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RESEARCH PAPER · CrystEngComm · 2012

Amine-templated polymeric Mg formates: crystalline scaffolds exhibiting extensive hydrogen bonding

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Amine-templated polymeric Mg formates: crystalline scaffolds exhibiting extensive hydrogen bondingOriginalEvolved Gas Analysis by Mass Spectrometry69Amine-Templated Polymeric Lanthanide Formates: Synthesis, Characterization, and Applications in Luminescence and Magnetism77A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties86Phase Transitions, Prominent Dielectric Anomalies, and Negative Thermal Expansion in Three High Thermally Stable Ammonium Magnesium–Formate Frameworks143[NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering187Synthesis and order–disorder transition in a novel metal formate framework of [(CH 3 ) 2 NH 2 ]Na 0.5 Fe 0.5 (HCOO) 3 ]82Evolved Gas Analysis by Mass Spectrometry55Perovskite Metal Formate Framework of [NH2-CH+-NH2]Mn(HCOO)3]: Phase Transition, Magnetic, Dielectric, and Phonon Properties164Synthesis, crystal structure, magnetic and vibrational properties of formamidine-templated Co and Fe formates40Vibrational properties and DFT calculations of formamidine-templated Co and Fe formates42Raman and IR Studies of Pressure- and Temperature-Induced Phase Transitions in [(CH2)3NH2][Zn(HCOO)3]48Metal–Organic Frameworks: Functional Magnetic Materials with Formate4Effect of aliovalent doping on the properties of perovskite-like multiferroic formates76Magnesium-based systems for carbon dioxide capture, storage and recycling: from leaves to synthetic nanostructured materials70Synthesis and characterization of [(CH 3 ) 2 NH 2 ][Na 0.5 Cr 0.5 (HCOO) 3 ]: a rare example of luminescent metal–organic frameworks based on Cr( iii ) ions69Temperature-dependent studies of [(CH 3 ) 2 NH 2 ][Fe III M II (HCOO) 6 ] frameworks (M II = Fe and Mg): structural, magnetic, dielectric and phonon properties58Experimental and theoretical studies of structural phase transition in a novel polar perovskite-like [C 2 H 5 NH 3 ][Na 0.5 Fe 0.5 (HCOO) 3 ] formate109Synthesis, structure and optical properties of two novel luminescent polar dysprosium metal–organic frameworks: [(CH 3 ) 2 NH 2 ][Dy(HCOO) 4 ] and [N 2 H 5 ][Dy(HCOO) 4 ]18Phase transitions and chromium( iii ) luminescence in perovskite-type [C 2 H 5 NH 3 ][Na 0.5 Cr x Al 0.5−x (HCOO) 3 ] (x = 0, 0.025, 0.5), correlated with structural, dielectric and phonon properties39Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges159Polarized IR and Raman spectra of the novel metal-organic framework [CH3CH2NH3][Cd(HCOO)3]20Vibrational studies of non-centrosymmetric [N 2 H 5 ][M(HCOO) 4 ] (M = Dy, Er and Y) supported by DFT calculations and analysis of IR reflectance spectra using three different methods4Solid-state phase transition induced by ordering of flexible chain alkylamine in N-ethyl-n-butylammonium 3, 5-dinitrobenzoate monohydrate1Synthesis and temperature-dependent studies of a perovskite-like manganese formate framework templated with protonated acetamidine30The effect of K + cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K 0.5 Cr 0.5 (HCOO) 3 ], where cat is protonated dimethylamine or ethylamine31Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective28A multiferroic material [NH2-CH+-NH2]Co(HCOO)3 of metal-organic frameworks with weak ferromagnetism and dielectric relaxation5Synthesis, Structure and Properties of Formamidine‐templated Metal Formate Crystals4First Full Structural Characterization of Chloro Formamidinium Salts2The role of the counter-ion in metal-organic frameworks’ chemistry and applications204Temperature- and pressure-dependent studies of a highly flexible and compressible perovskite-like cadmium dicyanamide framework templated with protonated tetrapropylamine37Ultrahigh phase transition temperature in a metal–halide perovskite-type material containing unprecedented hydrogen bonding interactions18Hybrid Formate Perovskites0Phase Transition and Negative Thermal Expansion in Guanidinium Magnesium-Hypophosphite Hybrid Perovskite25Enhancing the chemical flexibility of hybrid perovskites by introducing divalent ligands5From ambient- to high-pressure dielectric response of perovskite formamidinium manganese formate7Structures and elastic properties of 1,2,4-triazolium magnesium hypophosphite hybrid perovskite8Metal–Organic Frameworks in Italy: From synthesis and advanced characterization to theoretical modeling and applications16Hydrogenation via a low energy mechanochemical approach: the MgB 2 case11Observation of an Intermediate to H 2 Binding in a Metal–Organic Framework72Molecular spectroscopy of hybrid organic–inorganic perovskites and related compounds68Dicyanamide-perovskites at the edge of dense hybrid organic–inorganic materials21Mixed Metal‐Organic Frameworks as Efficient Semi‐Solid Electrolytes for Magnesium‐Ion Batteries15Solvent-derived defects suppress adsorption in MOF-74154Structure, Luminescence and Temperature Detection Capability of [C(NH2)3]M(HCOO)3 (M = Mg2+, Mn2+, Zn2+) Hybrid Organic–Inorganic Formate Perovskites Containing Cr3+ Ions6Recent Progress of Multiferroicity and Magnetoelectric Effects in ABX3‐Type Perovskite Metal–Organic Frameworks22Effect of Guest Solvents on the Ionic Conductivity and Electrochemical Performance of Metal‐Organic Framework‐Based Magnesium Semi‐Solid Electrolytes7White Light Emission and Energy Transfer in Mixed‐Metal Europium/Terbium/Thulium Formate Metal–Organic Frameworks: Effect of Lanthanum Dilution0

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  2. Amine-Templated Polymeric Lanthanide Formates: Synthesis, Characterization, and Applications in Luminescence and Magnetism

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  3. A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties

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  4. Phase Transitions, Prominent Dielectric Anomalies, and Negative Thermal Expansion in Three High Thermally Stable Ammonium Magnesium–Formate Frameworks

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  5. [NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering

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  6. Synthesis and order–disorder transition in a novel metal formate framework of [(CH 3 ) 2 NH 2 ]Na 0.5 Fe 0.5 (HCOO) 3 ]

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  7. Evolved Gas Analysis by Mass Spectrometry

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  8. Perovskite Metal Formate Framework of [NH2-CH+-NH2]Mn(HCOO)3]: Phase Transition, Magnetic, Dielectric, and Phonon Properties

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  9. Synthesis, crystal structure, magnetic and vibrational properties of formamidine-templated Co and Fe formates

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  10. Vibrational properties and DFT calculations of formamidine-templated Co and Fe formates

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  11. Raman and IR Studies of Pressure- and Temperature-Induced Phase Transitions in [(CH2)3NH2][Zn(HCOO)3]

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  12. Metal–Organic Frameworks: Functional Magnetic Materials with Formate

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  13. Effect of aliovalent doping on the properties of perovskite-like multiferroic formates

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  14. Magnesium-based systems for carbon dioxide capture, storage and recycling: from leaves to synthetic nanostructured materials

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  15. Synthesis and characterization of [(CH 3 ) 2 NH 2 ][Na 0.5 Cr 0.5 (HCOO) 3 ]: a rare example of luminescent metal–organic frameworks based on Cr( iii ) ions

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  16. Temperature-dependent studies of [(CH 3 ) 2 NH 2 ][Fe III M II (HCOO) 6 ] frameworks (M II = Fe and Mg): structural, magnetic, dielectric and phonon properties

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  17. Experimental and theoretical studies of structural phase transition in a novel polar perovskite-like [C 2 H 5 NH 3 ][Na 0.5 Fe 0.5 (HCOO) 3 ] formate

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  18. Synthesis, structure and optical properties of two novel luminescent polar dysprosium metal–organic frameworks: [(CH 3 ) 2 NH 2 ][Dy(HCOO) 4 ] and [N 2 H 5 ][Dy(HCOO) 4 ]

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  19. Phase transitions and chromium( iii ) luminescence in perovskite-type [C 2 H 5 NH 3 ][Na 0.5 Cr x Al 0.5−x (HCOO) 3 ] (x = 0, 0.025, 0.5), correlated with structural, dielectric and phonon properties

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  20. Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges

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  21. Polarized IR and Raman spectra of the novel metal-organic framework [CH3CH2NH3][Cd(HCOO)3]

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  23. Solid-state phase transition induced by ordering of flexible chain alkylamine in N-ethyl-n-butylammonium 3, 5-dinitrobenzoate monohydrate

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  25. The effect of K + cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K 0.5 Cr 0.5 (HCOO) 3 ], where cat is protonated dimethylamine or ethylamine

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  26. Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective

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  28. Synthesis, Structure and Properties of Formamidine‐templated Metal Formate Crystals

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  29. First Full Structural Characterization of Chloro Formamidinium Salts

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  30. The role of the counter-ion in metal-organic frameworks’ chemistry and applications

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