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RESEARCH PAPER · Physical review. B./Physical review. B · 2016

Origin of ferroelectric polarization in tetragonal tungsten-bronze-type oxides

Gerhard Henning Olsen, Ulrich Aschauer, Nicola A. Spaldin, Sverre M. Selbach, Tor Grande

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Origin of ferroelectric polarization in tetragonal tungsten-bronze-type oxidesOriginalManipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba4-xSrxDy0.67□1.33Nb10O30, x = 0, 0.25, 0.5, 1, 2, 328Niobium-oxygen octahedra and oxygen interstitial defect emissions in calcium niobate matrix and its color manipulation via doping Pr3+9Feasibility of electron and hole injection in heavily doped strontium barium niobate (SBN50) Sr0.5Ba0.5Nb2O6 for thermoelectric applications11Role of Lone Pair Cations in Ferroelectric Tungsten Bronzes29Local environments and transport properties of heavily doped strontium barium niobates Sr0.5Ba0.5Nb2O66First-principles-based Landau-Devonshire potential for BiFeO325X-ray diffuse scattering observations for Sr x Ba1−x Nb2O6 single crystals with x=0.35 and 0.819Quantum critical points in ferroelectric relaxors: Stuffed tungsten bronze K3Li2Ta5O15 and lead pyrochlore ( Pb2Nb2O7 )5Vibronic (pseudo Jahn-Teller) theory of ferroelectricity: Novel aspects and applications34Multiple polarization mechanisms across the ferroelectric phase transition of the tetragonal tungsten-bronze Sr0.35Ba0.69Nb2O6.0414Composition and morphology tuning during hydrothermal synthesis of Sr x Ba 1−x Nb 2 O 6 tetragonal tungsten bronzes studied by in situ X-ray diffraction5Aging effect and metastable ferroelectric state in Ba4Eu2(Ti0.9Zr0.1)4Ta6O30 tetragonal tungsten bronze ceramic5Local structure of relaxor ferroelectric Sr x Ba 1 − x Nb 2 O 6 from a pair distribution function analysis26Innovative Approaches Towards the Synthesis of Thermoelectric Oxides1The Effect of Cation Disorder on Ferroelectric Properties of SrxBa1−xNb2O6 Tungsten Bronzes27Suppression of ferroelectric phase-transition in niobates via solid solution formation5Photo-Hall, photorefractive and photomagnetoelectric effects in tungsten bronzes and related tetragonal ferroelectrics0Dynamics of mesoscopic polarization in the uniaxial tetragonal tungsten bronze ( S r x B a 1 − x ) N b 2 O 69Long-Range and Local Structure of Sr x Ba 1– x Nb 2 O 6 ( x = 0.33 and 0.67) across the Ferroelectric–Relaxor Transition33Crystal structure effect on the phase transition of (Ca0.28Ba0.72)x(Sr0.61Ba0.39)1−xNb2O6 ceramics9Controlled Growth of SrxBa1−xNb2O6 Hopper‐ and Cube‐Shaped Nanostructures by Hydrothermal Synthesis9Disorder in Strontium Barium Niobate: Local Structure, Phonons, and Polarization Dynamics2Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion48Structural Evolution of Ferroelectric and Ferroelastic Barium Sodium Niobate Tungsten Bronze29Crossover from normal to relaxor ferroelectric in Sr0.25Ba0.75(Nb1−xTax)2O6 ceramics with tungsten bronze structure30Antiferroelectricity and robust dielectric response owing to competing polar and antipolar instabilities in tetragonal tungsten bronze K 2 R Nb 5 O 15 ( R : rare-earth)16Crystal structure, dielectric, and ferroelectric characteristics of zirconate tantalate ceramics with tungsten bronze structure6Ferroelectric transition and structural modulation in Sr2Na(Nb1−xTax)5O15 tungsten bronze ceramics24Ordering of A-cations in lead-free oxides with a filled tetragonal tungsten bronze structure3Purely one-dimensional ferroelectricity and antiferroelectricity from van der Waals niobium oxide trihalides29Effect of Intrinsic Nb5+ Vacancy on Dielectric and Polarization Behaviors of KSr2Nb5O15: First‐Principles Investigation3Grain-size-insensitive dielectric properties of Sr0.6Ba0.4Nb2O6 relaxor ferroelectric ceramics with tetragonal tungsten bronze structure8Computational exploration of low-dimensional materials with novel electronic and ferroic/multiferroic properties0Designing new polar materials1Effect of B-site Zr and Hf substitution on ferroelectric polar order for tetragonal tungsten bronze ceramic6Effect of the ratio of Sr to Ba at A2 sites on the dielectric and ferroelectric properties of tetragonal tungsten bronze Ca0.4SrxBa0.6−xNb2O6 ceramics3Origin of the crossover from ferroelectric to relaxor in tetragonal tungsten bronzes22Centrosymmetric Tetragonal Tungsten Bronzes A4Bi2Nb10O30 (A = Na, K, Rb) with a Bi 6s Lone Pair12Effect of A-site occupancy on phase transition and electric properties of CaxSr0.6-xBa0.4Nb2O6 ceramics7Enhanced energy storage properties on calcium modified strontium barium niobate lead-free ferroelectric relaxor ceramics4Low temperature relaxor, polarization dynamics and energy storage properties of Ca0.28Ba0.72Nb2O6 tungsten bronze ceramics17Ferroelectric relaxor behaviour in Bi and K/Na-substituted solid solutions of tetragonal tungsten bronze PbNb2O64The effect of cation size on structure and properties of Ba-based tetragonal tungsten bronzes Ba 4 M 2 Nb 10 O 30 (M = Na, K or Rb) and Ba 4 M 2 Nb 8 Ti 2 O 30 (M = Ca or Sr)8Preparation, Phase Composition, Nanostructure, Dielectric and Ferroelectric Characteristics of Sr0.6Ba0.4Nb2O6 Thin Films Grown on a Silicon Substrate in an Oxygen Atmosphere0On the solubility of Bi in tetragonal tungsten bronzes7Linear electro-optic effect in strontium barium niobate: A first principles study4Unveiling the role of ZrO2 doping in SrSmTiNbO ceramics: From structural study to dielectric enhancement9Evolution of Ferroelectricity in Sr0.6Ba0.4Nb2O6–BaTiO3 Solid Solution with a Strong Electrocaloric Effect6Mise en forme et caractérisation des propriétés diélectriques et calorimétriques de matériaux moléculaires ferroélectriques en vue d'applications en énergie électrique0Rhenium Bronze Oxide Containing Tellurium Ions with Two Lone Pairs0Temperature-dependent lattice dynamics of La and Ta-doped tungsten bronze relaxation ferroelectric ceramics1Harnessing Multisite High-Entropy Architecture for Ultrahigh Energy Storage Multilayer Capacitors28Ferroelectricity‐Enhanced Photocatalysis: Mechanisms, Materials, and Engineering Strategies0Correlation of structural, dielectric and electrical properties of Ta-substituted Sr0.6Ba0.4Nb2(1−x)Ta2xO6 ceramics0Antiferroelectric order and polarization fluctuations in tungsten bronze-type K 2 NdNb 5 O 15 revealed by machine-learning molecular dynamics simulations0Cr3+-driven evolution of the structural, optical, electrical, and magnetic properties of Ba0.95Sr0.05Ca₅Ti2Nb8O30 ceramics0Microstructure–defect–polarization coupling in dye-selective piezo–photocatalysis of an entropy-engineered tungsten bronze high-entropy oxide0

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  1. Manipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba4-xSrxDy0.67□1.33Nb10O30, x = 0, 0.25, 0.5, 1, 2, 3

    Applied Physics Letters · 2016-08-15

    Jonathan Gardner, Finlay D. Morrison

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  2. Niobium-oxygen octahedra and oxygen interstitial defect emissions in calcium niobate matrix and its color manipulation via doping Pr3+

    AIP Advances · 2017-02-01

    Chen Wu, Yezhou Li, Hongxia Gong, Jianping Gao, Zhaofeng Wang

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  3. Feasibility of electron and hole injection in heavily doped strontium barium niobate (SBN50) Sr0.5Ba0.5Nb2O6 for thermoelectric applications

    Journal of Applied Physics · 2017-02-28

    Riccardo Ottini, Cristina Tealdi, Corrado Tomasi, Ilenia Giuseppina Tredici, Alessandro Soffientini, Umberto Anselmi‐Tamburini, Paolo Ghigna, G. Spinolo

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  4. Role of Lone Pair Cations in Ferroelectric Tungsten Bronzes

    Chemistry of Materials · 2017-07-10

    Gerhard Henning Olsen, Magnus Helgerud Sørby, Sverre M. Selbach, Tor Grande

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  5. Local environments and transport properties of heavily doped strontium barium niobates Sr0.5Ba0.5Nb2O6

    Journal of Solid State Chemistry · 2017-10-01

    Riccardo Ottini, Cristina Tealdi, Corrado Tomasi, Ilenia Giuseppina Tredici, Alessandro Soffientini, R. Burriel, Elías Palacios, Miguel Castro, Umberto Anselmi‐Tamburini, Paolo Ghigna, G. Spinolo

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  6. First-principles-based Landau-Devonshire potential for BiFeO3

    Physical review. B./Physical review. B · 2017-11-17

    Pavel Márton, Antonín Klíč, Marek Antoni Pasciak, J. Hlinka

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  7. X-ray diffuse scattering observations for Sr x Ba1−x Nb2O6 single crystals with x=0.35 and 0.81

    Phase Transitions · 2018-08-07

    Marek Antoni Pasciak, M. Kopecký, J. Kub, Jan Fábry, J. Dec, P. Ondrejkovič, J. Hlinka, E. Buixaderas

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  8. Quantum critical points in ferroelectric relaxors: Stuffed tungsten bronze K3Li2Ta5O15 and lead pyrochlore ( Pb2Nb2O7 )

    Physical Review Materials · 2018-08-22

    Rebecca M. Smith, Jonathan Gardner, Finlay D. Morrison, Stephen E. Rowley, Catarina Ferraz, M. A. Carpenter, Jiasheng Chen, Jack Hodkinson, Siân E. Dutton, J. F. Scott

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  9. Vibronic (pseudo Jahn-Teller) theory of ferroelectricity: Novel aspects and applications

    Ferroelectrics · 2018-11-18

    Isaac B. Bersuker

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  10. Multiple polarization mechanisms across the ferroelectric phase transition of the tetragonal tungsten-bronze Sr0.35Ba0.69Nb2O6.04

    Physical Review Materials · 2018-12-26

    E. Buixaderas, Martin Kempa, Viktor Bovtun, Christelle Kadlec, M. Savinov, Fedir Borodavka, P. Vaněk, Gwladys Steciuk, Lukáš Palatinus, J. Dec

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  11. Composition and morphology tuning during hydrothermal synthesis of Sr x Ba 1−x Nb 2 O 6 tetragonal tungsten bronzes studied by in situ X-ray diffraction

    CrystEngComm · 2019-01-01

    Ola G. Grendal, Anders B. Blichfeld, T. Dan Vu, Wouter van Beek, Sverre M. Selbach, Tor Grande, Mari‐Ann Einarsrud

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  12. Aging effect and metastable ferroelectric state in Ba4Eu2(Ti0.9Zr0.1)4Ta6O30 tetragonal tungsten bronze ceramic

    Applied Physics Letters · 2019-02-25

    Wen Bin Feng, Xiao Li Zhu, Xiao Qiang Liu, Xiang Ming Chen

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  13. Local structure of relaxor ferroelectric Sr x Ba 1 − x Nb 2 O 6 from a pair distribution function analysis

    Physical review. B./Physical review. B · 2019-03-05

    Marek Antoni Pasciak, P. Ondrejkovič, J. Kulda, P. Vaněk, Jan Drahokoupil, Gwladys Steciuk, Lukáš Palatinus, Thomas Richard Welberry, Henry E. Fischer, J. Hlinka, E. Buixaderas

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  14. Innovative Approaches Towards the Synthesis of Thermoelectric Oxides

    Unknown journal · 2019-03-11

    Alessandro Soffientini, Paolo Ghigna, Paolo Ghigna, G. Spinolo, G. Spinolo, Umberto Anselmi‐Tamburini, Umberto Anselmi‐Tamburini

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  15. The Effect of Cation Disorder on Ferroelectric Properties of SrxBa1−xNb2O6 Tungsten Bronzes

    Materials · 2019-04-10

    Solveig Stubmo Aamlid, Sverre M. Selbach, Tor Grande

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  16. Suppression of ferroelectric phase-transition in niobates via solid solution formation

    Materials Letters · 2019-07-10

    Silvania Lanfredi, Fabiano R. Praxedes, Flávio F. Ivashita, Andrea Paesano, Marcos A.L. Nobre

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  17. Photo-Hall, photorefractive and photomagnetoelectric effects in tungsten bronzes and related tetragonal ferroelectrics

    Ferroelectrics · 2019-10-26

    Issyan Tekaya, Aymen Tekaya, Benoit Maximin

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  18. Dynamics of mesoscopic polarization in the uniaxial tetragonal tungsten bronze ( S r x B a 1 − x ) N b 2 O 6

    Physical review. B./Physical review. B · 2019-11-27

    E. Buixaderas, Martin Kempa, Šarūnas Svirskas, Christelle Kadlec, Viktor Bovtun, M. Savinov, Marek Antoni Pasciak, J. Dec

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  19. Long-Range and Local Structure of Sr x Ba 1– x Nb 2 O 6 ( x = 0.33 and 0.67) across the Ferroelectric–Relaxor Transition

    Chemistry of Materials · 2020-02-10

    Cheng Li, Yuanpeng Zhang, Jue Liu, Heribert A. Graetsch

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  20. Crystal structure effect on the phase transition of (Ca0.28Ba0.72)x(Sr0.61Ba0.39)1−xNb2O6 ceramics

    Journal of Materials Science Materials in Electronics · 2020-02-17

    Yu Xu, Hongbo Liu

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  21. Controlled Growth of SrxBa1−xNb2O6 Hopper‐ and Cube‐Shaped Nanostructures by Hydrothermal Synthesis

    Chemistry - A European Journal · 2020-03-03

    Ola G. Grendal, Inger‐Emma Nylund, Anders B. Blichfeld, Satoshi Tominaka, Koji Ohara, Sverre M. Selbach, Tor Grande, Mari‐Ann Einarsrud

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  22. Disorder in Strontium Barium Niobate: Local Structure, Phonons, and Polarization Dynamics

    IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control · 2020-04-01

    E. Buixaderas, Marek Antoni Pasciak

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  23. Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion

    Journal of the American Chemical Society · 2020-04-02

    Kun Lin, Pifu Gong, Shihang Chu, Qiang Li, Zheshuai Lin, Hui Wu, Qingxiao Wang, Jinguo Wang, Moon Jae Kim, Kenichi Kato, Chin‐Wei Wang, Xinzhi Liu, Qingzhen Huang, Jun Chen, He Sun Zhu, Jinxia Nancy Deng, Xianran Xing

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  24. Structural Evolution of Ferroelectric and Ferroelastic Barium Sodium Niobate Tungsten Bronze

    Inorganic Chemistry · 2020-06-02

    Solveig Stubmo Aamlid, Sverre M. Selbach, Tor Grande

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  25. Crossover from normal to relaxor ferroelectric in Sr0.25Ba0.75(Nb1−xTax)2O6 ceramics with tungsten bronze structure

    Applied Physics Letters · 2020-09-21

    Zi Jin Yang, Xiao Qiang Liu, Xiao Li Zhu, Xiang Ming Chen

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  26. Antiferroelectricity and robust dielectric response owing to competing polar and antipolar instabilities in tetragonal tungsten bronze K 2 R Nb 5 O 15 ( R : rare-earth)

    Physical Review Materials · 2020-10-29

    Tomoki Murata, Hirofumi Akamatsu, Daisuke Hirai, Fumiyasu Oba, Sakyo Hirose

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  27. Crystal structure, dielectric, and ferroelectric characteristics of zirconate tantalate ceramics with tungsten bronze structure

    Journal of Materials Science Materials in Electronics · 2021-02-24

    Wenbin Feng, Xiaoli Zhu, Xiangming Chen

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  28. Ferroelectric transition and structural modulation in Sr2Na(Nb1−xTax)5O15 tungsten bronze ceramics

    Journal of Applied Physics · 2021-06-24

    Ying Wang, Tulai Sun, Xiao Li Zhu, Lu Liu, Xiang Ming Chen

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  29. Ordering of A-cations in lead-free oxides with a filled tetragonal tungsten bronze structure

    Journal of Physics Conference Series · 2021-07-01

    M. A. Bunin, О. А. Бунина, K S Chumachenko

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  30. Purely one-dimensional ferroelectricity and antiferroelectricity from van der Waals niobium oxide trihalides

    npj Computational Materials · 2021-08-19

    Lei Zhang, Cheng Tang, Stefano Sanvito, Aijun Du

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  31. Effect of Intrinsic Nb5+ Vacancy on Dielectric and Polarization Behaviors of KSr2Nb5O15: First‐Principles Investigation

    physica status solidi (b) · 2021-10-30

    Qian Chen, Xiaoying Feng, Duo Teng, Jie Xu, Shuyao Cao, Artur Maciej Rydosz, Jie Kong, Feng Gao

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  32. Grain-size-insensitive dielectric properties of Sr0.6Ba0.4Nb2O6 relaxor ferroelectric ceramics with tetragonal tungsten bronze structure

    Ceramics International · 2021-11-25

    M. Tsuchiya, Shinobu Fujihara, Manabu Hagiwara

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  33. Computational exploration of low-dimensional materials with novel electronic and ferroic/multiferroic properties

    Queensland University of Technology · 2022-01-01

    Lei Zhang

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  34. Designing new polar materials

    Elsevier eBooks · 2022-01-28

    Emma E. McCabe

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  35. Effect of B-site Zr and Hf substitution on ferroelectric polar order for tetragonal tungsten bronze ceramic

    Journal of Asian Ceramic Societies · 2022-04-03

    Wenbin Feng, Sidi Long, Yi Wan, Dunpu Zhang

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  36. Effect of the ratio of Sr to Ba at A2 sites on the dielectric and ferroelectric properties of tetragonal tungsten bronze Ca0.4SrxBa0.6−xNb2O6 ceramics

    Journal of Materials Science Materials in Electronics · 2022-05-20

    Liangwen Hai, Hongbo Liu

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  37. Origin of the crossover from ferroelectric to relaxor in tetragonal tungsten bronzes

    Journal of Alloys and Compounds · 2022-09-22

    Hongbo Liu, Brahim Dkhil

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  38. Centrosymmetric Tetragonal Tungsten Bronzes A4Bi2Nb10O30 (A = Na, K, Rb) with a Bi 6s Lone Pair

    Chemistry of Materials · 2022-12-21

    Inger‐Emma Nylund, Caren Regine Zeiger, Peng Ding, Per Erik Vullum, Julian Walker, Mari‐Ann Einarsrud, Tor Grande

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  39. Effect of A-site occupancy on phase transition and electric properties of CaxSr0.6-xBa0.4Nb2O6 ceramics

    Ceramics International · 2023-04-07

    Liangwen Hai, Hongbo Liu

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  40. Enhanced energy storage properties on calcium modified strontium barium niobate lead-free ferroelectric relaxor ceramics

    Journal of Materials Science Materials in Electronics · 2023-06-01

    Shaobo Guo, Zhen Liu, Chunhua Yao, Fei Cao, Genshui Wang

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  41. Low temperature relaxor, polarization dynamics and energy storage properties of Ca0.28Ba0.72Nb2O6 tungsten bronze ceramics

    Chemical Engineering Journal · 2023-11-24

    Lei Cao, Yuanyuan Wang, Ying Yuan, Jianguo Zhu, Hadi Barzegar Bafrooei, Minmin Mao, Bing Liu, Hao Li, Dawei Wang, Zhilun Lu, Ge Wang, Kaixin Song

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  42. Ferroelectric relaxor behaviour in Bi and K/Na-substituted solid solutions of tetragonal tungsten bronze PbNb2O6

    Journal of Solid State Chemistry · 2023-12-06

    Mtabazi Geofrey Sahini, Benard Samwel Mwankemwa, Joyce Elisadiki

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  43. The effect of cation size on structure and properties of Ba-based tetragonal tungsten bronzes Ba 4 M 2 Nb 10 O 30 (M = Na, K or Rb) and Ba 4 M 2 Nb 8 Ti 2 O 30 (M = Ca or Sr)

    Physical Chemistry Chemical Physics · 2023-12-29

    Nora Statle Løndal, Benjamin A. D. Williamson, Julian Walker, Mari‐Ann Einarsrud, Tor Grande

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  44. Preparation, Phase Composition, Nanostructure, Dielectric and Ferroelectric Characteristics of Sr0.6Ba0.4Nb2O6 Thin Films Grown on a Silicon Substrate in an Oxygen Atmosphere

    Springer Proceedings in Materials · 2024-01-01

    Anatoly V. Pavlenko, Ya. Yu. Matyash, D. V. Stryukov, Norayr V. Makinyan

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  45. On the solubility of Bi in tetragonal tungsten bronzes

    Journal of the European Ceramic Society · 2024-01-06

    Caren Regine Zeiger, Benjamin A. D. Williamson, Julian Walker, Mari‐Ann Einarsrud, Tor Grande

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  46. Linear electro-optic effect in strontium barium niobate: A first principles study

    Journal of Applied Physics · 2024-02-22

    Sohm Apte, Alexander A. Demkov

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  47. Unveiling the role of ZrO2 doping in SrSmTiNbO ceramics: From structural study to dielectric enhancement

    Ceramics International · 2024-06-20

    Karim Chourti, Ilyas Jalafi, Amine Bendahhou, Soufian El Barkany, Mohamed Abou-Salama

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  48. Evolution of Ferroelectricity in Sr0.6Ba0.4Nb2O6–BaTiO3 Solid Solution with a Strong Electrocaloric Effect

    ACS Applied Materials & Interfaces · 2024-08-12

    Jian Yong Guo, Zhiming Geng, Lanji Wen, Ningchong Zheng, Ming-Qian Yuan, Ke Wang, Shan‐Tao Zhang

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  49. Mise en forme et caractérisation des propriétés diélectriques et calorimétriques de matériaux moléculaires ferroélectriques en vue d'applications en énergie électrique

    Unknown journal · 2024-12-16

    Gwenn Morvézen

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  50. Rhenium Bronze Oxide Containing Tellurium Ions with Two Lone Pairs

    Inorganic Chemistry · 2025-05-10

    Yasuhito Matsubayashi, Yuuki Kitanaka, Taku Goto, Toshiki Nishitoba, Katsuhiko Takeuchi, Hisashi Inoue, Kunimitsu Kataoka

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