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RESEARCH PAPER · TrAC Trends in Analytical Chemistry · 2015

Layered double hydroxides: Emerging sorbent materials for analytical extractions

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Layered double hydroxides: Emerging sorbent materials for analytical extractionsOriginalGraphite pencil electrodes as electrochemical sensors for environmental analysis: a review of features, developments, and applications158Magnetic solid phase extraction of polycyclic aromatic hydrocarbons and chlorophenols based on cyano-ionic liquid functionalized magnetic nanoparticles and their determination by HPLC-DAD42Layered-nanomaterial-amplified chemiluminescence systems and their analytical applications28Graphene/layered double hydroxides nanocomposites: A review of recent progress in synthesis and applications242Selective extraction by dissolvable (nitriloacetic acid-nickel)-layered double hydroxide coupled with reaction with potassium thiocyanate for sensitive detection of iron(III)16In-syringe extraction using dissolvable layered double hydroxide-polymer sponges templated from hierarchically porous coordination polymers30Determination of haloacetic acids in water using layered double hydroxides as a sorbent in dispersive solid‐phase extraction followed by liquid chromatography with tandem mass spectrometry21The alternative use of layered double hydroxides as extraction medium coupled with microcomplexation for determination of phosphate in water samples19Valorisation of post-sorption materials: Opportunities, strategies, and challenges127Combination of dispersive solid phase extraction and dispersive liquid–liquid microextraction for extraction of some aryloxy pesticides prior to their determination by gas chromatography43How Density Functional Theory Surface Energies May Explain the Morphology of Particles, Nanosheets, and Conversion Films Based on Layered Double Hydroxides35A comparative investigation of transgene expression and gene silencing of non-functionalized layered double hydroxides versus amino-acid functionalized hydrotalcites.0New insights into the interstratification phenomenon in layered double hydroxides (LDHs): a comparison of experimental and computational results for ZnAl-LDH containing bis-tetrazole13Opportunities and challenges in the use of layered double hydroxide to produce hybrid polymer composites7Evaluation of layered double hydroxide/graphene hybrid as a sorbent in membrane-protected stir-bar supported micro-solid-phase extraction for determination of organochlorine pesticides in urine samples85Preparation of a polymer monolith modified with delaminated layered double hydroxides for the microextraction of β‐agonists11Porous membrane protected micro-solid-phase extraction: A review of features, advancements and applications137A review on nanomaterial-based electrochemical sensors for H2O2, H2S and NO inside cells or released by cells155The study of C P determination of hydrotalcite intercalated with heavy metal ions7Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation518Bentonite-modified electrochemical sensors: a brief overview of features and applications24Layered double hydroxides based ion exchange extraction for high sensitive analysis of non-steroidal anti-inflammatory drugs36Recent Developments in Solid-phase Microextraction Coatings for Environmental and Biological Analysis40The use of dissolvable layered double hydroxide components in an in situ solid-phase extraction for chromatographic determination of tetracyclines in water and milk samples42Removal of heavy metals and organic pollutants from water using dendritic polymers based adsorbents: A critical review393Applications of biodegradable polymer/layered double hydroxide nanocomposites9Applications of layered double hydroxides based electrochemical sensors for determination of environmental pollutants: A review147Emerging materials for sample preparation48Coupling of two centrifugeless ultrasound-assisted dispersive solid/liquid phase microextractions as a highly selective, clean, and efficient method for determination of ultra-trace amounts of non-steroidal anti-inflammatory drugs in complicated matrices49Nitrate removal from model aqueous solutions and real water by calcined Mg/Al layered double hydroxides41Dendrimers based sorbents: Promising materials for analytical extractions43In situ immobilization of layered double hydroxides as stationary phase for capillary electrochromatography28Applications of Nanomaterials in Miniaturized Extraction Techniques7Magnetic solid phase extraction using Fe 3 O 4 @SiO 2 @C 8 nanoparticles performed in a narrow-bore tube followed by dispersive liquid–liquid microextraction for extraction and preconcentration of nine pesticides21Automated solid‐phase extraction of phenolic acids using layered double hydroxide–alumina–polymer disks19Magnetic nanoparticle based solid-phase extraction of heavy metal ions: A review on recent advances229A hybrid monolithic column based on layered double hydroxide-alginate hydrogel for selective solid phase extraction of lead ions in food and water samples70Fiber‐in‐tube solid‐phase microextraction of caffeine as a molecular tracer in wastewater by electrochemically deposited layered double hydroxide21Layered Double Hydroxides as a Coating for the Determination of Phthalate Esters in Aqueous Solution with Solid-Phase Microextraction Followed by Gas Chromatography22Removal of safranin dye from water using polypyrrole nanofiber/Zn-Fe layered double hydroxide nanocomposite (Ppy NF/Zn-Fe LDH) of enhanced adsorption and photocatalytic properties272In-Syringe Micro Solid-Phase Extraction Method for the Separation and Preconcentration of Parabens in Environmental Water Samples45Use of chicken feet yellow membrane as a biosorbent in miniaturized solid phase extraction for determination of polycyclic aromatic hydrocarbons in several real samples22Hazardous aluminum dross characterization and recycling strategies: A critical review312Evaluation of highly efficient on-line yarn-in-tube solid phase extraction method for ultra-trace determination of chlorophenols in honey samples25An overview of the most common lab-made coating materials in solid phase microextraction137Magnesium-aluminum-layered double hydroxide-graphene oxide composite mixed-matrix membrane for the thin-film microextraction of diclofenac in biological fluids56Removal of hexavalent chromium ions by core-shell sand/Mg-layer double hydroxides (LDHs) in constructed rapid infiltration system28A review on electrochemical biosensing platform based on layered double hydroxides for small molecule biomarkers determination144Removal of cadmium from wastewaters with low-cost adsorbents281Magnetic Fe3O4 based layered double hydroxides (LDHs) nanocomposites (Fe3O4/LDHs): recent review of progress in synthesis, properties and applications102Miniaturized Sample Preparation Methods for Saliva Analysis21Dispersive micro-solid phase extraction415One dimensional hierarchical nanoflakes with nickel-immobilization for high performance catalysis and histidine-rich protein adsorption24ESTUDO SOBRE AS RELAÇÕES ENTRE AS FUNÇÕES PSICOLÓGICAS SUPERIORES E OS PROCESSOS DE ELABORAÇÃO DE CONCEITOS CIENTÍFICOS0Determination of chromium (VI) by dispersive solid-phase extraction using dissolvable Zn-Al layered double hydroxide intercalated with l-Alanine as adsorbent51Recent strategies to enhance the performance of polymer monoliths for analytical separations26Dispersive Solid Phase Extraction Using Magnetic NanoparticlesPerformed in a Narrow-Bored Tube for Extraction of Atorvastatin,Losartan, and Valsartan in Plasma15A high-sensitivity thermal analysis immunochromatographic sensor based on au nanoparticle-enhanced two-dimensional black phosphorus photothermal-sensing materials94A fluorometric displacement assay for adenosine triphosphate using layered cobalt(II) double hydroxide nanosheets7Nickel-iron layered double hydroxide nanostructures for micro solid phase extraction of nonsteroidal anti-inflammatory drugs, followed by quantitation by HPLC-UV33Dissolvable layered double hydroxide as a sorbent in dispersive micro‐solid phase extraction for the determination of acidic quinolones in honey by HPLC23Recent Advances and Trends in Applications of Solid-Phase Extraction Techniques in Food and Environmental Analysis146A review on the recent advances, challenges and future aspect of layered double hydroxides (LDH) – Containing hybrids as promising adsorbents for dyes removal300A simple capture-release strategy based on an instantly formed mixed metal hydroxide sorbent for determination of salicylic acid in cosmetics16Micro solid-phase extraction (pipette tip and spin column) and thin film solid-phase microextraction: Miniaturized concepts for chromatographic analysis193Solid Phase Extraction: State of the Art and Future Perspectives0Surfactant-modified Zn/Al-layered double hydroxides for efficient extraction of alkyl phenols from aqueous samples24Ce-Doped CuMgAl Oxide as a Redox Couple Mediated Catalyst for Visible Light Aided Photooxidation of Organic Pollutants14Zn-Al layered double hydroxides intercalated with surfactant: Synthesis and applications for efficient removal of organic dyes87In-tube solid-phase microextraction20A new strategy for enhanced fabrication of flake-like zinc–aluminum layered double hydroxide on nickel–titanium alloy fiber for highly efficient solid-phase microextraction of ultraviolet filters9Woven cotton yarn-graphene oxide-layered double hydroxide composite as a sorbent for thin film microextraction of nonsteroidal anti-inflammatory drugs followed by quantitation through high performance liquid chromatography48Efficiency and mechanisms of cadmium removal via core-shell zeolite/Zn-layer double hydroxides15Development of dispersive solid phase extraction based on dissolvable Fe3O4-layered double hydroxide for high-performance liquid chromatographic determination of phenoxy acid herbicides in water samples32Electrospun NiFe layered double hydroxide/Nylon 6 composite nanofibers as a sorbent for micro solid phase extraction by packed sorbent of non-steroidal anti-inflammatory drugs in human blood29Layered rare-earth hydroxides: a new family of anion-exchangeable layered inorganic materials57Magnesium/aluminum-layered double hydroxide modified with hydrogen peroxide as a novel fiber coating for solid-phase microextraction of phthalate esters in aqueous samples27Materials for Solid-Phase Extraction of Organic Compounds72Removal of selenium from caustic solution by adsorption with Ca Al layered double hydroxides47Mg-Fe layered double hydroxide with chloride intercalated: synthesis, characterization and application for efficient nitrate removal58Recent advances in the application of layered double hydroxides in analytical chemistry: A review163Oleate Epoxidation in a Confined Matrix of Hydrotalcite3Removal and Extraction of Carboxylic Acids and Non-ionic Compounds with Simple Hydroxides and Layered Double Hydroxides7Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides)3A dispersive solid phase extraction-based method for chromium( vi ) analysis using a Zn–Al layered double hydroxide intercalated with l -aspartic acid as a dissolvable adsorbent16Advances in layered double hydroxide-based ternary nanocomposites for photocatalysis of contaminants in water35CO 2 -effervescence assisted dispersive micro solid-phase extraction based on a magnetic layered double hydroxide modified with polyaniline and a surfactant for efficient pre-concentration of heavy metals in cosmetic samples21Dissolvable Mg/Al layered double hydroxides and surfactant as an extractant for trace analysis of benzoylurea insecticides by high performance liquid chromatography18In situ growth of zeolitic imidazolate framework-8 on a GO–PVDF membrane as a sorbent for thin-film microextraction of caffeine followed by quantitation through high-performance liquid chromatography12Nanoparticles: Synthesis, characteristics, and applications in analytical and other sciences285Determination of Trace Level Perchlorate in Seawater Using Dispersive Solid-Phase Extraction and Co-precipitation Extraction with Layered Double Hydroxides Followed by Ion Chromatography Analysis12Application of Mg–Al and Zn–Al layered double hydroxides modified with sodium dodecyl benzene sulfonate as a solid sorbent for removal of diazinon from water samples16Comparison of Remazol Brilliant Blue Reactive Adsorption on Pristine and Calcined ZnAl, MgAl, ZnMgAl Layered Double Hydroxides34Overview of mixed-mode ion-exchange materials in the extraction of organic compounds49Improved performance of 3D hierarchical NiAl-LDHs micro-flowers via a surface anchored ZIF-8 for rapid multiple-pollutants simultaneous removal and residues monitoring54Surface area expansion by flower-like nanoscale layered double hydroxides for high efficient stir bar sorptive extraction24Effect of concentration in the equilibrium and kinetics of adsorption of acetylsalicylic acid on ZnAl layered double hydroxide37Catalytic activity of hierarchical structure based on Ni-Al layered double hydroxide1Solid phase adsorption of emodin on hydrotalcites and inorganic oxides: A preliminary study11Sonophotocatalytic activities of FeCuMg and CrCuMg LDHs: Influencing factors, antibacterial effects, and intermediate determination110Use of Nanomaterial-Based (Micro)Extraction Techniques for the Determination of Cosmetic-Related Compounds13Graphene oxide/ layered double hydroxides@ sulfonated polyaniline: A sorbent for ultrasonic assisted dispersive solid phase extraction of phthalates in distilled herbal beverages45Layered double hydroxide/poly(vinylpyrrolidone) coated solid phase microextraction Arrow for the determination of volatile organic compounds in water7Electrochemically synthesized NiFe layered double hydroxide modified Cu(OH)2 needle-shaped nanoarrays: A novel sorbent for thin-film solid phase microextraction of antifungal drugs40In situ growth of zeolitic imidazolate framework-8 on woven cotton yarn for the thin film microextraction of quercetin in human plasma and food samples36A comparative evaluation of LHT-9 layered titanates synthesized by reflux and microwave routes for waste treatment applications2In-tube stir bar sorptive extraction based on 3-aminopropyl triethoxysilane surface-modified Ce-doped ZnAl layered double hydroxide thin film for determination of nonsteroidal anti-inflammatory drugs in saliva samples19Starch-Mg/Al layered double hydroxide composites as an efficient solid phase extraction sorbent for non-steroidal anti-inflammatory drugs as environmental pollutants77Pipette-tip SPE based on Graphene/ZnCr LDH for Pb(II) analysis in hair samples followed by GFAAS40Chitosan-Ni/Fe layered double hydroxide composites as an efficient solid phase extraction sorbent for HPLC-PDA monitoring of parabens in personal care products48Preparation and characterization of a recyclable high-branched/genera- tion dendrimer nano-polymer based on the enhanced magnetic core for naphthalene sorption from aqueous solutions3A Novel Approach to Recycle Waste Serpentine Tailing for Mg/Al Layered Double Hydroxide Used as Adsorption Material6Layered double hydroxides/biochar composites as adsorbents for water remediation applications: recent trends and perspectives146Effect of LDHs and Other Clays on Polymer Composite in Adsorptive Removal of Contaminants: A Review94Dispersive micro-solid phase extraction combined with switchable hydrophilicity solvent-based homogeneous liquid-liquid microextraction for enrichment of non‐steroidal anti‐inflammatory drugs in environmental water samples29Facile Fabrication of ZnMgAl/LDH/Algae Composites as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and Equilibrium Studies23Innovative extraction materials for fiber-in-tube solid phase microextraction: A review50Solid phase microextraction of organochlorine pesticides in water using MWCNTs-doped polypyrrole coated on steel fiber7Kinetics and Thermodynamics Studies for Cadmium (II) Adsorption onto Functionalized Chitosan with Hexa-Decyl-Trimethyl-Ammonium Chloride6Selenium oxyanion exchange with Mg(II)-Fe(III) and Fe(II)-Fe(III) layered double hydroxides12Application of magnetic nanomaterials in environmental monitoring10Application of magnetic nanomaterials in food analysis5Co-precipitation based on layered double hydroxides and anionic surfactants for preconcentration of six benzoylurea insecticides in soft drinks before simultaneous analysis by high-performance liquid chromatography8Determination of seven tetracyclines in milk by dissolvable layered double hydroxide-based solid-phase extraction coupled with high-performance liquid chromatography28Gallic acid removal using fresh and calcined Ni-Al layered double hydroxides: Kinetics, equilibrium and response surface methodology (RSM) optimisation12Applications of porous frameworks in solid‐phase microextraction28One-pot synthesis of Mg Al layered double hydroxide (LDH) using MgO and metakaolin (MK) as precursors49Application of Zn–Fe layered double hydroxide and its composites with biochar and carbon nanotubes to the adsorption of lead in a batch system: kinetics and isotherms13Field sample preparation of trace inorganic anions in environmental waters with in-tip microextraction device based on anion-exchange monolithic adsorbent followed by ion chromatography quantification28Ferrofluids based analytical extractions and evaluation of their greenness34Magnetic layered double hydroxide/zeolitic imidazolate framework-8 nanocomposite as a novel adsorbent for enrichment of four endocrine disrupting compounds in milk samples37A review of CO2 adsorbents performance for different carbon capture technology processes conditions176In situ assembling of layered double hydroxide to magadiite layered silicate with enhanced photocatalytic and recycling performance21Layered double hydroxide photocatalysts for solar fuel production79Layered double hydroxide-modified membranes for water treatment: Recent advances and prospects124Preparation of 3D flower-like double oxide hydrotalcite composite using pollen as a biotemplate and their effective adsorption for quinolone antibiotics14Switchable hydrophilicity solvent based homogeneous liquid-liquid microextraction for enrichment of pyrethroid insecticides in wolfberry18Recent Advances in Layered Double Hydroxide-Based Electrochemical and Optical Sensors70Nanotechnology Strategies for Plant Genetic Engineering158Efficient Ion Separation from Environmental and Biological Samples Using a Novel Sorbent Based on Ni-Substituted ZIF-67: Optimization, Equilibrium, Kinetic, and Thermodynamic Study7Nanomaterials: types, properties, recent advances, and toxicity concerns176In-Situ Formation of Modified Nickel–Zinc-Layered Double Hydroxide Followed by HPLC Determination of Neonicotinoid Insecticide Residues8A review of the synthesis methods, properties, and applications of layered double hydroxides/carbon nanocomposites59Controllable Preparation of Highly Dispersed Vertical Eg/Ldhs Composites and Fluorinion Adsorption Properties and Mechanism0Fundamentals of layered double hydroxides and environmental applications4Kinetics, isothermal and mechanistic insight into the adsorption of eosin yellow and malachite green from water via tri-metallic layered double hydroxide nanosheets69Progress in Pre-Treatment and Extraction of Pollutants by Layered Double Hydroxide0Ethylenediaminetetraacetate functionalized MgFe layered double hydroxide/biochar composites for highly efficient adsorptive removal of lead ions from aqueous solutions16Current trends in the development of polymer‐based monolithic stationary phases13Increasing the hydrophyte removal rate of dissolved inorganic phosphorus using a novel Fe-Mg-loaded activated carbon hydroponic substrate with adsorption-release dual functions18

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