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RESEARCH PAPER · Inorganic Chemistry · 2015

Coordination Polymers Based on Diiron Tetrakis(dithiolato) Bridged by Alkali Metals, Electrical Bistability around Room Temperature, and Strong Antiferromagnetic Coupling

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Coordination Polymers Based on Diiron Tetrakis(dithiolato) Bridged by Alkali Metals, Electrical Bistability around Room Temperature, and Strong Antiferromagnetic CouplingOriginalUnprecedented layered coordination polymers of dithiolene group 10 metals: magnetic and electrical properties13Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)]0Structural Diversity of Compounds Based on Iron-Dithiolene with Sodium or Potassium Complexes10Unprecedented Inequivalent Metal Coordination Environments in a Mixed‐Ligand Dicobalt Complex5A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde7A new semiconducting 1D Cu( i )–Cu( ii ) mixed-valence coordination polymer with Cu( ii ) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu( i )–Br cluster unit14Crystal Structure and Band-Gap Engineering of a Semiconducting Coordination Polymer Consisting of Copper(I) Bromide and a Bridging Acceptor Ligand26Copper dithiolene [Cu(SC 6 H 2 Cl 2 S) 2 ] − units connected to alkaline/copper complexes: from ionic assemblies to discrete molecular entities and coordination polymers4Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations2Organic ligand capping of CuI for enhanced electrical and ionic conductivity5Structural Study of the Compounds Formed in the Reactions of FeCl3·6H2O with Ni(OH)2 in the Presence of Dithiolenes HSRSH (R = C6H2Cl2 or C6H4)2Structural Factors Governing the Formation of Extended Structures in Group 10 and 12 Metal-Dithiolenes3Proton and Electron Transfer in the Formation of a Copper Dithiolene-Based Coordination Polymer7Conductive MOFs based on Thiol-functionalized Linkers: Challenges, Opportunities, and Recent Advances111

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  1. Unprecedented layered coordination polymers of dithiolene group 10 metals: magnetic and electrical properties

    Dalton Transactions · 2016-01-01

    Esther Delgado, Carlos J. Gómez‐García, Diego Hernández, Elisa Hernández, Avelino Martı́n, Félix Zamora

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  2. Di-μ-dimethylformamide-κ4O:O-μ-tetrahydrofuran-κ2O:O-bis[(tetrahydrofuran-κO)sodium(I)] bis(μ-3,6-dichlorobenzene-1,2-dithiolato-κ3S,S′:S)bis[(3,6-dichlorobenzene-1,2-dithiolato-κ2S,S′)iron(III)]

    IUCrData · 2016-04-22

    Jesús Barrio, Esther Delgado, Diego Hernández, Elisa Hernández, Josefina Perles, Félix Zamora

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  3. Structural Diversity of Compounds Based on Iron-Dithiolene with Sodium or Potassium Complexes

    Crystal Growth & Design · 2016-07-20

    Óscar Castillo, Esther Delgado, Diego Hernández, Elisa Hernández, Avelino Martı́n, Ignacio Martín, Félix Zamora

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  4. Unprecedented Inequivalent Metal Coordination Environments in a Mixed‐Ligand Dicobalt Complex

    European Journal of Inorganic Chemistry · 2017-07-07

    Giacomo Cioncoloni, Stephen A. Sproules, Claire Wilson, Mark D. Symes

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  5. A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde

    Inorganic Chemistry Communications · 2017-12-20

    Kento Himoto, Toshiya Horii, Takumi Syoji, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda‐Sowa

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  6. A new semiconducting 1D Cu( i )–Cu( ii ) mixed-valence coordination polymer with Cu( ii ) dimethylpiperidine–dithiocarbamate and a tetranuclear Cu( i )–Br cluster unit

    New Journal of Chemistry · 2018-01-01

    Kento Himoto, Shimpei Suzuki, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda‐Sowa

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  7. Crystal Structure and Band-Gap Engineering of a Semiconducting Coordination Polymer Consisting of Copper(I) Bromide and a Bridging Acceptor Ligand

    Inorganic Chemistry · 2018-02-12

    Takashi Okubo, Kento Himoto, Koki Tanishima, Sanshiro Fukuda, Yusuke Noda, Masanobu Nakayama, Kunihisa Sugimoto, Masahiko Maekawa, Takayoshi Kuroda‐Sowa

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  8. Copper dithiolene [Cu(SC 6 H 2 Cl 2 S) 2 ] − units connected to alkaline/copper complexes: from ionic assemblies to discrete molecular entities and coordination polymers

    CrystEngComm · 2018-11-21

    Pilar Amo‐Ochoa, Óscar Castillo, Esther Delgado, Ana Gallut, Elisa Hernández, Josefina Perles, Félix Zamora

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  9. Synthesis and structural characterization of transition metal dithiolene derivatives containing divalent metals as counter-cations

    CrystEngComm · 2019-01-01

    Óscar Castillo, Esther Delgado, Diego Hernández, Elisa Hernández, Avelino Martı́n, Félix Zamora

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  10. Organic ligand capping of CuI for enhanced electrical and ionic conductivity

    Journal of Materials Research and Technology · 2019-04-01

    Jositta Sherine, Emayavaramban Indubala, Revathy Rajagopal, Seshadri Harinipriya

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  11. Structural Study of the Compounds Formed in the Reactions of FeCl3·6H2O with Ni(OH)2 in the Presence of Dithiolenes HSRSH (R = C6H2Cl2 or C6H4)

    Molecules · 2020-05-10

    Esther Delgado, Elisa Hernández, María Pérez, Josefina Perles, Félix Zamora

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  12. Structural Factors Governing the Formation of Extended Structures in Group 10 and 12 Metal-Dithiolenes

    Crystal Growth & Design · 2020-05-12

    Óscar Castillo, Esther Delgado, Elisa Hernández, María Pérez, Félix Zamora

    Read original paper ↗ ·
  13. Proton and Electron Transfer in the Formation of a Copper Dithiolene-Based Coordination Polymer

    Inorganic Chemistry · 2021-06-02

    Stefan Henfling, Anastasia Kultaeva, Andreas Pöppl, Jennifer Klose, Berthold Kersting, K.V. Domasevitch, Harald Krautscheid

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  14. Conductive MOFs based on Thiol-functionalized Linkers: Challenges, Opportunities, and Recent Advances

    Coordination Chemistry Reviews · 2021-10-08

    Xiangling Deng, Sai-Li Zheng, Yuan‐Hui Zhong, Jieying Hu, Lai‐Hon Chung, Jun Hui He

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