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RESEARCH PAPER · Chemical Reviews · 2016

Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design

Bayrammurad Saparov, David B. Mitzi

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Organic–Inorganic Perovskites: Structural Versatility for Functional Materials DesignOriginalIntriguing Optoelectronic Properties of Metal Halide Perovskites2020Optoelectronic Properties of (CH3NH3)3Sb2I9 Thin Films for Photovoltaic Applications375Color-Pure Violet-Light-Emitting Diodes Based on Layered Lead Halide Perovskite Nanoplates447Two-Dimensional Colloidal Nanocrystals525Enhanced Optical and Electrical Properties of Polymer‐Assisted All‐Inorganic Perovskites for Light‐Emitting Diodes375Lead‐Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22%793Mixed Cation FAxPEA1–xPbI3 with Enhanced Phase and Ambient Stability toward High‐Performance Perovskite Solar Cells347Pure Cs4PbBr6: Highly Luminescent Zero-Dimensional Perovskite Solids595Beyond methylammonium lead iodide: prospects for the emergent field of ns 2 containing solar absorbers433Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells258The Additive Coordination Effect on Hybrids Perovskite Crystallization and High‐Performance Solar Cell305Electron–Phonon Scattering in Atomically Thin 2D Perovskites263Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors439Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality735Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-Based Perovskite Solar Cells598Structure–Band Gap Relationships in Hexagonal Polytypes and Low-Dimensional Structures of Hybrid Tin Iodide Perovskites282Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation430A critical review on tin halide perovskite solar cells600Stable high efficiency two-dimensional perovskite solar cells via cesium doping678The rapid evolution of highly efficient perovskite solar cells1140One-dimensional organic lead halide perovskites with efficient bluish white-light emission804Solution-processed semiconductors for next-generation photodetectors1523Chemically diverse and multifunctional hybrid organic–inorganic perovskites1273Zero-Dimensional Cs 4 PbBr 6 Perovskite Nanocrystals348Dismantling the “Red Wall” of Colloidal Perovskites: Highly Luminescent Formamidinium and Formamidinium–Cesium Lead Iodide Nanocrystals534High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH3(CH2)3NH3)2(CH3NH3)4Pb5I16418Low-Dimensional-Networked Metal Halide Perovskites: The Next Big Thing476Progress on lead-free metal halide perovskites for photovoltaic applications: a review614White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites664Addressing Toxicity of Lead: Progress and Applications of Low‐Toxic Metal Halide Perovskites and Their Derivatives432The Evolution of Quantum Confinement in CsPbBr3 Perovskite Nanocrystals360Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study387Tailoring the Energy Landscape in Quasi-2D Halide Perovskites Enables Efficient Green-Light Emission510Colloidal Halide Perovskite Nanoplatelets: An Exciting New Class of Semiconductor Nanomaterials285Perovskite Tandem Solar Cells337Low‐Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation329One-Year stable perovskite solar cells by 2D/3D interface engineering2068Cesium Doped NiO x as an Efficient Hole Extraction Layer for Inverted Planar Perovskite Solar Cells457High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers646Inorganic CsPbI3 Perovskite‐Based Solar Cells: A Choice for a Tandem Device350A Direct Bandgap Copper–Antimony Halide Perovskite314Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions593Highly Efficient Perovskite–Perovskite Tandem Solar Cells Reaching 80% of the Theoretical Limit in Photovoltage368Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two‐Dimensional Multilayered Perovskite Ferroelectric for a High‐Performance Photodetector288Tunable White-Light Emission in Single-Cation-Templated Three-Layered 2D Perovskites (CH 3 CH 2 NH 3 ) 4 Pb 3 Br 10– x Cl x431Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity587Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI 3414Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance1236Progress in Theoretical Study of Metal Halide Perovskite Solar Cell Materials344A Review on Organic–Inorganic Halide Perovskite Photodetectors: Device Engineering and Fundamental Physics820Flexible Photodetectors Based on Novel Functional Materials359Advances and challenges to the commercialization of organic–inorganic halide perovskite solar cell technology286Vapor-Deposited Perovskites: The Route to High-Performance Solar Cell Production?379Colloidal Synthesis of Air-Stable Alloyed CsSn1–xPbxI3 Perovskite Nanocrystals for Use in Solar Cells385Magnetic functionalities in MOFs: from the framework to the pore802Properties and potential optoelectronic applications of lead halide perovskite nanocrystals2632Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency657Low-Dimensional Organometal Halide Perovskites755Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices516A Zero‐Dimensional Organic Seesaw‐Shaped Tin Bromide with Highly Efficient Strongly Stokes‐Shifted Deep‐Red Emission289Toward high-efficiency, hysteresis-less, stable perovskite solar cells: unusual doping of a hole-transporting material using a fluorine-containing hydrophobic Lewis acid271Two-dimensional halide perovskite nanomaterials and heterostructures445Copper Iodide Based Hybrid Phosphors for Energy‐Efficient General Lighting Technologies306Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals2277Hybrid Dion–Jacobson 2D Lead Iodide Perovskites980Electrons, Excitons, and Phonons in Two-Dimensional Hybrid Perovskites: Connecting Structural, Optical, and Electronic Properties397What Remains Unexplained about the Properties of Halide Perovskites?293Layered Halide Double Perovskites: Dimensional Reduction of Cs 2 AgBiBr 6396Phase Transition Control for High Performance Ruddlesden–Popper Perovskite Solar Cells294Electron–phonon interaction in efficient perovskite blue emitters662Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n = 1 Layered Perovskites through Organic Cation Design365Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering429Metal-free three-dimensional perovskite ferroelectrics811Efficient Light-Emitting Diodes Based on in Situ Fabricated FAPbBr3 Nanocrystals: The Enhancing Role of the Ligand-Assisted Reprecipitation Process298The 2019 materials by design roadmap322Thermodynamically Stable Orthorhombic γ‑CsPbI3 Thin Films for High-Performance Photovoltaics380Molecularly thin two-dimensional hybrid perovskites with tunable optoelectronic properties due to reversible surface relaxation404Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites508Perovskite Quantum Dot Photovoltaic Materials beyond the Reach of Thin Films: Full-Range Tuning of A-Site Cation Composition264Recent Advances in Flexible Perovskite Solar Cells: Fabrication and Applications461Oriented Quasi‐2D Perovskites for High Performance Optoelectronic Devices358Synthetic Approaches for Halide Perovskite Thin Films631Two-Dimensional Hybrid Halide Perovskites: Principles and Promises1584Dimensionality engineering of hybrid halide perovskite light absorbers333Dimensional tailoring of hybrid perovskites for photovoltaics978Rational chemical doping of metal halide perovskites290Structural and thermodynamic limits of layer thickness in 2D halide perovskites363Mixed Dimensional 2D/3D Hybrid Perovskite Absorbers: The Future of Perovskite Solar Cells?345Low dimensional metal halide perovskites and hybrids489Phonon coherences reveal the polaronic character of excitons in two-dimensional lead halide perovskites384Luminescent perovskites: recent advances in theory and experiments259Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes361Role of oxygen vacancies and Mn sites in hierarchical Mn2O3/LaMnO3-δ perovskite composites for aqueous organic pollutants decontamination306Quantum and Dielectric Confinement Effects in Lower-Dimensional Hybrid Perovskite Semiconductors864Two-Dimensional Hybrid Perovskite-Type Ferroelectric for Highly Polarization-Sensitive Shortwave Photodetection335From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives1090Tuning the Luminescence of Layered Halide Perovskites802Two‐Dimensional Halide Perovskites in Solar Cells: 2D or not 2D?287Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties934Strain engineering in perovskite solar cells and its impacts on carrier dynamics1042Toward development of high-performance perovskite solar cells based on CH3NH3GeI3 using computational approach351Halide Perovskites: Is It All about the Interfaces?558The First 2D Homochiral Lead Iodide Perovskite Ferroelectrics: [ R ‐ and S ‐1‐(4‐Chlorophenyl)ethylammonium] 2 PbI 4389Halide Perovskites for Nonlinear Optics355Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites308A review on catalyst development for dry reforming of methane to syngas: Recent advances748Solution‐Processable Perovskite Solar Cells toward Commercialization: Progress and Challenges255Perovskites for Next-Generation Optical Sources983Structural and Functional Diversity in Lead‐Free Halide Perovskite Materials348Enabling Flexible All-Perovskite Tandem Solar Cells493Absolute energy level positions in tin- and lead-based halide perovskites734Lead halide perovskites for photocatalytic organic synthesis455Two-Dimensional Dion–Jacobson Hybrid Lead Iodide Perovskites with Aromatic Diammonium Cations386Flexible Perovskite Solar Cells448Reducing Detrimental Defects for High‐Performance Metal Halide Perovskite Solar Cells541Intrinsic Self‐Trapped Emission in 0D Lead‐Free (C4H14N2)2In2Br10 Single Crystal374Highly Stable Lead-Free Perovskite Field-Effect Transistors Incorporating Linear π-Conjugated Organic Ligands291Optimization of Low‐Dimensional Components of Quasi‐2D Perovskite Films for Deep‐Blue Light‐Emitting Diodes334All‐Inorganic CsCu 2 I 3 Single Crystal with High‐PLQY (≈15.7%) Intrinsic White‐Light Emission via Strongly Localized 1D Excitonic Recombination351Emerging Self‐Emissive Technologies for Flexible Displays316Stability of all-inorganic perovskite solar cells291Molecular engineering of organic–inorganic hybrid perovskites quantum wells499Spin-dependent charge transport through 2D chiral hybrid lead-iodide perovskites533Advances in two-dimensional organic–inorganic hybrid perovskites627Doping and ion substitution in colloidal metal halide perovskite nanocrystals484Long-range exciton transport and slow annihilation in two-dimensional hybrid perovskites272On-device lead sequestration for perovskite solar cells429Heterogeneous Photocatalysis in Organic Synthesis312From bulk to molecularly thin hybrid perovskites264Two-dimensional halide perovskite lateral epitaxial heterostructures466Unveiling the Structural Descriptor of A3B2X9 Perovskite Derivatives toward X‐Ray Detectors with Low Detection Limit and High Stability272Thiophene-Based Two-Dimensional Dion–Jacobson Perovskite Solar Cells with over 15% Efficiency272Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport422Design Principles for Enhancing Photoluminescence Quantum Yield in Hybrid Manganese Bromides421Efficient Lone-Pair-Driven Luminescence: Structure–Property Relationships in Emissive 5s2 Metal Halides416Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling456Stabilizing Perovskite Solar Cells to IEC61215:2016 Standards with over 9,000-h Operational Tracking386Semiconductor physics of organic–inorganic 2D halide perovskites520Lead‐Free Halide Perovskites for Light Emission: Recent Advances and Perspectives337The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency1085Reconfiguring the band-edge states of photovoltaic perovskites by conjugated organic cations330Electrical doping in halide perovskites364A review on perovskite solar cells (PSCs), materials and applications420An Overview for Zero‐Dimensional Broadband Emissive Metal‐Halide Single Crystals270ZnIn2S4‐Based Photocatalysts for Energy and Environmental Applications319Colloidal Metal‐Halide Perovskite Nanoplatelets: Thickness‐Controlled Synthesis, Properties, and Application in Light‐Emitting Diodes273Surface Passivation Using 2D Perovskites toward Efficient and Stable Perovskite Solar Cells531Recent Advances in Organic and Organic–Inorganic Hybrid Materials for Piezoelectric Mechanical Energy Harvesting335Recent advances in the design of afterglow materials: mechanisms, structural regulation strategies and applications475Perovskite Type ABO 3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects352

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