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RESEARCH PAPER · AIP Advances · 2016

Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides

Yuanyuan Li, Olga Kraynis, Joshua J. Kas, Tsu‐Chien Weng, Dimosthenis Sokaras, Renee Zacharowicz, Igor Lubomirsky, Anatoly I. Frenkel

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Geometry of electromechanically active structures in Gadolinium - doped Cerium oxidesOriginalUNDERSTANDING OXYGEN VACANCY FORMATION, INTERACTION, TRANSPORT, AND STRAIN IN SOFC COMPONENTS VIA COMBINED THERMODYNAMICS AND FIRST PRINCIPLES CALCULATIONS1Electromechanical properties of electrostrictive CeO2:Gd membranes: Effects of frequency and temperature23Relaxation and saturation of electrostriction in 10 mol% Gd-doped ceria ceramics70Anisotropic chemical strain in cubic ceria due to oxygen-vacancy-induced elastic dipoles50Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode8Towards the surface hydroxyl species in CeO 2 nanoparticles74Suitability of Raman Spectroscopy for Assessing Anisotropic Strain in Thin Films of Doped Ceria16Coordination Numbers in Sm-Doped Ceria Using X-ray Absorption Spectroscopy19A computational study of gadolinium-doped ceria: Relationship between atomic arrangement and electrostriction9Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties60Modeling Strain Distribution at the Atomic Level in Doped Ceria Films with Extended X-ray Absorption Fine Structure Spectroscopy44Enhanced electro-mechanical coupling of TiN/Ce0.8Gd0.2O1.9 thin film electrostrictor22A review of defect structure and chemistry in ceria and its solid solutions627Electro-chemo-mechanical effect in Gd-doped ceria thin films with a controlled orientation34Electromechanical dopant–defect interaction in acceptor-doped ceria26Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles202Electrostrictive Ceramics and Their Applications11Enhanced Electromechanical Response in Sm and Nd Co-doped Ceria23Enhanced Electromechanical Response in Defective Sm and Nd Co-doped Ceria0Dopant Concentration Controls Quasi-Static Electrostrictive Strain Response of Ceria Ceramics31Electromechanically active pair dynamics in a Gd-doped ceria single crystal16Gigantic electro-chemo-mechanical properties of nanostructured praseodymium doped ceria13Trivalent Dopant Size Influences Electrostrictive Strain in Ceria Solid Solutions25High energy resolution X-ray spectroscopy of f-electron systems0Non‐Classical Electrostriction in Hydrated Acceptor Doped BaZrO3: Proton Trapping and Dopant Size Effect27Active sites of atomically dispersed Pt supported on Gd-doped ceria with improved low temperature performance for CO oxidation15The elastic component of anisotropic strain dominates the observed shift in the F 2g Raman mode of anelastic ceria thin films5The role of dopant on the defect chemistry of metal oxides4From Molecular Oxo-Hydroxo Ce Clusters to Crystalline CeO 223Lead-free Zr-doped ceria ceramics with low permittivity displaying giant electrostriction28Elastic Dipole Alignment is the Origin of Anelasticity and Electrostriction in Aliovalent-Doped Ceria2Non-classical electrostriction in calcium-doped cerium oxide ceramics11Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics6Electronic‐Structure Interpretation: How Much Do We Understand Ce L3 XANES?33Correlated Displacement of Dynamic Elastic Dipoles Produces Nonclassical Electrostriction in Zr-Doped Ceria6Oxygen-defective electrostrictors for soft electromechanics13Electromechanical coupling in alkaline-earth doped-ceria ceramics12Enhanced non-classical electrostriction in strained tetragonal ceria8Determination of Local Structural and Dynamic Descriptors in Doped Oxides: The Case of Zr-Doped Ceria, a Non-Classical Electrostrictor4Dynamic Features of Cu-Ceria Interface under CO 2 Hydrogenation to Methanol5Applicability of the small anharmonicity approximation to electrostriction in Zr-doped ceria0

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  1. UNDERSTANDING OXYGEN VACANCY FORMATION, INTERACTION, TRANSPORT, AND STRAIN IN SOFC COMPONENTS VIA COMBINED THERMODYNAMICS AND FIRST PRINCIPLES CALCULATIONS

    PhDT · 2017-01-01

    Tridip Das

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  2. Electromechanical properties of electrostrictive CeO2:Gd membranes: Effects of frequency and temperature

    Applied Physics Letters · 2017-04-03

    Andrei D. Ushakov, Eran Mishuk, Evgeniy Makagon, Denis Alikin, Alexander A. Esin, Ivan S. Baturin, Alexander Tselev, V. Ya. Shur, Igor Lubomirsky, Andréi L. Kholkin

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  3. Relaxation and saturation of electrostriction in 10 mol% Gd-doped ceria ceramics

    Acta Materialia · 2017-10-30

    Nimrod Yavo, Ori Yeheskel, Ellen J. Wachtel, David Ehre, Anatoly I. Frenkel, Igor Lubomirsky

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  4. Anisotropic chemical strain in cubic ceria due to oxygen-vacancy-induced elastic dipoles

    Physical Chemistry Chemical Physics · 2018-01-01

    Tridip Das, Jason D. Nicholas, Brian W. Sheldon, Yue Qi

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  5. Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode

    Review of Scientific Instruments · 2018-04-01

    Harishchandra Singh, D. Donetsky, Jinghe Liu, Klaus Attenkofer, Bin Cheng, Jason R. Trelewicz, Igor Lubomirsky, Eli Stavitski, Anatoly I. Frenkel

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  6. Towards the surface hydroxyl species in CeO 2 nanoparticles

    Nanoscale · 2019-01-01

    Tatiana V. Plakhova, Anna Yu. Romanchuk, Sergei M. Butorin, Anastasia D. Konyukhova, Alexander V. Egorov, Andrei A. Shiryaev, Alexander E. Baranchikov, Павел В. Дороватовский, Thomas Huthwelker, Evgeny Gerber, Stephen Bauters, Madina M. Sozarukova, Andreas C. Scheinost, Vladimir K. Ivanov, Stepan Nikolaevich Kalmykov, Kristina O. Kvashnina

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  7. Suitability of Raman Spectroscopy for Assessing Anisotropic Strain in Thin Films of Doped Ceria

    Advanced Functional Materials · 2019-01-04

    Olga Kraynis, Evgeniy Makagon, Eran Mishuk, Michal Hartstein, Ellen J. Wachtel, Igor Lubomirsky, Tsachi Livneh

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  8. Coordination Numbers in Sm-Doped Ceria Using X-ray Absorption Spectroscopy

    The Journal of Physical Chemistry C · 2019-03-13

    Julius Koettgen, Manfred Martin

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  9. A computational study of gadolinium-doped ceria: Relationship between atomic arrangement and electrostriction

    APL Materials · 2019-04-01

    Maor Asher, Oswaldo Diéguez

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  10. Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties

    Acta Materialia · 2019-05-09

    Ahsanul Kabir, Simone Santucci, Ngo Van Nong, Maxim Varenik, Igor Lubomirsky, Robin Nigon, Paul Muralt, Vincenzo Esposito

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  11. Modeling Strain Distribution at the Atomic Level in Doped Ceria Films with Extended X-ray Absorption Fine Structure Spectroscopy

    Inorganic Chemistry · 2019-05-15

    Olga Kraynis, Janis Timoshenko, Jiahao Huang, Harishchandra Singh, Ellen J. Wachtel, Anatoly I. Frenkel, Igor Lubomirsky

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  12. Enhanced electro-mechanical coupling of TiN/Ce0.8Gd0.2O1.9 thin film electrostrictor

    APL Materials · 2019-07-01

    Simone Santucci, Haiwu Zhang, Simone Sanna, Nini Pryds, Vincenzo Esposito

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  13. A review of defect structure and chemistry in ceria and its solid solutions

    Chemical Society Reviews · 2019-12-24

    Rafael Schmitt, Andreas Nenning, Olga Kraynis, Roman Korobko, Anatoly I. Frenkel, Igor Lubomirsky, Sossina Mariam Haile, Jennifer L. M. Rupp

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  14. Electro-chemo-mechanical effect in Gd-doped ceria thin films with a controlled orientation

    Journal of Materials Chemistry A · 2020-01-01

    Simone Santucci, Haiwu Zhang, Simone Sanna, Nini Pryds, Vincenzo Esposito

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  15. Electromechanical dopant–defect interaction in acceptor-doped ceria

    Materials Advances · 2020-01-01

    Ahsanul Kabir, Victor Buratto Tinti, Maxim Varenik, Igor Lubomirsky, Vincenzo Esposito

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  16. Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles

    Inorganic Chemistry · 2020-04-01

    Damien Prieur, Walter Bonani, Karin Popa, Olaf Walter, Kyle W. Kriegsman, Mark Engelhard, Xiaofeng Guo, R. Eloirdi, T. Gouder, Aaron Beck, Tonya Vitova, Andreas C. Scheinost, Kristina O. Kvashnina, P. Martín

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  17. Electrostrictive Ceramics and Their Applications

    Elsevier eBooks · 2020-04-15

    Simone Santucci, Vincenzo Esposito

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  18. Enhanced Electromechanical Response in Sm and Nd Co-doped Ceria

    Materialia · 2020-05-20

    Ahsanul Kabir, Jacob R. Bowen, Maxim Varenik, Igor Lubomirsky, Vincenzo Esposito

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  19. Enhanced Electromechanical Response in Defective Sm and Nd Co-doped Ceria

    arXiv (Cornell University) · 2020-06-16

    Ahsanul Kabir, Jacob R. Bowen, Maxim Varenik, Igor Lubomirsky, Vincenzo Esposito

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  20. Dopant Concentration Controls Quasi-Static Electrostrictive Strain Response of Ceria Ceramics

    ACS Applied Materials & Interfaces · 2020-07-23

    Maxim Varenik, Juan C. Nino, Ellen J. Wachtel, Sangtae Kim, Ori Yeheskel, Nimrod Yavo, Igor Lubomirsky

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  21. Electromechanically active pair dynamics in a Gd-doped ceria single crystal

    Physical Chemistry Chemical Physics · 2021-01-01

    Simone Santucci, Haiwu Zhang, Ahsanul Kabir, Carlo Marini, Simone Sanna, Jyn Kyu Han, Gregor Ulbrich, Eva M. Heppke, Ivano E. Castelli, Vincenzo Esposito

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  22. Gigantic electro-chemo-mechanical properties of nanostructured praseodymium doped ceria

    Nanoscale · 2021-01-01

    Victor Buratto Tinti, Ahsanul Kabir, Jin Kyu Han, Sebastian Molin, Vincenzo Esposito

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  23. Trivalent Dopant Size Influences Electrostrictive Strain in Ceria Solid Solutions

    ACS Applied Materials & Interfaces · 2021-04-22

    Maxim Varenik, Juan C. Nino, Ellen J. Wachtel, Sangtae Kim, Sidney Cohen, Igor Lubomirsky

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  24. High energy resolution X-ray spectroscopy of f-electron systems

    Unknown journal · 2021-09-10

    Evgeny Gerber

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  25. Non‐Classical Electrostriction in Hydrated Acceptor Doped BaZrO3: Proton Trapping and Dopant Size Effect

    Advanced Functional Materials · 2021-09-12

    Evgeniy Makagon, Olga Kraynis, Rotraut Merkle, Joachim Maier, Igor Lubomirsky

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  26. Active sites of atomically dispersed Pt supported on Gd-doped ceria with improved low temperature performance for CO oxidation

    Chemical Science · 2023-01-01

    Yuanyuan Li, Haodong Wang, Haohong Song, Ning Rui, Matthew A. Kottwitz, Sanjaya D. Senanayake, Ralph G. Nuzzo, Zili Wu, De‐en Jiang, Anatoly I. Frenkel

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  27. The elastic component of anisotropic strain dominates the observed shift in the F 2g Raman mode of anelastic ceria thin films

    Physical Chemistry Chemical Physics · 2023-01-01

    Daniel Freidzon, Olga Kraynis, Ellen J. Wachtel, Igor Lubomirsky, Tsachi Livneh

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  28. The role of dopant on the defect chemistry of metal oxides

    Elsevier eBooks · 2023-01-01

    Victor Buratto Tinti, Ahsanul Kabir, Daniel Zanetti de Florio, Vincenzo Esposito

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  29. From Molecular Oxo-Hydroxo Ce Clusters to Crystalline CeO 2

    Chemistry of Materials · 2023-02-13

    Paul Estevenon, Lucia Amidani, Stephen Bauters, Christelle Tamain, Michael Bodensteiner, Florian Meurer, Christoph Hennig, G. Vaughan, Thomas Dumas, Kristina O. Kvashnina

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  30. Lead-free Zr-doped ceria ceramics with low permittivity displaying giant electrostriction

    Nature Communications · 2023-11-15

    Maxim Varenik, Boyuan Xu, Junying Li, Elad Gaver, Ellen J. Wachtel, David Ehre, Prahlad Kumar Routh, Sergey Khodorov, Anatoly I. Frenkel, Yue Qi, Igor Lubomirsky

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  31. Elastic Dipole Alignment is the Origin of Anelasticity and Electrostriction in Aliovalent-Doped Ceria

    Acta Materialia · 2024-01-01

    Anna Lavie, Boyuan Xu, Sergey Khodorov, Harishchandra Singh, Jinghe Liu, Tal-El Hajbi, Ellen J. Wachtel, Yishay Feldman, David Ehre, Dmitri Donetski, Anatoly I. Frenkel, Yue Qi, Igor Lubomirsky

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  32. Non-classical electrostriction in calcium-doped cerium oxide ceramics

    Journal of Materials Chemistry A · 2024-01-01

    Ahsanul Kabir, Victor Buratto Tinti, Simone Santucci, Maxim Varenik, Samuel Griffiths, Sebastian Molin, Igor Lubomirsky, Vincenzo Esposito

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  33. Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics

    ACS Applied Materials & Interfaces · 2024-03-01

    Ahsanul Kabir, Bartłomiej Lemieszek, Maxim Varenik, Victor Buratto Tinti, Sebastian Molin, Igor Lubomirsky, Vincenzo Esposito, Frank Kern

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  34. Electronic‐Structure Interpretation: How Much Do We Understand Ce L3 XANES?

    Chemistry - A European Journal · 2024-06-11

    Kristina O. Kvashnina

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  35. Correlated Displacement of Dynamic Elastic Dipoles Produces Nonclassical Electrostriction in Zr-Doped Ceria

    Chemistry of Materials · 2024-08-07

    Tali Pechersky-Savich, Boyuan Xu, Maxim Varenik, Junying Li, Ellen J. Wachtel, David Ehre, Prahlad Kumar Routh, Nicholas Marcella, Anatoly I. Frenkel, Yue Qi, Igor Lubomirsky

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  36. Oxygen-defective electrostrictors for soft electromechanics

    Science Advances · 2024-08-30

    Victor Buratto Tinti, Jin Kyu Han, Valdemar Frederiksen, Huaiyu Chen, Jesper Wallentin, Innokenty Yu. Kantor, Anton Lyksborg-Andersen, Thomas W. Hansen, Garam Bae, Wooseok Song, Eugen Stamate, Daniel Zanetti de Florio, Henrik Bruus, Vincenzo Esposito

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  37. Electromechanical coupling in alkaline-earth doped-ceria ceramics

    Acta Materialia · 2024-09-02

    Victor Buratto Tinti, Ahsanul Kabir, Daniel Zanetti de Florio, Vincenzo Esposito

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  38. Enhanced non-classical electrostriction in strained tetragonal ceria

    Nature Communications · 2025-01-02

    Simone Santucci, Milica M. Vasiljević, Haiwu Zhang, Victor Buratto Tinti, Achilles Bergne, Armando Antonio Morin-Martinez, Sandeep Kumar Chaluvadi, P. Orgiani, Simone Sanna, Anton Lyksborg-Andersen, Thomas W. Hansen, Ivano E. Castelli, Nini Pryds, Vincenzo Esposito

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  39. Determination of Local Structural and Dynamic Descriptors in Doped Oxides: The Case of Zr-Doped Ceria, a Non-Classical Electrostrictor

    Journal of the American Chemical Society · 2025-05-21

    Tali Pechersky-Savich, Kaifeng Zheng, Ryuichi Shimogawa, Prahlad Kumar Routh, Maxim Varenik, David Ehre, Igor Lubomirsky, Anatoly I. Frenkel

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  40. Dynamic Features of Cu-Ceria Interface under CO 2 Hydrogenation to Methanol

    ACS Catalysis · 2025-12-23

    Yuanyuan Li, Yiming Chen, Haohong Song, Kinga A. Unocic, Jorge E. Perez-Aguilar, Jiyun Hong, Adam S. Hoffman, Jorge Moncada, Jeongjin John Kim, Luke Daemen, Yongqiang Q. Cheng, Caiqi Wang, Sanjaya D. Senanayake, Simon R. Bare, De-en Jiang, Z. Y. Wu

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  41. Applicability of the small anharmonicity approximation to electrostriction in Zr-doped ceria

    Physical Chemistry Chemical Physics · 2026-01-01

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