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RESEARCH PAPER · Chemistry - A European Journal · 2013

A Racemic and Enantiopure Unsymmetric Diiron(III) Complex with a Chiral o‐Carborane‐Based Pyridylalcohol Ligand: Combined Chiroptical, Magnetic, and Nonlinear Optical Properties

Florencia Di Salvo, Min Ying Tsang, Francesç Teixidor, Clara Viñas, José Giner Planas, Jeanne Crassous, Nicolas Vanthuyne, Núria Aliaga‐Alcalde, Eliseo Ruíz, Gérard Coquerel, Simon Clevers, Valérie Dupray, Duane Choquesillo‐Lazarte, Mark E. Light, Michael B. Hursthouse

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A Racemic and Enantiopure Unsymmetric Diiron(III) Complex with a Chiral o‐Carborane‐Based Pyridylalcohol Ligand: Combined Chiroptical, Magnetic, and Nonlinear Optical PropertiesOriginalChirality Transfer in Magnetic Coordination Complexes Monitored by Vibrational and Electronic Circular Dichroism16Synthesis, Structure, and Catalytic Applications for ortho- and meta-Carboranyl Based NBN Pincer-Pd Complexes65Carboranes in the chemist's toolbox235Intramolecular hydrogen bonding stabilizes the nuclearity of complexes. A comparative study based on the H-carborane and Me-carborane framework9Is Molecular Chirality Connected to Supramolecular Chirality? The Particular Case of Chiral 2-Pyridyl Alcohols18Facial Synthesis of o‐Carborane‐Substituted Alkenes and Allenes by a Regioselective Ene Reaction of 1,3‐Dehydro‐o‐carborane21Dearomative [2 + 2] Cycloaddition and Formal C–H Insertion Reaction of o-Carboryne with Indoles: Synthesis of Carborane-Functionalized Heterocycles58Mechano-induced multi-functional optical switches based on chiral cyclometalated platinum(II) complexes14Carboranes in Other Applications2Icosahedral Carboranes49Synthesis, structures and properties of ironIII complexes with (o-carboranyl)bis-(2-hydroxymethyl)pyridine: Racemic versus meso8N,O-Type Carborane-Based Materials28Carborane Bis-pyridylalcohols as Linkers for Coordination Polymers: Synthesis, Crystal Structures, and Guest-Framework Dependent Mechanical Properties45Crystalline Inclusion Compounds of a Palladacyclic Tetraol Host Featuring o‐Carborane Units5Enantioselective Synthesis of Chiral-at-Cage o -Carboranes via Pd-Catalyzed Asymmetric B–H Substitution97Asymmetric Hydroboration of Heteroaryl Ketones by Aluminum Catalysis54Tuning the architectures and luminescence properties of Cu( i ) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the ligand backbone22Rational design of carborane-based Cu 2 -paddle wheel coordination polymers for increased hydrolytic stability19Indium( iii )/2-benzoylpyridine chemistry: interesting indium( iii ) bromide-assisted transformations of the ligand3Water-Stable Carborane-Based Eu3+/Tb3+ Metal–Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding58Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)42Catalytic asymmetric synthesis of carboranylated diols bearing two adjacent stereocenters located at the α,β-position of o -carborane cage carbon5Synthesis and structural, magnetic and spectroscopic characterization of iron( iii ) complexes with in situ formed ligands from methyl-2-pyridyl ketone transformations3A Metal‐Organic Framework Incorporating Eight Different Size Rare‐Earth Metal Elements: Toward Multifunctionality À La Carte32Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group4Engineering robust MOFs: Fundamental design paradigms, advanced synthetic strategies, and emerging technological frontiers23

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  1. Chirality Transfer in Magnetic Coordination Complexes Monitored by Vibrational and Electronic Circular Dichroism

    ChemPlusChem · 2014-02-24

    Tao Wu, Xiao‐Peng Zhang, Xiao‐Zeng You, Yizhi Li, Petr Bouř

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  2. Synthesis, Structure, and Catalytic Applications for ortho- and meta-Carboranyl Based NBN Pincer-Pd Complexes

    Inorganic Chemistry · 2014-08-11

    Min Ying Tsang, Clara Viñas, Francesç Teixidor, José Giner Planas, Nerea Conde, Raúl SanMartı́n, María Teresa Herrero, Esther Domı́nguez, Agustı́ Lledós, Pietro Vidossich, Duane Choquesillo‐Lazarte

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  3. Carboranes in the chemist's toolbox

    Dalton Transactions · 2015-01-01

    Russell N. Grimes

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  4. Intramolecular hydrogen bonding stabilizes the nuclearity of complexes. A comparative study based on the H-carborane and Me-carborane framework

    Dalton Transactions · 2015-01-01

    Mònica Fontanet, Montserrat Rodrı́guez, Xavier Fontrodona, Isabel Romero, Clara Viñas, Francesç Teixidor

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  5. Is Molecular Chirality Connected to Supramolecular Chirality? The Particular Case of Chiral 2-Pyridyl Alcohols

    Crystal Growth & Design · 2015-01-13

    Min Ying Tsang, Florencia Di Salvo, Francesç Teixidor, Clara Viñas, José Giner Planas, Duane Choquesillo‐Lazarte, Nicolas Vanthuyne

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  6. Facial Synthesis of o‐Carborane‐Substituted Alkenes and Allenes by a Regioselective Ene Reaction of 1,3‐Dehydro‐o‐carborane

    Chemistry - A European Journal · 2015-06-12

    Da Chuan Zhao, Jiji Zhang, Zuowei Xie

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  7. Dearomative [2 + 2] Cycloaddition and Formal C–H Insertion Reaction of o-Carboryne with Indoles: Synthesis of Carborane-Functionalized Heterocycles

    Journal of the American Chemical Society · 2015-07-10

    Da Chuan Zhao, Jiji Zhang, Zuowei Xie

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  8. Mechano-induced multi-functional optical switches based on chiral cyclometalated platinum(II) complexes

    Inorganica Chimica Acta · 2015-12-15

    Xiaopeng Zhang, Linhua Zhu, Xianghui Wang, Zaifeng Shi, Qiang Lin

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  9. Carboranes in Other Applications

    Elsevier eBooks · 2016-01-01

    Russell N. Grimes

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  10. Icosahedral Carboranes

    Elsevier eBooks · 2016-01-01

    Russell N. Grimes

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  11. Synthesis, structures and properties of ironIII complexes with (o-carboranyl)bis-(2-hydroxymethyl)pyridine: Racemic versus meso

    Inorganica Chimica Acta · 2016-04-30

    Min Ying Tsang, Francesç Teixidor, Clara Viñas, Duane Choquesillo‐Lazarte, Núria Aliaga‐Alcalde, José Giner Planas

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  12. N,O-Type Carborane-Based Materials

    Crystals · 2016-05-04

    José Giner Planas, Francesç Teixidor, Clara Viñas

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  13. Carborane Bis-pyridylalcohols as Linkers for Coordination Polymers: Synthesis, Crystal Structures, and Guest-Framework Dependent Mechanical Properties

    Crystal Growth & Design · 2016-12-24

    Min Ying Tsang, Sabina Rodríguez‐Hermida, Kyriakos C. Stylianou, Fangchang Tan, Divya Negi, Francesç Teixidor, Clara Viñas, Duane Choquesillo‐Lazarte, Cristóbal Verdugo‐Escamilla, Miguel A. Guerrero, Jordi Sort, Judith Juanhuix, Daniel Maspoch, José Giner Planas

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  14. Crystalline Inclusion Compounds of a Palladacyclic Tetraol Host Featuring o‐Carborane Units

    European Journal of Inorganic Chemistry · 2017-07-14

    Min Ying Tsang, Clara Viñas, Francesç Teixidor, Duane Choquesillo‐Lazarte, José Giner Planas

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  15. Enantioselective Synthesis of Chiral-at-Cage o -Carboranes via Pd-Catalyzed Asymmetric B–H Substitution

    Journal of the American Chemical Society · 2018-03-26

    Ruofei Cheng, Bowen Li, Jie Wu, Jie Zhang, Zaozao Qiu, Wenjun Tang, Shu‐Li You, Yong Jin Tang, Zuowei Xie

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  16. Asymmetric Hydroboration of Heteroaryl Ketones by Aluminum Catalysis

    Journal of the American Chemical Society · 2019-11-08

    Yury Lebedev, Iuliia Polishchuk, Bholanath Maity, Miguel Dinis Veloso Guerreiro, Luigi Cavallo, Magnus Rueping

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  17. Tuning the architectures and luminescence properties of Cu( i ) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the ligand backbone

    Journal of Materials Chemistry C · 2021-01-01

    Joan Soldevila-Sanmartín, Eliseo Ruíz, Duane Choquesillo‐Lazarte, Mark E. Light, Clara Viñas, Francesç Teixidor, Rosario Núñez, Josefina Pons, José Giner Planas

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  18. Rational design of carborane-based Cu 2 -paddle wheel coordination polymers for increased hydrolytic stability

    Dalton Transactions · 2021-12-09

    Zhen Li, Duane Choquesillo‐Lazarte, Julio Fraile, Clara Viñas, Francesç Teixidor, José Giner Planas

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  19. Indium( iii )/2-benzoylpyridine chemistry: interesting indium( iii ) bromide-assisted transformations of the ligand

    Dalton Transactions · 2022-01-01

    Christina Stamou, Zoi G. Lada, Christos T. Chasapis, Dionissios A. Papaioannou, Pierre Dechambenoit, Spyros P. Perlepes

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  20. Water-Stable Carborane-Based Eu3+/Tb3+ Metal–Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding

    Chemistry of Materials · 2022-04-29

    Zhen Li, Rosario Núñez, Mark E. Light, Eliseo Ruíz, Francesç Teixidor, Clara Viñas, Daniel Ruiz‐Molina, Claudio Roscini, José Giner Planas

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  21. Effect of Nature of Substituents on Coordination Properties of Mono- and Disubstituted Derivatives of Boron Cluster Anions [BnHn]2– (n = 10, 12) and Carboranes with exo-Polyhedral B–X Bonds (X = N, O, S, Hal)

    Inorganics · 2022-12-02

    E. Yu. Matveev, Varvara Vladimirovna Avdeeva, Konstantin Yu. Zhizhin, Еlena А. Malinina, Nikolay T. Kuznetsov

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  22. Catalytic asymmetric synthesis of carboranylated diols bearing two adjacent stereocenters located at the α,β-position of o -carborane cage carbon

    Dalton Transactions · 2023-01-01

    Hui‐Xin Duan, Haonan Li, Yong Yang, Xiaojun Wu, You‐Qing Wang

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  23. Synthesis and structural, magnetic and spectroscopic characterization of iron( iii ) complexes with in situ formed ligands from methyl-2-pyridyl ketone transformations

    Dalton Transactions · 2023-01-01

    Sofia Tzani, M. Pissas, Vassilis Psycharis, Dimitrios A. Pantazis, Yiannis Sanakis, Catherine P. Raptopoulou

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  24. A Metal‐Organic Framework Incorporating Eight Different Size Rare‐Earth Metal Elements: Toward Multifunctionality À La Carte

    Advanced Functional Materials · 2023-07-11

    Zhen Li, Xiao‐Bao Li, Mark E. Light, Anna Esther Carrillo, Ana B. Arauzo, Manuel Valvidares, Claudio Roscini, Francesç Teixidor, Clara Viñas, Felipe Gándara, Elena Bartolomé, José Giner Planas

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  25. Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group

    International Journal of Molecular Sciences · 2023-10-11

    Dmitriy K. Semyonov, Marina Yu. Stogniy, Sergey A. Anufriev, Sergey V. Timofeev, Kyrill Yu. Suponitsky, Igor B. Sivaev

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  26. Engineering robust MOFs: Fundamental design paradigms, advanced synthetic strategies, and emerging technological frontiers

    eScience Energy · 2025-11-15

    Dian Xu, Guangxun Zhang, Huan Pang

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