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RESEARCH PAPER · ChemInform · 2006

Applications of Layered Double Hydroxides

Feng Li, Xue Duan

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Applications of Layered Double HydroxidesOriginalElaboration et caractérisation de matrices hydroxydes doubles lamellaires macroporeuses1Preparation of low-molecular-weight polyamide 6/hydrotalcite intercalated nanocomposites via insitu polymerization5Microstructure-controlled synthesis of oriented layered double hydroxide thin films: Effect of varying the preparation conditions and a kinetic and mechanistic study of film formation29Preparation of meixnerite (Mg–Al–OH) type layered double hydroxide by a mechanochemical route127Mechanochemical route for synthesizing nitrate form of layered double hydroxide88Adsorption of 2,4-D on Mg/Al–NO3 layered double hydroxides with varying layer charge density89Novel hybrid materials obtained by intercalation of organic comb polymers into Ca–Al–LDH19Application of layered double hydroxides for removal of oxyanions: A review1708Facile Preparation of Magnesium Ferrite Film via a Single-source Precursor Route11Synthesis and anion exchange chemistry of new intercalation hosts containing lanthanide cations, Ln2(OH)5(NO3)·xH2O (Ln=Y, Gd–Lu)63Alkaline phosphatase biosensors based on layered double hydroxides matrices: Role of LDH composition59Co-based catalysts from Co/Fe/Al layered double hydroxides for preparation of carbon nanotubes96Preparation of Co–Al layered double hydroxides by the hydrothermal urea method for controlled particle size93In situ growth of layered double hydroxide films on anodic aluminum oxide/aluminum and its catalytic feature in aldol condensation of acetone92Preparation of macrospherical magnesia-rich magnesium aluminate spinel catalysts for methanolysis of soybean oil45New hydroxyapatite–hydrotalcite composites II. microwave irradiation effect on structure and texture8Release studies of different NSAIDs encapsulated in Mg,Al,Fe-hydrotalcites90Experimental investigation of sheet flexibility of layered double hydroxides: One-pot morphosynthesis of inorganic intercalates44Layer-by-layer assembly of ruthenium(ii) complex anion/layered double hydroxide ordered ultrathin films with polarized luminescence49Alkyl sulfonate modified LDH: Effect of alkyl chain length on intercalation behavior, particle morphology and thermal stability68Structural and morphological transformations of Zn–Al layered double hydroxides through hydrothermal treatment26Mechanistic and thermodynamic studies of oxyanion sorption by various synthetic Mg/Al layered double hydroxides3Comparison of the evolution and growth processes of films of M/Al-layered double hydroxides with M=Ni or Zn62Fibrillar Templating of Hydrotalcites2The Formation of Layered Double Hydroxides on Alumina Surface in Aqueous Solutions Containing Divalent Metal Cations6Facile preparation of pure CaAl-layered double hydroxides and their application as a hardening accelerator in concrete126Removal of Naphthol Green B from Aqueous Solution by Calcined Layered Double Hydroxides: Adsorption Property and Mechanism Studies24Synthesis of Novel Submicrometer‐Scale Flat Carbon Fibers and Application in the Electrooxidation of Methanol14Sorption of Pb(II) on Mg‐Fe Layered Double Hydroxide48Biotemplated Hierarchical Nanostructure of Layered Double Hydroxides with Improved Photocatalysis Performance283Preparation of layered double hydroxides intercalated with organic anions and their application in LDH/poly(butyl methacrylate) nanocomposites110Self-assembling organomodified Co/Al based layered double hydroxides (LDH) via one-step route27A strategy to the ordered assembly of functional small cations with layered double hydroxides for luminescent ultra-thin films90Facile synthesis and novel electrocatalytic performance of nanostructured Ni–Al layered double hydroxide/carbon nanotube composites162Layered double hydroxide films: synthesis, properties and applications461Preparation, stability and rheology of polyacrylamide/pristine layered double hydroxide nanocomposites87Sorption of oxyanions on nanocrystalline Mg/Al layered double hydroxides : sorption characteristics, mechanisms, and matrix interferences0Template-assisted fabrication of macroporous NiFe2O4 films with tunable microstructural, magnetic and interfacial properties29Formation and catalytic performance of supported ni nanoparticles via self‐reduction of hybrid NiAl‐LDH/C composites33Protein template effect on hydrotalcite morphology5Biopolymer-induced microstructure-controlled fabrication of Ni–Al layered double hydroxide films12A novel organic–inorganic microhybrids containing anticancer agent doxifluridine and layered double hydroxides: Structure and controlled release properties69Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles101Optimization of the wash process and wash water recycling in the preparation of MgZnAl–CO3 layered double hydroxides4Facile Fabrication and Magnetic Properties of Macroporous Spinel Microspheres from Layered Double Hydroxide Microsphere Precursor8Sorption of lead ion by layered double hydroxide intercalated with diethylenetriaminepentaacetic acid134New Template Effect in Hydrotalcite Synthesis. Nodular vs. Layered Morphologies7Layered intercalated functional materials based on efficient utilization of magnesium resources in China14Synthesis of carbon nanotubes/metal oxide composites over layered double hydroxides and application in electrooxidation of ethanol32Thermal decomposition, gas phase hydration and liquid phase reconstruction in the system Mg/Al hydrotalcite/mixed oxide: A comparative study95Electrochemical detection of dopamine on a Ni/Al layered double hydroxide modified carbon ionic liquid electrode116Reconstitution effect of Mg/Ni/Al layered double hydroxide14Layered double hydroxides with interlayer borate anions: A critical evaluation of synthesis methodology and pH-independent orientations in nano-galleries70An examination of the applicability of hydrotalcite for removing oxalate anions from Bayer process solutions4The urea method for the direct synthesis of ZnAl layered double hydroxides with nitrate as the interlayer anion125The Effect of Zn-Al-Hydrotalcites Composited with Calcium Stearate and β-Diketone on the Thermal Stability of PVC33Catalytic wet peroxide oxidation of phenol over Cu–Ni–Al hydrotalcite92Methotrexate intercalated ZnAl-layered double hydroxide76Treatment of 2,4,5-trichlorophenol by MgAl–SDBS organo-layered double hydroxides: Kinetic and equilibrium studies66PREPARATION OF LAYERED DOUBLE HYDROXIDES10Visible-light-induced heterostructured Zn–Al–In mixed metal oxide nanocomposite photocatalysts derived from a single precursor57Layered double hydroxides — multifunctional nanomaterials165Mobility and phyto-availability of arsenic in soil-plant system and decontamination techniques of arsenic polluted areas0Preparation and characterisation of ammonium polyphosphate intercalated layered double hydroxides composite by joint method with or without sonochemical technique8Entrapment of Mg-Al layered double hydroxide in calcium alginate beads for phosphate removal from aqueous solution43Solubility product (Ksp)-controlled removal of chromate and phosphate by hydrocalumite83Síntese de nanocompósitos poliméricos de poli(acrilato de n-butila-co-metacrilato de metila) P(BA-co-MMA) e Hidróxidos Duplos Lamelares (HDL) por meio da técnica de polimerização em miniemulsão0Mathematical Model and Equations of Wash Water Recycling in the Preparation of Layered Double Hydroxides0Removal of phenylalanine from water with calcined CuZnAl-CO3 layered double hydroxides16Mg–Al layered double hydroxide intercalated with sodium lauryl sulfate as a sorbent for 152+154Eu from aqueous solutions26Thermally activated iron containing layered double hydroxides as potential catalyst for N2O abatement34Silver-layered double hydroxides self-assemblies3Ceramic Nano-Vehicles for Controlled Delivery of Functional Bio-Molecules0Zinc/Aluminum layered double hydroxide–titanium dioxide composite nanosheet film as novel solid phase microextraction fiber for the gas chromatographic determination of valproic acid56The crystal structure of cualstibite-1M (formerly cyanophyllite), its revised chemical formula and its relation to cualstibite-1T11Influence of the pore structure of Ce/MgAl hydrotalcite-derived mixed oxides on its SO x pick-up capacity2Adsorption of Phosphate by Calcinated Mg-Fe Layered Double Hydroxide10Recent Advances in Stimuli‐Responsive Photofunctional Materials Based on Accommodation of Chromophore into Layered Double Hydroxide Nanogallery21The investigation of Ni–Al and Co–Al based layered double hydroxides and their derived mixed oxides thin films deposited by pulsed laser deposition16Calcined graphene/MgAl-layered double hydroxides for enhanced Cr(VI) removal350Advances in Inorganic and Hybrid Ion Exchangers40Correlation of structural and chemical characteristics with catalytic performance of hydrotalcite-based CuNiAl mixed oxides for SO2 abatement26Thiamine pyrophosphate intercalation in layered double hydroxides (LDHs): An active bio-hybrid catalyst for pyruvate decarboxylation30Intercalation Assembly Method and Intercalation Process Control of Layered Intercalated Functional Materials19Functional Materials - Syntheses, Characterisation and Catalytic Applications2Synthesis of Mg2Al-Cl layered double hydroxide nanosheets in a surfactant-free reverse microemulsion38Synthesis of hybrid Zn–Al–In mixed metal oxides/carbon nanotubes composite and enhanced visible-light-induced photocatalytic performance38Drug Delivery Using Nanosized Layered Double Hydroxide, an Anionic Clay10Multi-cationic layered double hydroxides: Calcined products as photocatalysts for decomposition of NOx16Thermodynamic properties and thermal behavior of Friedel's salt119Removal of vanadate anion by calcined Mg/Al-CO3 layered double hydroxide in aqueous solution19Electrochemical synthesis of nickel–iron layered double hydroxide: Application as a novel modified electrode in electrocatalytic reduction of metronidazole79Oriented CuZnAl Ternary Layered Double Hydroxide Films: In situ Hydrothermal Growth and Anticorrosion Properties24Formation and crystallization of Mg2+–Fe3+–SO42−–CO32−-type anionic clays16A novel approach to hierarchical sphere-like ZnAl-layered double hydroxides and their enhanced adsorption capability97Synergism between LDH and Nano-Zinc Phosphate on the Flammability and Mechanical Properties of Polypropylene13Preparation of Zn-Al CLDH to Remove Bromate from Drinking Water13Preparation and Anti-mildew Properties of TPN-SDS-layered Double Hydroxide Nanohybrids3Integrative strategies to hybrid lamellar compounds: an integration challenge55MTX/LDHs hybrids synthesized from reverse microemulsions: Particle control and bioassay study41Preparation of layered nickel aluminium double hydroxide from waste solution of nickel9A nonenzymatic reduced glutathione sensor based on Ni–Al LDHs/MWCNTs composites26Layered double hydroxide: a new promising nanomaterial in energy application13Emerging applications of graphene and its derivatives in carbon capture and conversion: Current status and future prospects79Silylated MgAl LDHs intercalated with MnO2 nanowires: Highly efficient catalysts for the solvent-free aerobic oxidation of ethylbenzene70Non-enzymatic glucose sensor based on Au nanoparticles decorated ternary Ni-Al layered double hydroxide/single-walled carbon nanotubes/graphene nanocomposite181Adsorption of glutamic acid from aqueous solution with calcined layered double Mg–Fe–CO3 hydroxide13Intercalation Assembly and Chemical Product Engineering of Layered Intercalated Functional Materials Based on Efficient Utilization of Magnesium Resources in Salt Lakes2Synthesis and Characterization of Layered Double Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite5Thermal decomposition of layered double hydroxides Mg-Al, Ni-Al, Mg-Ga: Structural features of hydroxide, dehydrated, and oxide phases11Photochromic Intercalation Compounds26Theoretical investigations on the layer-anion interaction in Mg–Al layered double hydroxides: Influence of the anion nature and layer composition8Sorbent effect on the sorption of Cr(VI) on a Mg6AlFe-layered double hydroxide and its calcined product in aqueous solutions20Dehydration-rehydration induced structural changes in pristine and composite layered double hydroxides0One-Pot Microwave-Assisted Synthesis of Graphene/Layered Double Hydroxide (LDH) Nanohybrids106Porous Two-Dimensional Nanosheets Converted from Layered Double Hydroxides and Their Applications in Electrocatalytic Water Splitting298Modified hydrotalcites for enhancement of biohydrogen production12Synthesizing NiAl-layered double hydroxide microspheres with hierarchical structure and electrochemical detection of hydroquinone and catechol49Precipitation of aluminum and magnesium secondary minerals from uranium mill raffinate (pH 1.0–10.5) and their controls on aqueous contaminants15Mechanochemical approaches to synthesize layered double hydroxides: a review184Zn–Al layered double hydroxides intercalated with carbonate, nitrate, chloride and sulphate ions: Synthesis, characterisation and dye removal properties260Arsenate removal by layered double hydroxides embedded into spherical polymer beads: Batch and column studies23Flexible polyurethane foam nanocomposites with modified layered double hydroxides60Electrochemical Determination of Papaverine on Mg-Al Layered Double Hydroxide/ Graphene Oxide and CNT Modified Carbon Paste Electrode24Structure and properties of polyurethane-based powder clear coatings systems modified with hydrotalcites23Nanoparticles: From Diagnosis to Therapy8Equilibrium, kinetic and thermodynamic studies of the uptake of copper by layered double hydroxide4Heterogeneous Base Metal Catalyzed Oxidative Depolymerization of Lignin and Lignin Model Compounds0Preparation of Fe(II)–Al layered double hydroxides: Application to the adsorption/reduction of chromium88Graphitic-C 3 N 4 modified ZnAl-layered double hydroxides for enhanced photocatalytic removal of organic dye85Coordination of arsenic and nickel to aluminum and magnesium phases in uranium mill raffinate precipitates4Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation518Recent advances in layered double hydroxides as electrode materials for high-performance electrochemical energy storage devices95Amino acids-intercalated Mg/Al layered double hydroxides as dual-electronic adsorbent for effective removal of cationic and oxyanionic metal ions128Nanofillers in the electrolytes of dye-sensitized solar cells – A short review74Photocatalytic reduction of CO2 on Cu2O-loaded Zn-Cr layered double hydroxides168Calcined layered double hydroxides/reduced graphene oxide composites with improved photocatalytic degradation of paracetamol and efficient oxidation-adsorption of As(III)131Facile synthesis of cation doped ZnO-ZnCo2O4 hetero-nanocomposites for photocatalytic decomposition of aqueous organics under visible light53Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials930Advances in Theoretical Studies on Solid Catalysts for Renewable Energy Production0Efficient removal of copper and lead by Mg/Al layered double hydroxides intercalated with organic acid anions: Adsorption kinetics, isotherms, and thermodynamics138Ultrahigh-capacity and fast-rate removal of graphene oxide by calcined MgAl layered double hydroxide11New insight into the preferred valency of interlayer anions in hydrotalcite-like compounds: The effect of Mg/Al ratio57Rhodium incorporated monometallic cobalt hydrotalcite-type materials: Preparation and its applications for the hydroformylation of alkenes30[Mg-Al]-LDH and [Zn-Al]-LDH as Matrices for Removal of High Loadings of Phosphate42The activity of Mg-Al layered double hydroxides intercalated with nitrogen-containing anions towards the removal of carbon dioxide from natural gas28Thermo-physical properties of Cu-Zn-Al LDH nanofluid and its application in spray cooling80Nano-photosensitizer based on layered double hydroxide and isophthalic acid for singlet oxygenation and photodynamic therapy307Layered Double Hydroxides as Hosting Matrices for Storage and Slow Release of Phosphate Analyzed by Stirred-Flow Method72Amphiphilic CdTe Quantum Dots@Layered Double Hydroxides/Arachidate Nanocomposite Langmuir–Blodgett Ultrathin Films: Its Assembly and Response Mechanism as VOC Fluorescence Sensors16

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  1. Elaboration et caractérisation de matrices hydroxydes doubles lamellaires macroporeuses

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  2. Preparation of low-molecular-weight polyamide 6/hydrotalcite intercalated nanocomposites via insitu polymerization

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  3. Microstructure-controlled synthesis of oriented layered double hydroxide thin films: Effect of varying the preparation conditions and a kinetic and mechanistic study of film formation

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    Zhi Hong Lu, Fazhi Zhang, Xiaodong Lei, Lan Yang, David G. Evans, Xue Duan

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  4. Preparation of meixnerite (Mg–Al–OH) type layered double hydroxide by a mechanochemical route

    Journal of Materials Science · 2007-07-26

    William Tongamp, Qiwu Zhang, Fumio Saito

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  5. Mechanochemical route for synthesizing nitrate form of layered double hydroxide

    Powder Technology · 2007-10-01

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  6. Adsorption of 2,4-D on Mg/Al–NO3 layered double hydroxides with varying layer charge density

    Applied Clay Science · 2007-10-25

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  7. Novel hybrid materials obtained by intercalation of organic comb polymers into Ca–Al–LDH

    Journal of Physics and Chemistry of Solids · 2007-11-06

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  8. Application of layered double hydroxides for removal of oxyanions: A review

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  9. Facile Preparation of Magnesium Ferrite Film via a Single-source Precursor Route

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  10. Synthesis and anion exchange chemistry of new intercalation hosts containing lanthanide cations, Ln2(OH)5(NO3)·xH2O (Ln=Y, Gd–Lu)

    Journal of Physics and Chemistry of Solids · 2007-12-01

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  11. Alkaline phosphatase biosensors based on layered double hydroxides matrices: Role of LDH composition

    Sensors and Actuators B Chemical · 2008-03-21

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  12. Co-based catalysts from Co/Fe/Al layered double hydroxides for preparation of carbon nanotubes

    Applied Clay Science · 2008-04-27

    X XIANG, Liqun Zhang, H. Hima, Fei Li, Deborah S. Evans

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  13. Preparation of Co–Al layered double hydroxides by the hydrothermal urea method for controlled particle size

    Applied Clay Science · 2008-05-05

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  14. In situ growth of layered double hydroxide films on anodic aluminum oxide/aluminum and its catalytic feature in aldol condensation of acetone

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    Zhi Hong Lu, Fazhi Zhang, Xiaodong Lei, Lan Yang, Sailong Xu, Xue Duan

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  15. Preparation of macrospherical magnesia-rich magnesium aluminate spinel catalysts for methanolysis of soybean oil

    Chemical Engineering Science · 2008-05-24

    Yanchang Wang, Fazhi Zhang, Sailong Xu, Lan Yang, Dianqing Li, David G. Evans, Xue Duan

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  16. New hydroxyapatite–hydrotalcite composites II. microwave irradiation effect on structure and texture

    Journal of Porous Materials · 2008-06-03

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  17. Release studies of different NSAIDs encapsulated in Mg,Al,Fe-hydrotalcites

    Applied Clay Science · 2008-07-04

    Margarita del Arco, A FERNANDEZ, C. Dianne Martin, V. Rives

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  18. Experimental investigation of sheet flexibility of layered double hydroxides: One-pot morphosynthesis of inorganic intercalates

    Chemical Engineering Journal · 2008-07-07

    Bo Li, Jing He, David G. Evans

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  19. Layer-by-layer assembly of ruthenium(ii) complex anion/layered double hydroxide ordered ultrathin films with polarized luminescence

    Chemical Communications · 2009-01-01

    Dongpeng Yan, Jun Guo Lu, Min Wei, Jing Ma, David G. Evans, Xue Duan

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  20. Alkyl sulfonate modified LDH: Effect of alkyl chain length on intercalation behavior, particle morphology and thermal stability

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  21. Structural and morphological transformations of Zn–Al layered double hydroxides through hydrothermal treatment

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  22. Mechanistic and thermodynamic studies of oxyanion sorption by various synthetic Mg/Al layered double hydroxides

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  23. Comparison of the evolution and growth processes of films of M/Al-layered double hydroxides with M=Ni or Zn

    Chemical Engineering Science · 2009-03-06

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  24. Fibrillar Templating of Hydrotalcites

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  25. The Formation of Layered Double Hydroxides on Alumina Surface in Aqueous Solutions Containing Divalent Metal Cations

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  26. Facile preparation of pure CaAl-layered double hydroxides and their application as a hardening accelerator in concrete

    Chemical Engineering Journal · 2009-08-19

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  27. Removal of Naphthol Green B from Aqueous Solution by Calcined Layered Double Hydroxides: Adsorption Property and Mechanism Studies

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  28. Synthesis of Novel Submicrometer‐Scale Flat Carbon Fibers and Application in the Electrooxidation of Methanol

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  29. Sorption of Pb(II) on Mg‐Fe Layered Double Hydroxide

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  30. Biotemplated Hierarchical Nanostructure of Layered Double Hydroxides with Improved Photocatalysis Performance

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  31. Preparation of layered double hydroxides intercalated with organic anions and their application in LDH/poly(butyl methacrylate) nanocomposites

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  32. Self-assembling organomodified Co/Al based layered double hydroxides (LDH) via one-step route

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  33. A strategy to the ordered assembly of functional small cations with layered double hydroxides for luminescent ultra-thin films

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  34. Facile synthesis and novel electrocatalytic performance of nanostructured Ni–Al layered double hydroxide/carbon nanotube composites

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  35. Layered double hydroxide films: synthesis, properties and applications

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  36. Preparation, stability and rheology of polyacrylamide/pristine layered double hydroxide nanocomposites

    Journal of Materials Chemistry · 2010-01-01

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  37. Sorption of oxyanions on nanocrystalline Mg/Al layered double hydroxides : sorption characteristics, mechanisms, and matrix interferences

    Unknown journal · 2010-01-01

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  38. Template-assisted fabrication of macroporous NiFe2O4 films with tunable microstructural, magnetic and interfacial properties

    Journal of Materials Chemistry · 2010-01-01

    Guoli Fan, Xu Xiang, Jun Fan, Feng Li

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  39. Formation and catalytic performance of supported ni nanoparticles via self‐reduction of hybrid NiAl‐LDH/C composites

    AIChE Journal · 2010-01-27

    Xu Xiang, Lu Bai, Feng Li

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  40. Protein template effect on hydrotalcite morphology

    Polymers for Advanced Technologies · 2010-02-05

    Alicia E. Sommer-Márquez, Geolar Fetter, Pedro Bosch, Omar Novelo-Peralta

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  41. Biopolymer-induced microstructure-controlled fabrication of Ni–Al layered double hydroxide films

    Chemical Engineering Journal · 2010-02-11

    Hui Wang, Zheng Chen, Feng Li

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  42. A novel organic–inorganic microhybrids containing anticancer agent doxifluridine and layered double hydroxides: Structure and controlled release properties

    Chemical Engineering Science · 2010-03-17

    Dengke Pan, Hui Zhang, Ting Zhang, Xue Duan

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  43. Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles

    Journal of Hazardous Materials · 2010-03-25

    Kok-Hui Goh, Teik‐Thye Lim, Agnieszka Banaś, Zhiling Dong

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  44. Optimization of the wash process and wash water recycling in the preparation of MgZnAl–CO3 layered double hydroxides

    Particuology · 2010-03-30

    Xuefei Jia, Dianqing Li, David G. Evans, Yanjun Lin

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  45. Facile Fabrication and Magnetic Properties of Macroporous Spinel Microspheres from Layered Double Hydroxide Microsphere Precursor

    Chemistry Letters · 2010-05-08

    Fazhi Zhang, Yaru Xie, Sailong Xu, Xiaofei Zhao, Xiaodong Lei

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  46. Sorption of lead ion by layered double hydroxide intercalated with diethylenetriaminepentaacetic acid

    Colloids and Surfaces A Physicochemical and Engineering Aspects · 2010-05-18

    Xuefeng Liang, Wanguo Hou, Yingming Xu, Guohong Sun, Lin Wang, Yang Sun, Xu Qin

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  47. New Template Effect in Hydrotalcite Synthesis. Nodular vs. Layered Morphologies

    Clays and Clay Minerals · 2010-06-01

    Alicia E. Sommer-Márquez, Geolar Fetter, Pedro Bosch, Victor Hugo Lara

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  48. Layered intercalated functional materials based on efficient utilization of magnesium resources in China

    Science China Chemistry · 2010-07-01

    Xiangyu Xu, Yanjun Lin, David G. Evans, Xue Duan

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  49. Synthesis of carbon nanotubes/metal oxide composites over layered double hydroxides and application in electrooxidation of ethanol

    Applied Clay Science · 2010-07-22

    Lu Zhang, Feng Li

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  50. Thermal decomposition, gas phase hydration and liquid phase reconstruction in the system Mg/Al hydrotalcite/mixed oxide: A comparative study

    Applied Clay Science · 2010-08-03

    M. Mokhtar, Alexandra Inayat, Jimmy Ofili, Wilhelm Schwieger

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