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RESEARCH PAPER · Inorganic Chemistry · 2013

New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents

Subrata Kumar Ghosh, Ann Ojeda, J. Guerrero-Leal, Nattamai S. P. Bhuvanesh, John Andrew Gladysz

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New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous SolventsOriginalFluorofluorophores: Fluorescent Fluorous Chemical Tools Spanning the Visible Spectrum82Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon–Carbon Bond Forming Reactions44Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors1Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis78Synthesis and fluorophilicity of compounds with tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silyl substituent6Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts85Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity4A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines47Anion Exchange Drives Reversible Phase Transfer of Coordination Cages and Their Cargoes52Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions10Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents36Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents8Selective Separation of Polyaromatic Hydrocarbons by Phase Transfer of Coordination Cages118Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization55Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization5Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions14Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**18Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**5Counterion Exchange Enhances the Brightness and Photostability of a Fluorous Cyanine Dye9Counterion-Enhanced Brightness of Fluorous-Soluble Heptamethine Cyanine Dyes for Near- and Shortwave Infrared Fluorescence Imaging1

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  1. Fluorofluorophores: Fluorescent Fluorous Chemical Tools Spanning the Visible Spectrum

    Journal of the American Chemical Society · 2014-09-17

    Ellen M. Sletten, Timothy Manning Swager

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  2. Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon–Carbon Bond Forming Reactions

    Organometallics · 2014-11-17

    Tathagata Mukherjee, Carola Ganzmann, Nattamai S. P. Bhuvanesh, John Andrew Gladysz

    Read original paper ↗ ·

  3. Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors

    Dalton Transactions · 2015-01-01

    Cheng‐Pan Zhang, Zhenxing Xi, Kory M. Mueller, Bradley J. Holliday, Hassan Said Bazzi, John Andrew Gladysz

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  4. Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis

    ACS Central Science · 2015-03-23

    Kyle G. Lewis, Subrata Kumar Ghosh, Nattamai S. P. Bhuvanesh, John Andrew Gladysz

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  5. Synthesis and fluorophilicity of compounds with tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silyl substituent

    Journal of Fluorine Chemistry · 2015-06-23

    Tomáš Strašák, Lucie Červenková Šťastná, Veronika Bílková, Veronika Skoupá, Jindřich Karban, Petra Cuřínová, Jan Čermák

    Read original paper ↗ ·

  6. Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts

    Chemical Society Reviews · 2016-01-01

    Andreas Ehnbom, Subrata Kumar Ghosh, Kyle G. Lewis, John Andrew Gladysz

    Read original paper ↗ ·

  7. Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity

    Beilstein Journal of Organic Chemistry · 2017-11-23

    Tathagata Mukherjee, Soumik Biswas, Andreas Ehnbom, Subrata Kumar Ghosh, Ibrahim El‐Zoghbi, Nattamai S. P. Bhuvanesh, Hassan Said Bazzi, John Andrew Gladysz

    Read original paper ↗ ·

  8. A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines

    Organic Chemistry Frontiers · 2018-01-01

    Subrata Kumar Ghosh, Christopher C. Cummins, John Andrew Gladysz

    Read original paper ↗ ·

  9. Anion Exchange Drives Reversible Phase Transfer of Coordination Cages and Their Cargoes

    Journal of the American Chemical Society · 2018-10-16

    Angela Beth Grommet, Jack B. Hoffman, Edmundo G. Percástegui, Jesús Mosquera, Duncan J. Howe, Jeanne L. Bolliger, Jonathan R. Nitschke

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  10. Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions

    Inorganic Chemistry · 2019-06-25

    Jonathan C. Axtell, Marco S. Messina, Jiyuan Liu, Daria V. Galaktionova, Josef Schwan, Tyler M. Porter, Miles D. Savage, Alex Ian Wixtrom, Arnold L. Rheingold, Clifford P. Kubiak, Jay R. Winkler, Harry B. Gray, Petr Král, Anastassia N. Alexandrova, Alexander M. Spokoyny

    Read original paper ↗ ·

  11. Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents

    Angewandte Chemie International Edition · 2019-07-23

    Robert Pollice, Felix Fleckenstein, Ilya G. Shenderovich, Peter Chen

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  12. Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents

    Angewandte Chemie · 2019-07-23

    Robert Pollice, Felix Fleckenstein, Ilya G. Shenderovich, Peter Chen

    Read original paper ↗ ·

  13. Selective Separation of Polyaromatic Hydrocarbons by Phase Transfer of Coordination Cages

    Journal of the American Chemical Society · 2019-11-15

    Dawei Zhang, Tanya K. Ronson, Roy Lavendomme, Jonathan R. Nitschke

    Read original paper ↗ ·

  14. Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization

    Angewandte Chemie International Edition · 2019-11-27

    Manuel Schnitte, Janine S. Scholliers, Kai Riedmiller, Stefan Mecking

    Read original paper ↗ ·

  15. Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization

    Angewandte Chemie · 2019-11-27

    Manuel Schnitte, Janine S. Scholliers, Kai Riedmiller, Stefan Mecking

    Read original paper ↗ ·

  16. Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions

    ACS Catalysis · 2021-06-11

    Connor Quinton Kabes, Reagan F. Lucas, Jack H. Gunn, John Andrew Gladysz

    Read original paper ↗ ·

  17. Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

    Angewandte Chemie International Edition · 2022-12-05

    Irene Lim, Eric Yu Lin, Joseph A. Garcia, Shang Jia, Robert E. Sommerhalter, Subrata Kumar Ghosh, John Andrew Gladysz, Ellen M. Sletten

    Read original paper ↗ ·

  18. Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

    Angewandte Chemie · 2022-12-06

    Irene Lim, Eric Yu Lin, Joseph A. Garcia, Shang Jia, Robert E. Sommerhalter, Subrata Kumar Ghosh, John Andrew Gladysz, Ellen M. Sletten

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  19. Counterion Exchange Enhances the Brightness and Photostability of a Fluorous Cyanine Dye

    Chemistry - A European Journal · 2024-09-04

    Helen H. Lin, Irene Lim, Ellen M. Sletten

    Read original paper ↗ ·

  20. Counterion-Enhanced Brightness of Fluorous-Soluble Heptamethine Cyanine Dyes for Near- and Shortwave Infrared Fluorescence Imaging

    Chemical & Biomedical Imaging · 2026-02-26

    Helen H. Lin, Emily B. Mobley, Eric Yu Lin, Rana Amini, Petr Pospíšil, Shuo‐Ting Yen, Otger Campàs, Ellen M. Sletten

    Read original paper ↗ ·
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