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RESEARCH PAPER · Journal of the American Chemical Society · 2015

Dynamic Optical Properties of CH 3 NH 3 PbI 3 Single Crystals As Revealed by One- and Two-Photon Excited Photoluminescence Measurements

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Dynamic Optical Properties of CH 3 NH 3 PbI 3 Single Crystals As Revealed by One- and Two-Photon Excited Photoluminescence MeasurementsOriginalDegradation mechanism of perovskite CH3NH3PbI3 diode devices studied by electroluminescence and photoluminescence imaging spectroscopy33Distinctive excitonic recombination in solution-processed layered organic–inorganic hybrid two-dimensional perovskites24Interplay of structural and compositional effects on carrier recombination in mixed-halide perovskites24Optical characterizations of the surface states in hybrid lead–halide perovskites60Fast Free‐Carrier Diffusion in CH3NH3PbBr3 Single Crystals Revealed by Time‐Resolved One‐ and Two‐Photon Excitation Photoluminescence Spectroscopy118Hybrid organic—inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties1556Interfacial Oxygen Vacancies as a Potential Cause of Hysteresis in Perovskite Solar Cells154Experimental Evidence of Localized Shallow States in Orthorhombic Phase of CH3NH3PbI3 Perovskite Thin Films Revealed by Photocurrent Beat Spectroscopy37Charge Carrier Lifetimes Exceeding 15 μs in Methylammonium Lead Iodide Single Crystals284Carrier injection and recombination processes in perovskite CH3NH3PbI3solar cells studied by electroluminescence spectroscopy1Two-Photon-Pumped Perovskite Semiconductor Nanocrystal Lasers574Diffusion-correlated local photoluminescence kinetics in CH3NH3PbI3 perovskite single-crystalline particles18Growth and Characterization of PDMS-Stamped Halide Perovskite Single Microcrystals33Structural Phase- and Degradation-Dependent Thermal Conductivity of CH 3 NH 3 PbI 3 Perovskite Thin Films64Controlling the Cavity Structures of Two‐Photon‐Pumped Perovskite Microlasers240Amplified Spontaneous Emission from Organic–Inorganic Hybrid Lead Iodide Perovskite Single Crystals under Direct Multiphoton Excitation59Optical characterization of voltage-accelerated degradation in CH_3NH_3PbI_3 perovskite solar cells28The Effects of Electronic Impurities and Electron–Hole Recombination Dynamics on Large‐Grain Organic–Inorganic Perovskite Photovoltaic Efficiencies79Interfacial Charge-Carrier Trapping in CH3NH3PbI3-Based Heterolayered Structures Revealed by Time-Resolved Photoluminescence Spectroscopy68Halide Perovskites: Poor Man's High‐Performance Semiconductors460Discerning the Surface and Bulk Recombination Kinetics of Organic–Inorganic Halide Perovskite Single Crystals347Slow Organic‐to‐Inorganic Sub‐Lattice Thermalization in Methylammonium Lead Halide Perovskites Observed by Ultrafast Photoluminescence38Role of Cations on the Electronic Transport and Optical Properties of Lead-Iodide Perovskites73Free Carriers versus Excitons in CH3NH3PbI3 Perovskite Thin Films at Low Temperatures: Charge Transfer from the Orthorhombic Phase to the Tetragonal Phase89Is CH3NH3PbI3 Polar?158Recent progress on perovskite solar cells and our materials science1Ultrahigh sensitivity of methylammonium lead tribromide perovskite single crystals to environmental gases369Low Threshold Two-Photon-Pumped Amplified Spontaneous Emission in CH3NH3PbBr3 Microdisks62Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation548Charge Injection at the Heterointerface in Perovskite CH3NH3PbI3 Solar Cells Studied by Simultaneous Microscopic Photoluminescence and Photocurrent Imaging Spectroscopy40Limits of Carrier Diffusion in n ‑Type and p ‑Type CH3NH3PbI3 Perovskite Single Crystals103CH 3 NH 3 PbI 3 : precise structural consequences of water absorption at ambient conditions42Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction71Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction18Screening in crystalline liquids protects energetic carriers in hybrid perovskites811Mechanism for rapid growth of organic–inorganic halide perovskite crystals266Persistent Energetic Electrons in Methylammonium Lead Iodide Perovskite Thin Films130Free Excitons and Exciton–Phonon Coupling in CH3NH3PbI3 Single Crystals Revealed by Photocurrent and Photoluminescence Measurements at Low Temperatures109Carrier Decay Properties of Mixed Cation Formamidinium–Methylammonium Lead Iodide Perovskite [HC(NH2)2]1–x[CH3NH3]xPbI3 Nanorods69Narrow Linewidth Excitonic Emission in Organic–Inorganic Lead Iodide Perovskite Single Crystals102Inorganic Lead Halide Perovskite Single Crystals: Phase‐Selective Low‐Temperature Growth, Carrier Transport Properties, and Self‐Powered Photodetection472Internal luminescence efficiencies in InGaP/GaAs/Ge triple-junction solar cells evaluated from photoluminescence through optical coupling between subcells19Size-dependent one-photon- and two-photon-pumped amplified spontaneous emission from organometal halide CH 3 NH 3 PbBr 3 perovskite cubic microcrystals38Global Analysis of Perovskite Photophysics Reveals Importance of Geminate Pathways27An optical dynamic study of MAPbBr 3 single crystals passivated with MAPbCl 3 /I 3 -MAPbBr 3 heterojunctions50Crystal structure and electron transition underlying photoluminescence of methylammonium lead bromide perovskites76Luminescence spectroscopy of lead-halide perovskites: materials properties and application as photovoltaic devices130Photon Emission and Reabsorption Processes in CH3NH3PbBr3 Single Crystals Revealed by Time-Resolved Two-Photon-Excitation Photoluminescence Microscopy142Long Minority‐Carrier Diffusion Length and Low Surface‐Recombination Velocity in Inorganic Lead‐Free CsSnI3 Perovskite Crystal for Solar Cells239Analyzing the Electrical Performance of a Solar Cell with Time-Resolved Photoluminescence: Methodology for Fast Optical Screening23Double Charged Surface Layers in Lead Halide Perovskite Crystals66Charge Injection Mechanism at Heterointerfaces in CH3NH3PbI3 Perovskite Solar Cells Revealed by Simultaneous Time-Resolved Photoluminescence and Photocurrent Measurements108Sensitive monitoring of photocarrier densities in the active layer of a photovoltaic device with time-resolved terahertz reflection spectroscopy11Time-Resolved Infrared Spectroscopy Directly Probes Free and Trapped Carriers in Organo-Halide Perovskites51Quantification of re-absorption and re-emission processes to determine photon recycling efficiency in perovskite single crystals245Unbalanced Hole and Electron Diffusion in Lead Bromide Perovskites136Tuning the Competitive Recombination of Free Carriers and Bound Excitons in Perovskite CH3NH3PbBr3 Single Crystal21Dynamics of Charged Excitons and Biexcitons in CsPbBr3 Perovskite Nanocrystals Revealed by Femtosecond Transient-Absorption and Single-Dot Luminescence Spectroscopy210Improved Performance and Stability of All‐Inorganic Perovskite Light‐Emitting Diodes by Antisolvent Vapor Treatment263Reduced Interface‐Mediated Recombination for High Open‐Circuit Voltages in CH3NH3PbI3 Solar Cells253Origin of Open-Circuit Voltage Loss in Polymer Solar Cells and Perovskite Solar Cells38Charge carrier injection at the heterointerface in CH3NH3PbI3 perovskite solar cells studied by time-resolved photoluminescence and photocurrent imaging spectroscopy1Free excitons and exciton-phonon coupling in CH3NH3PbI3 perovskite single crystals at low temperatures0Impact of photon recycling on carrier recombination processes in CH3NH3PbBr3 single crystals revealed by time-resolved two-photon-excitation microscopy0The Emergence of the Mixed Perovskites and Their Applications as Solar Cells146Symmetrization of the Crystal Lattice of MAPbI3 Boosts the Performance and Stability of Metal–Perovskite Photodiodes70Impact of Reabsorption on the Emission Spectra and Recombination Dynamics of Hybrid Perovskite Single Crystals121Photocarrier Recombination and Injection Dynamics in Long-Term Stable Lead-Free CH3NH3SnI3 Perovskite Thin Films and Solar Cells102Dependence of the Electronic and Optical Properties of Methylammonium Lead Triiodide on Ferroelectric Polarization Directions and Domains: A First Principles Computational Study11Ion Migration Heals Trapping Centers in CH3NH3PbBr3 Perovskite64Ultralong Radiative States in Hybrid Perovskite Crystals: Compositions for Submillimeter Diffusion Lengths100Ultrasensitive and Fast All‐Inorganic Perovskite‐Based Photodetector via Fast Carrier Diffusion319Consolidation of the optoelectronic properties of CH3NH3PbBr3 perovskite single crystals259Free Carrier Radiative Recombination and Photon Recycling in Lead Halide Perovskite Solar Cell Materials76Nonlinear photocarrier recombination dynamics in mixed-halide CH3NH3Pb(I1− x Br x )3 perovskite thin films10Robust Cesium Lead Halide Perovskite Microcubes for Frequency Upconversion Lasing72Review—Light Emission from Thin Film Solar Cell Materials: An Emerging Infrared and Visible Light Emitter12Enhanced Size Selection in Two-Photon Excitation for CsPbBr3 Perovskite Nanocrystals50Structural Evolution in BaSn2F5X (X = Cl, Br, I): A Family of Alkaline Earth Metal Tin Mixed Halides15Prediction on electronic structure of CH 3 NH 3 PbI 3 /Fe 3 O 4 interfaces3Breathing bands due to molecular order in CH3NH3PbI316Two‐Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates38Recent Progress in Single‐Crystalline Perovskite Research Including Crystal Preparation, Property Evaluation, and Applications305Impact of Chemical Doping on Optical Responses in Bismuth-Doped CH3NH3PbBr3 Single Crystals: Carrier Lifetime and Photon Recycling114Impact of Postsynthetic Surface Modification on Photoluminescence Intermittency in Formamidinium Lead Bromide Perovskite Nanocrystals86Temperature-dependent electronic properties of inorganic-organic hybrid halide perovskite (CH3NH3PbBr3) single crystal14Photophysical Model for Non-Exponential Relaxation Dynamics in Hybrid Perovskite Semiconductors16Lasing Characteristics of CH3NH3PbCl3 Single‐Crystal Microcavities under Multiphoton Excitation25Crystal orientation-dependent optoelectronic properties of MAPbCl 3 single crystals95Improved performance of CsPbBr 3 perovskite light-emitting devices by both boundary and interface defects passivation37Photo-induced dual passivation via Usanovich acid–base on surface defects of methylammonium lead triiodide perovskite6Precursor purity effects on solution-based growth of MAPbBr 3 single crystals towards efficient radiation sensing55Surface potential mapping and n-type conductivity in organic–inorganic lead iodide crystals11Understanding the temperature-dependent charge transport, structural variation and photoluminescent properties in methylammonium lead halide perovskite single crystals18High‐Performance Single‐Crystalline Perovskite Thin‐Film Photodetector301Excitations Partition into Two Distinct Populations in Bulk Perovskites11Time-resolved photoluminescence studies on localization effects in orthorhombic phase of CH3NH3PbI3 perovskite thin film3Near-Band-Edge Optical Responses of CH 3 NH 3 PbCl 3 Single Crystals: Photon Recycling of Excitonic Luminescence101Photophysics of organic-inorganic hybrid perovskite solar cells0Observation of Unusual Optical Band Structure of CH3NH3PbI3 Perovskite Single Crystal38Top-Down Approaches Towards Single Crystal Perovskite Solar Cells43Diversity of band gap and photoluminescence properties of lead halide perovskite: A halogen-dependent spectroscopic study10Photorefractive Effect in Organic–Inorganic Hybrid Perovskites and Its Application to Optical Phase Shifter43Evaluation of the effect that the substitution of the ion MA by the ion Cs produces on the properties of thin films of Cs MA1-PbI3 prepared by spin-coating7Energy transfer mechanisms in layered 2D perovskites83Tunable Crystallization and Nucleation of Planar CH3NH3PbI3 through Solvent-Modified Interdiffusion15Hot Biexciton Effect on Optical Gain in CsPbI3 Perovskite Nanocrystals93Imaging Carrier Diffusion in Perovskites with a Diffractive Optic-Based Transient Absorption Microscope48Twin Domains in Organometallic Halide Perovskite Thin-Films25Bilayered Hybrid Perovskite Ferroelectric with Giant Two-Photon Absorption242Influence of the Concentration of Cs on the Properties of Thin Films of CsXMA(1-X)PbI3 to be used as Active Layer in Hybrid Solar Cells0Photon Upconversion through a Cascade Process of Two-Photon Absorption in CsPbBr3 and Triplet–Triplet Annihilation in Porphyrin/Diphenylanthracene20Nonlinear optical properties of lead halide perovskites1Radiative recombination and electron-phonon coupling in lead-free CH3NH3SnI3 perovskite thin films55Spatial-temporal spectroscopy characterizations and electronic structure of methylammonium perovskites14Can SHG Measurements Determine the Polarity of Hybrid Lead Halide Perovskites?31Nontrivial strength of van der Waals epitaxial interaction in soft perovskites51Template-Free Synthesis of High-Yield Fe-Doped Cesium Lead Halide Perovskite Ultralong Microwires with Enhanced Two-Photon Absorption84Photophysics of metal halide perovskites: From materials to devices70Yellow Emission from Low Coordination Site of Sr2SiO4:Eu2+, Ce3+: Influence of Lanthanide Dopants on the Electron Density and Crystallinity in Crystal Site Engineering Approach31Optoelectronic Dichotomy of Mixed Halide CH3NH3Pb(Br1– x Cl x )3 Single Crystals: Surface versus Bulk Photoluminescence24Compositional and orientational control in metal halide perovskites of reduced dimensionality469Photoelectronic properties of lead-free CH3NH3SnI3 perovskite solar cell materials and devices2Insight into Photon Recycling in Perovskite Semiconductors from the Concept of Photon Diffusion26Longitudinal Optical Phonons Modified by Organic Molecular Cation Motions in Organic-Inorganic Hybrid Perovskites79Quantitative monitoring of the internal field in the depletion layer of a GaAs-based solar cell with terahertz radiation4Surface Characterization and Reactivity of Methylammionium Lead Iodide0Optically tuned and large-grained bromine doped CH3NH3PbI3 perovskite thin films via aerosol-assisted chemical vapour deposition8The Photophysics of Halide Perovskite Solar Cells2Lead Vacancy Can Explain the Suppressed Nonradiative Electron–Hole Recombination in FAPbI3 Perovskite under Iodine-Rich Conditions: A Time-Domain Ab Initio Study35Dual-Emission and Two Charge-Transfer States in Ytterbium-doped Cesium Lead Halide Perovskite Solid Nanocrystals44Experimental Demonstration of Correlated Flux Scaling in Photoconductivity and Photoluminescence of Lead-Halide Perovskites17Atomic scale insights into structure instability and decomposition pathway of methylammonium lead iodide perovskite224Observation of positive and negative trions in organic-inorganic hybrid perovskite nanocrystals48Optical properties of CH3NH3PbI3 crystal grown using inverse temperature crystallization6Structural dynamics in hybrid halide perovskites: Bulk Rashba splitting, spin texture, and carrier localization26Enhanced single-mode lasers of all-inorganic perovskite nanocube by localized surface plasmonic effect from Au nanoparticles36Enhancing the Performance of Inverted Perovskite Solar Cells via Grain Boundary Passivation with Carbon Quantum Dots187Direct synthesis of cubic phase CsPbI 3 nanowires51Large scale quantum dynamics investigations on the sensing mechanism of H 2 O, acetone, NO 2 and O 3 adsorption on the (MA) 2 Pb(SCN) 2 I 2 surface11Liquid water-induced growth of the 1D morphology of CH 3 NH 3 PbI 3 hybrid perovskites21Monocrystalline perovskite wafers/thin films for photovoltaic and transistor applications45External stokes shift of perovskite nanocrystals enlarged by photon recycling46Photoexcited Dynamics in Metal Halide Perovskites: From Relaxation Mechanisms to Applications12Up-converted photoluminescence from CH3NH3PbI3 perovskite semiconductors: Implications for laser cooling41Charge Transfer Dynamics of Phase-Segregated Halide Perovskites: CH3NH3PbCl3 and CH3NH3PbI3 or (C4H9NH3)2(CH3NH3)n−1PbnI3n+1 Mixtures19X-ray luminescence in undoped and bismuth-doped single crystal hybrid lead halide perovskites4Doping-Enhanced Visible-Light Absorption of CH3NH3PbBr3 by the Bi3+-Induced Impurity Band without Sacrificing a Band gap29High-order harmonic generation from hybrid organic–inorganic perovskite thin films60The Dominant Energy Transport Pathway in Halide Perovskites: Photon Recycling or Carrier Diffusion?115

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  29. Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation

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  31. Limits of Carrier Diffusion in n ‑Type and p ‑Type CH3NH3PbI3 Perovskite Single Crystals

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  32. CH 3 NH 3 PbI 3 : precise structural consequences of water absorption at ambient conditions

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  33. Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction

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  34. Limiting Perovskite Solar Cell Performance by Heterogeneous Carrier Extraction

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  35. Screening in crystalline liquids protects energetic carriers in hybrid perovskites

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  36. Mechanism for rapid growth of organic–inorganic halide perovskite crystals

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  37. Persistent Energetic Electrons in Methylammonium Lead Iodide Perovskite Thin Films

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  38. Free Excitons and Exciton–Phonon Coupling in CH3NH3PbI3 Single Crystals Revealed by Photocurrent and Photoluminescence Measurements at Low Temperatures

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  39. Carrier Decay Properties of Mixed Cation Formamidinium–Methylammonium Lead Iodide Perovskite [HC(NH2)2]1–x[CH3NH3]xPbI3 Nanorods

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