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RESEARCH PAPER · Inorganic Chemistry · 2015

Ba3Pt4Al4—Structure, Properties, and Theoretical and NMR Spectroscopic Investigations of a Complex Platinide Featuring Heterocubane [Pt4Al4] Units

Frank Stegemann, Christopher Benndorf, Timo Bartsch, Rachid S. Touzani, Manfred Bartsch, H. Zacharias, Boniface P. T. Fokwa, Hellmut Eckert, Oliver Janka

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Ba3Pt4Al4—Structure, Properties, and Theoretical and NMR Spectroscopic Investigations of a Complex Platinide Featuring Heterocubane [Pt4Al4] UnitsOriginalChemInform Abstract: Ba3Pt4Al4 — Structure, Properties, and Theoretical and NMR Spectroscopic Investigations of a Complex Platinide Featuring Heterocubane [Pt4Al4] Units.0Palladium pnictide oxides Nd 10 Pd 3 As 8 O 10 and Sm 10 Pd 3 As 8 O 10 – low temperature structural phase transition and physical properties3Sr2Pd4Al5: Synthesis, Crystal and Electronic Structures, and Chemical Bonding of a Polar Intermetallic Compound11Experimental and theoretical investigations of the polar intermetallics SrPt3Al2 and Sr2Pd2Al23EuAu3Al2: Crystal and Electronic Structures and Spectroscopic, Magnetic, and Magnetocaloric Properties20Equiatomic AEAuX (AE=Ca−Ba, X=Al−In) Intermetallics: A Systematic Study of their Electronic Structure and Spectroscopic Properties15Network Formation by Condensed Tetrahedral [Au3Al] Units in Na2Au3Al: Crystal and Electronic Structure, Spectroscopic Investigations, and Physical Properties of an Ordered Ternary Auride16On Ternary Intermetallic Aurides: CaAu2Al2, SrAu2–xAl2+xand Ba3Au5+xAl6–x8Structural Characterization of Intermetallic Compounds by 27Al Solid State NMR Spectroscopy36Crystal Structure, Spectroscopic Investigations, and Physical Properties of the Ternary Intermetallic REPt2Al3 (RE = Y, Dy–Tm) and RE2Pt3Al4 Representatives (RE = Tm, Lu)12Two series of rare earth metal-rich ternary aluminium transition metallides – RE 6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE 6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu)12Temperature induced valence phase transition in intermediate-valent YbPd 2 Al 317Unusually strong heteroatomic bonding in the complex polyanion of intermetallic Ba 6 Pt 22 Al 535Correlations of Crystal and Electronic Structure via NMR and X-ray Photoelectron Spectroscopies in the RETMAl2(RE = Sc, Y, La–Nd, Sm, Gd–Tm, Lu; TM = Ni, Pd, Pt) Series31From 3D to 2D: Structural, Spectroscopic and Theoretical Investigations of the Dimensionality Reduction in the [PtAl2]δ− Polyanions of the Isotypic MPtAl2 Series (M=Ca–Ba, Eu)35On the formation of the Gd 3 Ru 4 Al 12 versus the Y 2 Co 3 Ga 9 type structure – M 3 Rh 4 Al 12 (M = Ca, Eu) versus M 2 T 3 Al 9 (M = Ca, Sr, Eu, Yb; T = Ir, Pt)11Structural, Physical, Theoretical and Spectroscopic Investigations of Mixed‐Valent Eu2Ni8Si3 and Its Structural Anti‐Type Sr2Pt3Al87Coordination of a Potentially Tritopic Ligand via Phosphorus, Nitrogen and Oxygen: From Ligand Design to Heterobimetallic Metal–Organic Frameworks and Supramolecules9Synthesis, crystal and electronic structure of CaNi 2 Al 83SrAl5Pt3 and Sr2Al16Pt9 – two new strontium aluminum platinides7Raman and NMR spectroscopic and theoretical investigations of the cubic laves-phases REAl 2 (RE = Sc, Y, La, Yb, Lu)11Theoretical and 27Al NMR Spectroscopic Investigations of Binary Intermetallic Alkaline-Earth Aluminides16Formation of the Sub-oxide Sc4Au2O1–x and the Drastically Negative 27Al NMR Shift in Sc2Al3Synthesis, magnetic and NMR spectroscopic properties of the MAl 5 Pt 3 series (M = Ca, Y, La–Nd, Sm–Er)5Nominal CaAl2Pt2 and Ca2Al3Pt – two new Intermetallic Compounds in the Ternary System Ca−Al−Pt1Structure, physical and 27Al NMR-spectroscopic properties of the equiatomic compounds of the type REAlRh (RE = Sm, Tb, Dy, Er, and Lu)1Temperature-dependent diffraction studies on the stannides Sr3Rh4Sn4, Sr3Ir4Sn4 and Sr2.43Eu0.57Ir4Sn40New alkaline earth and rare earth representatives adopting the Ce2Al16Pt9-type structure3SrAl8Rh2 – the first phase in the Sr/Al/Rh system and new representative of the CeAl8Fe2 type structure3Hf6Al7 and Hf4.44(1)Nb1.56(1)Al7—the First Fully Ordered Main Group Metal Containing W6Fe7 Type Compound and its Ternary Coloring Variant0

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  1. ChemInform Abstract: Ba3Pt4Al4 — Structure, Properties, and Theoretical and NMR Spectroscopic Investigations of a Complex Platinide Featuring Heterocubane [Pt4Al4] Units.

    ChemInform · 2015-12-21

    Frank Stegemann, Christopher Benndorf, Timo Bartsch, Rachid S. Touzani, Manfred Bartsch, H. Zacharias, Boniface P. T. Fokwa, Hellmut Eckert, Oliver Janka

    Read original paper ↗ ·

  2. Palladium pnictide oxides Nd 10 Pd 3 As 8 O 10 and Sm 10 Pd 3 As 8 O 10 – low temperature structural phase transition and physical properties

    Journal of Materials Chemistry C · 2016-01-01

    Timo Bartsch, Oliver Niehaus, Rolf‐Dieter Hoffmann, Manfred Bartsch, H. Zacharias, Dirk Johrendt, Rainer Pöttgen

    Read original paper ↗ ·

  3. Sr2Pd4Al5: Synthesis, Crystal and Electronic Structures, and Chemical Bonding of a Polar Intermetallic Compound

    European Journal of Inorganic Chemistry · 2016-02-04

    Frank Stegemann, Christopher Benndorf, Rachid S. Touzani, Boniface P. T. Fokwa, Oliver Janka

    Read original paper ↗ ·

  4. Experimental and theoretical investigations of the polar intermetallics SrPt3Al2 and Sr2Pd2Al

    Journal of Solid State Chemistry · 2016-07-20

    Frank Stegemann, Christopher Benndorf, Rachid S. Touzani, Boniface P. T. Fokwa, Oliver Janka

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  5. EuAu3Al2: Crystal and Electronic Structures and Spectroscopic, Magnetic, and Magnetocaloric Properties

    Inorganic Chemistry · 2016-08-17

    Jan‐Patrick Schmiegel, Theresa Block, Birgit Gerke, Thomas Fickenscher, Rachid S. Touzani, Boniface P. T. Fokwa, Oliver Janka

    Read original paper ↗ ·

  6. Equiatomic AEAuX (AE=Ca−Ba, X=Al−In) Intermetallics: A Systematic Study of their Electronic Structure and Spectroscopic Properties

    Chemistry - A European Journal · 2017-01-31

    Christopher Benndorf, Frank Stegemann, Stefan Seidel, Lea Schubert, Manfred Bartsch, H. Zacharias, Bernhard Mausolf, Frank Haarmann, Hellmut Eckert, Rainer Pöttgen, Oliver Janka

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  7. Network Formation by Condensed Tetrahedral [Au3Al] Units in Na2Au3Al: Crystal and Electronic Structure, Spectroscopic Investigations, and Physical Properties of an Ordered Ternary Auride

    Inorganic Chemistry · 2017-01-31

    Frank Stegemann, Christopher Benndorf, Yuemei Zhang, Manfred Bartsch, H. Zacharias, Boniface P. T. Fokwa, Hellmut Eckert, Oliver Janka

    Read original paper ↗ ·

  8. On Ternary Intermetallic Aurides: CaAu2Al2, SrAu2–xAl2+xand Ba3Au5+xAl6–x

    Zeitschrift für anorganische und allgemeine Chemie · 2017-05-19

    Frank Stegemann, Christopher Benndorf, Yuemei Zhang, Manfred Bartsch, H. Zacharias, Boniface P. T. Fokwa, Hellmut Eckert, Oliver Janka

    Read original paper ↗ ·

  9. Structural Characterization of Intermetallic Compounds by 27Al Solid State NMR Spectroscopy

    Accounts of Chemical Research · 2017-06-07

    Christopher Benndorf, Hellmut Eckert, Oliver Janka

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  10. Crystal Structure, Spectroscopic Investigations, and Physical Properties of the Ternary Intermetallic REPt2Al3 (RE = Y, Dy–Tm) and RE2Pt3Al4 Representatives (RE = Tm, Lu)

    Crystals · 2018-04-16

    Fabian Eustermann, Simon Gausebeck, Carsten Dosche, Mareike Haensch, Günther Wittstock, Oliver Janka

    Read original paper ↗ ·

  11. Two series of rare earth metal-rich ternary aluminium transition metallides – RE 6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE 6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu)

    Zeitschrift für Naturforschung B · 2018-09-27

    Frank Stegemann, Oliver Janka

    Read original paper ↗ ·

  12. Temperature induced valence phase transition in intermediate-valent YbPd 2 Al 3

    Chemical Science · 2019-01-01

    Frank Stegemann, Juliane Stahl, Manfred Bartsch, H. Zacharias, Dirk Johrendt, Oliver Janka

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  13. Unusually strong heteroatomic bonding in the complex polyanion of intermetallic Ba 6 Pt 22 Al 53

    Dalton Transactions · 2019-01-01

    Frank Stegemann, Rachid S. Touzani, Oliver Janka

    Read original paper ↗ ·

  14. Correlations of Crystal and Electronic Structure via NMR and X-ray Photoelectron Spectroscopies in the RETMAl2(RE = Sc, Y, La–Nd, Sm, Gd–Tm, Lu; TM = Ni, Pd, Pt) Series

    Inorganic Chemistry · 2019-05-07

    Mathis Radzieowski, Frank Stegemann, Carsten Doerenkamp, Samir F. Matar, Hellmut Eckert, Carsten Dosche, Günther Wittstock, Oliver Janka

    Read original paper ↗ ·

  15. From 3D to 2D: Structural, Spectroscopic and Theoretical Investigations of the Dimensionality Reduction in the [PtAl2]δ− Polyanions of the Isotypic MPtAl2 Series (M=Ca–Ba, Eu)

    Chemistry - A European Journal · 2019-05-29

    Frank Stegemann, Theresa Block, Steffen Klenner, Yuemei Zhang, Boniface P. T. Fokwa, Alexander Timmer, Harry Mönig, Carsten Doerenkamp, Hellmut Eckert, Oliver Janka

    Read original paper ↗ ·

  16. On the formation of the Gd 3 Ru 4 Al 12 versus the Y 2 Co 3 Ga 9 type structure – M 3 Rh 4 Al 12 (M = Ca, Eu) versus M 2 T 3 Al 9 (M = Ca, Sr, Eu, Yb; T = Ir, Pt)

    Dalton Transactions · 2020-01-01

    Frank Stegemann, Yuemei Zhang, Boniface P. T. Fokwa, Oliver Janka

    Read original paper ↗ ·

  17. Structural, Physical, Theoretical and Spectroscopic Investigations of Mixed‐Valent Eu2Ni8Si3 and Its Structural Anti‐Type Sr2Pt3Al8

    European Journal of Inorganic Chemistry · 2021-07-30

    Frank Stegemann, Theresa Block, Steffen Klenner, Yuemei Zhang, Boniface P. T. Fokwa, Carsten Doerenkamp, Hellmut Eckert, Oliver Janka

    Read original paper ↗ ·

  18. Coordination of a Potentially Tritopic Ligand via Phosphorus, Nitrogen and Oxygen: From Ligand Design to Heterobimetallic Metal–Organic Frameworks and Supramolecules

    Crystal Growth & Design · 2021-09-07

    Hans Gildenast, Franziska Busse, Ulli Englert

    Read original paper ↗ ·

  19. Synthesis, crystal and electronic structure of CaNi 2 Al 8

    Zeitschrift für Naturforschung B · 2021-09-22

    Elias C. J. Gießelmann, Rachid S. Touzani, Bernd Morgenstern, Oliver Janka

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  20. SrAl5Pt3 and Sr2Al16Pt9 – two new strontium aluminum platinides

    Zeitschrift für Naturforschung B · 2022-03-11

    Stefan Engel, Judith Bönnighausen, Frank Stegemann, Rachid S. Touzani, Oliver Janka

    Read original paper ↗ ·

  21. Raman and NMR spectroscopic and theoretical investigations of the cubic laves-phases REAl 2 (RE = Sc, Y, La, Yb, Lu)

    Dalton Transactions · 2023-01-01

    Elias C. J. Gießelmann, Stefan Engel, Weronika Kostusiak, Yuemei Zhang, Petra Herbeck‐Engel, Guido Kickelbick, Oliver Janka

    Read original paper ↗ ·

  22. Theoretical and 27Al NMR Spectroscopic Investigations of Binary Intermetallic Alkaline-Earth Aluminides

    Inorganic Chemistry · 2023-02-27

    Stefan Engel, Elias C. J. Gießelmann, Lukas E. Schank, Günter Heymann, Kristina Brix, Ralf Kautenburger, Horst Philipp Beck, Oliver Janka

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  23. Formation of the Sub-oxide Sc4Au2O1–x and the Drastically Negative 27Al NMR Shift in Sc2Al

    Inorganic Chemistry · 2023-06-02

    Elias C. J. Gießelmann, Mathis Radzieowski, Samir F. Matar, Oliver Janka

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  24. Synthesis, magnetic and NMR spectroscopic properties of the MAl 5 Pt 3 series (M = Ca, Y, La–Nd, Sm–Er)

    Dalton Transactions · 2024-01-01

    Stefan Engel, Elias C. J. Gießelmann, Lars Schumacher, Yuemei Zhang, Frank Müller, Oliver Janka

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  25. Nominal CaAl2Pt2 and Ca2Al3Pt – two new Intermetallic Compounds in the Ternary System Ca−Al−Pt

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-24

    Stefan Engel, Marcus Koch, Oliver Janka

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  26. Structure, physical and 27Al NMR-spectroscopic properties of the equiatomic compounds of the type REAlRh (RE = Sm, Tb, Dy, Er, and Lu)

    Zeitschrift für Naturforschung B · 2024-08-13

    Mathis Radzieowski, Elias C. J. Gießelmann, Stefan Engel, Oliver Janka

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  27. Temperature-dependent diffraction studies on the stannides Sr3Rh4Sn4, Sr3Ir4Sn4 and Sr2.43Eu0.57Ir4Sn4

    Zeitschrift für Kristallographie - Crystalline Materials · 2024-09-27

    Jutta Kösters, Judith Bönnighausen, Theresa Block, Rainer Pöttgen

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  28. New alkaline earth and rare earth representatives adopting the Ce2Al16Pt9-type structure

    Zeitschrift für Naturforschung B · 2024-12-01

    Stefan Engel, Oliver Janka

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  29. SrAl8Rh2 – the first phase in the Sr/Al/Rh system and new representative of the CeAl8Fe2 type structure

    Zeitschrift für Kristallographie - Crystalline Materials · 2025-01-01

    Stefan Engel, Maximilian Kai Reimann, Eteri Svanidze, Mitja Krnel, Nazar Zaremba, Markus Koenig, Oliver Janka

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  30. Hf6Al7 and Hf4.44(1)Nb1.56(1)Al7—the First Fully Ordered Main Group Metal Containing W6Fe7 Type Compound and its Ternary Coloring Variant

    Zeitschrift für anorganische und allgemeine Chemie · 2025-04-30

    Elias C. J. Gießelmann, Lena Ruck, Stefan Engel, Bernd Morgenstern, Lars Schumacher, Guido Kickelbick, Oliver Janka

    Read original paper ↗ ·
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