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RESEARCH PAPER · Journal of Materials Chemistry C · 2016

‘Ferroelectric’ metals reexamined: fundamental mechanisms and design considerations for new materials

Nicole A. Benedek, Turan Birol

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‘Ferroelectric’ metals reexamined: fundamental mechanisms and design considerations for new materialsOriginal[Early melena in newborn infants in high-risk pregnancy].0First-principles study of magnetoelectric effects and ferroelectricity in complex oxides1Optical steering of microbubbles for nanoparticle transport2Strain-Engineered Multiferroicity in Pnma NaMnF3 Fluoroperovskite44Interplay between electron correlations and polar displacements in metallic SrEuMo2O66Optical spectroscopy and band gap analysis of hybrid improper ferroelectric Ca3Ti2O731The origin of hyperferroelectricity in LiBO3 (B = V, Nb, Ta, Os)29Orbital configuration in CaTiO3 films on NdGaO39Prediction and control of spin polarization in a Weyl semimetallic phase of BiSb62Persistence of polar distortion with electron doping in lone-pair driven ferroelectrics64Effect of intrinsic point defects on ferroelectric polarization behavior of SrTiO 385Domain walls and ferroelectric reversal in corundum derivatives15Phase stability and large in-plane resistivity anisotropy in the 112-type iron-based superconductor Ca1−xLaxFeAs215Learning from data to design functional materials without inversion symmetry95A ferroelectric quantum phase transition inside the superconducting dome of Sr1−xCaxTiO3−δ235Pressure-induced insulator–metal transition in EuMnO 314Unusual Metallic Multiferroic Transitions in Electron‐Doped PbTiO317Design of new Mott multiferroics via complete charge transfer: promising candidates for bulk photovoltaics28Polar instability under electrostatic doping in tetragonal SnTiO317Prospects and applications near ferroelectric quantum phase transitions: a key issues review83Theoretical investigation of ferroic instabilities in confined geometries and distorted lattices0De la densité des fluides électroniques dans deux oxydes supraconducteurs0Engineering an Insulating Ferroelectric Superlattice with a Tunable Band Gap from Metallic Components19Structural prediction and theoretical characterization of Bi-Sb binaries: Spin-orbit coupling e↵ects3The chemical forces underlying octahedral tilting in halide perovskites38Meta-screening and permanence of polar distortion in metallized ferroelectrics55Strain-engineering stabilization of BaTiO3 -based polar metals35Observation of Quasi-Two-Dimensional Polar Domains and Ferroelastic Switching in a Metal, Ca3Ru2O792Artificial two-dimensional polar metal at room temperature90Design strategy for ferroelectric-based polar metals with dimensionality-tunable electronic states10Ferroelectric switching of a two-dimensional metal10404D-STEM Differential Phase Contrast Microscopy Across Ferroelectric Domain Walls1Parity-breaking in single-element phases: ferroelectric-like elemental polar metals19Ferroelectric switching of a two-dimensional metal21Linear and nonlinear optical probe of the ferroelectric-like phase transition in a polar metal, LiOsO335Polar metals as electrodes to suppress the critical-thickness limit in ferroelectric nanocapacitors36Design of a polar half-metallic ferromagnet with accessible and enhanced electric polarization10Polar metallic behavior of strained antiperovskites ACNi3(A=Mg,Zn,and Cd) from first principles20Two-dimensional polar metals in KNbO 3 /BaTiO 3 superlattices: first-principle calculations9Electronically enhanced layer buckling and Au-Au dimerization in epitaxial LaAuSb films6Probing ferroelectricity in highly conducting materials through their elastic response: Persistence of ferroelectricity in metallic BaTiO3−δ30Heteroanionic Materials by Design: Progress Toward Targeted Properties237Magnetoresistance in Metallic Ferroelectrics0First-principles screening of ABO3 oxides with two magnetic sublattices3Magnetoresistance in Metallic Ferroelectrics6A room-temperature ferroelectric semimetal329Evidence for the weakly coupled electron mechanism in an Anderson-Blount polar metal46Heusler interfaces—Opportunities beyond spintronics?24A first principles study of a spin-polarized two-dimensional polar metal at the SrVO3/PbTiO3 heterostructure interface9Creating multiferroic and conductive domain walls in common ferroelastic compounds6Polar and phase domain walls with conducting interfacial states in a Weyl semimetal MoTe271Raman interrogation of the ferroelectric phase transition in polar metal LiOsO 326Rationalizing and engineering Rashba spin-splitting in ferroelectric oxides86Conductivity, charge transport, and ferroelectricity of La-doped BaTiO 3 epitaxial thin films14Artificial two-dimensional polar metal by charge transfer to a ferroelectric insulator32Artificial two-dimensional polar metal by charge transfer to a ferroelectric insulator31Viewpoint: Atomic-Scale Design Protocols toward Energy, Electronic, Catalysis, and Sensing Applications39Surveying polar materials in the Inorganic Crystal Structure Database to identify emerging structure types11Temperature-dependent polarization in a non-polar crystal3Interface-induced magnetic polar metal phase in complex oxides48Recent Progress in Two‐Dimensional Ferroelectric Materials409High electrical conductivity in the epitaxial polar metals LaAuGe and LaPtSb20PAOFLOW-Aided Computational Materials Design0Two-dimensional polar metal of a PbTe monolayer by electrostatic doping27Spin Hall effect in prototype Rashba ferroelectrics GeTe and SnTe60Design of a multifunctional polar metal via first-principles high-throughput structure screening77Polar and Phase Domain Walls in Weyl Semimetallic MoTe 2 : New Paradigm for Topological Interfacial States0Two-dimensional metallic ferroelectricity in PbTe monolayer by electrostatic doping0Switchable two-dimensional electron gas based on ferroelectric Ca: SrTi O 329Review on ferroelectric/polar metals91Origin of the persistence of soft modes in metallic ferroelectrics7Room-temperature polar metal stabilized under high pressure10Multiband Quantum Criticality of Polar Metals17Electronically driven spin-reorientation transition of the correlated polar metal Ca 3 Ru 2 O 745Electrical detection of ferroelectriclike metals through the nonlinear Hall effect39Evidence for an extended critical fluctuation region above the polar ordering transition in LiOsO37Electric field induced metallic behavior in thin crystals of ferroelectric α -In2Se328Polar Nanodomains in a Ferroelectric Superconductor46Exploring the A2BX3 Family for New Functional Materials Using Crystallographic Database Mining and First-Principles Calculations5Polar nematic state in an iron-based superconductor LaFeAsO1-xHx0Metallic interfaces in a CaTiO3 / LaTiO3 superlattice4Possible antiferroelectric-to-ferroelectric transition and metallic antiferroelectricity caused by charge doping in PbZrO35Current-induced orbital magnetization in systems without inversion symmetry37A computational search for wurtzite-structured ferroelectrics with low coercive voltages52Strain-tunable giant anisotropic conductivity in the polar metal of KNbO3/BaTiO3 ferroelectric superlattice2A two-dimensional multiferroic metal with voltage-tunable magnetization and metallicity20Ferroelectricity promoted by cation/anion divacancies in SrMnO 315Interplay between ferroelectricity and metallicity in BaTiO 338Two-dimensional ferroelectric metal for electrocatalysis46Review on Recent Developments in 2D Ferroelectrics: Theories and Applications334Investigation into Cation-Ordered Magnetic Polar Double Perovskite Oxides45Topology and Symmetry of Quantum Materials via Nonlinear Optical Responses144Origin of ferroelectricity in cubic phase of Hf substituted BaTiO 329Switching a Polar Metal via Strain Gradients42Coexistence of ferroelectricity and metallicity in M-doped BaTiO3 (M = Al, V, Cr, Fe, Ni, and Nb): First-principles study14Coexistence of spontaneous polarization and superconductivity in hole-doped oxyhydrides ATiO2H ( A=K,Rb,Cs ): First-principles study3Polar Ferromagnetic Metal by Intercalation of Metal–Amine Complexes12Extreme Ultraviolet Second Harmonic Generation Spectroscopy in a Polar Metal23Switchable domains in point contacts based on transition metal tellurides6Free-Carrier-Induced Ferroelectricity in Layered Perovskites29Direct measurement of ferroelectric polarization in a tunable semimetal87Pressure-induced metal–insulator transition in oxygen-deficient LiNbO3-type ferroelectrics2Developing new antiferroelectric and ferroelectric oxides and chalcogenides within the A2BX3 family10Formation of a Polar Structure in the Metallic Niobium Sulfide Nb4S31Modeling of Ferroelectric Oxide Perovskites: From First to Second Principles60Tunable Microwave Conductance of Nanodomains in Ferroelectric PbZr0.2Ti0.8O3 Thin Film6Mechanism for switchability in electron-doped ferroelectric interfaces3Ferroelectric engineering: Enhanced thermoelectric performance by local structural heterogeneity12Designing new polar materials1Temperature-Pressure Phase Diagram and Possible Pressure-Driven New Electronic Phase in the Polar Metal LiOsO 32Spin-phonon resonances in nearly polar metals with spin-orbit coupling9Current-induced control of the polarization state in a polar-metal–based heterostructure SnSe/WTe 21Novel Functionality in Switchable Polar Materials4Progress on Emerging Ferroelectric Materials for Energy Harvesting, Storage and Conversion187Improper multiferroiclike transition in a metal9Recent progress in bismuth-based high Curie temperature piezo-/ferroelectric perovskites for electromechanical transduction applications88Topochemical Synthesis of LiCoF3 with a High-Temperature LiNbO3-Type Structure1LiMo8O10: Polar Crystal Structure with Infinite Edge-Sharing Molybdenum Octahedra0Dynamic negative capacitance response in GeTe Rashba ferroelectric7Anisotropic resistivity and superconducting instability in ferroelectric metals7Monolayer polar metals with large piezoelectricity derived from MoSi 2 N 419Polar metals taxonomy for materials classification and discovery37Ferroelectric control of charge and spin transport in oxide-based Rashba two-dimensional electron gases0Single crystal growths and magnetic properties of hexagonal polar semimetals RAuGe (R = Y, Gd–Tm, and Lu)6Polar Metals: Principles and Prospects61Theory of criticality for quantum ferroelectric metals12Polar Perturbations in Functional Oxide Heterostructures15Quantum fluctuation of ferroelectric order in polar metals5Predictive Design of Hybrid Improper Ferroelectric Double Perovskite Oxides5Nonzero spontaneous electric polarization in metals: novel predictive methods and applications4Polar metals with coexisting ferroelectricity and high-density conduction electrons7A correlated ferromagnetic polar metal by design48Unit‐Cell‐Thickness Electron Confinement by Geometrically Constrained Antipolar Ordering2Revealing a distortive polar order buried in the Fermi sea10Single-atom catalysts based on polarization switching of ferroelectric In2Se3 for N2 reduction9Magnetic ferroelectric metal in bilayer Fe3GeTe2 under interlayer sliding2Continuous crossover between insulating ferroelectrics and polar metals: Ab initio calculation of structural phase transitions of Li B O 3 ( B = Ta , W, Re, Os)2Unconventional superconductivity from electronic dipole fluctuations1Effect of (001) and (111) epitaxial strain on Pnma perovskite oxides4Polar charge density wave in a superconductor with crystallographic chirality5Two-Dimensional Topological Ferroelectric Metal with Giant Shift Current49Fundamentals of Flexoelectricity, Materials and Emerging Opportunities Toward Strain‐Driven Nanocatalysts49First-principles prediction of a polar half-metallic ferromagnet in a heterostructure based on PbMnO 3 and SrMnO 33Assessing the K 2 B O 3 family of materials as multiferroics3Enhanced photocatalytic and spintronic properties in proposed α-MXene family via ferroelectric effect5Janus S-XSSe: a new family of 2D polar half-metals with stacking-engineered magnetism and antiferromagnetic spin splitting3Optimization of out-of-plane polarization calculations for two-dimensional ferroelectric metals0Strain-induced metal to polar-metal transition and impact of metallicity on lattice vibrations in NbO2 -doped PbTiO30van der Waals Hybrids for Ferroelectric Device Application3Pressure-induced enhancement of polar distortions in a metal and implications for the Rashba spin splitting0

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  1. [Early melena in newborn infants in high-risk pregnancy].

    PubMed · 1977-03-17

    Stefano Cianci, G Santagelo, G Benfatto, Andrea Sorbello, N Maccarrone

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  2. First-principles study of magnetoelectric effects and ferroelectricity in complex oxides

    PhDT · 2016-01-01

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  3. Optical steering of microbubbles for nanoparticle transport

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  4. Strain-Engineered Multiferroicity in Pnma NaMnF3 Fluoroperovskite

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    Andrés Camilo Garcia-Castro, Aldo Humberto Romero, Éric Bousquet

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  5. Interplay between electron correlations and polar displacements in metallic SrEuMo2O6

    Physical review. B./Physical review. B · 2016-03-30

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  6. Optical spectroscopy and band gap analysis of hybrid improper ferroelectric Ca3Ti2O7

    Applied Physics Letters · 2016-06-27

    Judy Cherian, Turan Birol, Nathan C. Harms, Bin Gao, Sang‐Wook Cheong, David Vanderbilt, Janice L. Musfeldt

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  7. The origin of hyperferroelectricity in LiBO3 (B = V, Nb, Ta, Os)

    Scientific Reports · 2016-10-03

    Peng-Fei Li, Xinguo Ren, Guang‐Can Guo, Lixin He

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  8. Orbital configuration in CaTiO3 films on NdGaO3

    Applied Physics Letters · 2016-10-10

    Yanwei Cao, Se Young Park, Xiaoran Liu, Debraj Choudhury, S. Middey, Derek J. Meyers, M. Kareev, Padraic Shafer, Elke Arenholz, Jak Chakhalian

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  9. Prediction and control of spin polarization in a Weyl semimetallic phase of BiSb

    Physical review. B./Physical review. B · 2016-10-18

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  10. Persistence of polar distortion with electron doping in lone-pair driven ferroelectrics

    Physical review. B./Physical review. B · 2016-12-27

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  11. Effect of intrinsic point defects on ferroelectric polarization behavior of SrTiO 3

    Physical review. B./Physical review. B · 2017-01-04

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  12. Domain walls and ferroelectric reversal in corundum derivatives

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  13. Phase stability and large in-plane resistivity anisotropy in the 112-type iron-based superconductor Ca1−xLaxFeAs2

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  14. Learning from data to design functional materials without inversion symmetry

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  15. A ferroelectric quantum phase transition inside the superconducting dome of Sr1−xCaxTiO3−δ

    Nature Physics · 2017-04-17

    Carl Willem Rischau, Xiao Lin, Christoph P. Grams, Dennis Finck, Steffen Harms, Johannes Engelmayer, T. Lorenz, Yann Gallais, Benoît Fauqué, J. Hemberger, Kamran Behnia

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  16. Pressure-induced insulator–metal transition in EuMnO 3

    Journal of Physics Condensed Matter · 2017-05-30

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  17. Unusual Metallic Multiferroic Transitions in Electron‐Doped PbTiO3

    Advanced Electronic Materials · 2017-07-03

    Takahiro Shimada, Tao Xu, Yasumitsu Araki, Jie Wang, Takayuki Kitamura

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  18. Design of new Mott multiferroics via complete charge transfer: promising candidates for bulk photovoltaics

    Scientific Reports · 2017-07-17

    Hanghui Chen, Andrew J. Millis

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  19. Polar instability under electrostatic doping in tetragonal SnTiO3

    Physical review. B./Physical review. B · 2017-07-20

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  20. Prospects and applications near ferroelectric quantum phase transitions: a key issues review

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    Poonam Chandra, G. G. Lonzarich, Stephen E. Rowley, J. F. Scott

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  21. Theoretical investigation of ferroic instabilities in confined geometries and distorted lattices

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  22. De la densité des fluides électroniques dans deux oxydes supraconducteurs

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  23. Engineering an Insulating Ferroelectric Superlattice with a Tunable Band Gap from Metallic Components

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    Saurabh Ghosh, Albina Y. Borisevich, Sokrates T. Pantelides

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  24. Structural prediction and theoretical characterization of Bi-Sb binaries: Spin-orbit coupling e↵ects

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  25. The chemical forces underlying octahedral tilting in halide perovskites

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  26. Meta-screening and permanence of polar distortion in metallized ferroelectrics

    Physical review. B./Physical review. B · 2018-02-15

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  27. Strain-engineering stabilization of BaTiO3 -based polar metals

    Physical review. B./Physical review. B · 2018-03-01

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  28. Observation of Quasi-Two-Dimensional Polar Domains and Ferroelastic Switching in a Metal, Ca3Ru2O7

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  29. Artificial two-dimensional polar metal at room temperature

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  30. Design strategy for ferroelectric-based polar metals with dimensionality-tunable electronic states

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  31. Ferroelectric switching of a two-dimensional metal

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  32. 4D-STEM Differential Phase Contrast Microscopy Across Ferroelectric Domain Walls

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  33. Parity-breaking in single-element phases: ferroelectric-like elemental polar metals

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  34. Ferroelectric switching of a two-dimensional metal

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  35. Linear and nonlinear optical probe of the ferroelectric-like phase transition in a polar metal, LiOsO3

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  36. Polar metals as electrodes to suppress the critical-thickness limit in ferroelectric nanocapacitors

    Journal of Applied Physics · 2018-11-01

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  37. Design of a polar half-metallic ferromagnet with accessible and enhanced electric polarization

    Physical Review Materials · 2018-11-12

    Danilo Puggioni, Alessandro Stroppa, James M. Rondinelli

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  38. Polar metallic behavior of strained antiperovskites ACNi3(A=Mg,Zn,and Cd) from first principles

    Physical Review Materials · 2018-12-26

    Yasuhide Mochizuki, Yu Kumagai, Hirofumi Akamatsu, Fumiyasu Oba

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  39. Two-dimensional polar metals in KNbO 3 /BaTiO 3 superlattices: first-principle calculations

    RSC Advances · 2019-01-01

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  40. Electronically enhanced layer buckling and Au-Au dimerization in epitaxial LaAuSb films

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  41. Probing ferroelectricity in highly conducting materials through their elastic response: Persistence of ferroelectricity in metallic BaTiO3−δ

    Physical review. B./Physical review. B · 2019-02-12

    F. Cordero, F. Trequattrini, F. Craciun, Hans Theo Langhammer, David Antonio Barbosa Quiroga, Paulo Sergio Silva

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  42. Heteroanionic Materials by Design: Progress Toward Targeted Properties

    Advanced Materials · 2019-03-12

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  43. Magnetoresistance in Metallic Ferroelectrics

    arXiv (Cornell University) · 2019-06-04

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  44. First-principles screening of ABO3 oxides with two magnetic sublattices

    Physical Review Materials · 2019-06-10

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  45. Magnetoresistance in Metallic Ferroelectrics

    ACS Applied Electronic Materials · 2019-06-12

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  46. A room-temperature ferroelectric semimetal

    Science Advances · 2019-07-05

    Pankaj Kumar Sharma, Feixiang Xiang, Ding‐Fu Shao, Dawei Zhang, Evgeny Y. Tsymbal, A. R. Hamilton, Jan Seidel

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  47. Evidence for the weakly coupled electron mechanism in an Anderson-Blount polar metal

    Nature Communications · 2019-07-19

    Nicholas J. Laurita, A. Ron, Jun-Yi Shan, Danilo Puggioni, Nathan Z. Koocher, Kazunari Yamaura, Ying Shi, James M. Rondinelli, David Hsieh

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  48. Heusler interfaces—Opportunities beyond spintronics?

    APL Materials · 2019-08-01

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  49. A first principles study of a spin-polarized two-dimensional polar metal at the SrVO3/PbTiO3 heterostructure interface

    Journal of Applied Physics · 2019-08-28

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  50. Creating multiferroic and conductive domain walls in common ferroelastic compounds

    npj Computational Materials · 2019-09-12

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