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RESEARCH PAPER · RSC Advances · 2013

Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formate

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Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formateOriginalSynthesis and order–disorder transition in a novel metal formate framework of [(CH 3 ) 2 NH 2 ]Na 0.5 Fe 0.5 (HCOO) 3 ]82Mechanical Tunability via Hydrogen Bonding in Metal–Organic Frameworks with the Perovskite Architecture187[(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties17Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework195High-temperature ferroelectricity and strong magnetoelectric effects in a hybrid organic-inorganic perovskite framework82A prominent dielectric material with extremely high-temperature and reversible phase transition in the high thermally stable perovskite-like architecture26An organic approach for nanostructured multiferroics43Effect of aliovalent doping on the properties of perovskite-like multiferroic formates76Structure and magnetic properties of the AB(HCO 2 ) 3 (A = Rb + or Cs + , B = Mn 2+ , Co 2+ or Ni 2+ ) frameworks: probing the effect of size on the phase evolution of the ternary formates30Room-Temperature Polar Order in [NH4][Cd(HCOO)3] - A Hybrid Inorganic–Organic Compound with a Unique Perovskite Architecture88An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)114An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)22Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH3)2NH2][CrIIIMII(HCOO)6] (MII=Zn, Ni, Cu) and [(CH3)2NH2][AlIIIZnII(HCOO)6]:Cr3+21Raman scattering studies of pressure-induced phase transitions in perovskite formates [(CH3)2NH2][Mg(HCOO)3] and [(CH3)2NH2][Cd(HCOO)3]41Role of Temperature and Pressure on the Multisensitive Multiferroic Dicyanamide Framework [TPrA][Mn(dca)3] with Perovskite-like Structure75Experimental and theoretical studies of structural phase transition in a novel polar perovskite-like [C 2 H 5 NH 3 ][Na 0.5 Fe 0.5 (HCOO) 3 ] formate109Magnetic Ordering-Induced Multiferroic Behavior in [CH3NH3][Co(HCOO)3] Metal–Organic Framework195Multiple phase and dielectric transitions on a novel multi-sensitive [TPrA][M(dca) 3 ] (M: Fe 2+ , Co 2+ and Ni 2+ ) hybrid inorganic–organic perovskite family66Phase transitions and chromium( iii ) luminescence in perovskite-type [C 2 H 5 NH 3 ][Na 0.5 Cr x Al 0.5−x (HCOO) 3 ] (x = 0, 0.025, 0.5), correlated with structural, dielectric and phonon properties39Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges159Structural, thermal, dielectric and phonon properties of perovskite-like imidazolium magnesium formate47Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH 3 NH 2 ] 1−x [NH 3 OH] x Zn(HCOO) 339Dielectric properties induced by the framework in the hybrid organic–inorganic compounds M(dca)2pyz M = Fe, Co and Zn9Polarized IR and Raman spectra of the novel metal-organic framework [CH3CH2NH3][Cd(HCOO)3]20Switchable electric polarization and ferroelectric domains in a metal-organic-framework126Quantifying Thermal Disorder in Metal–Organic Frameworks: Lattice Dynamics and Molecular Dynamics Simulations of Hybrid Formate Perovskites16Electron paramagnetic resonance and electric characterization of a [CH 3 NH 2 NH 2 ][Zn(HCOO) 3 ] perovskite metal formate framework44Synthesis and temperature-dependent studies of a perovskite-like manganese formate framework templated with protonated acetamidine30The effect of K + cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K 0.5 Cr 0.5 (HCOO) 3 ], where cat is protonated dimethylamine or ethylamine31Chemically diverse and multifunctional hybrid organic–inorganic perovskites1273Vibrational and magnetic properties of [C 2 H 5 NH 3 ][Fe III M II (HCOO) 6 ] (M = Mn, Ni) and [C 2 H 5 NH 3 ][Cr III Mn II (HCOO) 6 ] framework compounds8Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures229Inorganic–Organic Hybrid 3D Redox Nanoarchitecture for the Electrocatalytic Sensing of Thiols9Synthesis, magnetic and vibrational properties of two novel mixed-valence iron(II)-iron(III) formate frameworks13Excited charge-transfer organics with multiferroicity4Heterometallic perovskite-type metal–organic framework with an ammonium cation: structure, phonons, and optical response of [NH 4 ]Na 0.5 Cr x Al 0.5−x (HCOO) 3 ( x = 0, 0.025 and 0.5)21Insight into understanding structural relaxation dynamics of [NH2NH3][Mn(HCOO)3] metal-organic formate7Magnetic structural unit with convex geometry: A building block hosting an exchange-striction-driven magnetoelectric coupling14Novel bimetallic MOF phosphors with an imidazolium cation: structure, phonons, high- pressure phase transitions and optical response24Pressure-enhanced ferroelectric polarisation in a polar perovskite-like [C 2 H 5 NH 3 ]Na 0.5 Cr 0.5 (HCOO) 3 metal–organic framework17The structural, phonon and optical properties of [CH 3 NH 3 ]M 0.5 Cr x Al 0.5−x (HCOO) 3 (M = Na, K; x = 0, 0.025, 0.5) metal–organic framework perovskites for luminescence thermometry13Ferroic multipolar order and disorder in cyanoelpasolite molecular perovskites16Ordered B-Site Vacancies in an ABX 3 Formate Perovskite29Multiferroic and thermal expansion properties of metal-organic frameworks36Hybrid Formate Perovskites0Magnetization Studied as a Function of Temperature and Magnetic Field for Ferromagnetic Transition in DMNaFe4Magneto-elastic coupling in multiferroic metal-organic framework [(CH3)2NH2]Co(HCOO)34Inorganic–Organic Hybrid Molecular Materials: From Multiferroic to Magnetoelectric83Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates3Magnetic, thermal and ferroelectric properties of MOFs (MHyM, M = Fe, Mn) close to phase transitions6A Single Crystal Hybrid Ligand Framework of Copper(II) with Stable Intrinsic Blue-Light Luminescence in Aqueous Solution14Molecular spectroscopy of hybrid organic–inorganic perovskites and related compounds68Dicyanamide-perovskites at the edge of dense hybrid organic–inorganic materials21Temperature and frequency dependence of dielectric relaxation in a metal–organic perovskite-like framework2A highly polar hybrid perovskite of [FCH2CH2NH3][Mn(HCOO)3]1Unprecedented Ferroelectricity and Ferromagnetism in a Cr 2+ ‐Based Two‐Dimensional Hybrid Perovskite9Unprecedented Ferroelectricity and Ferromagnetism in a Cr 2+ ‐Based Two‐Dimensional Hybrid Perovskite83Atypical Magnetic Behavior in the Incommensurate (CH3NH3)[Ni(HCOO)3] Hybrid Perovskite4Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks13A novel layered Cu-based perovskite metal–organic framework with 1,2-diaminoethane cations: synthesis, crystal structure, and thermal and magnetic properties2Electric-Field Modulation of Spin Resonance in a Perovskite-Like Multiferroic Fe–Metal–Organic Framework0

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  1. Synthesis and order–disorder transition in a novel metal formate framework of [(CH 3 ) 2 NH 2 ]Na 0.5 Fe 0.5 (HCOO) 3 ]

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  2. Mechanical Tunability via Hydrogen Bonding in Metal–Organic Frameworks with the Perovskite Architecture

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    Wei Li, A. Thirumurugan, Phillip T. Barton, Zheshuai Lin, Sebastian Henke, Hamish H.‐M. Yeung, Michael T. Wharmby, Erica G. Bithell, Christopher J. Howard, Anthony Kevin Cheetham

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  3. [(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties

    Inorganic Chemistry · 2014-07-29

    Qianqian Zhu, Ran Shang, Sa Chen, Chunli Liu, Zhe‐Ming Wang, Song Wei Gao

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  4. Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework

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    Ying Tian, Alessandro Stroppa, Yisheng Chai, Liqin Yan, Shouguo Wang, Paolo Barone, Silvia Picozzi, Young Sun

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  5. High-temperature ferroelectricity and strong magnetoelectric effects in a hybrid organic-inorganic perovskite framework

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    Ying Tian, Alessandro Stroppa, Yisheng Chai, Paolo Barone, Juan Manuel Perez-Mato, Silvia Picozzi, Young Sun

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  6. A prominent dielectric material with extremely high-temperature and reversible phase transition in the high thermally stable perovskite-like architecture

    Journal of Materials Chemistry C · 2015-01-01

    Fangfang Wang, Cheng Chen, Yi Zhang, Heng‐Yun Ye, Qiong Ye, Da‐Wei Fu

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  7. An organic approach for nanostructured multiferroics

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  8. Effect of aliovalent doping on the properties of perovskite-like multiferroic formates

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  9. Structure and magnetic properties of the AB(HCO 2 ) 3 (A = Rb + or Cs + , B = Mn 2+ , Co 2+ or Ni 2+ ) frameworks: probing the effect of size on the phase evolution of the ternary formates

    CrystEngComm · 2015-01-01

    Sally M. Bovill, Paul J. Saines

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  10. Room-Temperature Polar Order in [NH4][Cd(HCOO)3] - A Hybrid Inorganic–Organic Compound with a Unique Perovskite Architecture

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    L. C. Gómez-Aguirre, Breogán Pato‐Doldán, Alessandro Stroppa, Susana Yáñez‐Vilar, Lkhamsuren Bayarjargal, B. Winkler, Socorro Castro‐García, Jorge Mira, Manuel Sánchez‐Andújar, M. A. Señarı́s-Rodrı́guez

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  11. An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)

    Angewandte Chemie International Edition · 2015-08-04

    Sa Chen, Ran Shang, Bing‐Wu Wang, Zhe‐Ming Wang, Song Wei Gao

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  12. An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)

    Angewandte Chemie · 2015-08-04

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  13. Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH3)2NH2][CrIIIMII(HCOO)6] (MII=Zn, Ni, Cu) and [(CH3)2NH2][AlIIIZnII(HCOO)6]:Cr3+

    Journal of Solid State Chemistry · 2015-11-18

    Mirosław Mączka, A. Pietraszko, Adam Pikul, K. Hermanowicz

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  14. Raman scattering studies of pressure-induced phase transitions in perovskite formates [(CH3)2NH2][Mg(HCOO)3] and [(CH3)2NH2][Cd(HCOO)3]

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2015-12-02

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  15. Role of Temperature and Pressure on the Multisensitive Multiferroic Dicyanamide Framework [TPrA][Mn(dca)3] with Perovskite-like Structure

    Inorganic Chemistry · 2015-12-10

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  16. Experimental and theoretical studies of structural phase transition in a novel polar perovskite-like [C 2 H 5 NH 3 ][Na 0.5 Fe 0.5 (HCOO) 3 ] formate

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  17. Magnetic Ordering-Induced Multiferroic Behavior in [CH3NH3][Co(HCOO)3] Metal–Organic Framework

    Journal of the American Chemical Society · 2015-12-30

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  18. Multiple phase and dielectric transitions on a novel multi-sensitive [TPrA][M(dca) 3 ] (M: Fe 2+ , Co 2+ and Ni 2+ ) hybrid inorganic–organic perovskite family

    Journal of Materials Chemistry C · 2016-01-01

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  19. Phase transitions and chromium( iii ) luminescence in perovskite-type [C 2 H 5 NH 3 ][Na 0.5 Cr x Al 0.5−x (HCOO) 3 ] (x = 0, 0.025, 0.5), correlated with structural, dielectric and phonon properties

    Physical Chemistry Chemical Physics · 2016-01-01

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  20. Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges

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  21. Structural, thermal, dielectric and phonon properties of perovskite-like imidazolium magnesium formate

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  22. Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH 3 NH 2 ] 1−x [NH 3 OH] x Zn(HCOO) 3

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  23. Dielectric properties induced by the framework in the hybrid organic–inorganic compounds M(dca)2pyz M = Fe, Co and Zn

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  24. Polarized IR and Raman spectra of the novel metal-organic framework [CH3CH2NH3][Cd(HCOO)3]

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  25. Switchable electric polarization and ferroelectric domains in a metal-organic-framework

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  26. Quantifying Thermal Disorder in Metal–Organic Frameworks: Lattice Dynamics and Molecular Dynamics Simulations of Hybrid Formate Perovskites

    The Journal of Physical Chemistry C · 2016-12-12

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  27. Electron paramagnetic resonance and electric characterization of a [CH 3 NH 2 NH 2 ][Zn(HCOO) 3 ] perovskite metal formate framework

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  28. Synthesis and temperature-dependent studies of a perovskite-like manganese formate framework templated with protonated acetamidine

    Dalton Transactions · 2017-01-01

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  29. The effect of K + cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K 0.5 Cr 0.5 (HCOO) 3 ], where cat is protonated dimethylamine or ethylamine

    Physical Chemistry Chemical Physics · 2017-01-01

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  30. Chemically diverse and multifunctional hybrid organic–inorganic perovskites

    Nature Reviews Materials · 2017-02-07

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  31. Vibrational and magnetic properties of [C 2 H 5 NH 3 ][Fe III M II (HCOO) 6 ] (M = Mn, Ni) and [C 2 H 5 NH 3 ][Cr III Mn II (HCOO) 6 ] framework compounds

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  32. Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures

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  33. Inorganic–Organic Hybrid 3D Redox Nanoarchitecture for the Electrocatalytic Sensing of Thiols

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  34. Synthesis, magnetic and vibrational properties of two novel mixed-valence iron(II)-iron(III) formate frameworks

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  35. Excited charge-transfer organics with multiferroicity

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  36. Heterometallic perovskite-type metal–organic framework with an ammonium cation: structure, phonons, and optical response of [NH 4 ]Na 0.5 Cr x Al 0.5−x (HCOO) 3 ( x = 0, 0.025 and 0.5)

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  37. Insight into understanding structural relaxation dynamics of [NH2NH3][Mn(HCOO)3] metal-organic formate

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  38. Magnetic structural unit with convex geometry: A building block hosting an exchange-striction-driven magnetoelectric coupling

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  39. Novel bimetallic MOF phosphors with an imidazolium cation: structure, phonons, high- pressure phase transitions and optical response

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  40. Pressure-enhanced ferroelectric polarisation in a polar perovskite-like [C 2 H 5 NH 3 ]Na 0.5 Cr 0.5 (HCOO) 3 metal–organic framework

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  41. The structural, phonon and optical properties of [CH 3 NH 3 ]M 0.5 Cr x Al 0.5−x (HCOO) 3 (M = Na, K; x = 0, 0.025, 0.5) metal–organic framework perovskites for luminescence thermometry

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  42. Ferroic multipolar order and disorder in cyanoelpasolite molecular perovskites

    Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences · 2019-05-27

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  43. Ordered B-Site Vacancies in an ABX 3 Formate Perovskite

    Journal of the American Chemical Society · 2019-10-30

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  44. Multiferroic and thermal expansion properties of metal-organic frameworks

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  45. Hybrid Formate Perovskites

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  46. Magnetization Studied as a Function of Temperature and Magnetic Field for Ferromagnetic Transition in DMNaFe

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  47. Magneto-elastic coupling in multiferroic metal-organic framework [(CH3)2NH2]Co(HCOO)3

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  48. Inorganic–Organic Hybrid Molecular Materials: From Multiferroic to Magnetoelectric

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  49. Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates

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    L. C. Gómez-Aguirre, Jorge Otero‐Canabal, Manuel Sánchez‐Andújar, M. A. Señarı́s-Rodrı́guez, Socorro Castro‐García, Breogán Pato‐Doldán

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  50. Magnetic, thermal and ferroelectric properties of MOFs (MHyM, M = Fe, Mn) close to phase transitions

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    H. Yurtseven, Emel Kılıt Dogan

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