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RESEARCH PAPER · Nature Communications · 2015

Entropy-stabilized oxides

Christina M. Rost, Edward Sachet, Trent M. Borman, Ali Moballegh, Elizabeth C. Dickey, Dong Hua Hou, Jacob L. Jones, Stefano Curtarolo, Jon‐Paul Maria

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Entropy-stabilized oxidesOriginalRoom temperature lithium superionic conductivity in high entropy oxides766Colossal dielectric constant in high entropy oxides693Multicomponent equiatomic rare earth oxides356Nanocrystalline multicomponent entropy stabilised transition metal oxides365Ultra-high temperature ceramics: Materials for extreme environments1055A critical review of high entropy alloys and related concepts8956High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics1240Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency314Controlled Jahn-Teller distortion in (MgCoNiCuZn)O-based high entropy oxides279Local structure of the Mg x Ni x Co x Cu x Zn x O( x =0.2) entropy‐stabilized oxide: An EXAFS study261Polymorphism in a high-entropy alloy329Entropy as a Gene‐Like Performance Indicator Promoting Thermoelectric Materials348A new class of high-entropy perovskite oxides962Electronic-Structure Origin of Cation Disorder in Transition-Metal Oxides224Phase stability and distortion in high-entropy oxides283Rare earth and transition metal based entropy stabilised perovskite type oxides577Synthesis and microstructure of the (Co,Cr,Fe,Mn,Ni) 3 O 4 high entropy oxide characterized by spinel structure628Entropy-stabilized metal oxide solid solutions as CO oxidation catalysts with high-temperature stability328High-entropy fluorite oxides636Mechanochemical‐Assisted Synthesis of High‐Entropy Metal Nitride via a Soft Urea Strategy537A five-component entropy-stabilized fluorite oxide391Microstructure of (Hf-Ta-Zr-Nb)C high-entropy carbide at micro and nano/atomic level234(Hf 0.2 Zr 0.2 Ta 0.2 Nb 0.2 Ti 0.2 )C high‐entropy ceramics with low thermal conductivity614The search for high entropy alloys: A high-throughput ab-initio approach206High-entropy carbide: A novel class of multicomponent ceramics461High entropy oxides for reversible energy storage1348Novel processing route for the fabrication of bulk high-entropy metal diborides239High-entropy functional materials306Data-Driven Design of Ecofriendly Thermoelectric High-Entropy Sulfides349Charge‐Induced Disorder Controls the Thermal Conductivity of Entropy‐Stabilized Oxides508A high entropy oxide (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O) with superior lithium storage performance369High-entropy high-hardness metal carbides discovered by entropy descriptors1079Mechanical properties of high-entropy alloys with emphasis on face-centered cubic alloys1171Demystifying the sluggish diffusion effect in high entropy alloys338First‐principles study, fabrication, and characterization of (Hf 0.2 Zr 0.2 Ta 0.2 Nb 0.2 Ti 0.2 )C high‐entropy ceramic389Phase stability and mechanical properties of novel high entropy transition metal carbides734Low-temperature synthesis of small-sized high-entropy oxides for water oxidation402Multi-anionic and -cationic compounds: new high entropy materials for advanced Li-ion batteries446Review of high entropy ceramics: design, synthesis, structure and properties755High entropy oxides as anode material for Li-ion battery applications: A practical approach213Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO2 Fixation217High-entropy environmental barrier coating for the ceramic matrix composites286A high-entropy metal oxide as chemical anchor of polysulfide for lithium-sulfur batteries315A high entropy silicide by reactive spark plasma sintering285High‐Entropy Oxides: Fundamental Aspects and Electrochemical Properties1233High-entropy oxides: An emerging prospect for magnetic rare-earth transition metal perovskites250First-principles study, fabrication and characterization of (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramics546A high-entropy silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2343High entropy carbide ceramics from different starting materials224Oxidation behavior of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics at 1073-1473 K in air259High entropy alloys as a bold step forward in alloy development403Equiatomic quaternary (Y1/4Ho1/4Er1/4Yb1/4)2SiO5 silicate: A perspective multifunctional thermal and environmental barrier coating material216Long-Range Antiferromagnetic Order in a Rocksalt High Entropy Oxide196Microstructure and mechanical properties of high-entropy borides derived from boro/carbothermal reduction240Metal oxide nanoparticles and their applications in nanotechnology1132Mechanochemical Synthesis of High Entropy Oxide Materials under Ambient Conditions: Dispersion of Catalysts via Entropy Maximization254High-entropy alloys4959(La0.2Ce0.2Nd0.2Sm0.2Eu0.2)2Zr2O7: A novel high-entropy ceramic with low thermal conductivity and sluggish grain growth rate446High-entropy pyrochlores with low thermal conductivity for thermal barrier coating materials475High‐temperature oxidation behavior of (Hf 0.2 Zr 0.2 Ta 0.2 Nb 0.2 Ti 0.2 )C high‐entropy ceramics in air192A new class of spinel high-entropy oxides with controllable magnetic properties231High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries771Room‐Temperature Synthesis of High‐Entropy Perovskite Oxide Nanoparticle Catalysts through Ultrasonication‐Based Method205Dielectric properties and electrocaloric effect of high-entropy (Na0.2Bi0.2Ba0.2Sr0.2Ca0.2)TiO3 ceramic252Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides309Microstructure and dielectric properties of high entropy Ba(Zr0.2Ti0.2Sn0.2Hf0.2Me0.2)O3 perovskite oxides247Synthesis and structures of high-entropy pyrochlore oxides228Multicomponent high-entropy zirconates with comprehensive properties for advanced thermal barrier coating310An innovative approach to design SOFC air electrode materials: high entropy La 1−x Sr x (Co,Cr,Fe,Mn,Ni)O 3−δ ( x = 0, 0.1, 0.2, 0.3) perovskites synthesized by the sol–gel method200High entropy spinel oxide nanoparticles for superior lithiation–delithiation performance341Photocatalytic hydrogen evolution on a high-entropy oxide249Theoretical prediction on thermal and mechanical properties of high entropy (Zr0.2Hf0.2Ti0.2Nb0.2Ta0.2)C by deep learning potential236From high-entropy ceramics to compositionally-complex ceramics: A case study of fluorite oxides301High-entropy ceramics2045Size disorder as a descriptor for predicting reduced thermal conductivity in medium- and high-entropy pyrochlore oxides330Phase Engineering of High‐Entropy Alloys463High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis383A step forward from high-entropy ceramics to compositionally complex ceramics: a new perspective293The emergent field of high entropy oxides: Design, prospects, challenges, and opportunities for tailoring material properties299Discovery of high-entropy ceramics via machine learning275Dielectric and energy storage properties of flash-sintered high-entropy (Bi0.2Na0.2K0.2Ba0.2Ca0.2)TiO3 ceramic220Mechanical properties of hot-pressed high-entropy diboride-based ceramics226Holey Lamellar High‐Entropy Oxide as an Ultra‐High‐Activity Heterogeneous Catalyst for Solvent‐free Aerobic Oxidation of Benzyl Alcohol271High entropy defective fluorite structured rare-earth niobates and tantalates for thermal barrier applications219High entropy oxides: The role of entropy, enthalpy and synergy388Spinel-structured high entropy oxide (FeCoNiCrMn)3O4 as anode towards superior lithium storage performance383Stabilizing Oxygen Vacancy in Entropy-Engineered CoFe2O4-Type Catalysts for Co-prosperity of Efficiency and Stability in an Oxygen Evolution Reaction194High-entropy thermal barrier coating of rare-earth zirconate: A case study on (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 prepared by atmospheric plasma spraying220Entropy-stabilized single-atom Pd catalysts via high-entropy fluorite oxide supports394Searching for high entropy alloys: A machine learning approach215A novel facile strategy to suppress Sr segregation for high-entropy stabilized La0·8Sr0·2MnO3-δ cathode228Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries689Thermodynamics of high entropy oxides315High-Entropy Perovskites: An Emergent Class of Oxide Thermoelectrics with Ultralow Thermal Conductivity200Recent progress of high-entropy materials for energy storage and conversion592Bulk high-entropy nitrides and carbonitrides210High-entropy effect of a metal phosphide on enhanced overall water splitting performance247High-entropy energy materials: challenges and new opportunities959Simultaneous Multication Exchange Pathway to High-Entropy Metal Sulfide Nanoparticles224Denary oxide nanoparticles as highly stable catalysts for methane combustion321Emerging 2D metal oxides and their applications327Preparation and phase evolution of high-entropy oxides A2B2O7 with multiple elements at A and B sites197A New High Entropy Glycerate for High Performance Oxygen Evolution Reaction196Electrical and thermal transport behaviours of high-entropy perovskite thermoelectric oxides213High entropy oxides-exploring a paradigm of promising catalysts: A review342High-entropy materials for energy-related applications278High-entropy-stabilized chalcogenides with high thermoelectric performance1172Carbon‐Supported High‐Entropy Oxide Nanoparticles as Stable Electrocatalysts for Oxygen Reduction Reactions209A high-entropy phosphate catalyst for oxygen evolution reaction208High-entropy ceramics: Present status, challenges, and a look forward1107Extreme mixing in nanoscale transition metal alloys276A universal configurational entropy metric for high-entropy materials227High-entropy materials for catalysis: A new frontier921Entropy engineering promotes thermoelectric performance in p-type chalcogenides259High-Entropy 2D Carbide MXenes: TiVNbMoC 3 and TiVCrMoC 3422A perspective on the catalysis using the high entropy alloys2602D High‐Entropy Transition Metal Dichalcogenides for Carbon Dioxide Electrocatalysis209Defect‐Rich High‐Entropy Oxide Nanosheets for Efficient 5‐Hydroxymethylfurfural Electrooxidation432High‐Entropy Metal–Organic Frameworks for Highly Reversible Sodium Storage364High‐Entropy Atomic Layers of Transition‐Metal Carbides (MXenes)321High-entropy ceramics: Review of principles, production and applications1006High entropy spinel-structure oxide for electrochemical application247Advances in ultra-high temperature ceramics, composites, and coatings787Noble-metal-based high-entropy-alloy nanoparticles for electrocatalysis194Boosting electrochemical reaction and suppressing phase transition with a high-entropy O3-type layered oxide for sodium-ion batteries210High‐Entropy Sulfides as Electrode Materials for Li‐Ion Batteries215High-entropy oxides as advanced anode materials for long-life lithium-ion Batteries320Review of computational approaches to predict the thermodynamic stability of inorganic solids196General synthesis of high-entropy alloy and ceramic nanoparticles in nanoseconds320High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery1069High Configuration Entropy Activated Lattice Oxygen for O 2 Formation on Perovskite Electrocatalyst334High-entropy spinel ferrites MFe2O4 (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) with tunable electromagnetic properties and strong microwave absorption289High-entropy enhanced capacitive energy storage614Solid-State Reaction Synthesis of Nanoscale Materials: Strategies and Applications228Rapid Joule-Heating Synthesis for Manufacturing High-Entropy Oxides as Efficient Electrocatalysts203High-entropy oxides for catalysis: A diamond in the rough230High‐Entropy and Superstructure‐Stabilized Layered Oxide Cathodes for Sodium‐Ion Batteries280Structural Defects in Phase‐Regulated High‐Entropy Oxides toward Superior Microwave Absorption Properties486High-Entropy Perovskite Oxide: A New Opportunity for Developing Highly Active and Durable Air Electrode for Reversible Protonic Ceramic Electrochemical Cells221High‐Entropy Enhanced Microwave Attenuation in Titanate Perovskites440Entropy‐Driven Liquid Electrolytes for Lithium Batteries190Understanding the Role of Entropy in High Entropy Oxides568Band Gap Narrowing in a High-Entropy Spinel Oxide Semiconductor for Enhanced Oxygen Evolution Catalysis242Engineering relaxors by entropy for high energy storage performance320Li-S Batteries: Challenges, Achievements and Opportunities404High‐Entropy Lithium Argyrodite Solid Electrolytes Enabling Stable All‐Solid‐State Batteries192The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries278More is better: high-entropy electrolyte design in rechargeable batteries196High-entropy materials for energy and electronic applications447Surface restructuring and predictive design of heterogeneous catalysts213

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  46. Ultrastable metal oxide nanotube arrays achieved by entropy-stabilization engineering

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  48. Evidence for Jahn-Teller compression in the (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxide: A DFT study

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  49. Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy

    Science and Technology of Welding & Joining · 2018-02-26

    Zhenggang Wu, S. A. David, Donovan N. Leonard, Zhili Feng, Hongbin Bei

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  50. Synthesis and sintering of (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxides obtained by wet chemical methods

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