries

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  13. Optimizing the Structural Evolution of Li-Rich Oxide Cathode Materials via Microwave-Assisted Pre-Activation

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  14. Co-regulating the surface and bulk structure of Li-rich layered oxides by a phosphor doping strategy for high-energy Li-ion batteries

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  15. Li/Fe substitution in Li-rich Ni, Co, Mn oxides for enhanced electrochemical performance as cathode materials

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  16. A Cobalt‐Free Li(Li0.16Ni0.19Fe0.18Mn0.46)O2 Cathode for Lithium‐Ion Batteries with Anionic Redox Reactions

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  17. A Cobalt‐Free Li(Li0.17Ni0.17Fe0.17Mn0.49)O2 Cathode with More Oxygen‐Involving Charge Compensation for Lithium‐Ion Batteries

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  18. Improving the electrochemical properties of Mn-rich Li1.20[Mn0.54Ni0.13Co0.13]O2 by Nb and F co-doping

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  19. Towards improved structural stability and electrochemical properties of a Li-rich material by a strategy of double gradient surface modification

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  20. Oxygen Release Degradation in Li‐Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches

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  21. Surface modification using Sm-oxide of Fe- and Ni-substituted Li2MnO3 cathodes

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  22. In situ thermally reduced graphene oxide enhancing lithium storage of 0.3Li2MnO3•0.7LiNi1/3Co1/3Mn1/3O2 cathode material

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  23. Elucidating the Effect of Iron Doping on the Electrochemical Performance of Cobalt‐Free Lithium‐Rich Layered Cathode Materials

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  24. AxIrO3 (A = Li, Na or H) for the electrochemical storage and conversion of energy

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  26. Morphology and Interconnected Microstructure-Driven High-Rate Capability of Li-Rich Layered Oxide Cathodes

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  27. Inhibition of transition metals dissolution in cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte

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  30. Effects of chelators on the structure and electrochemical properties of Li-rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials

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  31. Roles of Mn and Ni in Li-rich Mn-Ni-Fe oxide cathodes

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  32. Enhancing the electrochemical performance of Li-rich cathode material by a flexible precursor treatment method

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  33. Synergistic effect of bulk phase doping and layered-spinel structure formation on improving electrochemical performance of Li-Rich cathode material

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  34. Enhanced electrochemical performances of cerium-doped Li-Rich Li1.2Ni0.13Co0.13Mn0.54O2 cathode materials

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  35. Charge Compensation Mechanism and Structural Change of Li-Rich Layered Oxide Li 1.23 Mn 0.46 Fe 0.15 Ni 0.15 O 2 Electrode during Charging and Discharging

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  38. Understanding Li roles in chemical reversibility of O2-type Li-rich layered cathode materials

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  43. Correlating the initial gas evolution and structural changes to cycling performance of Co-free Li-rich layered oxide cathode

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  44. Modulating the Voltage Decay and Cationic Redox Kinetics of Li‐Rich Cathodes via Controlling the Local Electronic Structure

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  46. Cycling-Driven Electrochemical Activation of Li-Rich NMC Positive Electrodes for Li-Ion Batteries

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  47. Recent progress in Mn and Fe-rich cathode materials used in Li-ion batteries

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  48. Enhanced cathode materials for advanced lithium-ion batteries using nickel-rich and lithium/manganese-rich LiNi Mn Co O2

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  49. Formation of Rocksalt Domains by Dual Substitution to Boost Electrochemical Capability of Co-Free Li-Rich Layered Cathodes

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  50. Revealing Li-ion diffusion kinetic limitations in micron-sized Li-rich layered oxides

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