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RESEARCH PAPER · Journal of the American Chemical Society · 2012

Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)

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Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)OriginalHomochiral iron(II) complexes based on imidazole Schiff-base ligands: Syntheses, structures, and spin-crossover properties16Phase Transitions, Prominent Dielectric Anomalies, and Negative Thermal Expansion in Three High Thermally Stable Ammonium Magnesium–Formate Frameworks143[NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering187Highly enantioselective oxidative tandem cyclization reaction: a chiral ligand and an anion cooperatively control stereoselectivity25Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime1On the Nature of the Structural and Magnetic Phase Transitions in the Layered Perovskite-Like (CH3NH3)2[FeIICl4]62Iso-structural phase transition in tetramethylammonium nickel(II) nitrite [(CH3)4N][Ni(NO2)3]21Phase Transition Originating from Order–Disorder Transformations of Carboxy Oxygen Atoms Coupled with Dynamic Proton Motions in [PhCH2NH(CH3)2]2C2O4⋅H2C2O424Novel Phase-Transition Materials Coupled with Switchable Dielectric, Magnetic, and Optical Properties: [(CH3)4P][FeCl4] and [(CH3)4P][FeBr4]119Temperature-Triggered Reversible Dielectric and Nonlinear Optical Switch Based on the One-Dimensional Organic–Inorganic Hybrid Phase Transition Compound [C 6 H 11 NH 3 ] 2 CdCl 496Thermodynamic Phase Transition Triggered by Distinct Distortion and Ordering of Dipropylammonium Picrate12A family of homochiral spin-crossover iron(II) imidazole Schiff-base complexes20Chiral tetrahedral iron( ii ) cages: diastereoselective subcomponent self-assembly, structure interconversion and spin-crossover properties108Metal–Organic Frameworks: Functional Magnetic Materials with Formate4Crystal structures, phase transitions, and switchable dielectric behaviors: comparison of a series of N-heterocyclic ammonium perchlorates24Two reversible ferroelectric phase transitions in diisopropylammonium perchlorate22Toward chiral iron(II) spin-crossover grafted resins with imidazole Schiff-base ligands13High Magnetic Hardness for the Canted Antiferromagnetic, Ferroelectric, and Ferroelastic Layered Perovskite-like (C 2 H 5 NH 3 ) 2 [Fe II Cl 4 ]59Speciation Analysis in Iron-Mediated ATRP Studied via FT-Near-IR and Mössbauer Spectroscopy22Reversible Phase Transitions and Dielectric Properties in [(CH3)4P]2[Cr2O7] and [Et4P]2[Cr3O10]8Dibutylammonium Hydrogen Oxalate: An Above-Room-Temperature Order–Disorder Phase Transition Molecular Material17Reversible Phase Transition Triggered by Order–Disorder Transformation of Carboxyl Oxygen Atoms Coupled with Distinct Reorientations in [HN(C4H9)3](fumrate)0.5·(fumaric acid)0.521Importing spontaneous polarization into a Heisenberg ferromagnet for a potential single-phase multiferroic53Orientational ordering of guest induced structural phase transition coupled with switchable dielectric properties in a host–guest crystal: bis(thiourea) thiazolium chloride2Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C 6 H 14 )NH 2 ] 2 ·CuBr 453Reversible phase transition triggered by order–disorder transformations and distortions in dipropylammonium d -(+)-10-camphorsulfonate9Symmetry breaking in molecular ferroelectrics693Molecular Ferroelectric Pyridin-4-ylmethanaminium Perchlorate Undergoes Paraelectric–Ferroelectric and Ferroelectric–Ferroelectric Phase Transitions23Magnetic structures and dynamics of multiferroic systems obtained with neutron scattering61A High‐Temperature Order–Disorder Phase Transition Coupled With Conformational Change in the Hybrid Material [C6H13NH]2⋅ZnBr419Synthesis, crystal structure and magnetic properties of an azido-bridged complex [C6H11NH3]2[Mn(N3)4]1Symmetry Breaking Phase Transition, Second-Order Nonlinear Optical and Dielectric Properties of a One-Dimensional Organic–Inorganic Hybrid Zigzag Chain Compound [NH3(CH2)5NH3]SbBr524Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex43Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex7Inorganic–organic hybrid switchable dielectric materials with the coexistence of magnetic anomalies induced by reversible high-temperature phase transition58Prominent dielectric transitions in layered organic–inorganic hybrids: (isoamyl-ammonium) 2 CdX 4 (X = Cl and Br)19Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic–inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl 5 ·2H 2 O12An insight into the magnetoelectric coupling effect in the MOF of [NH2(CH3)2]n[FeIIIFeII(HCOO)6]n23Synthesis, crystal structure, and magnetic properties of an azido-bridged Mn(II) complex [C3H5NH3][Mn(N3)3]6A Ferroelectric Iron(II) Spin Crossover Material87A Ferroelectric Iron(II) Spin Crossover Material21Unusual Long-Range Ordering Incommensurate Structural Modulations in an Organic Molecular Ferroelectric41High-temperature sequential structural transitions with distinct switchable dielectric behaviors in two organic ionic plastic crystals: [C 4 H 11 NBr] [ClO 4 ] and [C 4 H 11 NBr] [BF 4 ]20A temperature-triggered triplex bistable switch in a hybrid multifunctional material: [(CH 2 ) 4 N(CH 2 ) 4 ] 2 [MnBr 4 ]55Spin-reorientation-induced magnetodielectric coupling effects in two layered perovskite magnets63Palladium‐Catalyzed Enantioselective Desymmetrizing Aza‐Wacker Reaction: Development and Application to the Total Synthesis of (−)‐Mesembrane and (+)‐Crinane59Palladium‐Catalyzed Enantioselective Desymmetrizing Aza‐Wacker Reaction: Development and Application to the Total Synthesis of (−)‐Mesembrane and (+)‐Crinane8A Molecular Ferroelectric Showing Room‐Temperature Record‐Fast Switching of Spontaneous Polarization38A Molecular Ferroelectric Showing Room‐Temperature Record‐Fast Switching of Spontaneous Polarization15Observation of Magnetodielectric Effect in a Dysprosium-Based Single-Molecule Magnet126Metal-free three-dimensional perovskite ferroelectrics811Reversible Thermal Dielectric Switch Triggered by Blooming-Flower Structural Phase Transition in Ionic Crystal without Metal22Crystal structures and dielectric properties of two salts of nickel-bis-1,2-dithiolene with noncentrosymmetric organic cations0Strain-Mediated Converse Magnetoelectric Coupling in La 0.7 Sr 0.3 MnO 3 /Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 Multiferroic Heterostructures23Structure–Property Relations in Multiferroic [(CH3)2NH2]M(HCOO)3(M= Mn, Co, Ni)21High-temperature phase transitions, switchable dielectric behaviors and barocaloric effects in three new organic molecule-based crystals9Magnetoelectric Radical Hydrocarbons6From Synapse to Function: A Perspective on the Role of Neuroproteomics in Elucidating Mechanisms of Drug Addiction21Coexistence of Magnetic-Optic-Electric Triple Switching and Thermal Energy Storage in a Multifunctional Plastic Crystal of Trimethylchloromethyl Ammonium Tetrachloroferrate(III)57The ferroelectric properties of 4-aminopyridinium perchlorate4Synthesis, crystal structure, and magnetic properties of a multicage compound: [(Me)2EtNH][Mn(N3)3] with a perovskite-related structure6A molecular perovskite solid solution with piezoelectricity stronger than lead zirconate titanate619Above Room Temperature Reversible Phase Transition Induces Distinct Dielectric and Nonlinear Optical Switching Response Behavior in Crown-Ether-Based Supramolecular Clathrate11Molecular dynamics simulations of ferroelectricity in di-isopropyl-ammonium halide molecular crystals6High-Temperature Molecular Ferroelectric Tris(2-hydroxyethyl) Ammonium Bromide with Dielectric Relaxation14Above room-temperature dielectric switching and semiconducting properties of a layered organic–inorganic hybrid compound: (C 6 H 12 N) 2 Pb(NO 3 ) 418Bistable molecular materials with dynamic structures117Ferroelectricity of trimethylammonium bromide below room temperature12Halogen substitution regulates the phase transition temperature and band gap of semiconductor compounds29Regulated molecular rotor in phase transition materials with switchable dielectric and SHG effect31Recent progress in molecular ferroelectrics with perovskite structure16Low-magnetic-field controlled magnetodielectric coupling at room temperature in a chiral layered diphenylalanine-based 1D-coordination-polymer2Room temperature magnetoelectric coupling in a molecular ferroelectric ytterbium(III) complex210Giant Single‐Crystal Shape Transformation with Wide Thermal Hysteresis Actuated by Synergistic Motions of Molecular Cations and Anions25Magnetoelectric Coupling Springing Up in Molecular Ferroelectric: [N(C2H5)3CH3][FeCl4]20The Mechanism of the Magnetodielectric Response in a Molecule‐Based Trinuclear Iron Cluster Material26The Mechanism of the Magnetodielectric Response in a Molecule‐Based Trinuclear Iron Cluster Material7Developing the Pressure–Temperature–Magnetic Field Phase Diagram of Multiferroic [(CH3)2NH2]Mn(HCOO)320Advances and Property Investigations of an Organic–Inorganic Ferroelectric: (diisopropylammonium)2[CdBr4]34Photo-degradation organic dyes by Sb-based organic-inorganic hybrid ferroelectrics15A Molecular Crystal Shows Multiple Correlated Magnetic and Ferroelectric Switchings22Interplay between spin crossover and proton migration along short strong hydrogen bonds36Intrinsic Magnetic Order of Chemically Exfoliated 2D Ruddlesden–Popper Organic–Inorganic Halide Perovskite Ultrathin Films18(C 2 H 5 NH 3 ) 3 [InBr 6 ]: an indium( iii ) organic–inorganic hybrid phase transition compound exhibiting a switchable dielectric response9Coexistence of magnetic and electric orderings in a divalent Cr 2+ -based multiaxial molecular ferroelectric58Molecular motion of halogenated ethylammonium/[18]crown-6 supramolecular ions in nickel dithiolate magnetic crystals9Two In-based organic–inorganic hybrid compounds with reversible phase transition derived from the order–disorder changes of cations or anions14Phase Transition and Dielectric Response Originating from Disorder‐Order Transition in the In‐Based Organic‐Inorganic Hybrid Material [NH3(CH2)5NH3][InCl5(H2O)] ⋅ H2O12Inorganic–Organic Hybrid Molecular Materials: From Multiferroic to Magnetoelectric83Reversible phase transition, switchable dielectric response in In(III)‐based organic–inorganic hybrid compound: [C3H8N]3InBr682D Hydrogen-Bonded Molecular Crystals Showing Terminal-Group-Triggered Phase Transitions and Dielectric Responses6An In(III)‐Based Organic‐Inorganic Hybrid Compound (C3H7NH3)3[InCl5(H2O)]Cl with Dielectric Response Behavior Derived from Order‐Disorder Changes of n‐Propylammonium Cations8Synthesis, crystal structure, optical, thermal and magnetic studies of a new organic-inorganic hybrid based on tetrachloroferrate (III)11High-Temperature Phase Transition Containing Switchable Dielectric Behavior, Long Fluorescence Lifetime, and Distinct Photoluminescence Changes in a 2D Hybrid CuBr4 Perovskite19Two host–guest grown ether supramolecules show switchable phase transition, dielectric and second-harmonic generation effect11High-Field Magnetoelectric and Spin-Phonon Coupling in Multiferroic (NH4)2[FeCl5·(H2O)]6Mesophase Transitions in [(C 2 H 5 ) 4 N][FeBrCl 3 ] and [(CH 3 ) 4 N][FeBrCl 3 ] Ferroic Plastic Crystals16Reversible Switchability of Magnetic Anisotropy and Magnetodielectric Effect Induced by Intermolecular Motion28Reversible Switchability of Magnetic Anisotropy and Magnetodielectric Effect Induced by Intermolecular Motion4Lithiating magneto-ionics in a rechargeable battery12New Room-Temperature Molecular Ferroelectric (C 6 H 16 N 2 O)CdBr 4 ·H 2 O with Preferable Luminescent Properties6Magnetic and Dielectric Switchings Actuated by the Rotation of the Picoline Ligand in an Iron-Based Dinuclear Phase-Transition Complex7Coupling Dielectric Functionality with Magnetic Properties in Coordination Metal Complexes5Magnetic Switchability via Thermal-Induced Structural Phase Transitions in Molecular Solids4Near‐Room‐Temperature Synergetic Response of Magnetism, Dielectricity and Luminescence Based on (C5NH13Cl)2MnBr414Excellent Switchable Properties, Broad-Band Emission, Ferroelectricity, and High Tc in a Two-Dimensional Hybrid Perovskite: (4,4-DCA)2PbBr4 Exploited by H/F Substitution17New Room-Temperature Ferroelectrics with Photoluminescent Properties6Crystal growth, Hirshfeld analysis, thermal behavior and magnetic properties of a new hybrid material (C5H14N2)[MnCl3(H2O)3]Cl2Photophysical Behavior of Triethylmethylammonium Tetrabromoferrate(III) under High Pressure2High temperature synergistic response of magnetism, dielectricity, and luminescence in a Mn( ii )-based molecular organic–inorganic hybrid11The past 10 years of molecular ferroelectrics: structures, design, and properties1732D Molecular Ferroelectric with Large Out‐of‐plane Polarization for In‐Memory Computing18Chirality Triggered Biferroicity in a 3D Rubidium Based Perovskite27Biodegradable ferroelectric molecular crystal with large piezoelectric response267Room Temperature Giant Magnetoelectric Coupling for Magnetic Energy Harvesting in Single Phase {CoIII3DyIII} Molecular Nanogenerator0Integrated Multi‐Channel Responsive Switches in a Room‐Temperature Crystal Actuator14A Multiferroic Spin‐Crossover Molecular Crystal32Exploration of room temperature magnetodielectric behavior in Nd0.5Dy0.5FeO3 thin films and transmission line resonators in GHz frequency range1Precisely Regulating Photoactivated Dynamic Room Temperature Phosphorescence by Alkyl Chain‐Induced Lattice‐Softening20Strain‐Induced Tunable Enhancement of Piezoelectricity in a Novel Molecular Multiferroic Material29Perspective on room temperature and low-field-induced magnetoelectric coupling in molecular complexes5Directional Design of Intrachain Electron Transfer in [Fe2Co] Chains Enables Switchable Magnetoelectric Bistability0The First Molecular Ferroelectric Mott Insulator10Molecular dynamics simulations of ferroelectricity in P(VDF-TrFE)1Precise Design of Organic–Inorganic Hybrid Indium Molecular Ferroelectrics Based on Halogen Substitution13Self‐Poled Halide Perovskite Ruddlesden‐Popper Ferroelectric‐Photovoltaic Semiconductor Thin Films and Their Energy Harvesting Properties10Multichannel Magnetic Switching Observed in a Fe(II) Spin-Crossover Compound Bearing Rotatable Ligands1Electrical Detection of Magnetic Perturbations through the Magnetoelectric Effect of a Molecular Spin Triangle2Computational profiling of optical and NLO properties of diisopropylammonium perchlorate5Molecular Ferroelectric Material Realizes Two-Step Wide-Temperature Second-Harmonic Generation Response0A Large Enthalpy Change in One-Dimensional Hybrid Perovskites with Multichannel Switches2Molecular Ferroelectric Exhibiting a 10-Fold Enhancement in Second Harmonic Generation over KDP6An organic–inorganic hybrid indium molecular ferroelectric originating from a “butterfly-flapping” model of 1,5-diazabicyclo[3.3.0]octane2Record‐Low Compressibility in [N(C 2 H 5 ) 3 CH 3 ]FeCl 4 Expands Phase Engineering Horizons in Hybrid Molecular Ferroelectrics0Room Temperature Giant Magnetoelectric Coupling in {Co III 3 Dy III } Molecular Single Crystal Derived Nanogenerator5Chiral Ni2+/Yb3+ molecular complex with room-temperature magnetic-field driven 180° polarization reversal0A Halogen-Substitution Strategy for Tuning Structure, Phase Transition, and Ferroelectric/Nonlinear Optical Properties in Fe-Based ABX4-Type Organic–Inorganic Hybrid Molecular Ferroelectrics0High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0

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  2. Phase Transitions, Prominent Dielectric Anomalies, and Negative Thermal Expansion in Three High Thermally Stable Ammonium Magnesium–Formate Frameworks

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  3. [NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering

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  4. Highly enantioselective oxidative tandem cyclization reaction: a chiral ligand and an anion cooperatively control stereoselectivity

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  5. Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime

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  6. On the Nature of the Structural and Magnetic Phase Transitions in the Layered Perovskite-Like (CH3NH3)2[FeIICl4]

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  7. Iso-structural phase transition in tetramethylammonium nickel(II) nitrite [(CH3)4N][Ni(NO2)3]

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  8. Phase Transition Originating from Order–Disorder Transformations of Carboxy Oxygen Atoms Coupled with Dynamic Proton Motions in [PhCH2NH(CH3)2]2C2O4⋅H2C2O4

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  9. Novel Phase-Transition Materials Coupled with Switchable Dielectric, Magnetic, and Optical Properties: [(CH3)4P][FeCl4] and [(CH3)4P][FeBr4]

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  10. Temperature-Triggered Reversible Dielectric and Nonlinear Optical Switch Based on the One-Dimensional Organic–Inorganic Hybrid Phase Transition Compound [C 6 H 11 NH 3 ] 2 CdCl 4

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  11. Thermodynamic Phase Transition Triggered by Distinct Distortion and Ordering of Dipropylammonium Picrate

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  12. A family of homochiral spin-crossover iron(II) imidazole Schiff-base complexes

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  13. Chiral tetrahedral iron( ii ) cages: diastereoselective subcomponent self-assembly, structure interconversion and spin-crossover properties

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  14. Metal–Organic Frameworks: Functional Magnetic Materials with Formate

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  15. Crystal structures, phase transitions, and switchable dielectric behaviors: comparison of a series of N-heterocyclic ammonium perchlorates

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  16. Two reversible ferroelectric phase transitions in diisopropylammonium perchlorate

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  17. Toward chiral iron(II) spin-crossover grafted resins with imidazole Schiff-base ligands

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  18. High Magnetic Hardness for the Canted Antiferromagnetic, Ferroelectric, and Ferroelastic Layered Perovskite-like (C 2 H 5 NH 3 ) 2 [Fe II Cl 4 ]

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  19. Speciation Analysis in Iron-Mediated ATRP Studied via FT-Near-IR and Mössbauer Spectroscopy

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  20. Reversible Phase Transitions and Dielectric Properties in [(CH3)4P]2[Cr2O7] and [Et4P]2[Cr3O10]

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  21. Dibutylammonium Hydrogen Oxalate: An Above-Room-Temperature Order–Disorder Phase Transition Molecular Material

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  22. Reversible Phase Transition Triggered by Order–Disorder Transformation of Carboxyl Oxygen Atoms Coupled with Distinct Reorientations in [HN(C4H9)3](fumrate)0.5·(fumaric acid)0.5

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  23. Importing spontaneous polarization into a Heisenberg ferromagnet for a potential single-phase multiferroic

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  24. Orientational ordering of guest induced structural phase transition coupled with switchable dielectric properties in a host–guest crystal: bis(thiourea) thiazolium chloride

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  25. Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C 6 H 14 )NH 2 ] 2 ·CuBr 4

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  26. Reversible phase transition triggered by order–disorder transformations and distortions in dipropylammonium d -(+)-10-camphorsulfonate

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  27. Symmetry breaking in molecular ferroelectrics

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  28. Molecular Ferroelectric Pyridin-4-ylmethanaminium Perchlorate Undergoes Paraelectric–Ferroelectric and Ferroelectric–Ferroelectric Phase Transitions

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  29. Magnetic structures and dynamics of multiferroic systems obtained with neutron scattering

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  30. A High‐Temperature Order–Disorder Phase Transition Coupled With Conformational Change in the Hybrid Material [C6H13NH]2⋅ZnBr4

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  31. Synthesis, crystal structure and magnetic properties of an azido-bridged complex [C6H11NH3]2[Mn(N3)4]

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  32. Symmetry Breaking Phase Transition, Second-Order Nonlinear Optical and Dielectric Properties of a One-Dimensional Organic–Inorganic Hybrid Zigzag Chain Compound [NH3(CH2)5NH3]SbBr5

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  33. Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex

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  34. Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex

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  35. Inorganic–organic hybrid switchable dielectric materials with the coexistence of magnetic anomalies induced by reversible high-temperature phase transition

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  36. Prominent dielectric transitions in layered organic–inorganic hybrids: (isoamyl-ammonium) 2 CdX 4 (X = Cl and Br)

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  37. Sequential dielectric phase transitions induced by the vibrations of water molecules in an organic–inorganic hybrid halide (N-(2-ammoniumethyl)piperazinium) CuCl 5 ·2H 2 O

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  38. An insight into the magnetoelectric coupling effect in the MOF of [NH2(CH3)2]n[FeIIIFeII(HCOO)6]n

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  39. Synthesis, crystal structure, and magnetic properties of an azido-bridged Mn(II) complex [C3H5NH3][Mn(N3)3]

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