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RESEARCH PAPER · Inorganic Chemistry · 2001

Solid-State Coordination Chemistry: Structural Influences of Copper−Phenanthroline Subunits on Oxovanadium Organophosphonate Phases. Hydrothermal Synthesis and Structural Characterization of the Two-Dimensional Materials [Cu(phen)(VO)(O3PCH2PO3)(H2O)], [{Cu(phen)}2(V2O5)(O3PCH2CH2PO3)], and [{Cu(phen)}2(V3O5)(O3PCH2CH2CH2PO3)2(H2O)] and of the Three-Dimensional Phase [{Cu(phen)}2(V3O5)(O3PCH2PO3)2(H2O)]

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Solid-State Coordination Chemistry: Structural Influences of Copper−Phenanthroline Subunits on Oxovanadium Organophosphonate Phases. Hydrothermal Synthesis and Structural Characterization of the Two-Dimensional Materials [Cu(phen)(VO)(O3PCH2PO3)(H2O)], [{Cu(phen)}2(V2O5)(O3PCH2CH2PO3)], and [{Cu(phen)}2(V3O5)(O3PCH2CH2CH2PO3)2(H2O)] and of the Three-Dimensional Phase [{Cu(phen)}2(V3O5)(O3PCH2PO3)2(H2O)]Original15 Copper3Copper(ii) and cobalt(ii) coordination polymers with bridging 1,2,4,5-benzenetetracarboxylate and N-methylimidazole: coordination number-determined sheet topology53Ligand Influences on Copper Molybdate Networks: The Structures and Magnetism of [Cu(3,4‘-bpy)MoO4], [Cu(3,3‘-bpy)0.5MoO4], and [Cu(4,4‘-bpy)0.5MoO4]·1.5H2O90The synthesis and characterization of two new copper phosphonates: the one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)]·4H2O and the molecular [{Cu(phen)(H2O)}2(O3PCH2CH2PO3)]·9H2O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)31Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO3)], a one-dimensional ribbon21Synthesis and Characterization of [Mo7O16(O3PCH2PO3)3]:8- A Mixed-Valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum63The synthesis, magnetic properties and crystal structure of a Cu(II) methylenediphosphonate, [Cu2(O3PCH2PO3)]16Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n12A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na2[{Mn(phen)2(H2O)}{Mn(phen)2}3{Mn Mo12vO24 (HPO4)6(PO4)2(OH)6}]·4H2O (phen=1, 10-phenanthroline)45Self‐Assembly of Organodiphosphonate, Polyoxomolybdate and Diphenanthrolinecobalt( II ) into Two Clusters and One Linear Polymer15Single crystal structure of a heterometallic one-dimensional polymer: [{Cu(1,10-phen)}2(V2O4)(O3PCH2CH2CH2CH2PO3H)2(H2O)]15Hydrothermal syntheses, characterizations and crystal structures of three new cadmium (II) amino-diphosphonates: effects of substitute groups on the structures of metal phosphonates37Synthesis of Novel Mesoporous Aluminum Organophosphonate by Using Organically Bridged Diphosphonic Acid96Solid state coordination chemistry: structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–{O 3 P(CH 2 ) n PO 3 } 4− system, n = 1–6 (bisterpy = 2,2′:4′,4″:2″,2‴-quarterpyridyl-6′,6″-di-2-pyridine)44Supramolecular bidentate amine derivatives of copper(ii) organophosphonatesElectronic Supplementary Information (ESI) available: 3D images for compound 1 and compound 2. See http://www.rsc.org/suppdata/ce/b4/b400064a/27New Types of Layered and Pillared Layered Metal Carboxylate-Phosphonates Based on the 4,4‘-Bipyridine Ligand155Syntheses, crystal structures and magnetic properties of two new bimetallic phosphates M(phen)(H2O)(VO)(H2O)(HPO4)2 (; phen=1,10-phenanthroline)18Syntheses and Crystal Structures of Two Cobalt Carboxylate−Phosphonates with 4,4′‐Bipyridine as a Secondary Metal Linker34Syntheses, Crystal Structures, and Luminescent Properties of Novel Layered Lanthanide Sulfonate−Phosphonates150Solid state coordination chemistry of metal oxides: structural consequences of fluoride incorporation into the oxovanadium–copper–bisterpy–{O 3 P(CH 2 ) n PO 3 } 4− system, n = 1–5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′,6″-di-2-pyridine)51X-ray diffraction study of bisphosphonate metal complexes: Mg and Ca complexes of (dichloromethylene)bisphosphonic acid P,P′-diisopropyl ester30Temperature dependence of the crystal chemistry of the oxovanadium–ethylenediphosphonate/copper(II)--bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO2(O3PCH2CH2PO3H)]•1.5H2O and of the one-dimensional [Cu(bpy)VO2(O3PCH2CH2PO3H)]33Synthesis of Mesostructured and Mesoporous Aluminum Organophosphonates Prepared by Using Diphosphonic Acids with Alkylene Groups92Secondary metal–ligand cationic subunits {ML}n+ as structural determinants in the oxovanadium/phenylphosphonate/{ML}n+ system, where {ML} is a Cu2+/organonitrogen moiety34Solid state coordination chemistry of the copper(ii)-terpyridine/oxovanadium organophosphonate system: hydrothermal syntheses, structural characterization and magnetic properties38Structural consequences of the steric effects of the organoimine ligand in the oxovanadium–organophosphonate/copper–mephenterpy family of hybrid oxides (mephenterpy = 4′-(4-methyphenyl)-2,2′∶6′,2″-terpyridine)35New Types of Metal Squarato-phosphonates: Condensation of Aminodiphosphonate with Squaric Acid under Hydrothermal Conditions60New Types of Blue, Red or Near IR Luminescent Phosphonate‐Decorated Lanthanide Oxalates130Syntheses, structures and properties of three metal pyridinecarboxylates13Hydrothermal syntheses, structures and characterizations of three one-dimensional polyoxomolybdates with 4,4′-dimethylenebiphenyl diphosphonic acid as bridge11Solid state coordination chemistry: temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO2(O3PC6H5)(HO3PC6H5)], [{Cu3(bpy)3(H2O)}V4O9(O3PC6H5)4], [{Cu(bpy)}2V3O6(O3PC6H5)3(HO3PC6H5)] and [{Cu(bpy)}VO(O3PC6H5)2]33Bis[μ-bis(4-nitrophenyl)phosphato-κ2O:O′]bis{[bis(2-pyridylmethyl)amine-κ3N,N′,N′′′]copper(II)} diperchlorate acetonitrile hemisolvate5Hydrothermal synthesis and structure of a three-dimensional trimetallic oxide, Na2[CuV2O2(H2O)2(O3PCH2PO3)2]3Introducing a Second Ligand: New Route to Luminescent Lanthanide Polyphosphonates88Structural Diversity of the Oxovanadium Organodiphosphonate System: A Platform for the Design of Void Channels69Phosphonate based hybrid organic/inorganic open network compounds [Cu(bipy)(VO2)2(O3PCH2PO3)H2O] and [Cu(bipy)(VO2)(O3P(CH2)2PO2OH)]·1.5H2O7X-ray diffraction study of polymeric Mg complexes of clodronic acid14Transformation from a Low-Dimensional Framework to a High-Dimensional Architecture Based on Different Metal Ions: Syntheses, Structures, and Photoluminescences71Two New Hybrid Organic/Inorganic Copper(II)−Oxovanadate(V) Diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)]·H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)]·C3H8. Synthesis, Structure, and Magnetic Properties22Three Novel Zinc(II) Sulfonate−Phosphonates with Tetranuclear or Hexanuclear Cluster Units108Magnetic properties of hybrid organo-inorganic copper(II) oxovanadate(V) phosphate and phosphonate bridged systems7Inorganic−Organic Framework Structures; M(II) Ethylenediphosphonates (M = Co, Ni, Mn) and a Mn(II) Ethylenediphosphonato-phenanthroline38Novel Luminescent Lanthanide(III) Diphosphonates with Rarely Observed Topology61Synthesis and characterization of nickel phosphonopropionate hybrid materials13Structures and luminescent properties of lanthanide phosphonates375Three barium diphosphonates with 3-D structures7Synthesis, structure, and properties of the first trimetallic phosphate [Ni(H2O)4]Cd(VO)(PO4)2 with neutral 3-D pillared-layer framework5Synthesis and Characterization of Four Metal−Organophosphonates with One-, Two-, and Three-Dimensional Structures78A New Approach to Novel Cluster Compounds of Lead(II) Phosphonates33Synthesis, Molecular Structure and Characterizations of a Novel 2D Metal Diphosphonate Complex0Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)−Hydroxide Clusters or Zinc(II)−Carboxylate Layers131Novel Copper(I)− and Copper(II)−Guanazolate Complexes: Structure, Network Topologies, Photoluminescence, and Magnetic Properties45Solid state coordination chemistry of the oxovanadium-diphosphonate/copper-bipyrimidine system: Crystal structures of [{Cu2(bpyr)}VO(H2O)(HO3PCH2PO3)2] and [{Cu2(bpyr)}{Cu2(bpyr)(H2O)2}(VO2)2(HO3PCH2PO3)2(HO3PCH2PO3H)2]16A Highly Anisotropic Cobalt(II)-Based Single-Chain Magnet: Exploration of Spin Canting in an Antiferromagnetic Array140Four Novel Metal Diphosphonate Compounds Based on 2-(1-Triazole)-1-Hydroxyl-1,1′-Ethylidenediphosphonic Acid: Syntheses, Topological Structures, and Magnetic Properties38X-ray diffraction study of bisphosphonate metal complexes: Mg, Sr and Ba complexes of (dichloromethylene)bisphosphonic acid P,P′-dibenzoyl anhydride18Phosphonate and sulfonate metal organic frameworks674Hydrothermal chemistry of vanadium oxides with aromatic di- and tri-phosphonates in the presence of secondary metal copper(II) cationic complex subunits47Cadmium(II) Complexes with 2,2′‐Dithiodibenzoate Ligand: Syntheses, Crystal Structures, and Emission Properties10Syntheses, X‐ray Diffraction Study and Characterisations of Ni and Zn Complexes of Clodronic Acid and Its Dibenzoyl Derivative4Alkaline and alkaline earth metal complexes of dianhydride derivatives of clodronate and their hydrolysis products10Spontaneous resolution of a new diphosphonate-functionalized polyoxomolybdate32Metal-organophosphonates: hydrothermal synthesis and structures of [Cu(O3PC10H6CO2H)] and [Cu(bpy)(HO3PC10H6CO2)] (H2O3PC10H6CO2H = 2,6-carboxynaphthalene phosphonic acid)7Organic‐Inorganic Hybrid Materials: Syntheses, X‐ray Diffraction Study, and Characterisations of Manganese, Cobalt, and Copper Complexes of Modified Bis(phosphonates)14Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4)2(HPO4)2]·2H2O14Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde32Distorted cubic tetranuclear vanadium(iv) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages29Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties126Synthesis, crystal structures, and surface photovoltage properties of four new metal diphosphonates based on the mixed ligands30Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands13TDDFT studies on electronic structures, chiroptical properties and solvent effect on the CD spectra of diphosphonate-functionalized polyoxomolybdates2Chiral and achiral imidazole-linked tetrahedral zinc phosphonate frameworks with photoluminescent properties34Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands4Di-, tri- and tetranuclear molecular vanadium phosphonates: a chloride encapsulated tetranuclear bowl17Metal phosphonate hybrid materials: from densely layered to hierarchically nanoporous structures159Investigations of organic–inorganic hybrid materials: Ligand influences on the structures of copper-vanadium oxide materials4Three New Silver Uranyl Diphosphonates: Structures and Properties23Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains3History and Classification of Non-Siliceous Hybrid Materials6Rational Design of Two‐Dimensional Bimetallic Wave Structures from Zigzag Chains via Site‐Specific Coordination around the 2,6‐Naphthalenediphosphonic Acid Motif18Synthesis, crystal structure, characterization and magnetic property of a new organophosphonate-based polyoxovanadate16Hydrothermal syntheses and structures of cobalt(II) and copper(II) coordination polymers with 1-tetrazole-phenyl-4-methylphosphonate ligands6A potential Cu/V-organophosphonate platform for tailored void spacesviaterpyridine mold casting17DIRECT SYNTHESIS AND CRYSTAL STRUCTURE OF BIS(BROMIDO-BIS(1,10 PHENANTHROLINE)-COPPER(II)) NITROPRUSSIDE DIMETHYLFORMAMIDE SOLVATE1Synthesis and characterization of two benzylarsonate functionalized polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde8Metal-organic solids derived from arylphosphonic acids121Anomalous magnetic exchange in a dimerized quantum magnet composed of unlike spin species3Layered metal phosphonates: Structures and properties7Overview of organophosphonate covalently modified polyoxometalates: From synthesis and structural diversity to applications14

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  2. Copper(ii) and cobalt(ii) coordination polymers with bridging 1,2,4,5-benzenetetracarboxylate and N-methylimidazole: coordination number-determined sheet topology

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  3. Ligand Influences on Copper Molybdate Networks: The Structures and Magnetism of [Cu(3,4‘-bpy)MoO4], [Cu(3,3‘-bpy)0.5MoO4], and [Cu(4,4‘-bpy)0.5MoO4]·1.5H2O

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  4. The synthesis and characterization of two new copper phosphonates: the one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)]·4H2O and the molecular [{Cu(phen)(H2O)}2(O3PCH2CH2PO3)]·9H2O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)

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  5. Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO3)], a one-dimensional ribbon

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  6. Synthesis and Characterization of [Mo7O16(O3PCH2PO3)3]:8- A Mixed-Valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum

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  7. The synthesis, magnetic properties and crystal structure of a Cu(II) methylenediphosphonate, [Cu2(O3PCH2PO3)]

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  8. Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

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  9. A two-dimensional molybdenum (V) phosphate with covalently bonded transition metal coordination complexes: hydrothermal synthesis and structure characterization of Na2[{Mn(phen)2(H2O)}{Mn(phen)2}3{Mn Mo12vO24 (HPO4)6(PO4)2(OH)6}]·4H2O (phen=1, 10-phenanthroline)

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  10. Self‐Assembly of Organodiphosphonate, Polyoxomolybdate and Diphenanthrolinecobalt( II ) into Two Clusters and One Linear Polymer

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  11. Single crystal structure of a heterometallic one-dimensional polymer: [{Cu(1,10-phen)}2(V2O4)(O3PCH2CH2CH2CH2PO3H)2(H2O)]

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  12. Hydrothermal syntheses, characterizations and crystal structures of three new cadmium (II) amino-diphosphonates: effects of substitute groups on the structures of metal phosphonates

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  13. Synthesis of Novel Mesoporous Aluminum Organophosphonate by Using Organically Bridged Diphosphonic Acid

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  14. Solid state coordination chemistry: structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–{O 3 P(CH 2 ) n PO 3 } 4− system, n = 1–6 (bisterpy = 2,2′:4′,4″:2″,2‴-quarterpyridyl-6′,6″-di-2-pyridine)

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  15. Supramolecular bidentate amine derivatives of copper(ii) organophosphonatesElectronic Supplementary Information (ESI) available: 3D images for compound 1 and compound 2. See http://www.rsc.org/suppdata/ce/b4/b400064a/

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  16. New Types of Layered and Pillared Layered Metal Carboxylate-Phosphonates Based on the 4,4‘-Bipyridine Ligand

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  17. Syntheses, crystal structures and magnetic properties of two new bimetallic phosphates M(phen)(H2O)(VO)(H2O)(HPO4)2 (; phen=1,10-phenanthroline)

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  18. Syntheses and Crystal Structures of Two Cobalt Carboxylate−Phosphonates with 4,4′‐Bipyridine as a Secondary Metal Linker

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  19. Syntheses, Crystal Structures, and Luminescent Properties of Novel Layered Lanthanide Sulfonate−Phosphonates

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  20. Solid state coordination chemistry of metal oxides: structural consequences of fluoride incorporation into the oxovanadium–copper–bisterpy–{O 3 P(CH 2 ) n PO 3 } 4− system, n = 1–5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′,6″-di-2-pyridine)

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  21. X-ray diffraction study of bisphosphonate metal complexes: Mg and Ca complexes of (dichloromethylene)bisphosphonic acid P,P′-diisopropyl ester

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  22. Temperature dependence of the crystal chemistry of the oxovanadium–ethylenediphosphonate/copper(II)--bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO2(O3PCH2CH2PO3H)]•1.5H2O and of the one-dimensional [Cu(bpy)VO2(O3PCH2CH2PO3H)]

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  23. Synthesis of Mesostructured and Mesoporous Aluminum Organophosphonates Prepared by Using Diphosphonic Acids with Alkylene Groups

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  24. Secondary metal–ligand cationic subunits {ML}n+ as structural determinants in the oxovanadium/phenylphosphonate/{ML}n+ system, where {ML} is a Cu2+/organonitrogen moiety

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  25. Solid state coordination chemistry of the copper(ii)-terpyridine/oxovanadium organophosphonate system: hydrothermal syntheses, structural characterization and magnetic properties

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  26. Structural consequences of the steric effects of the organoimine ligand in the oxovanadium–organophosphonate/copper–mephenterpy family of hybrid oxides (mephenterpy = 4′-(4-methyphenyl)-2,2′∶6′,2″-terpyridine)

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  27. New Types of Metal Squarato-phosphonates: Condensation of Aminodiphosphonate with Squaric Acid under Hydrothermal Conditions

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  28. New Types of Blue, Red or Near IR Luminescent Phosphonate‐Decorated Lanthanide Oxalates

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  29. Syntheses, structures and properties of three metal pyridinecarboxylates

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  30. Hydrothermal syntheses, structures and characterizations of three one-dimensional polyoxomolybdates with 4,4′-dimethylenebiphenyl diphosphonic acid as bridge

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  31. Solid state coordination chemistry: temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO2(O3PC6H5)(HO3PC6H5)], [{Cu3(bpy)3(H2O)}V4O9(O3PC6H5)4], [{Cu(bpy)}2V3O6(O3PC6H5)3(HO3PC6H5)] and [{Cu(bpy)}VO(O3PC6H5)2]

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    Gündoğ Yücesan, W. Ouellette, V. Golub, Charles J. O’Connor, Jon A. Zubieta

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  32. Bis[μ-bis(4-nitrophenyl)phosphato-κ2O:O′]bis{[bis(2-pyridylmethyl)amine-κ3N,N′,N′′′]copper(II)} diperchlorate acetonitrile hemisolvate

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  33. Hydrothermal synthesis and structure of a three-dimensional trimetallic oxide, Na2[CuV2O2(H2O)2(O3PCH2PO3)2]

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  34. Introducing a Second Ligand: New Route to Luminescent Lanthanide Polyphosphonates

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  35. Structural Diversity of the Oxovanadium Organodiphosphonate System: A Platform for the Design of Void Channels

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    W. Ouellette, Ming Hui Yu, Charles J. O’Connor, Jon A. Zubieta

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  36. Phosphonate based hybrid organic/inorganic open network compounds [Cu(bipy)(VO2)2(O3PCH2PO3)H2O] and [Cu(bipy)(VO2)(O3P(CH2)2PO2OH)]·1.5H2O

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    Svetlana Ushak, Evgenia Spodine, Diego A. Venegas-Yazigi, Éric Le Fur, Jean‐Yves Pivan

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  37. X-ray diffraction study of polymeric Mg complexes of clodronic acid

    Solid State Sciences · 2006-05-23

    Mervi Kontturi, Susan Kunnas-Hiltunen, Jouko Vepsäläinen, Markku Ahlgrén

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  38. Transformation from a Low-Dimensional Framework to a High-Dimensional Architecture Based on Different Metal Ions: Syntheses, Structures, and Photoluminescences

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