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RESEARCH PAPER · ChemSusChem · 2015

Enhancing the Performance of a Robust Sol–Gel‐Processed p‐Type Delafossite CuFeO 2 Photocathode for Solar Water Reduction

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Enhancing the Performance of a Robust Sol–Gel‐Processed p‐Type Delafossite CuFeO 2 Photocathode for Solar Water ReductionOriginalInvestigations to diagnose cause of dizziness in elderly people. Algorithm should ask whether patient is taking drugs that may cause dizziness.2Hydrothermal synthesis of delafossite CuFeO 2 crystals at 100 °C70La 5 Ti 2 Cu 1−x Ag x S 5 O 7 photocathodes operating at positive potentials during photoelectrochemical hydrogen evolution under irradiation of up to 710 nm65Oxygen-tolerant proton reduction catalysis: much O 2 about nothing?87Recent progress in photocathodes for hydrogen evolution182Sol–gel copper chromium delafossite thin films as stable oxide photocathodes for water splitting45Surface modification of semiconductor photoelectrodes181Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production278Templating Sol–Gel Hematite Films with Sacrificial Copper Oxide: Enhancing Photoanode Performance with Nanostructure and Oxygen Vacancies44Improving charge collection with delafossite photocathodes: a host–guest CuAlO 2 /CuFeO 2 approach102Delafossite Nanoparticle as New Functional Materials: Advances in Energy, Nanomedicine and Environmental Applications74Electronic structure, photovoltage, and photocatalytic hydrogen evolution with p-CuBi 2 O 4 nanocrystals192Earth-abundant trigonal BaCu 2 Sn(Se x S 1−x ) 4 (x = 0–0.55) thin films with tunable band gaps for solar water splitting42Multinary Metal Oxide Photoelectrodes14Room temperature synthesis of a highly active Cu/Cu 2 O photocathode for photoelectrochemical water splitting49Solution synthesis of pure 2H CuFeO 2 at low temperatures38Surface functionalized H 2 Ti 3 O 7 nanowires engineered for visible-light photoswitching, electrochemical water splitting, and photocatalysis74Nanostructured Ternary FeCrAl Oxide Photocathodes for Water Photoelectrolysis13Semiconducting materials for photoelectrochemical energy conversion1645A Bottom‐Up Approach toward All‐Solution‐Processed High‐Efficiency Cu(In,Ga)S2 Photocathodes for Solar Water Splitting97Solar Hydrogen Production from Zinc Telluride Photocathode Modified with Carbon and Molybdenum Sulfide47Solution Combustion Synthesis, Characterization, and Photoelectrochemistry of CuNb2O6 and ZnNb2O6 Nanoparticles77Stand-alone photoconversion of carbon dioxide on copper oxide wire arrays powered by tungsten trioxide/dye-sensitized solar cell dual absorbers65Crystal structural, optical properties and mott-schottky plots of p-type Ca doped CuFeO 2 nanoplates65Comprehensive Evaluation of CuBi 2 O 4 as a Photocathode Material for Photoelectrochemical Water Splitting356Investigating Water Splitting with CaFe2O4 Photocathodes by Electrochemical Impedance Spectroscopy62Copper(I)-Based p-Type Oxides for Photoelectrochemical and Photovoltaic Solar Energy Conversion209Oxygen-Intercalated CuFeO2 Photocathode Fabricated by Hybrid Microwave Annealing for Efficient Solar Hydrogen Production146Solution-processed CuSbS2 thin film: A promising earth-abundant photocathode for efficient visible-light-driven hydrogen evolution76Stable and Enhanced Visible-Light Water Electrolysis Using C, N, and S Surface Functionalized ZnO Nanorod Photoanodes: Engineering the Absorption and Electronic Structure51Template-directed fabrication of vertically aligned Cu2ZnSnS4 nanorod arrays for photoelectrochemical applications via a non-toxic solution process16Robust Hierarchically Structured Biphasic Ambipolar Oxide Photoelectrodes for Light‐Driven Chemical Regulation and Switchable Logic Applications37The effect of Mg-doping and Cu nonstoichiometry on the photoelectrochemical response of CuFeO 258Assessing the Suitability of Iron Tungstate (Fe2WO6) as a Photoelectrode Material for Water Oxidation58Facilitating hole transfer on electrochemically synthesized p-type CuAlO 2 films for efficient solar hydrogen production from water48Erste Preise von Air Liquide für essenzielle kleine Moleküle: K. Sivula, S.Kitagawa, R. Matsuda, J.‐M. Savéant, M. Robert und C. Costentin / Wolf‐Preis für Chemie: R. G. Bergman / Preise der Schweizerischen Chemischen Gesellschaft: K. Sivula, C. Sparr und R. R. Knowles / Ritterstand: S. Balasubramanian / Wheeler Bequest Award: J. I. Seeman0First Air Liquide Awards on Essential Small Molecules: K. Sivula, S.Kitagawa, R. Matsuda, J.‐M. Savéant, M. Robert, and C. Costentin / Wolf Prize in Chemistry: R. G. Bergman / Swiss Chemical Society Awards: K. Sivula, C. Sparr, and R. R. Knowles / Knighthood: S. Balasubramanian / Wheeler Bequest Award: J. I. Seeman0Direct Fabrication of a CuFeO2/Fe Photocathode for Solar Hydrogen Production by Hydrothermal Method9Metal Doping to Enhance the Photoelectrochemical Behavior of LaFeO3 Photocathodes83Emerging Earth-abundant materials for scalable solar water splitting21Solution Combustion Synthesis, Characterization, and Photocatalytic Activity of CuBi 2 O 4 and Its Nanocomposites with CuO and α-Bi 2 O 376Efficient solar photo-electrochemical hydrogen generation using nanocrystalline CeFeO 3 synthesized by a modified microwave assisted method60Enhanced Photocurrent of Transparent CuFeO2 Photocathodes by Self-Light-Harvesting Architecture43Recent developments in complex metal oxide photoelectrodes165Enhanced Photoelectrochemical Performance of Cuprous Oxide/Graphene Nanohybrids155Evaluating Charge Carrier Transport and Surface States in CuFeO2 Photocathodes164YFeO3 Photocathodes for Hydrogen Evolution40Nano-engineering of p–n CuFeO 2 -ZnO heterojunction photoanode with improved light absorption and charge collection for photoelectrochemical water oxidation38Copper ferrites@reduced graphene oxide anode materials for advanced lithium storage applications115Vibrational Spectroscopy of Oxide Overlayers59Roadmap on solar water splitting: current status and future prospects220Evaluating spinel ferrites MFe 2 O 4 (M = Cu, Mg, Zn) as photoanodes for solar water oxidation: prospects and limitations157Solar H 2 generation in water with a CuCrO 2 photocathode modified with an organic dye and molecular Ni catalyst75Hydrogen Production from Photoelectrochemical Water Splitting22Electrocatalytic and Photoelectrochemical Reduction of Carbon Dioxide in Aqueous Media: Toward Generation of Fuels and Utility Chemicals8Delafossite CuFeO2Photocathodes Grown by Direct Liquid Injection Chemical Vapor Deposition for Efficient Photoelectrochemical Water Reduction15Enhanced oxygen electroreduction over nitrogen-free carbon nanotube-supported CuFeO 2 nanoparticles33Review—Copper Oxide-Based Ternary and Quaternary Oxides: Where Solid-State Chemistry Meets Photoelectrochemistry104Effects of electrochemical synthetic conditions on surface property and photocatalytic performance of copper and iron-mixed p-type oxide electrodes12Proton Conduction and Fuel Cell Using the CuFe-Oxide Mineral Composite Based on CuFeO 2 Structure32Reduction of carbon dioxide at copper(I) oxide photocathode activated and stabilized by over-coating with oligoaniline26Potentiality of CuFeO2-delafossite as a solar energy converter34Cathodic Electrodeposition of Ni−Mo on Semiconducting NiFe2O4 for Photoelectrochemical Hydrogen Evolution in Alkaline Media3A highly efficient Cu(In,Ga)(S,Se)2 photocathode without a hetero-materials overlayer for solar-hydrogen production19Rapid synthesis of interconnected CuCrO 2 nanostructures: A promising electrode material for photoelectrochemical fuel generation24Hole Thermalization Dynamics Facilitate Ultrafast Spatial Charge Separation in CuFeO2 Solar Photocathodes32Aerobic Conditions Enhance the Photocatalytic Stability of CdS/CdOx Quantum Dots15Enhancing the Lifetime of Photoinduced Charge Carriers in CuFeO2 Nanoplates by Hydrothermal Doping of Mg for Photoelectrochemical Water Reduction26p-Type CuFeO2 nanoflakes prepared by sodium alginate-assisted hydrothermal method for photoelectrochemical water reduction16Recent advances in rational engineering of multinary semiconductors for photoelectrochemical hydrogen generation181Improving the Stability and Efficiency of CuO Photocathodes for Solar Hydrogen Production through Modification with Iron71The photocathodic properties of a Fe2O3 wrapped CuFeO2 layer on ITO glass for water splitting9Recent Advances in Earth‐Abundant Photocathodes for Photoelectrochemical Water Splitting117High figure of merit p-type transparent conducting thin film based on solution processed CuS-ZnS nanocomposite30Artificial Photosynthesis with Inorganic Particles8Hydrogen Production from Photoelectrochemical Water Splitting13Delafossite CuFeO2 thin films via aerosol assisted CVD: Synthesis and characterization21All-Bismuth-Based Oxide Tandem Cell for Solar Overall Water Splitting28Revealing the Performance-Limiting Factors in α-SnWO4 Photoanodes for Solar Water Splitting83Recent Advances and Emerging Trends in Photo‐Electrochemical Solar Energy Conversion319Polyvinylpyrrolidone-Assisted Hydrothermal Synthesis of CuCoO 2 Nanoplates with Enhanced Oxygen Evolution Reaction Performance69Hydrogen Production Through Solar-Driven Water Splitting: Cu(I) Oxide-Based Semiconductor Nanoparticles as the Next-Generation Photocatalysts0Nanostructured LaFeO3 Photocathodes with Onset Potentials for the Hydrogen Evolution Reaction Over 1.4 V vs. RHE18Rapid advances in antimony triselenide photocathodes for solar hydrogen generation40Strategies for enhancing the photocurrent, photovoltage, and stability of photoelectrodes for photoelectrochemical water splitting787Toward practical solar hydrogen production – an artificial photosynthetic leaf-to-farm challenge1321Photoelectrochemical Water Splitting with p‐Type Metal Oxide Semiconductor Photocathodes164Hydrothermal improvement for 3R-CuFeO2 delafossite growth by control of mineralizer and reaction atmosphere25Boosting Visible Light Harvesting in p‐Type Ternary Oxides for Solar‐to‐Hydrogen Conversion Using Inverse Opal Structure64Rapid Flame-Annealed CuFe2O4 as Efficient Photocathode for Photoelectrochemical Hydrogen Production126Carbon paste electrode modified with AgFeO2 as an electrocatalyst with excellent activity for water reduction and oxidation12Wetting properties of hydrothermally synthesized crystalline CuFeO2 delafossite porous surfaces1Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes912Elaborately Modified BiVO 4 Photoanodes for Solar Water Splitting538Electronic Structure and Performance Bottlenecks of CuFeO 2 Photocathodes72Localized Surface Plasmon Resonance Absorption Generated by Free Carriers in Zn‐Doped CuGa1−xZnxO2 Nanoplates4Insights on the Stability and Cationic Nonstoichiometry of CuFeO 2 Delafossite40Oxid alapú összetett fotoelektródok előállítása és vizsgálata0Effect of annealing temperature on structural properties of the co-precipitated delafossite AgFeO216Recent advances on state-of-the-art copper (I/II) oxide as photoelectrode for solar green fuel generation: Challenges and mitigation strategies30Boosting the performance of delafossite photocathode through constructing a CuFeO2/CuO heterojunction for photoelectrochemical water reduction34Photoelectrochemical Reduction of CO2 to Alcohols at CuO/CuFeO2 Thin Film Electrode18Facile Two‐Step Synthesis of Delafossite CuFeO2 Photocathodes by Ultrasonic Spray Pyrolysis and Hybrid Microwave Annealing21Rapid Performance Optimization Method for Photoelectrodes10The role of phase impurities and lattice defects on the electron dynamics and photochemistry of CuFeO2 solar photocathodes40Influence of Reduced Cu Surface States on the Photoelectrochemical Properties of CuBi2O440State-of-the-art progress in the use of ternary metal oxides as photoelectrode materials for water splitting and organic synthesis117Directly Photoexcited Oxides for Photoelectrochemical Water Splitting21Structural, optical and photoelectrochemical properties of p type Ni doped CuFeO2 by hydrothermal method37A triptych photocatalyst based on the Co-Integration of Ag nanoparticles and carbo-benzene dye into a TiO2 thin film13Electrochemical Evaluation for Multiple Functions of Pt‐loaded TiO 2 Nanoparticles Deposited on a Photocathode15Copper zinc oxide heterostructure nanoflowers for hydrogen evolution23Band gap determination in multi-band-gap CuFeO2 delafossite epitaxial thin film by photoconductivity27Hybrid Microwave Annealing Synthesizes Highly Crystalline Nanostructures for (Photo)electrocatalytic Water Splitting43ZnBi38O60/Bi2O3 photocathode for hydrogen production from water splitting17Perspectives on the Development of Oxide-Based Photocathodes for Solar Fuel Production91Inorganic CuFeO2 Delafossite Nanoparticles as Effective Hole Transport Materials for Highly Efficient and Long-Term Stable Perovskite Solar Cells79Thermodynamic Stability and Native Point Defects of CuFeO2 Photocathodes in Dry and Electrochemical Environments25Fundamental properties of delafossite CuFeO2 as photocatalyst for solar energy conversion116Roll-to-Roll Deposition of Semiconducting 2D Nanoflake Films of Transition Metal Dichalcogenides for Optoelectronic Applications49Strategies for the deposition of LaFeO 3 photocathodes: improving the photocurrent with a polymer template22Effects of the addition of surfactants on the direct fabrication of a CuFeO2/Fe photocathode by hydrothermal method1Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO 2 -cobaloxime photocathode10Characteristics of crystalline sputtered LaFeO 3 thin films as photoelectrochemical water splitting photocathodes37Correction: Wet chemical epitaxial growth of a cactus-like CuFeO 2 /ZnO heterojunction for improved photocatalysis4Earth-abundant Cu-based metal oxide photocathodes for photoelectrochemical water splitting269Elucidating the optical, electronic, and photoelectrochemical properties of p-type copper vanadate (p-Cu 5 V 2 O 10 ) photocathodes30Ferrites: emerging light absorbers for solar water splitting93How photocorrosion can trick you: a detailed study on low-bandgap Li doped CuO photocathodes for solar hydrogen production30Photoelectrocatalytic production of solar fuels with semiconductor oxides: materials, activity and modeling35Semiconductor-based photocatalysts for photocatalytic and photoelectrochemical water splitting: will we stop with photocorrosion?433Towards sustainable and efficient p-type metal oxide semiconductor materials in dye-sensitised photocathodes for solar energy conversion46Wet chemical epitaxial growth of a cactus-like CuFeO 2 /ZnO heterojunction for improved photocatalysis11Pinning of the Fermi Level in CuFeO 2 by Polaron Formation Limiting the Photovoltage for Photochemical Water Splitting67Effective combination of CuFeO2 with high temperature resistant Nb-doped TiO2 nanotube arrays for CO2 photoelectric reduction44PrFeO3 Photocathodes Prepared Through Spray Pyrolysis37Thickness-dependent microstructural properties of heteroepitaxial (00.1) CuFeO2 thin films on (00.1) sapphire by pulsed laser deposition17Semiconducting p-Type Copper Iron Oxide Thin Films Deposited by Hybrid Reactive-HiPIMS + ECWR and Reactive-HiPIMS Magnetron Plasma System13Hydrogenation of ZnFe2O4 Flat Films: Effects of the Pre-Annealing Temperature on the Photoanodes Efficiency for Water Oxidation14Establishing best practices to model the electronic structure of CuFeO2 from first principles10Grain Boundaries Limit the Charge Carrier Transport in Pulsed Laser Deposited α-SnWO4 Thin Film Photoabsorbers47Excess oxygen in delafossite CuFeO2+δ: Synthesis, characterization, and applications in solar energy conversion33Generalized Synthesis to Produce Transparent Thin Films of Ternary Metal Oxide Photoelectrodes10Improvement of CuFeO2/Fe photocathodes by applying a posttreatment0Photoelectrochemical CO2 Reduction via Cu2O/CuFeO2 Hierarchical nanorods photocatalyst24Promoting Active Electronic States in LaFeO3 Thin-Films Photocathodes via Alkaline-Earth Metal Substitution22Phase-Pure Copper Vanadate (α-CuV2O6): Solution Combustion Synthesis and Characterization46A Beehive Inspired Hydrogen Photocatalytic Device Integrating a Carbo‐Benzene Triptych Material for Efficient Solar Photo‐Reduction of Seawater15Extending lifetime of photoinduced charge carriers in CuO photocathode by Zn doping for photoelectrochemical water reduction82D TMDC Materials for hydrogen evolution through solar water splitting0

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  1. Investigations to diagnose cause of dizziness in elderly people. Algorithm should ask whether patient is taking drugs that may cause dizziness.

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  2. Hydrothermal synthesis of delafossite CuFeO 2 crystals at 100 °C

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  3. La 5 Ti 2 Cu 1−x Ag x S 5 O 7 photocathodes operating at positive potentials during photoelectrochemical hydrogen evolution under irradiation of up to 710 nm

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  4. Oxygen-tolerant proton reduction catalysis: much O 2 about nothing?

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  5. Recent progress in photocathodes for hydrogen evolution

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  6. Sol–gel copper chromium delafossite thin films as stable oxide photocathodes for water splitting

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  7. Surface modification of semiconductor photoelectrodes

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  8. Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production

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  9. Templating Sol–Gel Hematite Films with Sacrificial Copper Oxide: Enhancing Photoanode Performance with Nanostructure and Oxygen Vacancies

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  10. Improving charge collection with delafossite photocathodes: a host–guest CuAlO 2 /CuFeO 2 approach

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  11. Delafossite Nanoparticle as New Functional Materials: Advances in Energy, Nanomedicine and Environmental Applications

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  12. Electronic structure, photovoltage, and photocatalytic hydrogen evolution with p-CuBi 2 O 4 nanocrystals

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  14. Multinary Metal Oxide Photoelectrodes

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  15. Room temperature synthesis of a highly active Cu/Cu 2 O photocathode for photoelectrochemical water splitting

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  16. Solution synthesis of pure 2H CuFeO 2 at low temperatures

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  17. Surface functionalized H 2 Ti 3 O 7 nanowires engineered for visible-light photoswitching, electrochemical water splitting, and photocatalysis

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  19. Semiconducting materials for photoelectrochemical energy conversion

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  20. A Bottom‐Up Approach toward All‐Solution‐Processed High‐Efficiency Cu(In,Ga)S2 Photocathodes for Solar Water Splitting

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  21. Solar Hydrogen Production from Zinc Telluride Photocathode Modified with Carbon and Molybdenum Sulfide

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  25. Comprehensive Evaluation of CuBi 2 O 4 as a Photocathode Material for Photoelectrochemical Water Splitting

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  27. Copper(I)-Based p-Type Oxides for Photoelectrochemical and Photovoltaic Solar Energy Conversion

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  33. The effect of Mg-doping and Cu nonstoichiometry on the photoelectrochemical response of CuFeO 2

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  34. Assessing the Suitability of Iron Tungstate (Fe2WO6) as a Photoelectrode Material for Water Oxidation

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  35. Facilitating hole transfer on electrochemically synthesized p-type CuAlO 2 films for efficient solar hydrogen production from water

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  36. Erste Preise von Air Liquide für essenzielle kleine Moleküle: K. Sivula, S.Kitagawa, R. Matsuda, J.‐M. Savéant, M. Robert und C. Costentin / Wolf‐Preis für Chemie: R. G. Bergman / Preise der Schweizerischen Chemischen Gesellschaft: K. Sivula, C. Sparr und R. R. Knowles / Ritterstand: S. Balasubramanian / Wheeler Bequest Award: J. I. Seeman

    Angewandte Chemie · 2017-02-10

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  37. First Air Liquide Awards on Essential Small Molecules: K. Sivula, S.Kitagawa, R. Matsuda, J.‐M. Savéant, M. Robert, and C. Costentin / Wolf Prize in Chemistry: R. G. Bergman / Swiss Chemical Society Awards: K. Sivula, C. Sparr, and R. R. Knowles / Knighthood: S. Balasubramanian / Wheeler Bequest Award: J. I. Seeman

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  38. Direct Fabrication of a CuFeO2/Fe Photocathode for Solar Hydrogen Production by Hydrothermal Method

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  39. Metal Doping to Enhance the Photoelectrochemical Behavior of LaFeO3 Photocathodes

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  40. Emerging Earth-abundant materials for scalable solar water splitting

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  42. Efficient solar photo-electrochemical hydrogen generation using nanocrystalline CeFeO 3 synthesized by a modified microwave assisted method

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  43. Enhanced Photocurrent of Transparent CuFeO2 Photocathodes by Self-Light-Harvesting Architecture

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  44. Recent developments in complex metal oxide photoelectrodes

    Journal of Physics D Applied Physics · 2017-04-10

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  45. Enhanced Photoelectrochemical Performance of Cuprous Oxide/Graphene Nanohybrids

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