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RESEARCH PAPER · Reports on Progress in Physics · 2015

Electron beam damage in oxides: a review

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Electron beam damage in oxides: a reviewOriginalNanowire growth kinetics in aberration corrected environmental transmission electron microscopy25Beam damage by the induced electric field in transmission electron microscopy54Influence of electron beam irradiation on structural and optical properties of α-Ag 2 WO 4 nanoparticles29On the threshold conditions for electron beam damage of asbestos amosite fibers in the transmission electron microscope (TEM)6Dose-rate-dependent damage of cerium dioxide in the scanning transmission electron microscope58Implementing an accurate and rapid sparse sampling approach for low-dose atomic resolution STEM imaging111On the spatial resolution limit of direct-write electron beam lithography20In situ tracking the reversible spinel-rocksalt structural transformation between Mn3O4 and MnO9Effect of temperature on beam damage of asbestos fibers in the transmission electron microscope (TEM) at 100kV4Nanoscale controlled Li-insertion reaction induced by scanning electron-beam irradiation in a Li 4 Ti 5 O 12 electrode material for lithium-ion batteries16In situ TEM study of electron-beam radiation induced boron diffusion and effects on phase and microstructure evolution in nanostructured CoFeB/SiO2 thin film7Effect of accelerating voltage on beam damage of asbestos fibers in the transmission electron microscope (TEM)4Perovskite-Inspired Photovoltaic Materials: Toward Best Practices in Materials Characterization and Calculations142Advanced electron microscopy characterization of nanomaterials for catalysis149Ondrej Krivanek's early scientific research0Tipping solutions: emerging 3D nano‐fabrication/ ‐imaging technologies55Defect Chemistry of Pr Doped Ceria Thin Films Investigated by in Situ Optical and Impedance Measurements38Computational Modeling for the Ag Nanoparticle Coalescence Process: A Case of Surface Plasmon Resonance22Note on in situ (scanning) transmission electron microscopy study of liquid samples42Outrunning damage: Electrons vs X-rays—timescales and mechanisms59Damage by Induced Electric Field in Beam-sensitive Materials1Electron Beam Effects on Liquid Specimens in (S)TEM0Electron Beam Etching of CaO Crystals Observed Atom by Atom28Local electric field direct writing – Electron-beam lithography and mechanism3Atom-by-atom fabrication by electron beam via induced phase transformations22Single-atom dynamics in scanning transmission electron microscopy40Placing single atoms in graphene with a scanning transmission electron microscope147Mitigating e-beam-induced hydrocarbon deposition on graphene for atomic-scale scanning transmission electron microscopy studies39In situ Formation of Metal Nanoparticles through Electron Beam Irradiation: Modeling Real Materials from First-Principles Calculations15Atomic-Scale Insights into the Oxidation of Aluminum152Electron irradiation induced amorphous SiO2 formation at metal oxide/Si interface at room temperature; electron beam writing on interfaces18Sculpting Nanoscale Functional Channels in Complex Oxides Using Energetic Ions and Electrons11Preparation and observation methods can produce misleading artefacts in human sperm ultrastructural morphology17Modelling electron beam induced dynamics in metallic nanoclusters26Encoding Optoelectrical Sub-Components in an Al2O3 Nanowire for Rewritable High-Resolution Nanopatterning11In Situ TEM Investigation of Electron Irradiation Induced Metastable States in Lithium-Ion Battery Cathodes: Li2FeSiO4 versus LiFePO427Electron radiation-induced material diffusion and nanocrystallization in nanostructured amorphous CoFeB thin film15Mapping mesoscopic phase evolution during E-beam induced transformations via deep learning of atomically resolved images50E-beam manipulation of Si atoms on graphene edges with an aberration-corrected scanning transmission electron microscope25Interfacial Defects Dictated In Situ Fabrication of Yolk–Shell Upconversion Nanoparticles by Electron‐Beam Irradiation29Design of compact ultrafast microscopes for single- and multi-shot imaging with MeV electrons26The mechanism of nanoparticle precipitation induced by electron irradiation in transmission electron microscopy4Investigating chemical and structural instabilities of lead halide perovskite induced by electron beam irradiation28Atomistic Insight into the Redox Reactions in Fe/Oxide Core–Shell Nanoparticles37Adatom dynamics and the surface reconstruction of Si(110) revealed using time-resolved electron microscopy13Probing the Location and Speciation of Elements in Zeolites with Correlated Atom Probe Tomography and Scanning Transmission X‐Ray Microscopy25Creation of glass-characteristic point defects in crystalline SiO2 by 2.5 MeV electrons and by fast neutrons15Compressed Sensing of Scanning Transmission Electron Microscopy (STEM) With Nonrectangular Scans44Atomistic manipulation of reversible oxidation and reduction in Ag with an electron beam22Negative threshold voltage shift in an a-IGZO thin film transistor under X-ray irradiation48Inner structure and inclusions in radiocesium-bearing microparticles emitted in the Fukushima Daiichi Nuclear Power Plant accident14Radiation damage to organic and inorganic specimens in the TEM450High‐Resolution Cryo‐Scanning Electron Microscopy of Macromolecular Complexes1Artifacts from manganese reduction in rock samples prepared by focused ion beam (FIB) slicing for X-ray microspectroscopy6TEM Studies on Electrode Materials for Secondary Ion Batteries2Engineering High-k/SiGe Interface with ALD Oxide for Selective GeOx Reduction24Quantifying transmission electron microscopy irradiation effects using two-dimensional materials144Atom-by-atom fabrication with electron beams128Brownmillerite phase formation and evolution in epitaxial strontium ferrite heterostructures44Direct observation of oxygen-vacancy formation and structural changes in Bi2WO6 nanoflakes induced by electron irradiation14Structural Evolution and Dynamics of an In 2 O 3 Catalyst for CO 2 Hydrogenation to Methanol: An Operando XAS-XRD and In Situ TEM Study379Interstitial defects in the van der Waals gap of Bi2Se319Damage by Induced Electric Field versus Radiolysis1Silicon microspectrometer chip based on nanostructured fishnet photodetectors with tailored responsivities and machine learning43The impact of swift electrons on the segregation of Ni-Au nanoalloys11LiberTEM/LiberTEM-blobfinder: 0.4.048Probing the Crystal and Electronic Structures of Molybdenum Oxide in Redox Process: Implications for Energy Applications11Pulsed laser deposition of a ZnO:Eu3+ thin film: Study of the luminescence and surface state under electron beam irradiation37Conversion of ethanol to butadiene on zinc-tantalum catalysts0Photon-Induced, Timescale, and Electrode Effects Critical for the in Situ X‑ray Spectroscopic Analysis of Electrocatalysts: The Water Oxidation Case40X-ray Microscopy57A Bit of History0Appendix A X-Ray Data Tabulations0Applications, and Future Prospects1Coherent Imaging0Foreword0Imaging Physics0Radiation Damage and Cryo Microscopy1References0X-Ray Focusing Optics1X-Ray Microscope Instrumentation0X-Ray Microscope Systems0X-Ray Microscopes: a Short Introduction0X-Ray Physics0X-Ray Spectromicroscopy1X-Ray Tomography2Facet-dependent active sites of a single Cu2O particle photocatalyst for CO2 reduction to methanol552A novel nondestructive diagnostic method for mega-electron-volt ultrafast electron diffraction12Damage in electron cryomicroscopy: Lessons from biology for materials science20Laser formation of nano-Si structures in glasses0Materials and Devices with Probes and Beams: Down to the Atomic Level and Back Up3Improving the synthesis of Zn-Ta-TUD-1 for the Lebedev process using the Design of Experiments methodology15Analysis of Ceramics Using Scanning Electron Microscopy2Artefacts of Human Sperm Ultrastructural Morphology1Atlas of Human Sperm Ultrastructural Morphology1Distinctive stability of a free-standing monolayer clay mineral nanosheet via transmission electron microscopy6Electron beam irradiation for the formation of thick Ag film on Ag 3 PO 427Revealing Nonclassical Nucleation Pathways Using Cryogenic Electron Microscopy3COUNTING THE LAYER NUMBER OF FREE-STANDING MONTMORILLONITE NANOSHEETS USING ANNULAR DARK FIELD SCANNING TRANSMISSION ELECTRON MICROSCOPY3Variable voltage electron microscopy: Toward atom-by-atom fabrication in 2D materials20Electron‐Beam‐Related Studies of Halide Perovskites: Challenges and Opportunities93Configurable Resistive Response in BaTiO3 Ferroelectric Memristors via Electron Beam Radiation45Catalytic activity, water formation, and sintering: Methane activation over Co- and Fe-doped MgO nanocrystals14Imaging Beam‐Sensitive Materials by Electron Microscopy219Electron-beam irradiation alters bond strength in zinc oxide single crystal24Formation of Defects in Two-Dimensional MoS2 in the Transmission Electron Microscope at Electron Energies below the Knock-on Threshold: The Role of Electronic Excitations105Atomic-Scale Imaging of a Free-Standing Monolayer Clay Mineral Nanosheet Using Scanning Transmission Electron Microscopy14Atomic resolution enabled STEM imaging of nanocrystals at cryogenic temperature15Highly Conductive Sb–SnO2 Nanocrystals Synthesized by Dual Nonthermal Plasmas24Mitigation of radiation damage in biological macromolecules via tunable picosecond pulsed transmission electron microscopy6Structural and optical properties of beta irradiated YAlO3 single crystals8In Situ X-ray Diffraction and Spectro-Microscopic Study of ALD Protected Copper Films8In Situ TEM Study on Conversion‐Type Electrodes for Rechargeable Ion Batteries104Beam Damage by Transmission Electron Microscopy in FinFet Structures1Microstructure and Optical Properties of E-Beam Evaporated Zinc Oxide Films—Effects of Decomposition and Surface Desorption11The cono-dos and cono-dont’s of phosphatic microfossil preparation and microanalysis6Glass shaping at nanoscale: Mechanical forming of brittle amorphous silica by engineered inelastic interaction of scanning electrons with matter1Atomic Resolution Observation of the Oxidation of Niobium Oxide Nanowires: Implications for Renewable Energy Applications7Structural Instability in Electrically Stressed, Oxygen Deficient BaTiO3 Nanocrystals14Defect and structural evolution under high-energy ion irradiation informs battery materials design for extreme environments65Origin and Suppression of Beam Damage-Induced Oxygen-K Edge Artifact from γ-Al2O3 using Cryo-EELS26Compositional Decoupling of Bulk and Surface in Open-Structured Complex Mixed Oxides9Ultra-high contrast STEM imaging for segmented/pixelated detectors by maximizing the signal-to-noise ratio57In Situ Oxidation Studies of High-Entropy Alloy Nanoparticles157Determination of Dose Distributions by High-energy Electrons in Alumina Pellets Using Monte Carlo Simulations0Direct Observation of Electron Beam-Induced Phase Transition in MgCrMnO426A scalable electron beam irradiation platform applied for allotropic carbon transformation18Nanoscale control of LaAlO3/SrTiO3 metal–insulator transition using ultra-low-voltage electron-beam lithography14Defect structures of the Cr 2 O 3 (1120) surface: effect of electron beam irradiation10Imaging atomic motion of light elements in 2D materials with 30 kV electron microscopy19Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions26In Situ Study of the Wet Chemical Etching of SiO2 and Nanoparticle@SiO2 Core–Shell Nanospheres20In Situ Characterization of Catalysis and Electrocatalysis Using APXPS113Different Oxygen Desorption Durabilities of Lithium Titanium Oxides as Confirmed by Transmission Electron Energy-Loss Spectroscopy Analysis of Li4Ti5O12 and β-Li2TiO3 Biphase Specimens8Visualizing lattice dynamic behavior by acquiring a single time-resolved MeV diffraction image4Irradiation and Size Effects on Redox Reaction Mechanisms in Iron Oxides18Athermal Activation in Glassy Fluid0Combining RBS/Channeling, X-ray diffraction and atomic-scale modelling to study irradiation-induced defects and microstructural changes0Exploiting the Acceleration Voltage Dependence of EMCD2TEM and EELS characterization of Ni–Fe layered double hydroxide decompositions caused by electron beam irradiation30Cryo-ePDF: Overcoming Electron Beam Damage to Study the Local Atomic Structure of Amorphous ALD Aluminum Oxide Thin Films within a TEM23Exploring order parameters and dynamic processes in disordered systems via variational autoencoders69Sculpting the plasmonic responses of nanoparticles by directed electron beam irradiation1Deep Learning‐Assisted Quantification of Atomic Dopants and Defects in 2D Materials87Combined FIB/SEM tomography and TEM analysis to characterize high aspect ratio Mg-silicate particles inside silica-based optical fibres17Transformation and degradation of metal halide perovskites induced by energetic electrons and their practical implications14Decoupling bulk and surface recombination properties in silicon by depth-dependent carrier lifetime measurements7Defects in Photocatalysis2A Review of Grain Boundary and Heterointerface Characterization in Polycrystalline Oxides by (Scanning) Transmission Electron Microscopy56Probing atom dynamics of excited Co-Mo-S nanocrystals in 3D34

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